CN115052920B - 成型材料及纤维增强复合材料 - Google Patents

成型材料及纤维增强复合材料 Download PDF

Info

Publication number
CN115052920B
CN115052920B CN202180011336.6A CN202180011336A CN115052920B CN 115052920 B CN115052920 B CN 115052920B CN 202180011336 A CN202180011336 A CN 202180011336A CN 115052920 B CN115052920 B CN 115052920B
Authority
CN
China
Prior art keywords
fiber
epoxy resin
reinforced composite
resin composition
composite material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202180011336.6A
Other languages
English (en)
Chinese (zh)
Other versions
CN115052920A (zh
Inventor
松川滉
小柳静惠
平野公则
富冈伸之
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Publication of CN115052920A publication Critical patent/CN115052920A/zh
Application granted granted Critical
Publication of CN115052920B publication Critical patent/CN115052920B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/243Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/58Epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4014Nitrogen containing compounds
    • C08G59/4028Isocyanates; Thioisocyanates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/504Amines containing an atom other than nitrogen belonging to the amine group, carbon and hydrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/686Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/042Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with carbon fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/043Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/244Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/06Elements
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/70Wind energy
    • Y02E10/72Wind turbines with rotation axis in wind direction

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Reinforced Plastic Materials (AREA)
  • Laminated Bodies (AREA)
  • Polyurethanes Or Polyureas (AREA)
CN202180011336.6A 2020-02-03 2021-01-27 成型材料及纤维增强复合材料 Active CN115052920B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP2020015995 2020-02-03
JP2020-015995 2020-02-03
JP2020027904 2020-02-21
JP2020-027904 2020-02-21
PCT/JP2021/002756 WO2021157442A1 (ja) 2020-02-03 2021-01-27 成形材料および繊維強化複合材料

Publications (2)

Publication Number Publication Date
CN115052920A CN115052920A (zh) 2022-09-13
CN115052920B true CN115052920B (zh) 2024-05-03

Family

ID=77199477

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202180011336.6A Active CN115052920B (zh) 2020-02-03 2021-01-27 成型材料及纤维增强复合材料

Country Status (6)

Country Link
US (1) US20230027417A1 (https=)
EP (1) EP4101878A4 (https=)
JP (1) JP7694381B2 (https=)
CN (1) CN115052920B (https=)
AU (1) AU2021217266A1 (https=)
WO (1) WO2021157442A1 (https=)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20230406994A1 (en) * 2020-11-16 2023-12-21 Toray Industries, Inc. Thermosetting epoxy resin composition, molded article of same, fiber-reinforced composite material, molding material for fiber-reinforced composite materials, and method for producing fiber-reinforced composite material
WO2026014455A1 (ja) * 2024-07-10 2026-01-15 東レ株式会社 エポキシ樹脂組成物、繊維強化複合材料用成形材料、繊維強化複合材料および構造部材
CN118725723B (zh) * 2024-07-12 2025-03-25 广州博为建科工程有限公司 一种建筑幕墙用保温耐火材料及其制备方法
CN119141978A (zh) * 2024-09-27 2024-12-17 黑龙江众合鑫成新材料有限公司 一种功能性复合板及其制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5659747A (en) * 1979-10-18 1981-05-23 Kuraray Co Ltd Substituted cyclopropanecarboxylic acid ester, and insecticide containing said compound as effective component
EP0119617A1 (en) * 1983-03-17 1984-09-26 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Flame retarded epoxy resin composition for use in the manufacture of electrical laminates
US4564651A (en) * 1983-06-27 1986-01-14 Siemens Aktiengesellschaft Method for the manufacture of reaction resin molding materials
US4631306A (en) * 1983-06-27 1986-12-23 Siemens Aktiengesellschaft Method for the manufacture of molded materials
JP2002194670A (ja) * 2000-12-21 2002-07-10 Unitika Glass Fiber Co Ltd ガラスクロス表面処理剤
JP2010037694A (ja) * 2008-08-07 2010-02-18 Toray Ind Inc 強化繊維基材、積層体および複合材料
CN103261290A (zh) * 2010-12-13 2013-08-21 东丽株式会社 碳纤维预浸料坯及其制造方法、碳纤维增强复合材料

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3416950A (en) * 1965-03-30 1968-12-17 Navy Usa Method of improving the bonding characteristics of glass surfaces
GB1285052A (en) * 1969-03-27 1972-08-09 Ici Ltd Polymers
JPS5659847A (en) * 1979-10-19 1981-05-23 Matsushita Electric Works Ltd Production of laminated board
JPS6092844A (ja) * 1983-10-26 1985-05-24 鐘淵化学工業株式会社 電気用積層板および金属箔張り積層板
DE4130329A1 (de) * 1991-09-12 1993-03-18 Bayer Ag Waermehaertbare reaktionsharzgemische, ein verfahren zu ihrer herstellung und die verwendung zur herstellung von press-massen und formkoerpern
US5462799A (en) * 1993-08-25 1995-10-31 Toray Industries, Inc. Carbon fibers and process for preparing same
JP3483999B2 (ja) * 1995-09-14 2004-01-06 東レ・ダウコーニング・シリコーン株式会社 プリプレグおよびガラス繊維強化樹脂成形物
JP3890770B2 (ja) * 1998-09-29 2007-03-07 東レ株式会社 炭素繊維束、およびその製造方法
JP4612207B2 (ja) * 2001-02-20 2011-01-12 三菱レイヨン株式会社 炭素繊維織物およびこれを用いたプリプレグ
JP5061813B2 (ja) * 2007-09-25 2012-10-31 東レ株式会社 プリプレグおよびゴルフクラブシャフト
GB0922599D0 (en) 2009-12-23 2010-02-10 Cytec Tech Corp Modified resin systems for liquid resin infusion applications, prepreg autoclave applications and hybrids thereof
EP2628827B1 (en) * 2010-10-13 2020-07-08 Mitsubishi Chemical Corporation Carbon fiber bundle, and uses thereof
JP6137407B2 (ja) 2015-03-27 2017-05-31 東レ株式会社 繊維強化複合材料用2液型エポキシ樹脂組成物および繊維強化複合材料
JP6780317B2 (ja) 2016-06-23 2020-11-04 Dic株式会社 硬化性組成物及び繊維強化複合材料

