CN104016802A - Natural multi-functional foliage fertilizer and preparation method thereof - Google Patents

Natural multi-functional foliage fertilizer and preparation method thereof Download PDF

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CN104016802A
CN104016802A CN201410276852.3A CN201410276852A CN104016802A CN 104016802 A CN104016802 A CN 104016802A CN 201410276852 A CN201410276852 A CN 201410276852A CN 104016802 A CN104016802 A CN 104016802A
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foliage fertilizer
natural
extracting solution
chinese pistache
functional
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CN104016802B (en
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吴丽芳
汤明礼
蔡冬清
吴正岩
李明浩
陈明
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Zhongke Meilan (Hefei) Biological Engineering Co., Ltd.
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Hefei Institutes of Physical Science of CAS
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Abstract

The invention discloses a natural multi-functional foliage fertilizer. The foliage fertilizer comprises the following raw materials in percentage by weight: 10-30% of Pistacia chinensis extraction solution, 5-10% of amino acid nutrient solution, 1-3% of trace elements, 2-4% of attapulgite, 1-3% of diatomaceous earth, and the balance of water. The invention also provides a preparation method of the foliage fertilizer, the method comprises the steps of taking leaves, buds, twigs and fruit peels of Pistacia chinensis, drying and crushing to fine powder; adding fine powder into the extraction solution at a ratio of fine powder to extraction solution being 1g/(5-40) ml and soaking; after soaking, heating, stirring and extracting, filtering the primary extraction solution and collecting the filtrate; centrifuging the filtrate, collecting the supernatant as the Pistacia chinensis extract solution; taking the raw materials in percentage by weight, mixing the raw material, heating and stirring until the raw materials are fully dissolved. The natural multi-functional foliage fertilizer has the advantages that the foliage fertilizer is natural, green, environmentally friendly and efficient, the yield-increasing effect is obvious, no residues of pesticides and fertilizers occur, the natural multi-functional foliage fertilizer can prevent pests and diseases of plants and is especially applicable to organic agriculture.

Description

A kind of natural and multi-functional foliage fertilizer and preparation method thereof
Technical field
The present invention relates to a kind of foliage fertilizer, in particular a kind of natural and multi-functional foliage fertilizer and preparation method thereof.
Background technology
Foliage fertilizer is a kind of fertilizer type that nutritive element is applied to farm crop blade surface and brings into play by the absorption of blade its function.The nutritive substance that sprays application to plant surface can be absorbed and be entered in plant materials and then be converted and utilize by the hole in plant leaf surface pore and stratum corneum.Leaf leaven, particularly contain some easily by the element of soil fixing as phosphorus, copper, manganese, iron, zinc etc., there is fast, the effective feature that absorbs, can meet in time the requirement of crop growth, can prevent and treat in time or correct again some nutritional deficiency disease or need to supply with rapidly the remedial measures of nutrient because of natural disaster.The nutrient of Foliage Absorption can affect vegetable nutritorium's metabolism fast, involved in plant metabolism, and the activity of reinforcement endoenzyme, can improve the resistance of plant, postpones leaf presenility, and can promote precocity etc.Foliage-spray both can have been saved with expenses of labour, can avoid again harm.Foliage-spray consumption is little, especially phosphorus, potash fertilizer and trace element fertilizer, and consumption is only the 1/10-1/5 of soil application amount, both can reduce investment outlay, the problem that also can avoid trace element fertilizer consumption too much to work the mischief.In a word, foliage fertilizer amount of application is few, effect is obvious rapidly, utilization rate of fertilizer is high, it is not only economic, but also fertilizer variety efficiently of one, particularly the reasonable interpolation of some trace elements has promoter action to plant-growth, has become the important supplementary fertilizer variety of large root fertilizer, has the larger market requirement and application prospect.
