CN115211439A - Environment-friendly pesticide containing humic acid and preparation method thereof - Google Patents
Environment-friendly pesticide containing humic acid and preparation method thereof Download PDFInfo
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- CN115211439A CN115211439A CN202210706376.9A CN202210706376A CN115211439A CN 115211439 A CN115211439 A CN 115211439A CN 202210706376 A CN202210706376 A CN 202210706376A CN 115211439 A CN115211439 A CN 115211439A
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- humic acid
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- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 239000004021 humic acid Substances 0.000 title claims abstract description 66
- 239000000575 pesticide Substances 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 230000000694 effects Effects 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims description 29
- 239000000243 solution Substances 0.000 claims description 25
- 238000002156 mixing Methods 0.000 claims description 22
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 16
- 239000011707 mineral Substances 0.000 claims description 16
- 239000011259 mixed solution Substances 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 239000003337 fertilizer Substances 0.000 claims description 13
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 claims description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 12
- 230000003213 activating effect Effects 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 12
- 229960002303 citric acid monohydrate Drugs 0.000 claims description 12
- 238000007598 dipping method Methods 0.000 claims description 10
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 claims description 8
- 240000001844 Capsicum baccatum Species 0.000 claims description 8
- 235000007862 Capsicum baccatum Nutrition 0.000 claims description 8
- 240000004460 Tanacetum coccineum Species 0.000 claims description 8
- ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 claims description 8
- 229910021645 metal ion Inorganic materials 0.000 claims description 8
- 229940015367 pyrethrum Drugs 0.000 claims description 8
- REPVLJRCJUVQFA-UHFFFAOYSA-N (-)-isopinocampheol Natural products C1C(O)C(C)C2C(C)(C)C1C2 REPVLJRCJUVQFA-UHFFFAOYSA-N 0.000 claims description 7
- 241000234282 Allium Species 0.000 claims description 7
- 235000002732 Allium cepa var. cepa Nutrition 0.000 claims description 7
- 235000002566 Capsicum Nutrition 0.000 claims description 7
- 239000006002 Pepper Substances 0.000 claims description 7
- 241000722363 Piper Species 0.000 claims description 7
- 235000016761 Piper aduncum Nutrition 0.000 claims description 7
- 235000017804 Piper guineense Nutrition 0.000 claims description 7
- 235000008184 Piper nigrum Nutrition 0.000 claims description 7
- 244000294611 Punica granatum Species 0.000 claims description 7
- 235000014360 Punica granatum Nutrition 0.000 claims description 7
- 241000220317 Rosa Species 0.000 claims description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
- 229940116229 borneol Drugs 0.000 claims description 7
- CKDOCTFBFTVPSN-UHFFFAOYSA-N borneol Natural products C1CC2(C)C(C)CC1C2(C)C CKDOCTFBFTVPSN-UHFFFAOYSA-N 0.000 claims description 7
- 239000004202 carbamide Substances 0.000 claims description 7
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 7
- 229940014062 garlic preparation Drugs 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 235000015398 thunder god vine Nutrition 0.000 claims description 7
- 241000283690 Bos taurus Species 0.000 claims description 6
- 230000001376 precipitating effect Effects 0.000 claims description 6
- 210000000582 semen Anatomy 0.000 claims description 6
- 238000007873 sieving Methods 0.000 claims description 6
- 241000830536 Tripterygium wilfordii Species 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 230000006837 decompression Effects 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 230000001804 emulsifying effect Effects 0.000 claims description 4
- 238000001125 extrusion Methods 0.000 claims description 4
- 239000000706 filtrate Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 238000010298 pulverizing process Methods 0.000 claims description 4
- 238000007789 sealing Methods 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 244000187664 Nerium oleander Species 0.000 claims description 3
- 238000007670 refining Methods 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 235000013305 food Nutrition 0.000 abstract description 8
- 241000196324 Embryophyta Species 0.000 description 5
- 241000893864 Nerium Species 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 241000227129 Aconitum Species 0.000 description 2
- 244000037364 Cinnamomum aromaticum Species 0.000 description 2
- 235000014489 Cinnamomum aromaticum Nutrition 0.000 description 2
- 244000144972 livestock Species 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 241000628997 Flos Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 125000002587 enol group Chemical group 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 238000010327 methods by industry Methods 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 239000000447 pesticide residue Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 125000004151 quinonyl group Chemical group 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/46—Stemonaceae [Stemona family], e.g. croomia
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N61/00—Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/14—Celastraceae [Staff-tree or Bittersweet family], e.g. spindle tree, bittersweet or thunder god vine
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/32—Ranunculaceae [Buttercup family], e.g. hepatica, hydrastis or goldenseal
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/42—Aloeaceae [Aloe family] or Liliaceae [Lily family], e.g. aloe, veratrum, onion, garlic or chives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P7/00—Arthropodicides
- A01P7/04—Insecticides
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
The invention discloses a green environment-friendly pesticide containing humic acid and a preparation method thereof. The invention belongs to the technical field of pesticide preparation, and particularly relates to a humic acid-containing green environment-friendly pesticide and a preparation method thereof, wherein the humic acid-containing green environment-friendly pesticide has low cost, good effect and low harm, can meet the pursuit of vast residents on healthy, organic, green and pollution-free food, and can well exert the efficacy of humic acid.
