CN114958468A - 一种高性能冷却润滑剂 - Google Patents

一种高性能冷却润滑剂 Download PDF

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CN114958468A
CN114958468A CN202210709644.2A CN202210709644A CN114958468A CN 114958468 A CN114958468 A CN 114958468A CN 202210709644 A CN202210709644 A CN 202210709644A CN 114958468 A CN114958468 A CN 114958468A
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parts
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base oil
cooling lubricant
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路冉
管栋
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Zhejiang Bowie Energy Technology Co ltd
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Abstract

本申请公开了一种高性能冷却润滑剂，按质量份数计，包括基础油100份、极压抗磨剂0.1～2.0份、抗氧剂0.05～1.00份、防锈剂0.05～1.00份、抗乳化剂0.02～0.50份、抗泡剂0.005～0.050份和辅助剂0.05～0.50份；基础油包括多元醇酯和聚醚型合成基础油，多元醇酯和聚醚型合成基础油的质量比为1:0.2～5.0；抗泡剂选用甲基硅油抗泡剂；辅助剂包括4～6wt％的聚甲基丙烯酸铵、2～3wt％的二甲基亚砜和91～94wt％的丙三醇，具有提高抗泡性的优点。

Description

一种高性能冷却润滑剂
技术领域
本发明涉及高性能冷却润滑剂。
背景技术
压缩机油主要用于润滑压缩机的气缸、活塞环、轴承、增速齿轮、曲柄连杆及曲轴箱润滑系统。对于回转式压缩机油，除了对机件润滑、冷却、密封外，由于油雾经过机械碰撞和吸附介质后与气体分离，反复循环，所以还突出地起到冷却压缩气体的作用。
压缩机油是由基础油、极压剂、抗氧剂、防腐剂、抗乳化剂、抗泡剂等调配而成，使其具有黏温性、好的积碳倾向性、氧化安定性和防腐防锈性等。
抗泡剂的作用主要是抑制泡沫产生，并使泡沫破裂。气泡会破坏润滑油均匀地沿输油管道送至整个润滑表面，破坏润滑油正常工作。目前最常用的抗泡剂之一是甲基硅油抗泡剂，其具有良好的黏温性能、防水、防潮及消除油品中产生气泡的性能，对金属无腐蚀。
然而在实际应用中发现，甲基硅油抗泡剂在基础油中的分散效果较差，影响了含甲基硅油抗泡剂在润滑剂中的抗泡效果。
发明内容
本发明的目的是提供一种高性能冷却润滑剂，具有提高抗泡性的优点。
本发明的上述技术目的是通过以下技术方案得以实现的：
一种高性能冷却润滑剂，按质量份数计，包括基础油100份、极压抗磨剂0.1～2.0份、抗氧剂0.05～1.00份、防锈剂0.05～1.00份、抗乳化剂0.02～0.50份、抗泡剂0.005～0.050份和辅助剂0.05～0.50份；
所述基础油包括多元醇酯和聚醚型合成基础油，所述多元醇酯和聚醚型合成基础油的质量比为1:0.2～5.0；
所述抗泡剂选用甲基硅油抗泡剂；
所述辅助剂包括4～6wt％的聚甲基丙烯酸铵、2～3wt％的二甲基亚砜和91～94wt％的丙三醇。
进一步的，在一种高性能冷却润滑剂中，所述极压抗磨剂的用量为0.1～0.5质量份数，所述极压抗磨剂选用异辛基酸性磷酸酯胺盐。
进一步的，在一种高性能冷却润滑剂中，所述抗氧剂的用量为0.10～0.30质量份数，所述抗氧剂包括质量比为1:1的对,对-二异辛基二苯胺和三甲基二羟基喹啉低聚物。