The commercialization of China's foliar nutrient is since the 1980s, through the development of two more than ten years, the production of foliar nutrient obtains huge development, develops into composite parts from single component, develops into trace element and beneficial element from macronutrient, develop into organic nutrient from inorganic nutrients, develop into interpolation plant-growth regulator from mineral nutrient, foliar nutrient item are various, of a great variety, multifarious, the whole country approximately has thousands of kinds more than.End in May, 2007, China's foliar nutrient is formally registered 737 of products, interim registration product reaches 1398, the annual amount of application in the whole nation is about 600,000 tons of left and right, that product relates to is big or middle, micronutrient element and different organic active substances, product form has comprised the type such as solid, liquid, and product function is also different.But these foliage fertilizers are mainly the material of chemosynthesis, less is natural, and is sprayed onto behind blade face, easily drenching with rain, run off under wind and solarization, causes environmental pollution.The more important thing is, some foliage fertilizer can cause blade face residual, is not suitable for Organic farming.In addition, existing foliage fertilizer does not generally possess the drug effect of sterilization and disinfestation, mostly is the fertilizer efficiency that promotes development growth.Therefore, need to develop a kind of natural multifunctional foliage fertilizer, for developing green Organic farming provides a kind of new foliar fertilizer.
Chinese pistache is Anacardiaceae deciduous species, is the xylophyta that integrates multiple use, is also important bioenergy seeds.Chinese pistache distributes wide, drought-resistant, saline and alkaline, barren in China, strong adaptability, suitable big area afforestation.The virgin phase of Chinese pistache is long, and dioecy, has a large amount of leaf buds to utilize.Studies show that all good agricultural chemicals of effect of the aqueous solution that the various piece (Turkey-galls, root, branch, skin, leaf) of Chinese pistache boils, multiple rice grub, aphid are had and well slaughter effect.Chinese pistache branches and leaves contain a large amount of polyphenol, they contain multiple poly-hydroxy groups, there is good chemical coordination character, can there is complexing action with the trace element such as Zn, Cu, Cl, Fe, its complex compound has good water-soluble, stability, can solve the problem that plant lacks yield reducation micro-and that cause and resistance decline.Chinese pistache polyphenol also has food refusal effect to insect, and the microorganisms such as bacterium are had to retarding effect.In addition, Chinese pistache polyphenol extract contains some colors conventionally, these materials have pigmentation and stimulate fruit increase effect fresh fruit, vegetables, can make the economic worth of fruits and vegetables greatly improve, and can increase orchard worker and vegetable grower's income.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of natural and multi-functional foliage fertilizer and preparation method thereof is provided.This natural and multi-functional foliage fertilizer adopts Chinese pistache extracting solution as main raw material and amino-acid nutrition liquid, trace element built first, and makes it possess sustained release performance with the natural clay material that possesses slow releasing function is composite.
The present invention is achieved by the following technical solutions:
A kind of natural and multi-functional foliage fertilizer, its raw material by following weight percent forms: Chinese pistache extracting solution 10-30%, amino-acid nutrition liquid 5-10%, micro-1-3%, attapulgite 2-4%, diatomite 1-3%, surplus is water.
As the preferred implementation of above-mentioned a kind of natural and multi-functional foliage fertilizer, boric acid, Zinc Sulphate Monohydrate, iron vitriol that described trace element is 1:1:1 by weight ratio form.
As the preferred implementation of above-mentioned a kind of natural and multi-functional foliage fertilizer, described amino-acid nutrition liquid is plant or the special amino-acid nutrition liquid of flowers.
As the preferred implementation of above-mentioned a kind of natural and multi-functional foliage fertilizer, described Chinese pistache extracting solution extracts one or more in leaf, bud, spray and the pericarp of Chinese pistache.
As the preferred implementation of above-mentioned a kind of natural and multi-functional foliage fertilizer, its raw material by following weight percent forms: Chinese pistache extracting solution 20%, amino-acid nutrition liquid 8%, trace element 2%, attapulgite 3%, diatomite 2%, surplus is water.
The making method that the invention also discloses above-mentioned a kind of natural and multi-functional foliage fertilizer, comprises the steps:
(1) get one or more in leaf, bud, spray and the pericarp of Chinese pistache, crushed after being dried is fine powder;
(2) the Chinese pistache fine powder after pulverizing is added in extracting solution and soaked by the solid-liquid ratio of 1g/ (5-40) ml;
(3) soak after 1-10 hour, heated and stirred is extracted, and the preliminary extracting solution extracting after filtering, is collected filtrate;
(4) filtrate, after centrifugal, is collected supernatant liquor for subsequent use as Chinese pistache extracting solution;
(5) getting weight percent is: Chinese pistache extracting solution 10-30%, amino-acid nutrition liquid 5-10%, micro-1-3%, attapulgite 2-4%, diatomite 1-3%, surplus is that water configures raw material, by above-mentioned raw materials mixing post-heating to 50-90 DEG C, be stirred to after abundant dissolving, be distributed into bottle.
