CN110314506A - A kind of space deodorant and preparation method thereof - Google Patents
A kind of space deodorant and preparation method thereof Download PDFInfo
- Publication number
- CN110314506A CN110314506A CN201910720467.6A CN201910720467A CN110314506A CN 110314506 A CN110314506 A CN 110314506A CN 201910720467 A CN201910720467 A CN 201910720467A CN 110314506 A CN110314506 A CN 110314506A
- Authority
- CN
- China
- Prior art keywords
- deodorant
- space
- zinc
- parts
- zinc salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/58—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The present invention provides a kind of space deodorants and preparation method thereof, belong to technical field of air purification.Space deodorant provided by the invention is by including that the component of following mass fraction is prepared: 2~4 parts of ethylene urea；3~5 parts of adipic dihydrazide；1~3 part of zinc salt deodorant；1~3 part of zinc ion activator；0.5~2 part of pH adjusting agent；0.5~1 part of surfactant；3~21 parts of organic solvent；6~85 parts of water.Ethylene urea and adipic dihydrazide synergistic effect, significantly improve the removal effect of PARA FORMALDEHYDE PRILLS(91,95)；Zinc ion in zinc salt deodorant can be formed very strong chemical combination key after the activation of zinc ion activator with nitrogen, the sulphur atom in stink, and the zinc ion in pH adjusting agent and zinc salt deodorant is complexed, and deodorizing effect is excellent；The addition of surfactant increases the penetrating power of space deodorant.Space deodorant provided by the invention can remove formaldehyde and peculiar smell simultaneously, and high-efficient, materials safety is without secondary pollution to environment.
Description
Technical field
The present invention relates to technical field of air purification, and in particular to a kind of space deodorant and preparation method thereof.
Background technique
Indoor pollution source is mainly finishing pollution and domestic pollution.The common method of air cleaning at present have absorption method,
Ultraviolet sterilization method, the photocatalyst method of purification, chemical scavenging method and physical containment method.Wherein chemical scavenging method, by will be different
Eliminating smell agent agent fixed placement is sprayed at wall, building material surface, using chemical reaction targetedly directly handle a certain item or
Several pollutants, but the duration is shorter, it is individual to administer the virose side effect of product, easily cause secondary pollution.
Summary of the invention
The purpose of the present invention is to provide a kind of space deodorants and preparation method thereof.Space deodorant provided by the invention
It can be achieved at the same time removal formaldehyde pollution and indoor domestic pollution, high-efficient, materials safety is without secondary pollution to environment.
In order to achieve the above-mentioned object of the invention, the present invention the following technical schemes are provided:
The present invention provides a kind of space deodorants, are prepared by the component for including following mass fraction:
2~4 parts of ethylene urea；
3~5 parts of adipic dihydrazide；
1~3 part of zinc salt deodorant；
1~3 part of zinc ion activator；
0.5~2 part of pH adjusting agent；
0.5~1 part of surfactant；
3~21 parts of organic solvent；
6~85 parts of water.
Preferably, the zinc salt deodorant includes zinc ricinate and/or nano zine oxide.
Preferably, the zinc ion activator includes amino acid.
Preferably, the pH adjusting agent includes triethanolamine.
Preferably, the surfactant includes octyl phenol polyoxyethylene ether and/or neopelex.
Preferably, the organic solvent of stating of institute includes methanol and/or ethyl alcohol.
The present invention also provides the preparation methods of space deodorant described in above-mentioned technical proposal, comprising the following steps:
Zinc salt deodorant and organic solvent are subjected to the first mixing, obtain zinc salt deodorization agent solution；
By the zinc salt deodorization agent solution, zinc ion activator, adipic dihydrazide, ethylene urea, pH adjusting agent, surface
Activating agent and water are stood after carrying out the second mixing, obtain space deodorant.
Preferably, the described first mixed temperature is 60~80 DEG C.
