CN102500599B - Deodorizing environment induction material - Google Patents

Deodorizing environment induction material Download PDF

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Publication number
CN102500599B
CN102500599B CN201110334991.3A CN201110334991A CN102500599B CN 102500599 B CN102500599 B CN 102500599B CN 201110334991 A CN201110334991 A CN 201110334991A CN 102500599 B CN102500599 B CN 102500599B
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acid
parts
deodorizing
induction material
environment induction
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CN102500599A (en
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朱守诚
武艳
漆静秋
褚维发
程世林
杨宏星
刘焕霞
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HEFEI DONGFANG MEIJIE MOLECULE MATERIAL TECHNOLOGY Co Ltd
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HEFEI DONGFANG MEIJIE MOLECULE MATERIAL TECHNOLOGY Co Ltd
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Abstract

The invention discloses deodorizing environment induction material, prepared from the following raw materials in parts by weight: 1-30 parts of non-volatile organic acid, 0.5-10 parts of non-volatile salt, 1-5 parts of oxidizer, 0.1-30 parts of other organic matter, 0.1-5 parts of complexing agent and 0.5-30 parts of adsorbing material. The deodorizing environment induction material disclosed by the invention can be directly mixed with odour source organic matter to rapidly induce and activate genetically engineered microorganism beneficial bacteria in a short time to propagate quickly, thus growth of spoilage bacteria is inhibited, and rapid odourless conversion of organic matter is realized by natural yarding; and the deodorizing environment induction material disclosed by the invention has low cost, obvious effect, convenience in application, wide application range, environmental friendliness and no secondary pollution, is easy to popularize and implement and is a simple, rapid, practical and environmentally friendly deodorizing induction material.