As the preferred implementation of the making method of above-mentioned a kind of natural and multi-functional foliage fertilizer, in described step (2), extracting solution is aqueous ethanolic solution, and the mass percent concentration of described aqueous ethanolic solution is 5-99%.
As the preferred implementation of the making method of above-mentioned a kind of natural and multi-functional foliage fertilizer, in described step (3), the stirring velocity of heated and stirred is 10-50rpm, and extraction time is 1-2 hour, and extraction time is 2 times.
As the preferred implementation of the making method of above-mentioned a kind of natural and multi-functional foliage fertilizer, in described step (4), centrifugal rotational speed is 5000-8000rpm, and centrifugation time is 10-15min.
As the preferred implementation of the making method of above-mentioned a kind of natural and multi-functional foliage fertilizer, described step (1) is: get one or more in leaf, bud, spray and the pericarp of Chinese pistache, crushed after being dried is 400-800 object fine powder.
The present invention has the following advantages compared to existing technology:
The present invention is first to extract the main raw material as foliage fertilizer from the Chinese pistache extracting solution of natural Chinese pistache, and with amino-acid nutrition liquid, trace element built, wherein Chinese pistache extracting solution contains a large amount of polyphenol, in polyphenol, contain multiple poly-hydroxy groups, there is good chemical coordination character, can there is complexing action with the trace element such as Zn, Cu, Cl, Fe, its complex compound has good water-soluble, stability, can solve the problem that plant lacks yield reducation micro-and that cause and resistance decline, there is good effect of increasing production.Its Chinese pistache polyphenol also, to insect being had to food refusal effect, has retarding effect to microorganisms such as bacteriums, therefore plant pest is had to good preventive effect.Simultaneously, Chinese pistache polyphenol extract contains some colors conventionally, these materials have pigmentation and stimulate fruit increase effect fresh fruit, vegetables, can make the economic worth of fruits and vegetables greatly improve, can increase orchard worker and vegetable grower's income, fruit color and maturation be had to regulating and controlling effect.Foliage fertilizer of the present invention is also composite, and to have natural clay material be attapulgite, diatomite, and the natural clays such as attapulgite, diatomite possess slow releasing function, thereby make this foliage fertilizer also possess sustained release performance, and slow release effect is obvious, and validity period is long.Foliage fertilizer provided by the invention is natural, green, environmental protection, efficient, can prevent plant pest, and effect of increasing production is obvious and residual without agriculture chemical, can produce organic non-harmful agricultural-food, and superior product quality, is particularly useful for Organic farming.
In addition, the present invention also provides the making method of this natural and multi-functional foliage fertilizer, and this making method technique is simple, and step is few, and the facility of drawing materials only needs simple equipment to complete, and makes easily, and cost is low.
Embodiment
Below embodiments of the invention are elaborated, the present embodiment is implemented under taking technical solution of the present invention as prerequisite, provided detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following embodiment.
Embodiment mono-
The present embodiment is the preferred embodiments of the present invention.
A kind of natural and multi-functional foliage fertilizer that the present embodiment provides, its raw material by following weight percent forms: Chinese pistache extracting solution 20%, amino-acid nutrition liquid 8%, trace element 2%, attapulgite 3%, diatomite 2%, surplus is water.
Wherein, Chinese pistache extracting solution extracts one or more in leaf, bud, spray and the pericarp of Chinese pistache.Amino-acid nutrition liquid is plant or the special amino-acid nutrition liquid of flowers.Boric acid, Zinc Sulphate Monohydrate, iron vitriol that trace element is 1:1:1 by weight ratio form.
The present embodiment also discloses the making method of above-mentioned a kind of natural and multi-functional foliage fertilizer, comprises the steps:
(1) get one or more in leaf, bud, spray and the pericarp of Chinese pistache, crushed after being dried is 600 object fine powders;
(2) the Chinese pistache fine powder after pulverizing is added in extracting solution and soaked by the solid-liquid ratio of 1g/20ml, wherein extracting solution is that mass percent concentration is 50% aqueous ethanolic solution;
(3) soak after 5 hours, heated and stirred is extracted, and the stirring velocity of heated and stirred is 30rpm, and extraction time is 1.5 hours, and extraction time is 2 times, merges the preliminary extracting solution that extracts for 2 times after filtering, collection filtrate;
(4) filtrate is centrifugal, centrifugal rotational speed is 6500rpm, and centrifugation time is 12min, and after centrifugal completing, collection supernatant liquor is for subsequent use as Chinese pistache extracting solution;
(5) recently configure raw material by the weight percent of above-mentioned raw materials, by above-mentioned raw materials mixing post-heating to 70 DEG C, be stirred to after abundant dissolving, be distributed into bottle.
