CN114733334A - Liquid biomass deodorant - Google Patents
Liquid biomass deodorant Download PDFInfo
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- CN114733334A CN114733334A CN202210270604.2A CN202210270604A CN114733334A CN 114733334 A CN114733334 A CN 114733334A CN 202210270604 A CN202210270604 A CN 202210270604A CN 114733334 A CN114733334 A CN 114733334A
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- sulfonic acid
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- deodorant
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- 239000002781 deodorant agent Substances 0.000 title claims abstract description 31
- 239000002028 Biomass Substances 0.000 title claims abstract description 18
- 239000007788 liquid Substances 0.000 title claims abstract description 18
- 150000002500 ions Chemical class 0.000 claims abstract description 53
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims abstract description 21
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229940092714 benzenesulfonic acid Drugs 0.000 claims abstract description 18
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004202 carbamide Substances 0.000 claims abstract description 17
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 claims abstract description 17
- 229940005642 polystyrene sulfonic acid Drugs 0.000 claims abstract description 17
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 claims abstract description 16
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229960000583 acetic acid Drugs 0.000 claims abstract description 13
- 239000012362 glacial acetic acid Substances 0.000 claims abstract description 13
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims abstract description 13
- 229940045136 urea Drugs 0.000 claims abstract description 13
- 239000004952 Polyamide Substances 0.000 claims abstract description 11
- 229920002647 polyamide Polymers 0.000 claims abstract description 11
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 7
- 229910001415 sodium ion Inorganic materials 0.000 claims abstract description 6
- 229910001410 inorganic ion Inorganic materials 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 7
- 238000009472 formulation Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229910001414 potassium ion Inorganic materials 0.000 abstract description 5
- 239000003337 fertilizer Substances 0.000 abstract description 4
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 241000894006 Bacteria Species 0.000 abstract description 2
- 244000052616 bacterial pathogen Species 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 235000015097 nutrients Nutrition 0.000 abstract description 2
- 238000004332 deodorization Methods 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 102000004169 proteins and genes Human genes 0.000 description 7
- 108090000623 proteins and genes Proteins 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 239000010828 animal waste Substances 0.000 description 3
- -1 aryl sulfonic acid Chemical compound 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 3
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 150000003568 thioethers Chemical class 0.000 description 3
- 241000255925 Diptera Species 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- QIAFMBKCNZACKA-UHFFFAOYSA-N N-benzoylglycine Chemical compound OC(=O)CNC(=O)C1=CC=CC=C1 QIAFMBKCNZACKA-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- 210000003608 fece Anatomy 0.000 description 2
- 150000002391 heterocyclic compounds Chemical class 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical group SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Chemical group CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- BQPIGGFYSBELGY-UHFFFAOYSA-N mercury(2+) Chemical compound [Hg+2] BQPIGGFYSBELGY-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 239000003895 organic fertilizer Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F3/00—Fertilisers from human or animal excrements, e.g. manure
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F9/00—Fertilisers from household or town refuse
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses a liquid biomass deodorant, which belongs to the technical field of deodorants and comprises the following components in percentage by weight: k+Ions, Fe3+Ion, H+Ion, Na+Ion, Ca2+Ions, Mg2+Ions, SO4 2‑Ion, NO3 ‑Ion, PO4 3+Ions, Cl‑Ions and OH‑Ions, water, organic compounds: urotropin, glacial acetic acid, polyamide, urea, polystyrene sulfonic acid, benzene sulfonic acid, p-methyl benzene sulfonic acid and dodecyl benzene sulfonic acid. Book (notebook)The liquid biomass deodorant disclosed by the invention can quickly fix compounds generating odor in water, has the function of killing bacteria and germs, retains nutrient components, can be further used for manufacturing organic fertilizers, does not generate odor per se, does not cause secondary pollution, and can permanently eliminate odor sources.
Description
Technical Field
The invention relates to the technical field of deodorizers, in particular to a liquid biomass deodorizer.
Background
The odor-presenting substance is a substance with extremely strong volatility, has various chemical characteristics such as acidity, alkalinity, polarity and non-polarity, and is mainly present in places such as garbage dumps, sewers, toilets, slaughterhouses and mortuary houses.
The existing deodorization methods mainly adopt a method that an aromatic agent is pressed against odor, and also adopt a method of air dilution for deodorization, but the greatest defects of the methods are that the odor is not really eliminated; the deodorization is carried out by an adsorption technology, and adsorbents such as active carbon, diatomite and the like are utilized, but the adsorbents have large using amount, high cost and low practicability; the mercury ion has good deodorization effect, but is easy to cause heavy metal pollution and is not available; although the method of oxidizing by the oxidant is adopted for disinfection and deodorization, although the method has certain effect, the oxidant is strong in corrosivity, sodium hypochlorite can release pungent odor, and the oxidative deodorant can not permanently eliminate the odor, so that the liquid biomass deodorant which can deodorize when being contacted and does not generate odor and cause secondary pollution is provided.