进一步的，在一种高性能冷却润滑剂中，所述防锈剂的用量为0.08～0.20质量份数，所述防锈剂包括质量比为3:1的碱性二壬基萘磺酸钡和2-巯基苯并噻唑。
进一步的，在一种高性能冷却润滑剂中，所述抗乳化剂的用量为0.05～0.10质量份数，所述抗乳化剂选用胺与环氧化物缩合物。
进一步的，在一种高性能冷却润滑剂中，所述抗泡剂的的用量为0.010～0.025质量份数，所述抗泡剂选用甲基硅油抗泡剂；所述辅助剂的用量为0.05～0.10质量份数，所述辅助剂包括5wt％的聚甲基丙烯酸铵、2.5wt％的二甲基亚砜和92.5wt％的丙三醇；
所述基础油包括多元醇酯和聚醚型合成基础油，所述多元醇酯和聚醚型合成基础油的质量比为1:3。
进一步的，所述一种高性能冷却润滑剂还包括热致型形状记忆高分子子4～6质量份数。
进一步的，所述一种高性能冷却润滑剂通过以下方法制备：向反应釜中加入配方量的基础油和抗乳化剂，加热至45～55℃使其熔化；向其中加入预分散均匀的抗泡剂和辅助剂，搅拌分散均匀；加入极压抗磨剂、抗氧剂和防锈剂，搅拌分散均匀，即得。
进一步的，所述一种高性能冷却润滑剂通过以下方法制备：向反应釜中加入配方量的基础油、抗乳化剂和热致型形状记忆高分子子，加热至45～55℃使其熔化；向其中加入预分散均匀的抗泡剂和辅助剂，搅拌分散均匀；加入极压抗磨剂、抗氧剂和防锈剂，搅拌分散均匀，即得。
本发明技术效果主要体现在以下方面：
通过甲基硅油抗泡剂与聚甲基丙烯酸铵、二甲基亚砜和丙三醇预分散，大大提高甲基硅油抗泡剂在润滑剂中的分散性，从而提高抗泡效果；
利用本申请的异辛基酸性磷酸酯胺盐、对,对-二异辛基二苯胺、三甲基二羟基喹啉低聚物、碱性二壬基萘磺酸钡和2-巯基苯并噻唑，结合基础油，提高防腐防锈性，从而提高使用寿命；
利用热致型形状记忆高分子子常温复形的特点，在使用过程中可利用析出的热致型形状记忆高分子子对润滑剂中的杂质进行吸附，而在过滤后除去杂质，从而减少杂质对后续工艺影响，进一步提高使用寿命。
具体实施方式
实施例1-3：一种高性能冷却润滑剂，其通过以下方法制备：向反应釜中加入配方量的基础油和抗乳化剂，加热至50℃使其熔化；向其中加入预分散均匀的抗泡剂和辅助剂，搅拌分散均匀；加入极压抗磨剂、抗氧剂和防锈剂，搅拌分散均匀，即得。
实施例1-3的配方信息如表1所示。
表1实施例1-3的配方信息(单位：重量份数)
Figure BDA0003707242240000031
Figure BDA0003707242240000041
实施例4：一种高性能冷却润滑剂，与实施例2的区别在于，还包括5质量份数的热致型形状记忆高分子子(简称SMP，购自日本旭化公司的苯乙烯-丁二烯共聚物)。
性能测试
对比例1：一种冷却润滑剂，包括三羟甲基丙烷三油酸酯25质量份数和聚醚型合成基础油(牌号为SDM-01A)75质量份数。
对比例2：一种冷却润滑剂，包括三羟甲基丙烷三油酸酯25质量份数、聚醚型合成基础油(牌号为SDM-01A)75质量份数和甲基硅油抗泡剂(简称T901)0.018质量份数。
对比例3：一种冷却润滑剂，与实施例2的区别在于，未含辅助剂。
测试内容：参照ASTM-D943-TOST测试润滑剂的使用寿命，测试结果如表2所示。
表2
样品 使用寿命(hr)
实施例1 8870
实施例2 9110
实施例3 8900
实施例4 9240
实施例4’ 9650
对比例1 5430
对比例2 7580
对比例3 7960
针对实施例4，在参照ASTM-D943-TOST的基础上，每使用100hr则将润滑剂降至室温(25±5℃)后过滤除固体再加入与初始值同等量的热致型形状记忆高分子子，测试其使用寿命，标记为实施例4’，结果如表2所示。
表2显示，与对比例相比，实施例1-4的使用寿命得到较大提高；与实施例2相比，实施例4的使用寿命提高，而经处理的实施例4’的使用寿命进一步提高。
当然，以上只是本发明的典型实例，除此之外，本发明还可以有其它多种具体实施方式，凡采用等同替换或等效变换形成的技术方案，均落在本发明要求保护的范围之内。

Claims (9)

1.一种高性能冷却润滑剂，其特征是，按质量份数计，包括基础油100份、极压抗磨剂0.1～2.0份、抗氧剂0.05～1.00份、防锈剂0.05～1.00份、抗乳化剂0.02～0.50份、抗泡剂0.005～0.050份和辅助剂0.05～0.50份；
所述基础油包括多元醇酯和聚醚型合成基础油，所述多元醇酯和聚醚型合成基础油的质量比为1:0.2～5.0；
所述抗泡剂选用甲基硅油抗泡剂；
所述辅助剂包括4～6wt％的聚甲基丙烯酸铵、2～3wt％的二甲基亚砜和91～94wt％的丙三醇。
2.根据权利要求1所述的一种高性能冷却润滑剂，其特征是，在一种高性能冷却润滑剂中，所述极压抗磨剂的用量为0.1～0.5质量份数，所述极压抗磨剂选用异辛基酸性磷酸酯胺盐。
3.根据权利要求2所述的一种高性能冷却润滑剂，其特征是，在一种高性能冷却润滑剂中，所述抗氧剂的用量为0.10～0.30质量份数，所述抗氧剂包括质量比为1:1的对,对-二异辛基二苯胺和三甲基二羟基喹啉低聚物。
4.根据权利要求3所述的一种高性能冷却润滑剂，其特征是，在一种高性能冷却润滑剂中，所述防锈剂的用量为0.08～0.20质量份数，所述防锈剂包括质量比为3:1的碱性二壬基萘磺酸钡和2-巯基苯并噻唑。
5.根据权利要求4所述的一种高性能冷却润滑剂，其特征是，在一种高性能冷却润滑剂中，所述抗乳化剂的用量为0.05～0.10质量份数，所述抗乳化剂选用胺与环氧化物缩合物。
6.根据权利要求5所述的一种高性能冷却润滑剂，其特征是，在一种高性能冷却润滑剂中，所述抗泡剂的的用量为0.010～0.025质量份数，所述抗泡剂选用甲基硅油抗泡剂；所述辅助剂的用量为0.05～0.10质量份数，所述辅助剂包括5wt％的聚甲基丙烯酸铵、2.5wt％的二甲基亚砜和92.5wt％的丙三醇；
所述基础油包括多元醇酯和聚醚型合成基础油，所述多元醇酯和聚醚型合成基础油的质量比为1:3。
7.根据权利要求6所述的一种高性能冷却润滑剂，其特征是，所述一种高性能冷却润滑剂还包括热致型形状记忆高分子子4～6质量份数。
8.根据权利要求1-6任一项所述的一种高性能冷却润滑剂，其特征是，所述一种高性能冷却润滑剂通过以下方法制备：向反应釜中加入配方量的基础油和抗乳化剂，加热至45～55℃使其熔化；向其中加入预分散均匀的抗泡剂和辅助剂，搅拌分散均匀；加入极压抗磨剂、抗氧剂和防锈剂，搅拌分散均匀，即得。
9.根据权利要求8所述的一种高性能冷却润滑剂，其特征是，所述一种高性能冷却润滑剂通过以下方法制备：向反应釜中加入配方量的基础油、抗乳化剂和热致型形状记忆高分子子，加热至45～55℃使其熔化；向其中加入预分散均匀的抗泡剂和辅助剂，搅拌分散均匀；加入极压抗磨剂、抗氧剂和防锈剂，搅拌分散均匀，即得。
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116948732A (zh) * 2023-07-18 2023-10-27 浙江渤威能源科技有限公司 一种压缩机用冷却润滑剂