Embodiment bis-
The present embodiment is wherein a kind of embodiment of the present invention.
A kind of natural and multi-functional foliage fertilizer that the present embodiment provides, its raw material by following weight percent forms: Chinese pistache extracting solution 10%, amino-acid nutrition liquid 10%, trace element 3%, attapulgite 4%, diatomite 1%, surplus is water.
Wherein, Chinese pistache extracting solution extracts one or more in leaf, bud, spray and the pericarp of Chinese pistache.Amino-acid nutrition liquid is plant or the special amino-acid nutrition liquid of flowers.Boric acid, Zinc Sulphate Monohydrate, iron vitriol that trace element is 1:1:1 by weight ratio form.
The present embodiment also discloses the making method of above-mentioned a kind of natural and multi-functional foliage fertilizer, comprises the steps:
(1) get one or more in leaf, bud, spray and the pericarp of Chinese pistache, crushed after being dried is 400 object fine powders;
(2) the Chinese pistache fine powder after pulverizing is added in extracting solution and soaked by the solid-liquid ratio of 1g/5ml, wherein extracting solution is that mass percent concentration is 5% aqueous ethanolic solution;
(3) soak after 1 hour, heated and stirred is extracted, and the stirring velocity of heated and stirred is 10rpm, and extraction time is 1 hour, and extraction time is 2 times, merges the preliminary extracting solution that extracts for 2 times after filtering, collection filtrate;
(4) filtrate is centrifugal, centrifugal rotational speed is 5000rpm, and centrifugation time is 10min, and after centrifugal completing, collection supernatant liquor is for subsequent use as Chinese pistache extracting solution;
(5) recently configure raw material by the weight percent of above-mentioned raw materials, by above-mentioned raw materials mixing post-heating to 50 DEG C, be stirred to after abundant dissolving, be distributed into bottle.
Embodiment tri-
The present embodiment is wherein a kind of embodiment of the present invention.
A kind of natural and multi-functional foliage fertilizer that the present embodiment provides, its raw material by following weight percent forms: Chinese pistache extracting solution 15%, amino-acid nutrition liquid 10%, trace element 2%, attapulgite 3%, diatomite 2%, surplus is water.
Wherein, Chinese pistache extracting solution extracts one or more in leaf, bud, spray and the pericarp of Chinese pistache.Amino-acid nutrition liquid is plant or the special amino-acid nutrition liquid of flowers.Boric acid, Zinc Sulphate Monohydrate, iron vitriol that trace element is 1:1:1 by weight ratio form.
The present embodiment also discloses the making method of above-mentioned a kind of natural and multi-functional foliage fertilizer, comprises the steps:
(1) get one or more in leaf, bud, spray and the pericarp of Chinese pistache, crushed after being dried is 500 object fine powders;
(2) the Chinese pistache fine powder after pulverizing is added in extracting solution and soaked by the solid-liquid ratio of 1g/10ml, wherein extracting solution is that mass percent concentration is 20% aqueous ethanolic solution;
(3) soak after 3 hours, heated and stirred is extracted, and the stirring velocity of heated and stirred is 20rpm, and extraction time is 1.5 hours, and extraction time is 2 times, merges the preliminary extracting solution that extracts for 2 times after filtering, collection filtrate;
(4) filtrate is centrifugal, centrifugal rotational speed is 6000rpm, and centrifugation time is 12min, and after centrifugal completing, collection supernatant liquor is for subsequent use as Chinese pistache extracting solution;
(5) recently configure raw material by the weight percent of above-mentioned raw materials, by above-mentioned raw materials mixing post-heating to 60 DEG C, be stirred to after abundant dissolving, be distributed into bottle.
Embodiment tetra-
The present embodiment is wherein a kind of embodiment of the present invention.
A kind of natural and multi-functional foliage fertilizer that the present embodiment provides, its raw material by following weight percent forms: Chinese pistache extracting solution 25%, amino-acid nutrition liquid 8%, trace element 2%, attapulgite 3%, diatomite 2%, surplus is water.