Preferably, the described second mixed mode is first to mix zinc salt deodorization agent solution and part water, is then successively added
Enter zinc ion activator to be mixed, adipic dihydrazide is added and ethylene urea is mixed, adds pH adjusting agent, surface
Activating agent and remaining water are mixed；
The part water accounts for the 15~30% of water gross mass.
Preferably, the time of the standing is 3~5h.
The present invention provides a kind of space deodorants, are prepared by the component for including following mass fraction: ethylene urea 2~
4 parts；3~5 parts of adipic dihydrazide；1~3 part of zinc salt deodorant；1~3 part of zinc ion activator；PH adjusting agent 0.5~2
Part；0.5~1 part of surfactant；3~21 parts of organic solvent；6~85 parts of water.Ethylene urea and adipic dihydrazide synergistic effect,
Significantly improve the removal effect of PARA FORMALDEHYDE PRILLS(91,95)；Zinc ion in zinc salt deodorant by after the activation of zinc ion activator can in stink
Nitrogen, sulphur atom form very strong chemical combination key, thoroughly eliminate stink；On the one hand pH adjusting agent can adjust space deodorant
On the other hand pH value can be complexed with the zinc ion in zinc salt deodorant, significantly improve deodorizing effect；The addition of surfactant
Increase the penetrating power of space deodorant.As shown in embodiment result, after space deodorant 30min provided by the invention is added
Ammonia concentration reduces 95% or more；Concentration of formaldehyde reduces 83% or more after 30min；The content of 12min after cure hydrogen reduces
To 0%, removal rate reaches 100%.Show that space deodorant provided by the invention can be achieved at the same time removal formaldehyde pollution and room
Interior domestic pollution, high-efficient, materials safety are without secondary pollution to environment.
Specific embodiment
The present invention provides a kind of space deodorants, are prepared by the component for including following mass fraction:
2~4 parts of ethylene urea；
3~5 parts of adipic dihydrazide；
1~3 part of zinc salt deodorant；
1~3 part of zinc ion activator；
0.5~2 part of pH adjusting agent；
0.5~1 part of surfactant；
3~21 parts of organic solvent；
6~85 parts of water.
In the present invention, if without specified otherwise, all raw material components are commercially available quotient well known to those skilled in the art
Product.
In the present invention, according to the mass fraction, the raw material for preparing the space deodorant includes 2~4 parts of ethylene urea, preferably
It is 2.2~3.8 parts, more preferably 2.5~3.5 parts, most preferably 3 parts.In the present invention, the ethylene urea can be sent out with formaldehyde
Raw Mannich reaction generates Mans alkali, to remove the formaldehyde in environment.In the present invention, the dosage of the ethylene urea is excessive,
It will lead to increased costs and influence the synergistic effect of each component；Dosage is very few, and space deodorant removes aldehyde decreased effectiveness.The present invention
By controlling the dosage of the ethylene urea, the removal effect of formaldehyde of space deodorant can be greatly improved.
In the present invention, in terms of the mass fraction of ethylene urea, the raw material for preparing the space deodorant includes adipic acid two
3~5 parts of hydrazides, preferably 3.2~4.8 parts, more preferably 3.5~4.5 parts, most preferably 4 parts.In the present invention, it is described oneself
Dihydrazi can be reacted with formaldehyde generates stable hydrazone compounds, to eliminate formaldehyde.In the present invention, the ethylene urea
And/or the dosage of adipic dihydrazide is excessive, will lead to increased costs and influences the synergistic effect of each component；Dosage is very few, room
Interior eliminating smell agent removes aldehyde decreased effectiveness.The present invention controls the two by the way that ethylene urea and adipic dihydrazide to be used cooperatively
Dosage can not only improve the synergistic effect of the two, substantially increase the effect of the elimination formaldehyde of space deodorant.