Description
Technical Field
The invention belongs to the technical field of pesticide preparation, and particularly relates to a green environment-friendly pesticide containing humic acid and a preparation method thereof.
Background
In the agricultural production process, pesticides are used for preventing crops from being harmed by pests and fungi, ensuring the healthy growth of the crops and achieving the purpose of increasing the yield. The use of a large amount of pesticides protects crops, ensures the yield and solves the world food crisis, but most of the pesticides have high toxicity and great harm to people and livestock, and the pesticide residue in the food is great, so that the safety of agricultural products is reduced. Meanwhile, with the development of national economy, the increase of the income of residents and the improvement of living standard, the desire for organic, green and pollution-free food is higher and higher, while the production of the organic and pollution-free food needs to replace chemical fertilizers and chemical pesticides with organic fertilizers and pollution-free pesticides, but the production and application of the organic fertilizers and the pollution-free pesticides are not in demand at present, and the price and the cost are higher, so that the production needs of the organic and pollution-free food are difficult to meet.
Humic acid (Humic acid) is an animal and plant residue, mainly a plant residue, is accumulated through the decomposition and conversion of microorganisms and a series of effects of geophysical chemistry, and is a group of organic condensed carboxylic acid amorphous mixtures which have relatively large molecular weight, very complex composition and multiple functions of phenolic hydroxyl, carboxyl, alcoholic hydroxyl, enol group, sulfo group, amino group, free quinonyl, semiquinonyl, quinoxy group, methoxy group and the like.
In the existing pesticide product, humic acid and other substances are combined to form a pesticide fertilizer with fertilizer and pesticide functions. Due to the technical characteristics of humic acid, the technical process conditions of the preparation are greatly different, and a special process and chemical engineering are required for preparing the humic acid green environment-friendly pesticide, so that in the existing preparation method, only the humic acid and other substances are simply mixed, only the physical action is involved in the mixing process, and in the prepared pesticide, the humic acid cannot be well combined with the pesticide and can not interact with the pesticide to enhance the effect.
Therefore, the invention provides the humic acid-containing green environment-friendly pesticide and the preparation method thereof, wherein the humic acid-containing green environment-friendly pesticide has low cost, good effect and low harm, can meet the pursuit of vast residents on healthy, organic, green and pollution-free food, and can well exert the efficacy of humic acid.
Disclosure of Invention
In order to solve the problems, the invention provides the humic acid-containing green environment-friendly pesticide and the preparation method thereof, wherein the humic acid-containing green environment-friendly pesticide has low cost, good effect and low harm, can meet the pursuit of vast residents on healthy, organic, green and pollution-free food, and can well exert the efficacy of humic acid.
In order to realize the functions, the technical scheme adopted by the invention is as follows: a green environment-friendly pesticide containing humic acid comprises mineral source humic acid complex, radix Aconiti, pyrethrum, radix Tripterygii Wilfordii, pericarpium Granati, fructus Zanthoxyli, borneolum Syntheticum, nerium indicum, pod pepper, radix Stemonae, semen Cassiae, herba Alii Fistulosi and Bulbus Allii preparation and flos Rosae Rugosae, and is prepared from the following raw materials in parts by weight: 20-25 parts of mineral source humic acid complex, 10-20 parts of radix aconiti, 5-15 parts of pyrethrum, 10-20 parts of tripterygium wilfordii, 5-15 parts of pomegranate rind, 5-10 parts of pepper, 5-10 parts of borneol, 5-10 parts of oleander, 5-10 parts of pod pepper, 5-20 parts of radix stemonae, 1-10 parts of semen cassiae, 5-20 parts of onion and garlic preparation and 5-10 parts of rose.
