CN102921028A - Completely biodegradable deodorant and application thereof - Google Patents
Completely biodegradable deodorant and application thereof Download PDFInfo
- Publication number
- CN102921028A CN102921028A CN2012103796004A CN201210379600A CN102921028A CN 102921028 A CN102921028 A CN 102921028A CN 2012103796004 A CN2012103796004 A CN 2012103796004A CN 201210379600 A CN201210379600 A CN 201210379600A CN 102921028 A CN102921028 A CN 102921028A
- Authority
- CN
- China
- Prior art keywords
- deodorizer
- fully biodegradable
- antibacterial
- pha
- deodorant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002781 deodorant agent Substances 0.000 title abstract description 9
- 230000000844 anti-bacterial effect Effects 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 101710108497 p-hydroxybenzoate hydroxylase Proteins 0.000 claims description 5
- 229920000520 poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Polymers 0.000 claims description 5
- -1 shepardite Substances 0.000 claims description 4
- PZBPKYOVPCNPJY-UHFFFAOYSA-N 1-[2-(allyloxy)-2-(2,4-dichlorophenyl)ethyl]imidazole Chemical compound ClC1=CC(Cl)=CC=C1C(OCC=C)CN1C=NC=C1 PZBPKYOVPCNPJY-UHFFFAOYSA-N 0.000 claims description 3
- 101001035951 Homo sapiens Hyaluronan-binding protein 2 Proteins 0.000 claims description 3
- 102100039238 Hyaluronan-binding protein 2 Human genes 0.000 claims description 3
- 239000005795 Imazalil Substances 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 229960002125 enilconazole Drugs 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 2
- 239000010881 fly ash Substances 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 235000012054 meals Nutrition 0.000 claims description 2
- 239000010865 sewage Substances 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 239000010902 straw Substances 0.000 claims description 2
- 239000002023 wood Substances 0.000 claims description 2
- 230000001877 deodorizing effect Effects 0.000 abstract description 6
- 229920000903 polyhydroxyalkanoate Polymers 0.000 abstract description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract description 3
- 239000007789 gas Substances 0.000 abstract description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 239000002075 main ingredient Substances 0.000 abstract 1
- 239000005014 poly(hydroxyalkanoate) Substances 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- 239000000178 monomer Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 238000004332 deodorization Methods 0.000 description 4
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000004071 soot Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WHBMMWSBFZVSSR-UHFFFAOYSA-M 3-hydroxybutyrate Chemical compound CC(O)CC([O-])=O WHBMMWSBFZVSSR-UHFFFAOYSA-M 0.000 description 1
- 229940006015 4-hydroxybutyric acid Drugs 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241001597008 Nomeidae Species 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- WHBMMWSBFZVSSR-UHFFFAOYSA-N R3HBA Natural products CC(O)CC(O)=O WHBMMWSBFZVSSR-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- HRKQOINLCJTGBK-UHFFFAOYSA-N dihydroxidosulfur Chemical compound OSO HRKQOINLCJTGBK-UHFFFAOYSA-N 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- OBNCKNCVKJNDBV-UHFFFAOYSA-N ethyl butyrate Chemical compound CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 1
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920000070 poly-3-hydroxybutyrate Polymers 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 210000000697 sensory organ Anatomy 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses a completely biodegradable deodorant; the main ingredient of the completely biodegradable deodorant is polyhydroxyalkanoate. The deodorant disclosed by the invention can be used for decomposing toxic smelly gas such as hydrogen sulfide, methane and the like in sewers so as to remove odor when being added to municipal sewers; meanwhile, as the main raw materials is completely biodegradable, no pollution can be caused to the environment during deodorizing.
Description
Technical field
The present invention relates to deodorizer, more particularly, relate to a kind of fully biodegradable deodorizer.
Background technology
Odor pollution extensively is subject to the attention of various countries, is thought one of six large public hazards that are only second to noise by many countries.Particularly in the resident lavatory and the stench on the ground such as drain of kitchen, garbage disposal plant, plant, public lavatory had a strong impact on especially environment.The chemical substance of distributing foul odour mainly is divided into five classes by chemical composition: sulfur-containing compound such as hydrogen sulfide, thio-alcohol, thioether etc.; Nitrogen-containing compound such as ammonia, amide etc.; Halogen and derivant thereof such as chlorine, halogenated hydrocarbons; Hydro carbons such as alkane, alkene, aromatic hydrocarbon etc.; Oxygen-containing organic compound is such as alcohol, phenol, aldehyde, ketone etc.