In the present invention, in terms of the mass fraction of ethylene urea, the raw material for preparing the space deodorant includes zinc salt deodorization
1~3 part of agent, preferably 1.2~2.2 parts, more preferably 1.5~2.5 parts, most preferably 2 parts.In the present invention, the zinc salt
Deodorant preferably includes zinc ricinate and/or nano zine oxide, more preferably zinc ricinate or nano zine oxide, most preferably
For zinc ricinate.In the present invention, the dosage of the zinc salt deodorant is excessive, and the insoluble matter that will lead in space deodorant increases
Add, and then influences product using effect；Dosage is very few, and space deodorant deodorizing effect weakens.The present invention is by controlling the zinc
The dosage of salt deodorant can effectively remove the stink in environment, purify air.
In the present invention, in terms of the mass fraction of ethylene urea, the raw material for preparing the space deodorant includes that zinc ion is living
1~3 part of agent, preferably 1.2~2.8 parts, more preferably 1.5~2.5 parts, most preferably 2 parts.In the present invention, the zinc
Ion activation agent preferably includes amino acid.In the present invention, the zinc salt deodorant and the zinc ion activator are to de-taste to remove
Smelly dose of bulk composition, the zinc ion activator can greatly improve the activity of zinc ion in zinc salt deodorant, after being activated
Zinc ion can generate hydrogen bond, covalent bond and chela with malodor molecules reactions such as the amine and sulfide that contain in odorous gas
Cooperation is used, and at biggish molecule, that is, the complex compound of weaker vapour pressure is generated, to thoroughly eliminate stink.In the present invention, described
The dosage of zinc ion activator is excessive, will affect the synergistic effect of each component；Dosage is very few, causes zinc ion activity low, indoor
The deodorizing effect of eliminating smell agent is poor.The present invention by with the use of zinc salt deodorant zinc ion activator and the dosage that both controls,
The two can be made preferably to play synergistic effect, with the excellent ability for removing sulfur-containing compound, go stink effect thorough, and
Stink no longer demutation, to realize the purpose of fresh air；Easily biological-degradable simultaneously, does not generate virose residue, will not
It threatens to human body and environment.
In the present invention, in terms of the mass fraction of ethylene urea, the raw material for preparing the space deodorant includes that pH value is adjusted
0.5~2 part of agent, preferably 0.8~1.8 part, more preferably 1~1.5 part, most preferably 1.2 parts.In the present invention, the pH
Value regulator preferably includes triethanolamine.In the present invention, the dosage of the pH adjusting agent is excessive, will lead to space deodorant
PH value it is higher, and then influence space deodorant stability and taste removal effect；Dosage is very few, will lead to the infiltration of space deodorant
Saturating reduced capability.In the present invention, it is 7~10 that the pH adjusting agent, which can control the pH value of space deodorant, meanwhile, institute
Emulsification and humidification can also be played by stating pH adjusting agent, additionally it is possible to be complexed with zinc ion in zinc salt deodorant, to improve
The deodorizing effect of zinc salt deodorant.
In the present invention, in terms of the mass fraction of ethylene urea, the raw material for preparing the space deodorant includes surface-active
0.5~1 part of agent, preferably 0.6~0.9 part, more preferably 0.7~0.8 part.In the present invention, the use of the surfactant
Amount is excessive, and the foam that will lead to space deodorant is too many, is unfavorable for using dosage is very few, after easily leading to space deodorant spraying
Mobility reduces, and then reduces its taste removal effect.In the present invention, the surfactant preferably includes octylphenol polyethylene ethylene oxide
Ether.In the present invention, the surfactant can reduce the volume of the drop of space deodorant, be conducive to increase indoor deodoring
The penetrating power of agent.
In the present invention, in terms of the mass fraction of ethylene urea, the raw material for preparing the space deodorant includes organic solvent 3
~21 parts, preferably 5~21 parts, more preferably 7~20 parts, most preferably 10~15 parts.In the present invention, the organic solvent
Methanol and/or ethyl alcohol, more preferably methanol or ethyl alcohol are preferably included, ethyl alcohol is most selected as.