Preferably, the mineral source humic acid complex is formed by the coordination reaction of mineral source humic acid molecules and metal ions or urea.
Preferably, the metal ion is K + 、Zn 2+ 、Fe 3+ B, ca, mg and Cu.
The invention also discloses a preparation method of the humic acid-containing green environment-friendly pesticide, which comprises the following steps:
material collection: collecting raw materials, sealing and storing;
(II) crushing and mixing raw materials: drying the raw materials in the sun, pulverizing with a pulverizer, sieving, and mixing;
adding water into the uniformly mixed raw materials, stirring while adding water to ensure that the raw materials are completely immersed in the water, wherein the ratio of the water to the raw materials is 1;
fourthly, heating and hot dipping the mixed solution obtained in the third step for 1.5 hours, and filtering;
(V) extracting and activating humic acid: preparing aqueous solution with the temperature of 70-85 ℃ by using potassium hydroxide and urea as activating solution, and mixing the humic acid raw ore and the activating solution according to the weight ratio of 5-15: 3, stirring by strong mechanical force after mixing, and then carrying out solid-liquid separation to obtain a solution containing humate;
(VI) preparing a humic acid complex by coordination reaction: adding citric acid monohydrate into the humate solution in the step (V), wherein the weight ratio of the citric acid monohydrate to the humate-containing solution is 5-15 per thousand, mixing and stirring the citric acid monohydrate and the humate solution, concentrating, mechanically oscillating and stirring the mixed solution by using a homogenizing and emulsifying device at the temperature of 60-85 ℃, refining the components in the mixed solution under the triple effects of extrusion, strong impact and decompression expansion, and performing coordination reaction more uniformly and fully to obtain a humic acid complex compound which is mixed with the mixed solution in the step (IV) to prepare the aqueous solution medical fertilizer;
(seventhly), bottling and precipitating: and (5) putting the aqueous solution medical fertilizer obtained in the step (VI) into a container, and precipitating for 20-25 days to obtain supernate, namely the agricultural preparation.
Preferably, the number of the sieve meshes in the step (two) is 40-60 meshes.
Preferably, the filtrate obtained in the step (iv) is subjected to hot dipping by secondary heating, and after hot dipping for 1 hour, filtration is performed again.
The invention adopts the structure to obtain the following beneficial effects: the humic acid-containing green environment-friendly pesticide provided by the invention is harmless to human and livestock, has no side effect, has efficient insecticidal action, no pollution to environment, no residue, good economic value and social value, wide source of used raw materials and low cost.
Detailed Description
The technical solutions of the present invention are described clearly and completely below, and it is obvious that the described embodiments are some, not all embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The invention relates to a humic acid-containing green environment-friendly pesticide, which comprises mineral source humic acid complex, radix aconiti, pyrethrum, thunder god vine, pomegranate rind, pepper, borneol, oleander, pod pepper, radix stemonae, semen cassiae, onion and garlic preparation and rose, and the raw materials are proportioned according to parts: 20 parts of mineral source humic acid complex, 10 parts of monkshood, 5 parts of pyrethrum, 20 parts of tripterygium wilfordii, 5 parts of pomegranate peel, 10 parts of pepper, 5 parts of borneol, 5 parts of oleander, 10 parts of pod pepper, 20 parts of radix stemonae, 1 part of cassia seed, 5 parts of onion and garlic preparation and 10 parts of rose.
The mineral source humic acid complex is formed by the coordination reaction of mineral source humic acid molecules and metal ions.
The metal ion is K + 、Zn 2+ And Fe 3+ And (3) combining the components.