Description

A kind of deodorizing environment induction material
One, technical field
The present invention relates to a kind of deodorizing environment induction material, for eliminating human and animal excreta, garbage loading embeading factory, meat packing, blue-green algae, mud and sludge, leather eider down wool real silk processing factory effluvial waste, belong to ecological environment treatment and pollute reparation field of purification.
Two, background technology
Occurring in nature almost every kind of material all has specific scent, and organic matter, the inorganic matter that in environment, can produce smell are numerous.Human and animal excreta, house refuse, sewage disposal mud, lake river silt, blue-green algae putrefaction, the protein Deng Chou source material that rots that goes mouldy, under uniform temperature damp condition, excessive multiplication due to putrefactive microorganisms, promote that organic matter rots to transform, produce the foul gas such as ammonia, hydrogen sulfide, thioether, indoles, mercaptan, constantly discharge diffusion, cause air pollution.
Foul gas mainly can be divided into five classes by chemical composition: 1. sulfur-containing compound, as hydrogen sulfide, sulfur dioxide, mercaptan, thioether; 2. nitrogen-containing compound, as amine, acid amides, indoles; 3. halogen and derivative, as chlorine, halogenated hydrocarbons; 4. hydro carbons: alkane, alkene, alkynes, aromatic hydrocarbon; 5. oxygen-containing organic compound, as alcohol, phenol, aldehyde, ketone, organic acid etc.
According to the concrete condition of China, intend adopting 6 grades of odor strengths to represent (according to Japan central public hazards countermeasure review conference, authorizing the regulation odorant passing through and the method for setting stench critical field 1973 Mays at noon), in Table 1.
6 grades of representations of table 1 odor strength
In the Nature, microbial action mainly can be divided into corrupt and regeneration two general orientation, if putrefactivebacteria has accounted for advantage, the system corruption of will festering, produces odorous gas.If beneficial bacterium is dominant, system just tends to optimum conversion, odorless regeneration.The organic accumulations such as organic waste, mud, human and animal excreta are one and are conducive to the environment that spoilage organisms grows, and spoilage organism often produces with foul gas in transportation, stacking process.In atmosphere, people is difficult for accepting stink the formations such as environment, health is had a strong impact on, and must effectively control or transform.
The method of processing foul smell has the methods such as soda acid absorbs, chemistry is covered, chemisorbed, catalytic combustion, microbial deodorization conventionally.Though these deodorizing methods have certain effect, but owing to only having applied single deodorization technology, can not reduce foul gas new in anoxic composting treatment process and produce or can not effectively remove all kinds of house refuse stench foul smell, can not accelerate composting treatment process and shorten the production cycle.
Three, summary of the invention
The present invention aims to provide a kind of for eliminating the deodorizing environment induction material of human and animal excreta, garbage loading embeading factory, meat packing, blue-green algae, mud and sludge, leather eider down wool real silk processing factory effluvial waste, technical problem to be solved is engineered microbes beneficial bacterium fast breeding in induction organic waste, the growth and breeding that suppresses spoilage organisms, thereby shorten the transformation period of organic waste, improve the value of converted product.
Environment-induced material refers to and can change environmental system soda acid pH value, C/N ratio, regulating microelement structure, promote the material of engineered microbes beneficial bacterium algae Fast Growth propagation, environment-induced material can obviously suppress the growth of spoilage organisms algae, is conducive to ecological conversion of organic matter and clears up.
In organic matter conversion process, the adjustable conversion environment of environment-induced material, by diffusing and penetrate into organic matter surface, rapidly deactivation activate the fast breeding of engineered microbes beneficial bacterium, suppress the growth of spoilage organisms simultaneously, reduce growing of fly mosquito, to element bio-transformations such as sulphur, nitrogen in organic matter conversion process, it is amino acid micromolecular, stop sulfur-bearing, nitrogen class volatility foul smell (ammonia, hydrogen sulfide, thioether, indoles, mercaptan) to form, having the good smelly deodorization effect that presses down, is that a kind of cost is low, conversion is fast, ecological efficient safe material.
Thinking of the present invention be by the organic matter of Chou source, add can induced environment in the environment-induced material of engineered microbes beneficial bacterium fast breeding, thereby suppress the growth of spoilage organisms, Shi Chou source material rapid conversion, fundamentally suppresses and eliminates the generation of various odorous gas.
Technical solution problem of the present invention adopts following technical scheme:
The feature of deodorizing environment induction material of the present invention is that its raw material is configured to by mass fraction:
Not volatile organic acid 1-30 part, is difficult for sal volatile 0.5-10 part, oxidant 1-5 part, other organic matters 0.1-30 part, complexing agent 0.1-5 part, sorbing material 0.5-30 part;
Described not volatile organic acid is selected from one or more in tannic acid, synthetic tannic acid, citric acid, tartaric acid, malic acid, humic acid, sulfamic acid; If when multiple, ratio is any;
The described sal volatile that is difficult for is selected from one or more in magnesium sulfate, zinc sulfate, copper sulphate, magnesium silicate; If when multiple, ratio is any;
Described oxidant is selected from one or more in potassium permanganate, manganese dioxide, hydrogen peroxide, ferrous sulfate; If when multiple, ratio is any;
Described other organic matters are selected from one or more in sodium humate, gaultherolin, polyacrylamide (PAM), polyacrylic acid (PAA) (molecular weight 2000-5000), pyridine; If when multiple, ratio is any;
Described complexing agent is selected from one or more in zinc oxide, calcium oxide, nano silicon oxide; If when multiple, ratio is any;
Described sorbing material is selected from one or more in bentonite, concave convex rod, active carbon, borax, zeolite; If when multiple, ratio is any.