International and domestic deodorizer commonly used mainly contains at present: several large series products such as natural plant liquid deodorizer, biological deodorant, fragrant and deodorizing agent, macromolecular deodorizer, activated charcoal deodorants.Wherein natural plant liquid deodorizer, fragrant and deodorizing agent, activated charcoal deodorants belong to spreadability deodorizer, also namely do not eliminate stink, but add in the spice in stink and stink, make it to reduce from sense organ the impact of stink.Biological deodorant is reactive deodorizer, principle is biological bacteria and the combination of deodorization molecule, reacts to reach deodorizing effect, but this deodorizer need to be concentrated gas extraction system, and microorganism fungus kind has requirement to ambient temperature, activity decreased when temperature is low in the winter time, deodorizing effect descends.Macromolecular deodorizer is absorption degradation type deodorizer, its principle is after relying on flocculation ability with the deodorization Molecular Adsorption, the effective ingredient degraded odorant pollutant of recycling in the deodorizer is reaching the purpose of deodorization, but general macromolecular deodorizer can produce pollution again to environment.
Summary of the invention
For overcoming above-mentioned technological deficiency, concentrate on studies through the people of the invention of this patent, a kind of fully biodegradable deodorizer is proposed.
Its technical scheme is as described below: a kind of fully biodegradable deodorizer, described deodorizer contains PHA.
Described PHA is any one or a few the mixture among PHBV, PHBH, P3HB4HB, PHBP, the PHO, described PHBV, PHBH, P3HB4HB, PHBP, PHO refer to respectively PHBV, poly--the 3-hydroxybutyrate ester-altogether-3-hydroxycaproic ester, poly--3-hydroxybutyrate ester-4 hydroxybutyric acid ester, poly butyric ester propionic ester, poly-Hydroxycaprylic acid ester.
Described deodorizer also contains antibacterial and other auxiliary agents.
Described antibacterial is two hot guanidinesalts, imazalil, spy one or more mixture in can be how.
Described other auxiliary agents are one or more mixture in starch, Pulvis Talci, calcium carbonate, Calx, Gypsum Fibrosum, montorillonite clay, Kaolin, shepardite, wood powder, straw, bentonite, flyash, conch meal, the carapace powder.
PHA, antibacterial and other auxiliary agent parts by weight are 100 in the described deodorizer: 0.5-15: 10-100..
PHA, antibacterial and other auxiliary agent parts by weight are 100 in the described deodorizer: 5-15: 50-100..
The invention also discloses the application of above-mentioned fully biodegradable deodorizer in municipal sewage system.
The invention also discloses the application of above-mentioned fully biodegradable deodorizer in refuse landfill.
The injected volume of deodorizer of the present invention in sewer and refuse landfill is 1-10000ppm, is preferably 100-1000ppm.Deodorizer of the present invention also can be prepared as powder or pellet.
In the present invention, because the primary raw material of deodorizer is PHA, combine the advantage of biological deodorant and macromolecular deodorizer, join in the sewers such as lavatory, kitchen and can decompose poisonous odorous gas such as the hydrogen sulfide in lavatory and the drain of kitchen, methane, to remove stench; Added simultaneously other auxiliary components, played slow releasing function, so that the effect of deodorizer can be continued; Simultaneously primary raw material of the present invention all is can complete biodegradable, can not pollute environment in deodorization again.
The specific embodiment
The below will the present invention is described in detail by specific embodiment.
Embodiment 1:
P3HB4HB (the 4HB content of monomer is 15%) is prepared into powder to be put in kitchen and the lavatory drain.
Embodiment 2:
PHBV (the HV content of monomer is 12%) is prepared into pellet to be put in kitchen and the lavatory drain.
Embodiment 3:
To contain P3HB4HB (the 4HB content of monomer is 12%): the antibacterial imazalil: the Pulvis Talci=deodorizer of preparation in 100: 10: 50 is made powder and is put in kitchen and the lavatory drain.
Embodiment 4:
To contain PHBH (the HH content of monomer is 15%): the two hot guanidinesalts of antibacterial: the calcium carbonate=deodorizer of preparation in 100: 5: 40 is made powder and is put in the soot.
Embodiment 5:
To contain PHO makes powder and puts in the soot.
Embodiment 6:
To contain PHBH (the HH content of monomer is 15%): the antibacterial spy can be many: the montorillonite clay=deodorizer of preparation in 100: 15: 100 is made powder and is put in the soot.
After 5 days the deodorizing effect in above-described embodiment is tested, stench alleviates a lot.
In sum, but the present invention is not limited to above-mentioned embodiment, and persons skilled in the art are in the disclosed technical scope of the present invention, and the variation that can expect easily is all within protection scope of the present invention.
Claims (9)
1. fully biodegradable deodorizer, it is characterized in that: described deodorizer contains PHA.
2. fully biodegradable deodorizer as claimed in claim 1 is characterized in that: described PHA is any one or a few the mixture among PHBV, PHBH, P3HB4HB, PHBP, the PHO.
3. fully biodegradable deodorizer as claimed in claim 1 is characterized in that: described deodorizer also contains antibacterial and other auxiliary agents.
4. fully biodegradable deodorizer as claimed in claim 3 is characterized in that: described antibacterial is two hot guanidinesalts, imazalil, spy one or more mixture in can be how.
5. fully biodegradable deodorizer as claimed in claim 3, it is characterized in that: described other auxiliary agents are one or more mixture in starch, Pulvis Talci, calcium carbonate, Calx, Gypsum Fibrosum, montorillonite clay, Kaolin, shepardite, wood powder, straw, bentonite, flyash, conch meal, the carapace powder.
6. fully biodegradable deodorizer as claimed in claim 3, it is characterized in that: PHA, antibacterial and other auxiliary agent parts by weight are 100 in the described deodorizer: 0.5-15: 10-100.
7. fully biodegradable deodorizer as claimed in claim 6, it is characterized in that: PHA, antibacterial and other auxiliary agent parts by weight are 100 in the described deodorizer: 5-15: 50-100.
8. such as the application of the described fully biodegradable deodorizer of claim 1-7 any one in municipal sewage system.
9. such as the application of the described fully biodegradable deodorizer of claim 1-7 any one in refuse landfill.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103796004A CN102921028A (en) | 2012-10-09 | 2012-10-09 | Completely biodegradable deodorant and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103796004A CN102921028A (en) | 2012-10-09 | 2012-10-09 | Completely biodegradable deodorant and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102921028A true CN102921028A (en) | 2013-02-13 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012103796004A Pending CN102921028A (en) | 2012-10-09 | 2012-10-09 | Completely biodegradable deodorant and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102921028A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104984993A (en) * | 2015-07-10 | 2015-10-21 | 武汉钢铁(集团)公司 | Deodorizer for organic pesticide-polluted soil as well as preparing method and application of deodorizer |
| CN111978614A (en) * | 2020-08-11 | 2020-11-24 | 青岛周氏塑料包装有限公司 | Antibacterial and deodorant plastic for garbage can and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20070056173A (en) * | 2005-11-29 | 2007-06-04 | 신꼬오 아크텍 가부시끼가이샤 | Deodorant |
| CN101263828A (en) * | 2008-04-30 | 2008-09-17 | 浙江林学院 | Disinfection antistaling agent containing vinegar liquid for plant and uses thereof |
| CN101928069A (en) * | 2009-06-19 | 2010-12-29 | 深圳市意可曼生物科技有限公司 | Sewage purifier and sewage purification method |
-
2012
- 2012-10-09 CN CN2012103796004A patent/CN102921028A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20070056173A (en) * | 2005-11-29 | 2007-06-04 | 신꼬오 아크텍 가부시끼가이샤 | Deodorant |
| CN101263828A (en) * | 2008-04-30 | 2008-09-17 | 浙江林学院 | Disinfection antistaling agent containing vinegar liquid for plant and uses thereof |
| CN101928069A (en) * | 2009-06-19 | 2010-12-29 | 深圳市意可曼生物科技有限公司 | Sewage purifier and sewage purification method |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104984993A (en) * | 2015-07-10 | 2015-10-21 | 武汉钢铁(集团)公司 | Deodorizer for organic pesticide-polluted soil as well as preparing method and application of deodorizer |
| CN111978614A (en) * | 2020-08-11 | 2020-11-24 | 青岛周氏塑料包装有限公司 | Antibacterial and deodorant plastic for garbage can and preparation method thereof |
| CN111978614B (en) * | 2020-08-11 | 2022-11-29 | 青岛周氏塑料包装有限公司 | Antibacterial and deodorant plastic for garbage can and preparation method thereof |
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