The invention also discloses a preparation method of the humic acid-containing green environment-friendly pesticide, which comprises the following steps:
material collection: collecting raw materials, sealing and storing;
(II) crushing and mixing raw materials: drying the raw materials in the sun, pulverizing with a pulverizer, sieving, and mixing;
adding water into the uniformly mixed raw materials, stirring while adding water to ensure that the raw materials are completely immersed in the water, wherein the ratio of the water to the raw materials is 1;
fourthly, heating and hot dipping the mixed solution obtained in the third step for 1.5 hours, and filtering;
and (V) extracting and activating humic acid: preparing an aqueous solution with the temperature of 85 ℃ by using potassium hydroxide and urea as an activating solution, and mixing the humic acid raw ore and the activating solution according to the weight ratio of 15:3 stirring by strong mechanical force after mixing, and then carrying out solid-liquid separation to obtain a solution containing humate;
(VI) preparing a humic acid complex by coordination reaction: adding citric acid monohydrate into the humate solution in the step (V), wherein the weight ratio of the citric acid monohydrate to the humate-containing solution is 15 per thousand, mixing and stirring the citric acid monohydrate and the humate solution, concentrating, mechanically oscillating and stirring the mixed solution by using a homogenizing and emulsifying device at the temperature of 75 ℃, refining the components in the mixed solution under the triple effects of extrusion, strong impact and decompression expansion, and carrying out more uniform and sufficient coordination reaction to obtain a humic acid complex which is mixed with the mixed solution in the step (IV) to prepare the aqueous solution medical fertilizer;
(seventhly), bottling and precipitating: and (5) putting the aqueous solution medical fertilizer obtained in the step (VI) into a container, and carrying out precipitation for 25 days to obtain supernate, namely the agricultural preparation.
The number of the sieving meshes in the step (II) is 45 meshes.
And (d) heating and hot dipping the filtrate obtained in the step (IV) for a second time, and filtering again after the hot dipping for 1 hour.
Example 2
The invention relates to a humic acid-containing green environment-friendly pesticide, which comprises mineral source humic acid complex, radix aconiti, pyrethrum, thunder god vine, pomegranate rind, pepper, borneol, oleander, pod pepper, radix stemonae, semen cassiae, onion and garlic preparation and rose, and the raw materials are proportioned according to parts: 23 parts of mineral source humic acid complex, 15 parts of monkshood, 10 parts of pyrethrum, 15 parts of tripterygium wilfordii, 10 parts of pomegranate rind, 7 parts of pepper, 8 parts of borneol, 7 parts of oleander, 8 parts of pod pepper, 15 parts of radix stemonae, 5 parts of cassia seed, 15 parts of onion and garlic preparation and 8 parts of rose.
The mineral source humic acid complex is formed by the coordination reaction of mineral source humic acid molecules and metal ions or urea.
The metal ion is Zn 2+ Ca and Mg.
The invention also discloses a preparation method of the humic acid-containing green environment-friendly pesticide, which comprises the following steps:
material collection: collecting raw materials, sealing and storing;
(II) crushing and mixing raw materials: drying the raw materials in the sun, pulverizing with a pulverizer, sieving, and mixing;
adding water into the uniformly mixed raw materials, stirring while adding water to ensure that the raw materials are completely immersed in the water, wherein the ratio of the water to the raw materials is 1;
fourthly, heating and hot dipping the mixed solution obtained in the third step for 1.5 hours, and filtering;
and (V) extracting and activating humic acid: preparing aqueous solution with the temperature of 80 ℃ by using potassium hydroxide and urea as activating solution, and mixing the humic acid raw ore and the activating solution according to the weight ratio of 10:3, stirring by strong mechanical force after mixing, and then carrying out solid-liquid separation to obtain a solution containing humate;
(VI) preparing a humic acid complex by coordination reaction: adding citric acid monohydrate into the humate solution in the step (V), wherein the weight ratio of the citric acid monohydrate to the humate-containing solution is 10 per thousand, mixing and stirring the citric acid monohydrate and the humate solution, concentrating, and mechanically oscillating and stirring the mixed solution by using a homogenizing and emulsifying device at the temperature of 70 ℃ to refine the components in the mixed solution under the triple effects of extrusion, strong impact and decompression expansion, so that a coordination reaction is more uniformly and fully carried out, and the humic acid complex is obtained and mixed with the mixed solution in the step (IV) to prepare the aqueous solution medical fertilizer;
(seventhly), bottling and precipitating: and (5) putting the aqueous solution medical fertilizer obtained in the step (six) into a container, and carrying out precipitation for 23 days to obtain a supernatant, namely the agricultural preparation.
The sieve mesh number in the step (II) is 50 meshes.
And (5) carrying out secondary heating and hot dipping on the filtrate obtained in the step (IV), carrying out hot dipping for 1 hour, and then filtering again.
When the pesticide prepared in the example 1-2 is used for spraying two acres of plants of the same soil and the same variety and the same production environment for 2 weeks, through comparison, the plants sprayed with the pesticide prepared in the example 2 have vigorous vitality and deep and strong seedlings compared with the plants sprayed with the pesticide prepared in the example 2.