The feature of deodorizing environment induction material of the present invention is also: described not volatile organic acid is humic acid and/or citric acid, if ratio is any two kinds time.
The feature of deodorizing environment induction material of the present invention is also: the described sal volatile that is difficult for is magnesium silicate.
The feature of deodorizing environment induction material of the present invention is also: described other organic matters are sodium humate and/or polyacrylic acid, if ratio is any two kinds time.
Deodorizing environment induction material of the present invention can be for eliminating the stench of human and animal excreta, garbage loading embeading factory, meat packing, blue-green algae, mud and sludge, leather, eider down, wool and real silk processing factory discarded object.
The using method of deodorizing induced material of the present invention is as follows:
Deodorizing environment induction material dilute with water 10-50 prepared by the present invention doubly, be sprayed onto the surface of smelly source organic pollution and be uniformly mixed, nature lucifuge is stacked and can be activated rapidly engineered microbes beneficial bacterium fast breeding, stop corrupt foul smell to produce, also can stack pond face covering immersion straw screen or mat prevention excessive vaporization; The 0.1-1% of the addition Wei Chou source organic pollution quality of deodorizing environment induction material.
Compared with the prior art, beneficial effect of the present invention is embodied in:
Deodorizing environment induction material of the present invention directly Yu Chou source organic matter mixes, rapid induction activate engineered microbes beneficial bacterium fast breeding at short notice, suppress the growth of spoilage organisms, by naturally banking up, realizing organic quick odorless transforms, the ecological path for transformation of induction organic matter, produce amino acid, organic acid, polysaccharide, the benefit materials such as various vitamin and organized enzyme, the generation and the release that significantly reduce or stop organic matter to bank up all kinds of foul gas in process completely, beneficial bacterium metabolin prevents that mosquitos and flies reproductive hormone from generating, it can not be bred by normal growth, reduce growing of mosquito, suppress the growth that harmful microorganism comprises all kinds of pathogens, reduce the generation of communicate illness, guarantee is subject to organic waste pollution district's ecological environment and near residents ' health.
Deodorizing environment induction material of the present invention is with low cost, and effect is remarkable, use conveniently, and wide application, environmentally friendly, do not produce secondary pollution, be easy to extensive promotion and implementation, be a kind of deodorizing induced material of simple and efficient Practical environmental protection.
Four, the specific embodiment
Below in conjunction with specific embodiment, the present invention is further analyzed and described.
Embodiment 1: smelly for blue algae Fender
The present embodiment deodorizing environment induction material is constructed as follows by mass fraction:
0.5 part, tannic acid, 0.5 part of synthetic tannic acid, 0.5 part of humic acid, 0.5 part, tartaric acid, 0.3 part, zinc sulfate, 0.2 part of magnesium silicate, 1 part, ferrous sulfate, 0.5 part of sodium humate, 0.1 part of polyacrylic acid PAA (molecular weight 3500), 0.4 part, zinc oxide, 1 part, calcium oxide, 2 parts of concave convex rods, 1 part of active carbon, 1 part of borax, 0.5 part of polyacrylamide PAM.
Embodiment 2: for the deodorizing of pig ox excrement of animals
The present embodiment deodorizing environment induction material is constructed as follows by mass fraction:
0.5 part of synthetic tannic acid, 0.5 part of citric acid, 0.5 part, zinc sulfate, 2 parts of magnesium silicates, 1 part, potassium permanganate, 0.5 part, ferrous sulfate, 1.5 parts of sodium humates, PAM0.5 part, 0.1 part of nano silicon oxide, 0.4 part, calcium oxide, 0.5 part, zinc oxide, 0.5 part, zeolite, 0.5 part of borax, 1 part of concave convex rod.
Embodiment 3: for house refuse deodorizing
The present embodiment deodorizing environment induction material is constructed as follows by mass fraction:
0.5 part, tartaric acid, 0.5 part of sulfamic acid, 0.02 part, zinc sulfate, 2.5 parts of magnesium silicates, 2 parts of sodium humates, 0.04 part of gaultherolin, 0.1 part, zinc oxide, 0.04 part of nano silicon oxide, 0.5 part of borax, 0.2 part, zeolite, 0.6 part of bentonite, 2 parts of attapulgites, 1 part of active carbon.
Embodiment 4: for mud sludge deodorization
The present embodiment deodorizing environment induction material is constructed as follows by mass fraction:
0.5 part of malic acid, 0.5 part of citric acid, 2.5 parts of magnesium silicates, 0.5 part, potassium permanganate, 0.5 part, hydrogen peroxide, 2 parts of sodium humates, 0.1 part of gaultherolin, 0.5 part, zinc oxide, 0.1 part of nano silicon oxide, 0.3 part, zeolite, 0.5 part of bentonite, 1 part of attapulgite, 1 part of active carbon.
Embodiment 5: for leather protein deodorizing
The present embodiment deodorizing environment induction material is constructed as follows by mass fraction:
0.5 part of citric acid, 0.5 part, tartaric acid, 0.4 part of sulfamic acid, 0.2 part, magnesium sulfate, 0.1 part, zinc sulfate, 0.1 part, copper sulphate, 0.6 part of magnesium silicate, 2 parts of sodium humates, 1 part, potassium permanganate, 0.5 part of gaultherolin, 0.1 part of PAM, 0.5 part, zinc oxide, 1.5 parts of bentonites, 1 part of concave convex rod, 1 part of active carbon.
The using method of environment-induced material of the present invention is as follows:
10 times of deodorizing induced material dilute with waters prepared by the present invention, are sprayed onto the surface of smelly source organic pollution and are uniformly mixed, and natural lucifuge is stacked, and also can cover immersion straw screen or mat at stacking pond face and stop excessive vaporization; The 0.1-1% of the addition Wei Chou source organic pollution quality of induced material.
The deodorizing effect of deodorizing environment induction material prepared by embodiment of the present invention 1-5 sees the following form:
Figure BDA0000103331500000041
Figure BDA0000103331500000051
As can be seen from the table, the smelly source Substance Transformation time of having added induced material shortens greatly, within 3 days, can realize odorless transforms, stink grade becomes 2 grades without obvious stink from 5 grades of stenches, pH maintains between 6~10, and C/N increases than along with the increase of induced material addition, more suitable beneficial microorganism propagation ,Chou source material appearance luster gradually becomes grey black or black.