Disclosure of Invention
The invention aims to solve the technical problem of providing a liquid biomass deodorant, which is characterized in that according to the biochemical principle, groups capable of generating odor in excrement and domestic garbage are fixed and dissolved in water, and are not released, so that bacteria and germs are effectively inactivated, and the liquid biomass deodorant is more environment-friendly and efficient.
In order to solve the technical problems, the invention provides the following technical scheme:
a liquid biomass deodorant comprising the following ingredients:
inorganic ions: k is+Ions, Fe3+Ion, H+Ion, Na+Ion, Ca2+Ions, Mg2+Ions, SO4 2-Ion, NO3 -Ion, PO4 3+Ions, Cl-ions and OH-Ions;
water;
an organic compound: urotropin, urea, glacial acetic acid, polyamide, polystyrene sulfonic acid, benzenesulfonic acid, p-toluenesulfonic acid, and dodecylbenzenesulfonic acid;
the liquid biomass deodorant is prepared by adopting the components through a scientific preparation process, wherein the total content of inorganic ions is not less than 1 x 10 < -5 > mol/L and not more than 1mol/L, the total effective content of organic compounds is not more than 2 percent and not less than 0.01 percent, and at least four inorganic ions are in the range.
The invention has the following beneficial effects:
1. the liquid biomass deodorant disclosed by the invention can be used for rapidly fixing malodorous gas generated by pyridine, indole, mercaptan, thioether, dimethyl disulfide, hydrogen sulfide, ammonia gas and heterocyclic compounds containing sulfur or nitrogen into water, and can be used for wrapping protein cells or protein and amino acid molecules to make the protein cells or protein and amino acid molecules lose activity, so that the aim of permanently deodorizing is fulfilled, and the feces and garbage treated by the deodorant are reserved in nutrient components and can be further used for manufacturing a nutritional organic fertilizer;
2. the deodorant is ecological and environment-friendly, and can achieve the effects of permanently deodorizing, sterilizing and removing fly and mosquito eggs, even in hot summer, after the deodorant is added into pig manure, the deodorant can be placed in an airtight environment in the open air and cannot cause odor and fly and mosquito, and nitrogen and sulfur which generate odor are fixed by chemical reaction and cannot be emitted into the air;
3. the odor of toilets, the foul odor of household garbage, the odor of sewer and the odor of various animal wastes can be removed from the source, the deodorized animal wastes or household garbage can be mixed with straws or other biomass materials and mineral substances and fermented into organic fertilizers, and the organic fertilizers have higher fertilizer efficiency than the animal wastes fermented by biogas.
Detailed Description
In order to make the technical problems, technical solutions and advantages to be solved by the present invention clearer, the following detailed description is given with reference to specific embodiments.
The invention provides a liquid biomass deodorant, which comprises the following components:
inorganic ions: k is+Ions, Fe3+Ion, H+Ion, Na+Ion, Ca2+Ions, Mg2+Ions, SO4 2-Ion, NO3 -Ion, PO4 3+Ions, Cl-Ions and OH-Ions;
water;
an organic compound: urotropin, glacial acetic acid, polyamide, urea, polystyrene sulfonic acid, benzene sulfonic acid, p-methyl benzene sulfonic acid, and dodecyl benzene sulfonic acid.
The principle of the invention is illustrated as follows:
the adopted organic compounds are all water-soluble materials;
glacial acetic acid can be used as an acidity regulator, acidulant, pickling agent, flavoring agent, perfume, etc., and can lower the pH below that required for optimal growth of microorganisms;
the urea can react with acid to generate salt with hydrolysis, and can effectively denature protein, especially can effectively destroy protein combined by non-covalent bond;
the benzenesulfonic acid can acidify a deep stratum, and compared with hydrochloric acid, the benzenesulfonic acid (and mixed aryl sulfonic acid) has the advantages of long effective period, low corrosivity and safe use;
under the condition of weak acidity (pH value is about 6.5), urotropine can be hydrolyzed into hippuric acid and formaldehyde, the formaldehyde can denature pathogen protein to play a nonspecific antibacterial effect, and the formaldehyde concentration has a sterilization or bacteriostasis effect according to different pH values;
the acidity of p-toluenesulfonic acid is one million times of that of benzoic acid, and the p-toluenesulfonic acid is soluble in water and used for synthesizing medicines, pesticides, stabilizers of polymerization reactions and catalysts of organic synthesis (esters and the like);
the dodecyl benzene sulfonic acid generates heat when being diluted by water, has the functions of emulsification, dispersion, decontamination and the like, has certain corrosivity, is used for preparing various liquid and solid detergents, is stable in an acid solution, and has good washing performance;
the polyamide is a general term for thermoplastic resin containing repeated amide groups on a molecular main chain, has the most outstanding advantages that the wear resistance is higher than that of all other fibers, and the polyamide is used for fixing materials when being used for preparing a deodorant and is convenient to use in the later period;
inorganic ions can generate chemical reaction or chemical adsorption with pyridine, indole, mercaptan, thioether, dimethyl disulfide, hydrogen sulfide, ammonia gas and heterocyclic compounds containing sulfur or nitrogen, odor molecules are enclosed, a water-soluble ion group is formed, and the generated malodorous gas is quickly fixed in water, so that the aim of permanent deodorization is fulfilled.