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5659747A (en) * 1979-10-18 1981-05-23 Kuraray Co Ltd Substituted cyclopropanecarboxylic acid ester, and insecticide containing said compound as effective component
EP0119617A1 (en) * 1983-03-17 1984-09-26 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Flame retarded epoxy resin composition for use in the manufacture of electrical laminates
US4564651A (en) * 1983-06-27 1986-01-14 Siemens Aktiengesellschaft Method for the manufacture of reaction resin molding materials
US4631306A (en) * 1983-06-27 1986-12-23 Siemens Aktiengesellschaft Method for the manufacture of molded materials
JP2002194670A (ja) * 2000-12-21 2002-07-10 Unitika Glass Fiber Co Ltd ガラスクロス表面処理剤
JP2010037694A (ja) * 2008-08-07 2010-02-18 Toray Ind Inc 強化繊維基材、積層体および複合材料
CN103261290A (zh) * 2010-12-13 2013-08-21 东丽株式会社 碳纤维预浸料坯及其制造方法、碳纤维增强复合材料

Also Published As

Publication number Publication date
AU2021217266A1 (en) 2022-08-18
US20230027417A1 (en) 2023-01-26
JP7694381B2 (ja) 2025-06-18
EP4101878A1 (en) 2022-12-14
JPWO2021157442A1 (https=) 2021-08-12
CN115052920A (zh) 2022-09-13
EP4101878A4 (en) 2024-02-28
WO2021157442A1 (ja) 2021-08-12

Similar Documents

Publication Publication Date Title
CN115052920B (zh) 成型材料及纤维增强复合材料
WO2014030638A1 (ja) エポキシ樹脂組成物、及びこれを用いたフィルム、プリプレグ、繊維強化プラスチック
KR20150070104A (ko) 고탄성률 섬유 강화 중합체 복합물
WO2014030636A1 (ja) エポキシ樹脂組成物及びこれを用いたフィルム、プリプレグ、繊維強化プラスチック
CN106687498A (zh) 环氧树脂组合物、树脂固化物、预浸料坯及纤维增强复合材料
CN110431166A (zh) 环氧树脂组合物、预浸料坯以及碳纤维增强复合材料
Dhanapal et al. Role of POSS as coupling agent for DGEBA/GF reinforced nanocomposites
US20230406994A1 (en) Thermosetting epoxy resin composition, molded article of same, fiber-reinforced composite material, molding material for fiber-reinforced composite materials, and method for producing fiber-reinforced composite material
US20230416521A1 (en) Thermosetting epoxy resin composition, molded article from thermosetting epoxy resin, molding material for fiber-reinforced composite material, fiber-reinforced composite material, and method for producing fiber-reinforced composite material
TWI875323B (zh) 一種碳纖維複合材料配方、加工方法及其所製成之纖維複合材料鋼頭鞋
JP7823570B2 (ja) エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料
EP4112795B1 (en) Stitched reinforcing fiber base material, preform material, fiber reinforced composite material, and manufacturing methods for same
CN118984844A (zh) 环氧树脂固化剂、环氧树脂组合物及其固化物、纤维增强复合材料、高压气体容器
CN113039236B (zh) 片状模塑料及纤维增强复合材料
JP7160219B1 (ja) 熱硬化性エポキシ樹脂組成物とその成形品、繊維強化複合材料、繊維強化複合材料用成形材料、および繊維強化複合材料の製造方法
JP7279868B1 (ja) エポキシ樹脂組成物及びその硬化物、プリプレグ、繊維強化複合材、高圧ガス容器
CN114729108B (zh) 环氧树脂组合物、预浸料及纤维增强复合材料
CN116615480A (zh) 热固性环氧树脂组合物及其成型品、纤维增强复合材料、纤维增强复合材料用成型材料、以及纤维增强复合材料的制造方法
JP2026061272A (ja) 成形材料および繊維強化複合材料
CN111601836B (zh) 预浸料及纤维增强复合材料
JP2026061271A (ja) 成形材料および繊維強化複合材料
EP4538308A1 (en) Epoxy resin composition
Sham Aan et al. Effect of PTMEG on the mechanical and flame retardance behaviour of novolac phenolic based CFRP
WO2026014455A1 (ja) エポキシ樹脂組成物、繊維強化複合材料用成形材料、繊維強化複合材料および構造部材
CN117043217A (zh) 环氧树脂组合物、预浸料及纤维增强复合材料

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant