KR20190072709A - Industrial deodorant to remove harmful gas and odor - Google Patents

Abstract

The present invention relates to an industrial deodorant for removing harmful gas and odor and, more specifically, to an industrial deodorant for removing harmful gas and odor comprising: 0.01 to 3 wt% of a functional active material; 0.02 to 5 wt% of a lipophilic fluid; 0.01 to 1 wt% of a surfactant; 0.02 to 1.5 wt% of a proton (hydrogen ion) emitting material; 0.01 to 1 wt% of a material having an anion dissociating group; and 88.5 to 99.93 wt% of an active water dissolved with active gas. Therefore, a manufactured mixture of the present invention is injected to harmful gas and odor-inducing pollutants generated in a manufacturing process of each industry and to odor-inducing pollutants generated in an organic fertilizer manufacturing process using poultry manure, livestock manure, sawdust and microorganisms, livestock breeding facilities and the like, thereby removing the odor-inducing pollutants by oxidation due to hydroxyl groups of a functional active material, dissolution of lipophilic pollutants due to a lipophilic fluid, reduction due to a proton emitting material, and an anion dissociation due to a material having an anion dissociating group, and then reducing the concentration of odor.

Description

{Industrial deodorant to remove harmful gas and odor}

The present invention relates to an industrial deodorant for removing harmful gases and odors, and more particularly, to an industrial deodorant for removing harmful gases and odors, and more particularly, to an industrial deodorant for removing toxic gases and odors, The mixture prepared by adding, stirring, and mixing a substance having a lipophilic fluid, a proton (H ⁺ ) releasing substance, and an anion dissociating group dissolving a substance, a lipophilic pollutant is mixed with harmful gas and odor generated in the manufacturing process of each industry It is sprayed on the odor pollutants generated from pollutants, stones, organic matter fertilizer manufacturing process using sawdust and microorganisms, and animal husbandry facilities, so that oxidative action by the hydroxyl groups of the functional active materials and lipophilic pollutants caused by lipophilic fluids Solubilization, reduction by proton-emitting materials, dissociation of anions by substances with anion-dissociating groups, Noxious gas and odor to the distilled to reduce the odor concentration relates to industrial deodorants.

Generally speaking, according to the definition of the term "odor prevention method", hydrogen sulfide, mercaptans, amines, and other irritating gaseous substances stimulate the smell of a person, thereby defining an odor that gives offensive and repulsive feelings. It is defined as a smell that gives offensive and repulsive effects by stimulating the smell of people by acting together with odorous substances of more than two kinds. Specified odor substances are substances causing odor such as ammonia, methyl mercaptan, hydrogen sulfide, dimethyl sulfide, Butyraldehyde, n-valer aldehyde, I-valder aldehyde, toluene, xylene, methyl ethyl ketone, methyl isobutyrate ketone, isopropyl alcohol, Propionic acid, n-butyric acid, n-valeric acid, i-butyric acid, and i-butyroalco. And strict acceptance criteria are set and managed.

On the other hand, various methods for removing odor substances or reducing odor concentration have been proposed. Commercial techniques to remove odorous substances can be divided into adsorption method, decomposition method, and microorganism method. The adsorption method uses an organic system of activated carbon or activated carbon fiber, a physical adsorption method using an inorganic system such as zeolite, Chemical adsorption method.

In addition, the decomposition method includes a method of ozone oxidation using ozone or an ultraviolet lamp, a catalyst oxidation method using a catalyst-bearing porous ceramic or plasma, an ozone catalytic oxidation method combining ozone generation and catalytic oxidation, a combustion method using direct combustion and catalytic combustion, A microbial method for removing odorous substances during microbial metabolism during the process of supporting microbes and passing polluted air containing odorous substances between carriers carrying microbes is applied to the removal of odorous substances, This is a way to build complex and large installations.

As another method for removing odor substances or reducing the odor concentration, various deodorant compositions such as transition metals capable of removing odor substances in water, natural deodorants such as Omiza extract, or addition of catalyst materials have been disclosed.

Korean Patent No. 10-1009480 discloses a catalytic deodorizing block. 10 to 80% by weight of fragrance oil, 10 to 80% by weight of a malodor neutralizing agent and 0.1 to 10% by weight of propylene glycol are supported on the porous block made of catalytic deodorizing block polyethylene and glass fiber and optionally containing activated carbon, Block, it is possible to omit the pretreatment and post-treatment steps, and when combined with other deodorizing apparatus, the volume can be remarkably reduced, but the fragrant oil contains all of the natural fragrance oil, the artificial fragrance oil and the chemical synthetic fragrance These fragrance oils have the disadvantage of increasing the odor concentration when analyzing the odor concentration by the sensory method although the odor specific to the process can be reduced by the masking effect.

Korea Patent No. 10-664882 A biofilter media composition for deodorization comprises 55 to 70 parts by weight of granular porous expanded clay having a particle size of 2 to 10 mm, 15 to 25 parts by weight of crushed porous expanded clay having a particle size of 2 to 10 mm, 3 to 5 parts by weight of a hydrophilic zeolite having a particle size of 1 to 3 mm and a capacity of 3 to 12 parts by weight of a 10% by weight Fe / MgO catalyst, and 10 to 20 parts by weight of a breathable mixed compost. And has a porosity of 18 to 23%, and has a low porosity of 18 to 23% as a filter media for deodorization, and is excellent in the deodorization effect, and the microorganisms supported on the filter media do not disappear but grow soundly It is possible.

Korean Patent Laid-Open Publication No. 2003-0014052 discloses a natural deodorant composition comprising a culture medium of a microorganism group composed of Bacillus sp. Bacteria, which has excellent organic decomposing ability and endogenous spores, a wood vinegar extracted from natural plants, a small amount of fragrance and purified water, It also has the advantage of having continuous and effective deodorizing ability and also having excellent antimicrobial action against the pathogenic bacteria by complementing the disadvantages of the single natural deodorant.