The deodorization principle is as follows: the biological deodorant mainly utilizes odor molecules which mostly have amino, carboxyl, hydroxyl, sulfydryl, thioether, disulfide, ether bond or heterocyclic rings containing nitrogen, sulfur and oxygen and derivatives thereof, wherein the odor molecules all contain abundant lone pair electrons, have electronegativity and have the tendency of adsorbing positive charges, the positive charges adsorb anions to form large ion groups to be dissolved in water, thereby achieving the deodorization effect, decomposed small molecular compounds such as hydrogen sulfide, ammonia, indole and the like also have the function of rapidly combining with iron ions, urea, polyamide, urotropine and the like to generate chemical reaction or hydrogen bond combination, organic macromolecules such as polystyrene sulfonic acid, polyamide and the like also play a role of wrapping the odor molecules or specific groups thereof, and the odor molecules or the specific groups thereof are not easy to volatilize and also play a role of water retention because the organic macromolecules are not easy to volatilize
Example 1:
NO3 -ion concentration + H+Ion concentration + SO4 2-Ion concentration + OH-Ion concentration of 1 × 10-5mol/L, the total weight of the inorganic ions and water accounts for 99 percent by weight; urotropin, urea, polystyrene sulfonic acid, benzene sulfonic acid, p-methyl benzene sulfonic acid, glacial acetic acid and dodecyl benzene sulfonic acid are 1 percent.
Example 2:
Fe3+ion concentration + H+Ion concentration + SO4 2-Ion concentration + OH-Ion concentration + NO3 -Ion concentration of 1 × 10- 5mol/L, the total weight of the inorganic ions and the water accounts for 98 percent; urotropin, urea, polystyrene sulfonic acid, benzene sulfonic acid, polyamide, p-methyl benzene sulfonic acid and dodecyl benzene sulfonic acid are 2 percent.
Example 3:
Fe3+ion concentration + H+Ion concentration + SO4 2-Ion concentration + OH-Ion concentration + Na+Ion concentration + Ca2+Ion concentration + Mg2+Ion concentration + NO3-ion concentration + PO4 3+The ion concentration + Cl-ion concentration is 1mol/L, and the total weight of the inorganic ions and the water accounts for 99 percent by weight; urotropin, glacial acetic acid, urea, polystyrene sulfonic acid, benzene sulfonic acid, p-methylbenzene sulfonic acid and dodecyl benzene sulfonic acid are 1 percent.
Example 4:
Fe3+ion concentration + H+Ion concentration + SO4 2-Ion concentration + OH-Ion concentration + K+Ion concentration + Ca2+Ion concentration + Mg2+Ion concentration + NO3-ion concentration + PO4 3+Ion concentration + Cl-ion concentration ═ 1X 10-4mol/L, the total weight of the inorganic ions and water accounts for 99.9 percent; urotropin, glacial acetic acid, urea, polystyrene sulfonic acid, benzene sulfonic acid, p-methylbenzene sulfonic acid and dodecyl benzene sulfonic acid are equal to 0.1 percent.
Example 5:
Fe3+ion concentration + H+Ion concentration + SO4 2-Ion concentration + OH-Ion concentration + K+Ion concentration + Ca2+Ion concentration + Mg2+Ion concentration + NO3 -Ion concentration + PO4 3+The ion concentration + Cl-ion concentration is 0.5mol/L, and the total weight of the inorganic ions and the water accounts for 98 percent by weight; 2% of urea, polystyrene sulfonic acid, benzene sulfonic acid, p-methyl benzene sulfonic acid, polyamide and dodecyl benzene sulfonic acid.
Example 6:
Fe3+ion concentration + H+Ion concentration + SO4 2-Ion concentration + OH-ion concentration + K+Ion concentration + NO3 -The ion concentration is 1mol/L, and the total weight of the inorganic ions and the water accounts for 98 percent; urotropin, urea, polystyrene sulfonic acid, benzene sulfonic acid, p-methyl benzene sulfonic acid, glacial acetic acid and dodecyl benzene sulfonic acid are 2 percent.