In the present invention, in terms of the mass fraction of ethylene urea, the raw material for preparing the space deodorant includes water 6~85
Part, preferably 15~80 parts, more preferably 40~80 parts, most preferably 62~80 parts.
The present invention provides the preparation methods of space deodorant described in above-mentioned technical proposal, comprising the following steps:
The present invention also provides the preparation methods of space deodorant described in above-mentioned technical proposal, comprising the following steps:
Zinc salt deodorant and organic solvent are subjected to the first mixing, obtain zinc salt deodorization agent solution；
By the zinc salt deodorization agent solution, zinc ion activator, adipic dihydrazide, ethylene urea, pH adjusting agent, surface
Activating agent and water are stood after carrying out the second mixing, obtain space deodorant.
Zinc salt deodorant and organic solvent are carried out the first mixing by the present invention, obtain zinc salt deodorization agent solution.In the present invention
In, the described first mixed temperature is preferably 60~80 DEG C, more preferably 60~75 DEG C, most preferably 65 DEG C.
After obtaining zinc salt deodorization agent solution, the present invention is by the zinc salt deodorization agent solution, zinc ion activator, adipic acid two
Hydrazides, ethylene urea, pH adjusting agent, surfactant and water are stood after carrying out the second mixing, obtain space deodorant.
In the present invention, second mixing carries out preferably in agitator tank.In the present invention, second mixing is preferred
It carries out under agitation.In the present invention, the described second mixed mode is first to mix zinc salt deodorization agent solution and part water
It closes, then sequentially adds zinc ion activator and mixed, adipic dihydrazide is added and ethylene urea is mixed, adds pH
Value regulator, surfactant and remaining water are mixed.In the present invention, the zinc salt deodorization agent solution and the mixing of part water
When the speed that stirs be preferably 250~350r/min, more preferably 300r/min；The time of the stirring is preferably 15~
20min, more preferably 15min.In the present invention, the speed stirred when zinc ion activator is mixed that is added is preferably
250~350r/min, more preferably 300r/min；The time of the stirring is preferably 5~10min, more preferably 5min.At this
In invention, the addition adipic dihydrazide, ethylene urea, which are mixed, is preferably added the mixing of zinc ion activator, is then added
The speed that adipic dihydrazide, ethylene urea stir when being mixed is preferably 250~350r/min, more preferably 300r/min；
The time of the stirring is preferably 5~10min, more preferably 5min.In the present invention, the addition pH adjusting agent, surface
The speed that activating agent and remaining water stir when being mixed is preferably 450~550r/min, more preferably 500r/min；It is described to stir
The time mixed is preferably 15~20min, more preferably 15min.
In the present invention, the part water preferably accounts for the 15~30% of water gross mass, more preferably 18~25%, most preferably
It is 20%.
In the present invention, the time of the standing is preferably 3~5h, more preferably 3.5~4.5h, most preferably 4h.?
In the present invention, the effect of the standing is that remaining micro insoluble contamination precipitation, effective component are thoroughly dissolved each other in space deodorant,
It acts synergistically to be conducive to each component with deodorization and except formaldehyde.
In the present invention, the application method of the space deodorant is it is preferable to use the space that gas watering can is sprayed on deodorization,
Especially source of odor surface.In the present invention, the dosage of the space deodorant is preferably 15~20mL/m2, more preferably
20mL/m2。
Preparation method provided by the invention is easy to operate, and preparation condition is mild, adapts to industrialized production.
Below in conjunction with the embodiment in the present invention, the technical solution in the present invention is clearly and completely described.It is aobvious
So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention
Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to
In the scope of protection of the invention.
Embodiment 1
2kg zinc ricinate and 14kg dehydrated alcohol are mixed under the conditions of 65 DEG C, obtain zinc ricinoleate solution；By castor
Sesame oil acid zinc solution is transferred in the agitator tank that capacity is 1 ton, and 200kg deionized water is first added, stirs under the conditions of 300r/min
15min is mixed, 2kg amino acid is added, stirs 5min, 4kg adipic dihydrazide and 3kg ethylene urea is added, stirs 5min, is added
0.8kg octyl phenol polyoxyethylene ether, 1kg triethanolamine and 800kg deionized water stir 15min under the conditions of 500r/min, quiet
4h is set, space deodorant is obtained.