Wherein, Chinese pistache extracting solution extracts one or more in leaf, bud, spray and the pericarp of Chinese pistache.Amino-acid nutrition liquid is plant or the special amino-acid nutrition liquid of flowers.Boric acid, Zinc Sulphate Monohydrate, iron vitriol that trace element is 1:1:1 by weight ratio form.
The present embodiment also discloses the making method of above-mentioned a kind of natural and multi-functional foliage fertilizer, comprises the steps:
(1) get one or more in leaf, bud, spray and the pericarp of Chinese pistache, crushed after being dried is 700 object fine powders;
(2) the Chinese pistache fine powder after pulverizing is added in extracting solution and soaked by the solid-liquid ratio of 1g/30ml, wherein extracting solution is that mass percent concentration is 80% aqueous ethanolic solution;
(3) soak after 8 hours, heated and stirred is extracted, and the stirring velocity of heated and stirred is 40rpm, and extraction time is 1.5 hours, and extraction time is 2 times, merges the preliminary extracting solution that extracts for 2 times after filtering, collection filtrate;
(4) filtrate is centrifugal, centrifugal rotational speed is 7000rpm, and centrifugation time is 13min, and after centrifugal completing, collection supernatant liquor is for subsequent use as Chinese pistache extracting solution;
(5) recently configure raw material by the weight percent of above-mentioned raw materials, by above-mentioned raw materials mixing post-heating to 80 DEG C, be stirred to after abundant dissolving, be distributed into bottle.
Embodiment five
The present embodiment is wherein a kind of embodiment of the present invention.
A kind of natural and multi-functional foliage fertilizer that the present embodiment provides, its raw material by following weight percent forms: Chinese pistache extracting solution 30%, amino-acid nutrition liquid 5%, trace element 1%, attapulgite 2%, diatomite 3%, surplus is water.
Wherein, Chinese pistache extracting solution extracts one or more in leaf, bud, spray and the pericarp of Chinese pistache.Amino-acid nutrition liquid is plant or the special amino-acid nutrition liquid of flowers.Boric acid, Zinc Sulphate Monohydrate, iron vitriol that trace element is 1:1:1 by weight ratio form.
The present embodiment also discloses the making method of above-mentioned a kind of natural and multi-functional foliage fertilizer, comprises the steps:
(1) get one or more in leaf, bud, spray and the pericarp of Chinese pistache, crushed after being dried is 800 object fine powders;
(2) the Chinese pistache fine powder after pulverizing is added in extracting solution and soaked by the solid-liquid ratio of 1g/40ml, wherein extracting solution is that mass percent concentration is 99% aqueous ethanolic solution;
(3) soak after 10 hours, heated and stirred is extracted, and the stirring velocity of heated and stirred is 50rpm, and extraction time is 2 hours, and extraction time is 2 times, merges the preliminary extracting solution that extracts for 2 times after filtering, collection filtrate;
(4) filtrate is centrifugal, centrifugal rotational speed is 8000rpm, and centrifugation time is 15min, and after centrifugal completing, collection supernatant liquor is for subsequent use as Chinese pistache extracting solution;
(5) recently configure raw material by the weight percent of above-mentioned raw materials, by above-mentioned raw materials mixing post-heating to 90 DEG C, be stirred to after abundant dissolving, be distributed into bottle.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments of doing within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.

Claims (10)

1. a natural and multi-functional foliage fertilizer, is characterized in that, its raw material by following weight percent forms: Chinese pistache extracting solution 10-30%, amino-acid nutrition liquid 5-10%, micro-1-3%, attapulgite 2-4%, diatomite 1-3%, surplus is water.
2. a kind of natural and multi-functional foliage fertilizer as claimed in claim 1, is characterized in that, boric acid, Zinc Sulphate Monohydrate, iron vitriol that described trace element is 1:1:1 by weight ratio form.
3. a kind of natural and multi-functional foliage fertilizer as claimed in claim 1, is characterized in that, described amino-acid nutrition liquid is plant or the special amino-acid nutrition liquid of flowers.
4. a kind of natural and multi-functional foliage fertilizer as claimed in claim 1, is characterized in that, described Chinese pistache extracting solution extracts one or more in leaf, bud, spray and the pericarp of Chinese pistache.