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6228813B1 (en) * 1993-04-30 2001-05-08 Nsk Ltd. Rolling bearing filled with a lubricant-containing polymer and process of the same
JP2004010799A (ja) * 2002-06-07 2004-01-15 Tonengeneral Sekiyu Kk 潤滑油組成物
CN1765459A (zh) * 2004-10-27 2006-05-03 上海师范大学 环保型高效强力消泡剂的配方及生产工艺
WO2010087196A1 (ja) * 2009-02-02 2010-08-05 サンノプコ株式会社 消泡剤
CN104263481A (zh) * 2014-10-22 2015-01-07 中国石油化工股份有限公司 一种空气压缩机油及其制备方法
JP2015034237A (ja) * 2013-08-09 2015-02-19 本田技研工業株式会社 摺動部材
WO2016156313A1 (en) * 2015-03-30 2016-10-06 Basf Se Lubricants leading to better equipment cleanliness
CN106010754A (zh) * 2016-05-31 2016-10-12 广东哈弗石油能源有限公司 一种含三羟甲基丙烷酯的压缩机油组合物
WO2017030204A1 (ja) * 2015-08-19 2017-02-23 Ｊｘエネルギー株式会社 潤滑油組成物および潤滑油の消泡方法、ならびに消泡剤組成物
CN108329978A (zh) * 2018-01-20 2018-07-27 盘锦北方沥青股份有限公司 一种聚醚螺杆空气压缩机油组合物及其制备方法
CN111303974A (zh) * 2020-03-26 2020-06-19 袁全 一种耐磨生态环保润滑油及其制备方法
CN111690457A (zh) * 2020-07-08 2020-09-22 卡松科技股份有限公司 合成环保冷冻机油
CN113025413A (zh) * 2021-02-04 2021-06-25 苏州润纳斯纳米科技有限公司 一种带有改性添加剂的润滑油及其制备方法

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6228813B1 (en) * 1993-04-30 2001-05-08 Nsk Ltd. Rolling bearing filled with a lubricant-containing polymer and process of the same
JP2004010799A (ja) * 2002-06-07 2004-01-15 Tonengeneral Sekiyu Kk 潤滑油組成物
CN1765459A (zh) * 2004-10-27 2006-05-03 上海师范大学 环保型高效强力消泡剂的配方及生产工艺
WO2010087196A1 (ja) * 2009-02-02 2010-08-05 サンノプコ株式会社 消泡剤
JP2015034237A (ja) * 2013-08-09 2015-02-19 本田技研工業株式会社 摺動部材
CN104263481A (zh) * 2014-10-22 2015-01-07 中国石油化工股份有限公司 一种空气压缩机油及其制备方法
WO2016156313A1 (en) * 2015-03-30 2016-10-06 Basf Se Lubricants leading to better equipment cleanliness
WO2017030204A1 (ja) * 2015-08-19 2017-02-23 Ｊｘエネルギー株式会社 潤滑油組成物および潤滑油の消泡方法、ならびに消泡剤組成物
CN106010754A (zh) * 2016-05-31 2016-10-12 广东哈弗石油能源有限公司 一种含三羟甲基丙烷酯的压缩机油组合物
CN108329978A (zh) * 2018-01-20 2018-07-27 盘锦北方沥青股份有限公司 一种聚醚螺杆空气压缩机油组合物及其制备方法
CN111303974A (zh) * 2020-03-26 2020-06-19 袁全 一种耐磨生态环保润滑油及其制备方法
CN111690457A (zh) * 2020-07-08 2020-09-22 卡松科技股份有限公司 合成环保冷冻机油
CN113025413A (zh) * 2021-02-04 2021-06-25 苏州润纳斯纳米科技有限公司 一种带有改性添加剂的润滑油及其制备方法

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
YULIANG XIA等: "A Review of Shape Memory Polymers and Composites：Mechanisms, Materials, and Applications", 《ADVANCED MATERIALS》 *
晨光化工研究院有机硅编写组: "《有机硅单体及聚合物》", 31 December 1986, 化学工业出版社 *
秦立新: "硅型抗泡剂在润滑油中应用效果探讨", 《润滑油》 *
耿英杰: "《石油产品添加剂基本知识》", 31 December 1982, 石油工业出版社 *
陈萍华等: "有机硅消泡剂的研究及其发展趋势", 《江西化工》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116948732A (zh) * 2023-07-18 2023-10-27 浙江渤威能源科技有限公司 一种压缩机用冷却润滑剂
CN116948732B (zh) * 2023-07-18 2024-04-26 浙江渤威能源科技有限公司 一种压缩机用冷却润滑剂

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