Claims (4)

1. a deodorizing environment induction material, is characterized in that its raw material is configured to by mass fraction:
Not volatile organic acid 1-30 part, is difficult for sal volatile 0.5-10 part, oxidant 1-5 part, other organic matters 0.1-30 part, complexing agent 0.1-5 part, sorbing material 0.5-30 part;
Described not volatile organic acid is selected from one or more in tannic acid, synthetic tannic acid, citric acid, tartaric acid, malic acid, humic acid, sulfamic acid;
The described sal volatile that is difficult for is selected from one or more in magnesium sulfate, zinc sulfate, copper sulphate, magnesium silicate;
Described oxidant is selected from one or more in potassium permanganate, manganese dioxide, hydrogen peroxide, ferrous sulfate;
Described other organic matters are selected from one or more in sodium humate, gaultherolin, polyacrylamide, polyacrylic acid, pyridine;
Described complexing agent is selected from one or more in zinc oxide, calcium oxide, nano silicon oxide;
Described sorbing material is selected from one or more in bentonite, concave convex rod, active carbon, borax, zeolite.
2. deodorizing environment induction material according to claim 1, is characterized in that: described not volatile organic acid is humic acid and/or citric acid.
3. deodorizing environment induction material according to claim 1, is characterized in that: the described sal volatile that is difficult for is magnesium silicate.
4. deodorizing environment induction material according to claim 1, is characterized in that: described other organic matters are sodium humate and/or polyacrylic acid.
CN201110334991.3A 2011-10-28 2011-10-28 Deodorizing environment induction material Expired - Fee Related CN102500599B (en)

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CN105211099A (en) * 2015-10-14 2016-01-06 文雪烽 A kind of bactericidal disinfectant material
CN105384516B (en) * 2015-11-12 2019-02-12 北京建筑材料科学研究总院有限公司 A kind of co-induction agent and its application method for kitchen waste compost deodorization
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CN107252613A (en) * 2017-07-27 2017-10-17 嘉兴市九分钟生物科技有限公司 It is a kind of to remove ammonia and the material for air purification of deodorization and preparation method thereof
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CN112645551A (en) * 2020-11-18 2021-04-13 河南宏景建筑工程有限公司 Community living excrement treatment method
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CN113387523B (en) 2021-04-26 2022-07-29 福州大学 Method for removing sludge odor by metal salt synergistic tannin extract, deodorized sludge and application thereof
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CN101658680A (en) * 2009-10-09 2010-03-03 李晓鲁 Medical environment-friendly sterilization ultrasound coupling agent and preparation method thereof

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