5. a kind of natural and multi-functional foliage fertilizer as described in as arbitrary in claim 1 to 4, it is characterized in that, its raw material by following weight percent forms: Chinese pistache extracting solution 20%, amino-acid nutrition liquid 8%, trace element 2%, attapulgite 3%, diatomite 2%, surplus is water.
6. the making method of a kind of natural and multi-functional foliage fertilizer as described in as arbitrary in claim 1 to 5, is characterized in that, comprises the steps:
(1) get one or more in leaf, bud, spray and the pericarp of Chinese pistache, crushed after being dried is fine powder;
(2) the Chinese pistache fine powder after pulverizing is added in extracting solution and soaked by the solid-liquid ratio of 1g/ (5-40) ml;
(3) soak after 1-10 hour, heated and stirred is extracted, and the preliminary extracting solution extracting after filtering, is collected filtrate;
(4) filtrate, after centrifugal, is collected supernatant liquor for subsequent use as Chinese pistache extracting solution;
(5) getting weight percent is: Chinese pistache extracting solution 10-30%, amino-acid nutrition liquid 5-10%, micro-1-3%, attapulgite 2-4%, diatomite 1-3%, surplus is that water configures raw material, by above-mentioned raw materials mixing post-heating to 50-90 DEG C, be stirred to after abundant dissolving, be distributed into bottle.
7. the making method of a kind of natural and multi-functional foliage fertilizer as claimed in claim 6, is characterized in that, in described step (2), extracting solution is aqueous ethanolic solution, and the mass percent concentration of described aqueous ethanolic solution is 5-99%.
8. the making method of a kind of natural and multi-functional foliage fertilizer as claimed in claim 6, is characterized in that, in described step (3), the stirring velocity of heated and stirred is 10-50rpm, and extraction time is 1-2 hour, and extraction time is 2 times.
9. the making method of a kind of natural and multi-functional foliage fertilizer as claimed in claim 6, is characterized in that, in described step (4), centrifugal rotational speed is 5000-8000rpm, and centrifugation time is 10-15min.
10. the making method of a kind of natural and multi-functional foliage fertilizer as claimed in claim 6, it is characterized in that, described step (1) is: get one or more in leaf, bud, spray and the pericarp of Chinese pistache, crushed after being dried is 400-800 object fine powder.
CN201410276852.3A 2014-06-19 2014-06-19 A kind of natural and multi-functional foliage fertilizer and preparation method thereof Active CN104016802B (en)

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CN105272465A (en) * 2015-10-28 2016-01-27 王懿成 Preparation methods of medical fungus and edible fungus biological nutrient solutions
CN107032886A (en) * 2017-04-26 2017-08-11 中国科学院合肥物质科学研究院 A kind of selenium-rich natural and multi-functional foliar fertilizer and preparation method thereof
CN107417436A (en) * 2017-09-27 2017-12-01 界首市明亮种植专业合作社 A kind of preparation method of high wall built-up foliar fertilizer
CN109678593A (en) * 2018-12-25 2019-04-26 广东高龙环保科技有限公司 A kind of amino acid foliage fertilizer
CN113519565A (en) * 2021-07-15 2021-10-22 广西荔浦市福燕农业科技有限公司 Plant protection liquid
CN115716767A (en) * 2022-11-30 2023-02-28 河北萌帮生物科技有限公司 Compound fertilizer for promoting plant growth and health and preparation method thereof

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105272465A (en) * 2015-10-28 2016-01-27 王懿成 Preparation methods of medical fungus and edible fungus biological nutrient solutions
CN107032886A (en) * 2017-04-26 2017-08-11 中国科学院合肥物质科学研究院 A kind of selenium-rich natural and multi-functional foliar fertilizer and preparation method thereof
CN107032886B (en) * 2017-04-26 2020-10-27 中国科学院合肥物质科学研究院 Selenium-rich natural multifunctional foliar fertilizer and preparation method thereof
CN107417436A (en) * 2017-09-27 2017-12-01 界首市明亮种植专业合作社 A kind of preparation method of high wall built-up foliar fertilizer
CN109678593A (en) * 2018-12-25 2019-04-26 广东高龙环保科技有限公司 A kind of amino acid foliage fertilizer
CN113519565A (en) * 2021-07-15 2021-10-22 广西荔浦市福燕农业科技有限公司 Plant protection liquid
CN115716767A (en) * 2022-11-30 2023-02-28 河北萌帮生物科技有限公司 Compound fertilizer for promoting plant growth and health and preparation method thereof

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