Embodiment 2
3kg zinc ricinate and 21kg dehydrated alcohol are mixed under the conditions of 65 DEG C, obtain zinc ricinoleate solution；By castor
Sesame oil acid zinc solution is transferred in the agitator tank that capacity is 1 ton, and 200kg deionized water is first added, stirs under the conditions of 300r/min
15min is mixed, 1kg amino acid is added, stirs 5min, 3kg adipic dihydrazide and 4kg ethylene urea is added, stirs 5min, is added
0.5kg octyl phenol polyoxyethylene ether, 2kg triethanolamine and 800kg deionized water stir 15min under the conditions of 500r/min, quiet
4h is set, space deodorant is obtained.
Embodiment 3
1kg zinc ricinate and 7kg dehydrated alcohol are mixed under the conditions of 65 DEG C, obtain zinc ricinoleate solution；By castor
Sesame oil acid zinc solution is transferred in the agitator tank that capacity is 1 ton, and 200kg deionized water is first added, stirs under the conditions of 300r/min
15min is mixed, 3kg amino acid is added, stirs 5min, 2kg adipic dihydrazide and 2kg ethylene urea is added, stirs 5min, is added
1kg octyl phenol polyoxyethylene ether, 0.5kg triethanolamine and 800kg deionized water stir 15min under the conditions of 500r/min, quiet
4h is set, space deodorant is obtained.
Reference examples 1
Space deodorant is prepared according to the method for embodiment 1, and the difference with embodiment 1 is only that, is added without ricinoleic acid
Zinc.
Reference examples 2
Space deodorant is prepared according to the method for embodiment 1, and the difference with embodiment 1 is only that, is added without amino acid.
Reference examples 3
Space deodorant is prepared according to the method for embodiment 1, and the difference with embodiment 1 is only that, is added without adipic acid two
Hydrazides.
Reference examples 4
Space deodorant is prepared according to the method for embodiment 1, and the difference with embodiment 1 is only that, is added without ethylene urea.
Reference examples 5
Space deodorant is prepared according to the method for embodiment 1, and the difference with embodiment 1 is only that, is added without octylphenol polyethylene
Ethylene oxide ether.
Reference examples 6
Space deodorant is prepared according to the method for embodiment 1, and the difference with embodiment 1 is only that, is added without triethanolamine.
Test case 1
The effect of space deodorant removal ammonia prepared by Examples 1 to 3 and reference examples 1~6 is tested, ammonia
Initial concentration is 75ppm, is denoted as 100%, be added after space deodorant be respectively separated 10min, 20min, 30min, 40min,
Test the final concentration of ammonia after 50min and 60min, content (%)=(initial concentration-final concentration)/initial concentration of ammonia ×
100%, the results are shown in Table 1.
The effect of 1 space deodorant of table removal ammonia
As shown in Table 1, the present invention is with ethylene urea, adipic dihydrazide, zinc ricinate, amino acid, octyl phenol polyoxy second
Alkene ether, triethanolamine, octyl phenol polyoxyethylene ether, triethanolamine are raw material, the indoor deodoring prepared using second alcohol and water as solvent
Agent, the effects for removing ammonia are best, wherein zinc ricinate and amino acid concentration highest in embodiment 2, thus remove ammonia
The effect of gas is best, and reference examples 1 and 2 are because not being activated that amino acid or amino acid is not added, thus remove removal ammonia
Effect it is poor, and after omitting other raw materials, the effect for removing ammonia can also be weakened.
Test case 2
The effect of space deodorant removal hydrogen sulfide gas prepared by Examples 1 to 3 and reference examples 1~6 is tested,
The initial concentration of hydrogen sulfide is 55ppm, is denoted as 100%, be added after space deodorant be respectively separated 2min, 4min, 6min,
The final concentration of hydrogen sulfide, the content (%) of hydrogen sulfide=(initial dense are tested after 8min, 10min, 12min, 14min and 16min
Degree-final concentration)/initial concentration × 100%, the results are shown in Table 2.
The effect of 2 space deodorant of table removal hydrogen sulfide
As shown in Table 2, the present invention is with ethylene urea, adipic dihydrazide, zinc ricinate, amino acid, octyl phenol polyoxy second
Alkene ether, triethanolamine, octyl phenol polyoxyethylene ether, triethanolamine are raw material, the indoor deodoring prepared using second alcohol and water as solvent
Agent, the effects for removing ammonia are best, and after omitting certain raw material therein, the effect for removing hydrogen sulfide can be weakened,
Wherein, the dosage of zinc ricinate influences the removal effect of hydrogen sulfide maximum.
Test case 3
The effect of space deodorant removal formaldehyde prepared by Examples 1 to 3 and reference examples 1~6 is tested, formaldehyde
Initial concentration is 0.37mg/m3, it is denoted as 100%.Be added space deodorant after be respectively separated 10min, 20min, 30min,
The final concentration of formaldehyde, content (%)=(initial concentration-final concentration) of formaldehyde/initial dense are tested after 40min, 50min and 60min
Degree × 100%, the results are shown in Table 3.
The effect of 3 space deodorant of table removal formaldehyde
As shown in Table 3, the present invention is with ethylene urea, adipic dihydrazide, zinc ricinate, amino acid, octyl phenol polyoxy second
Alkene ether, triethanolamine, octyl phenol polyoxyethylene ether, triethanolamine are raw material, the indoor deodoring prepared using second alcohol and water as solvent
Agent, the effects for removing ammonia are best, and after omitting certain raw material therein, the effect for removing ammonia can be weakened.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (10)
1. a kind of space deodorant, which is characterized in that be prepared by the component for including following mass fraction:
2~4 parts of ethylene urea；
3~5 parts of adipic dihydrazide；
1~3 part of zinc salt deodorant；
1~3 part of zinc ion activator；
0.5~2 part of pH adjusting agent；
0.5~1 part of surfactant；
3~21 parts of organic solvent；
6~85 parts of water.
2. space deodorant according to claim 1, which is characterized in that the zinc salt deodorant includes zinc ricinate
And/or nano zine oxide.
3. space deodorant according to claim 1, which is characterized in that the zinc ion activator includes amino acid.
4. space deodorant according to claim 1, which is characterized in that the pH adjusting agent includes triethanolamine.
5. space deodorant according to claim 1, which is characterized in that the surfactant includes octyl phenol polyoxy second
Alkene ether and/or neopelex.
6. space deodorant according to claim 1, which is characterized in that the organic solvent of stating of institute includes methanol and/or ethyl alcohol.
7. the preparation method of any one of claim 1~6 space deodorant, which comprises the following steps:
Zinc salt deodorant and organic solvent are subjected to the first mixing, obtain zinc salt deodorization agent solution；
By the zinc salt deodorization agent solution, zinc ion activator, adipic dihydrazide, ethylene urea, pH adjusting agent, surface-active
Agent and water are stood after carrying out the second mixing, obtain space deodorant.
8. preparation method according to claim 7, which is characterized in that the described first mixed temperature is 60~80 DEG C.
9. preparation method according to claim 7, which is characterized in that the described second mixed mode is first by zinc salt deodorization
Agent solution and the mixing of part water, then sequentially add zinc ion activator and are mixed, adipic dihydrazide and ethylene urea is added
It is mixed, adds pH adjusting agent, surfactant and remaining water and mixed；
The part water accounts for the 15~30% of water gross mass.
10. preparation method according to claim 7, which is characterized in that the time of the standing is 3~5h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910720467.6A CN110314506A (en) | 2019-08-06 | 2019-08-06 | A kind of space deodorant and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910720467.6A CN110314506A (en) | 2019-08-06 | 2019-08-06 | A kind of space deodorant and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110314506A true CN110314506A (en) | 2019-10-11 |
Family
ID=68125493
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910720467.6A Pending CN110314506A (en) | 2019-08-06 | 2019-08-06 | A kind of space deodorant and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110314506A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110801720A (en) * | 2019-11-15 | 2020-02-18 | 王再华 | Green and low-toxicity formaldehyde scavenger and preparation method thereof |
| CN111203091A (en) * | 2020-03-19 | 2020-05-29 | 河北登尚科技有限公司 | VOC (volatile organic compound) deodorant and preparation method thereof |
| CN111214690A (en) * | 2020-03-18 | 2020-06-02 | 谷双 | Deodorant and preparation method thereof |
| CN112191085A (en) * | 2020-09-30 | 2021-01-08 | 南京清卫源环境技术有限公司 | Preparation method of garbage deodorant |
| CN114733334A (en) * | 2022-03-18 | 2022-07-12 | 南阳迎盈环保科技有限公司 | Liquid biomass deodorant |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001178805A (en) * | 1999-12-27 | 2001-07-03 | Nichias Corp | Inorganic-fiber made heat insulation material and method of manufacturing it |
| CN101890212A (en) * | 2009-05-20 | 2010-11-24 | 广州薇美姿个人护理用品有限公司 | Strong penetration type formaldehyde scavenger |
| CN103257021A (en) * | 2013-05-17 | 2013-08-21 | 石家庄四药有限公司 | High-penetrating agent and preparation method thereof |
| US20180161469A1 (en) * | 2016-12-09 | 2018-06-14 | Ningbo Jiangbei Ocean Star Trading Co., Ltd. | Toilet Deodorizer |
| CN108159865A (en) * | 2017-12-20 | 2018-06-15 | 苏州禾川化学技术服务有限公司 | A kind of environment-friendly deodorant agent containing active zinc atom |
| CN109174010A (en) * | 2018-08-31 | 2019-01-11 | 深圳市迪莫斯环保科技有限公司 | One kind is except modified formaldehyde silica gel material and preparation method thereof |
| CN109925852A (en) * | 2019-03-20 | 2019-06-25 | 北京菲迪可环保科技有限公司 | A method of except formaldehyde composition and removal formaldehyde |
-
2019
- 2019-08-06 CN CN201910720467.6A patent/CN110314506A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001178805A (en) * | 1999-12-27 | 2001-07-03 | Nichias Corp | Inorganic-fiber made heat insulation material and method of manufacturing it |
| CN101890212A (en) * | 2009-05-20 | 2010-11-24 | 广州薇美姿个人护理用品有限公司 | Strong penetration type formaldehyde scavenger |
| CN103257021A (en) * | 2013-05-17 | 2013-08-21 | 石家庄四药有限公司 | High-penetrating agent and preparation method thereof |
| US20180161469A1 (en) * | 2016-12-09 | 2018-06-14 | Ningbo Jiangbei Ocean Star Trading Co., Ltd. | Toilet Deodorizer |
| CN108159865A (en) * | 2017-12-20 | 2018-06-15 | 苏州禾川化学技术服务有限公司 | A kind of environment-friendly deodorant agent containing active zinc atom |
| CN109174010A (en) * | 2018-08-31 | 2019-01-11 | 深圳市迪莫斯环保科技有限公司 | One kind is except modified formaldehyde silica gel material and preparation method thereof |
| CN109925852A (en) * | 2019-03-20 | 2019-06-25 | 北京菲迪可环保科技有限公司 | A method of except formaldehyde composition and removal formaldehyde |
Non-Patent Citations (1)
| Title |
|---|
| 奚元福等: "《环境统计答疑》", 30 June 1988, 四川科学技术出版社 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110801720A (en) * | 2019-11-15 | 2020-02-18 | 王再华 | Green and low-toxicity formaldehyde scavenger and preparation method thereof |
| CN111214690A (en) * | 2020-03-18 | 2020-06-02 | 谷双 | Deodorant and preparation method thereof |
| CN111203091A (en) * | 2020-03-19 | 2020-05-29 | 河北登尚科技有限公司 | VOC (volatile organic compound) deodorant and preparation method thereof |