Example 7:
Fe3+ion concentration + H+Ion concentration + SO4 2-Ion concentration + OH-Ion concentration + K+Ion concentration + Na+Ion concentration NO3 -Ion concentration + Cl-The ion concentration is 1mol/L, and the total weight of the inorganic ions and the water accounts for 98 percent; urotropin, urea, polystyrene sulfonic acid, benzene sulfonic acid, p-methyl benzene sulfonic acid, glacial acetic acid and dodecyl benzene sulfonic acid are 2 percent.
Example 8:
H+ion concentration + SO4 2-Ion concentration + OH-Ion concentration + NO3 -Ion concentration + PO4 3+Ion concentration + Cl-The ion concentration is 1mol/L, and the total weight of the inorganic ions and the water accounts for 99 percent by weight; urotropin, urea, polystyrene sulfonic acid, benzene sulfonic acid, p-methyl benzene sulfonic acid, glacial acetic acid and dodecyl benzene sulfonic acid are 1 percent.
Example 9:
Fe3+ion concentration + H+Ion concentration + SO4 2-Ion concentration + OH-The ion concentration is 1mol/L, and the total weight of the inorganic ions and the water accounts for 99.9 percent; urotropine, urea, polystyrene sulfonic acid, benzene sulfonic acid and p-methyl benzene sulfonic acid+ glacial acetic acid + dodecylbenzenesulfonic acid ═ 0.1%.
Example 10:
Fe3+ion concentration + H+Ion concentration + SO4 2-Ion concentration + OH-Ion concentration + NO3 -Ion concentration + PO4 3+Ion concentration + Cl-Ion concentration of 1 × 10-4mol/L, the total weight of the inorganic ions and the water accounts for 99.3 percent; urotropin, urea, polystyrene sulfonic acid, benzene sulfonic acid, p-methyl benzene sulfonic acid, glacial acetic acid and dodecyl benzene sulfonic acid are equal to 0.7 percent.
Example 11:
Fe3+ion concentration + H+Ion concentration + SO4 2-Ion concentration + OH-Ion concentration + NO3 -Ion concentration + PO4 3+Ion concentration + Cl-Ion concentration of 1 × 10-4mol/L, the total weight of the inorganic ions and water accounts for 99.2 percent; urea + polystyrene sulfonic acid + benzene sulfonic acid + polyamide + p-methyl benzene sulfonic acid + dodecylbenzene sulfonic acid ═ 0.8%.
Example 12:
Fe3+ion concentration + H+Ion concentration + SO4 2-Ion concentration + OH-Ion concentration + NO3 -Ion concentration + PO4 3+Ion concentration + Cl-Ion concentration of 1 × 10-4mol/L, the total weight of the inorganic ions and water accounts for 99.1 percent; urotropin + polystyrene sulfonic acid + benzene sulfonic acid + p-methyl benzene sulfonic acid + is 0.9%.
When the deodorant is used, the deodorant is diluted to a concentration below the formula of example 4, or the deodorant is diluted to a proper concentration according to specific conditions, the deodorant is mainly used in an aqueous solution, the deodorant can be directly sprayed into the air for deodorization for air deodorization, or the gas can be subjected to gas washing deodorization through a deodorant solution with a certain concentration, and the optimal deodorization effect can be achieved by adopting different formulas according to different odor sources (sulfur compounds, nitrogen compounds, halogens and compounds thereof, hydrocarbons, sulfur compounds and oxygen compounds).
While the foregoing is directed to the preferred embodiment of the present invention, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention as defined in the appended claims.
Claims (5)
1. A liquid biomass deodorant, comprising the following components:
inorganic ions: k is+Ions, Fe3+Ion, H+Ion, Na+Ion, Ca2+Ions, Mg2+Ions, SO4 2-Ion, NO3 -Ion, PO4 3+Ions, Cl-Ions and OH-Ions;
water;
an organic compound: urotropin, glacial acetic acid, polyamide, urea, polystyrene sulfonic acid, benzene sulfonic acid, p-methyl benzene sulfonic acid, and dodecyl benzene sulfonic acid.
2. The liquid biomass deodorant according to claim 1, wherein the total content of inorganic ions is not less than 1 x 10-5mol/L is not more than 1 mol/L.
3. The liquid biomass deodorant according to claim 1 wherein the inorganic ions are at least four of the above ranges.
4. The liquid biomass deodorant according to claim 1 wherein the total effective content of organic compounds is not greater than 2% and not less than 0.01%.
5. The liquid biomass deodorant according to claim 1, wherein the deodorant is prepared from the above components by a scientific formulation process.
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