The present invention and the embodiments thereof have been described above, but the description is not limited thereto, and the embodiments shown in the examples are only one of the embodiments of the present invention, and are not limited thereto. In conclusion, those skilled in the art should appreciate that they can readily use the disclosed conception and specific embodiments as a basis for designing or modifying other structures for carrying out the same purposes of the present invention without departing from the spirit and scope of the invention as defined by the appended claims.
Claims (6)
1. The green environment-friendly pesticide containing humic acid is characterized by comprising mineral source humic acid complex, radix aconiti, pyrethrum, tripterygium wilfordii, pomegranate rind, pepper, borneol, oleander, pod pepper, radix stemonae, semen cassiae, onion and garlic preparation and rose, and the raw materials are proportioned according to parts: 20-25 parts of mineral source humic acid complex, 10-20 parts of radix aconiti, 5-15 parts of pyrethrum, 10-20 parts of tripterygium wilfordii, 5-15 parts of pomegranate rind, 5-10 parts of pepper, 5-10 parts of borneol, 5-10 parts of oleander, 5-10 parts of pod pepper, 5-20 parts of radix stemonae, 1-10 parts of semen cassiae, 5-20 parts of onion and garlic preparation and 5-10 parts of rose.
2. The green and environment-friendly pesticide containing humic acid as claimed in claim 1, wherein the mineral source humic acid complex is formed by the coordination reaction of mineral source humic acid molecules and metal ions or urea.
3. The green and environment-friendly pesticide containing humic acid as claimed in claim 2, wherein the metal ion is K + 、Zn 2+ 、Fe 3+ B, ca, mg and Cu.
4. The preparation method of the humic acid-containing green environment-friendly pesticide according to any one of claims 1 to 3, which is characterized by comprising the following steps of:
material collection: collecting raw materials, sealing and storing;
(II) crushing and mixing raw materials: drying the raw materials in the sun, pulverizing with a pulverizer, sieving, and mixing well for use;
adding water into the uniformly mixed raw materials, stirring while adding water to ensure that the raw materials are completely immersed in the water, wherein the ratio of the water to the raw materials is 1;
fourthly, heating and hot dipping the mixed solution obtained in the third step for 1.5 hours, and filtering;
(V) extracting and activating humic acid: preparing aqueous solution with the temperature of 70-85 ℃ by using potassium hydroxide and urea as activating solution, and mixing the humic acid raw ore and the activating solution according to the weight ratio of 5-15: 3, stirring by strong mechanical force after mixing, and then carrying out solid-liquid separation to obtain a solution containing humate;
(VI) preparing a humic acid complex by coordination reaction: adding citric acid monohydrate into the humate solution in the step (V), wherein the weight ratio of the citric acid monohydrate to the humate-containing solution is 5-15 per thousand, mixing and stirring the citric acid monohydrate and the humate solution, concentrating, mechanically oscillating and stirring the mixed solution by using a homogenizing and emulsifying device at the temperature of 60-85 ℃, refining the components in the mixed solution under the triple effects of extrusion, strong impact and decompression expansion, and performing coordination reaction more uniformly and fully to obtain a humic acid complex, and mixing the humic acid complex with the mixed solution in the step (IV) to prepare the aqueous solution medical fertilizer;
(seventhly), bottling and precipitating: and (5) putting the aqueous solution medical fertilizer obtained in the step (VI) into a container, and precipitating for 20-25 days to obtain supernate, namely the agricultural preparation.
5. The method for preparing the green and environment-friendly pesticide containing the humic acid according to claim 4, wherein the sieving mesh number in the step (II) is 40-60 meshes.
6. The method for preparing the humic acid-containing green and environment-friendly pesticide as claimed in claim 4, wherein the filtrate obtained in the step (IV) is hot-dipped for a second time, and after being hot-dipped for 1 hour, is filtered again.
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| CN116965423A (en) * | 2023-09-25 | 2023-10-31 | 山西林海腐植酸科技有限公司 | Humic acid-containing green environment-friendly pesticide and preparation method thereof |
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| CN106561752A (en) * | 2015-10-10 | 2017-04-19 | 重庆鸿谦农业开发有限责任公司 | Biopesticide and preparation method thereof |
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| CN107691531A (en) * | 2017-11-16 | 2018-02-16 | 桂林市晟博科技服务有限公司 | A kind of green and environment-friendly pesticide and preparation method thereof |
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