| CN112191085A (en) * | 2020-09-30 | 2021-01-08 | 南京清卫源环境技术有限公司 | Preparation method of garbage deodorant |
| CN112191085B (en) * | 2020-09-30 | 2022-08-16 | 南京清卫源环境技术有限公司 | Preparation method of garbage deodorant |
| CN114733334A (en) * | 2022-03-18 | 2022-07-12 | 南阳迎盈环保科技有限公司 | Liquid biomass deodorant |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110314506A (en) | A kind of space deodorant and preparation method thereof | |
| CN102329544A (en) | Environmentally-friendly photocatalyst air freshening inner wall coating and preparation method thereof | |
| CN110898372B (en) | Indoor formaldehyde purification method | |
| CN204840387U (en) | Take slowly -releasing to adsorb novel air disinfection and purification device of chlorine dioxide device | |
| CN107737578B (en) | Preparation method of anion antibacterial adsorption material composition | |
| CN109663498A (en) | A kind of natural oxygen catalytic control agent for administering indoor decorating pollution | |
| CN104624037A (en) | Deodorant for decoration air pollution | |
| CN108187462A (en) | High-efficiency deodorant and preparation method thereof | |
| CN108653781A (en) | A kind of antibacterial deodorant and preparation method thereof | |
| CN107626070A (en) | Administer formula of interior decoration removing residue formaldehyde and preparation method thereof | |
| CN110665355A (en) | Deodorant composition containing woody plant essential oil and preparation method thereof | |
| CN111888909A (en) | Composition for removing ammonia and nitrogen compound related odor, preparation and application | |
| CN109731558A (en) | A kind of anion activity carbon nanometer composite material and the preparation method and application thereof | |
| CN104475033A (en) | Domestic formaldehyde remover formula | |
| CN104475034A (en) | Household formaldehyde remover and preparation method thereof | |
| KR20220037887A (en) | High performance deodorization material using hydrogen peroxide and preparing method thereof | |
| CN112876296A (en) | Deodorization method applied to kitchen waste compost | |
| CN112892190A (en) | Chemical deodorant and preparation method thereof | |
| CN111704816A (en) | Long-acting slow-release bactericidal antiviral coating and preparation method and application thereof | |
| JP3074597B2 (en) | Deodorant composition and method for producing deodorant | |
| CN104475035A (en) | Preparation method of household formaldehyde remover | |
| CN112246849B (en) | Organic contaminated soil deodorant and preparation method and application thereof | |
| CN108525493A (en) | A kind of quick eliminating smell agent of formaldehyde and preparation method thereof | |
| KR101274581B1 (en) | Method for manufacturing a liquid deodorant containing sericite ingredient, and a liquid deodorant produced thereby | |
| CN106621761A (en) | Gel air freshener and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 271000 mining equipment industry incubation base in west section of South Gate Street, hi tech Zone, Shandong, Tai'an Applicant after: Shandong Honghu JIAYE Environmental Protection Technology Group Co.,Ltd. Address before: Room 1108, Building 2, Fortune Center, Hengda Times, Huaiyin District, Jinan City, Shandong Province Applicant before: Shandong Honggu Jiaye Environmental Protection Technology Co.,Ltd. |
|
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20200917 Address after: 271000 mining equipment industry incubation base in west section of South Gate Street, hi tech Zone, Shandong, Tai'an Applicant after: Shandong Liyuan ecological environmental protection Co.,Ltd. Address before: 271000 mining equipment industry incubation base in west section of South Gate Street, hi tech Zone, Shandong, Tai'an Applicant before: Shandong Honghu JIAYE Environmental Protection Technology Group Co.,Ltd. |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20191011 |