U.S. Patent No. 4,996,055 discloses a composition for a deodorant composed of a mixture of microbial bacteria and microbes, which is a microorganism group that does not use chemical materials, and discloses a deodorant composition using Miyari bacteria as a nitric acid bacteria and Natto bacteria and Bacillus as super- .

Korean Patent No. 10-336006 discloses a solid deodorant composition containing at least one deodorizing active ingredient and a mixture of waxes having a melting point of more than 80 DEG C both as coagulants.

Korean Patent No. 421707 discloses a deodorizing and antibacterial composition composed of an oxide or hydroxide of an alkaline earth metal, hydrated silicic acid, and a cationic surfactant.

Korean Patent No. 724288 discloses a resin composition highly effective for deodorization and deodorization by commercializing activated carbon or a mixture of titanium oxide and zinc oxide.

However, these materials have a very low vapor-liquid contact efficiency between the liquid deodorant to be sprayed and the polluted air containing odorous substances, and the deodorization efficiency is also low, so that it is difficult to handle the odor generated at a high concentration in the industrial field, and various preprocessing such as scrubber or adsorption tower There is a problem that a post-processing apparatus is required and a large-scale processing apparatus is required.

Accordingly, there is a continuing need for the development of a deodorant with a new composition capable of enhancing the gas-liquid contact efficiency between the liquid deodorant and the polluted air containing odorous substances, thereby promoting the deodorizing effect in the deodorization process.

Disclosure of Invention Technical Problem [8] Accordingly, the present invention has been made keeping in mind the above problems occurring in the prior art, and an object of the present invention is to provide a water- The mixture prepared by adding, stirring and mixing a lipophilic fluid, a proton (H ⁺ ) releasing substance, and an anion dissociating material, which dissolve oily pollutants, is mixed with harmful gas and odor- It has been found that the oxidative action of hydroxyl groups of functional active materials, the dissolution of lipophilic pollutants by lipophilic fluids, and the protonation of lipophilic substances by spraying on stench-inducing contaminants such as straws, fodder, organic fertilizer manufacturing process using sawdust and microorganisms, Reducing effect by emissive material, dissociation by anion dissociation by substance having anion dissociation group, To provide a harmful gas and odor industrial deodorizer capable of reducing the concentration will in this purpose.

In order to achieve the object of the present invention, the deodorant for the harmful gas and odor removing industry according to the present invention comprises 0.01 to 3% by weight of the total amount of the functional active material, 0.02 to 5% by weight of the lipophilic fluid, (Proton (hydrogen ion) releasing substance in an amount of 0.02 to 1.5% by weight, a substance having an anion dissociating group in an amount of 0.01 to 1% by weight, an active gas-soluble active water in an amount of 0.01 to 1% And is composed of 88.5% by weight to 99.93% by weight of the total weight.

The functional active material of the present invention may be selected from the group consisting of carboxaldehyde having one or more hydroxyl groups, isoborneyol, 3-isocamphylcyclohexanol, 2-isopropenyl-5-methylcyclohexanol (isoprene) Isopropylcyclohexanol, isopropyl-4-methylcyclohex-3-enol (terpinenol), 4-isopropylcyclohexanol, 1- (4-isopropylcyclohexyl) Methylphenol (menthol), 2-isopropyl-5-methylphenol (thymol), 5-isopropyl- 2- (4-methylcyclohexyl) -2-propanol (dihydroterpineol), 4-methoxybenzyl alcohol), 4- (5,5,6- Trimethylbicyclo (2,2,1) hept-2-yl) cyclohexan-1-ol, 3,5,5-trimethylcyclohexanol, 2,4,6-trimethyl- Methanol, 5- (2,2,3-trimethyl-3-cyclopentenyl) -3-methylpentan-2-ol, 3,7,11-trimethyl-2,6,10- (Nerolitol), 3,5,5-trimethyl-1-hexanol (isononanol), 1-undecanol, 10-undecen-1-ol, betibrole, Phenylethyl alcohol, and phenylethyl alcohol.

The lipophilic fluid of the present invention may be selected from the group consisting of siloxane, octamethylcyclotetrasiloxane, dodecamethyl-cyclohexasiloxane (hexamer), decamethylcyclopentasiloxane, and mixtures thereof, diols, polyol esters, propylene glycol methyl ether, propyl ether, dipropylene glycol n-butyl ether, propylene glycol n-butyl ether, tripropylene glycol methyl ether, tripropylene glycol-propyl ether, tripropylene glycol n-propyl ether, tripropylene Glycol ether groups such as glycol t-butyl ether and tripropylene glycol n-butyl ether, 2,3-bis (1,1-dimethylethoxy) -1-propanol as a glycerin derivative solvent, 1-methoxy-2-propanol, 2-isopropyl-5-methylcyclohexanol (menthol), carbonic acid (2-hydroxy-1-methoxymethyl) ethyl ester methyl ester, Any one selected from the group consisting of carbonates, methyl carbonate, ethylene carbonate, propylene carbonate, glycerin ether, hydrofluoric acid, ether solvent, low volatile nonfluorescent solvent, dimethyl acrylate, methyl carbonate, ethyl carbonate, ethylene carbonate, propylene carbonate and glycerin carbonate The above-mentioned materials are used.

The surfactant of the present invention includes an anionic surfactant, an amphoteric surfactant, and a nonionic surfactant, and the anionic surfactant includes an alkyl ether sulfonate, a glycerol ether sulfonate, a sulfo fatty acid compound, a fatty acid alcohol ether sulfate, From the group consisting of alkyl sulfates, alkyl sulfosuccinates, alkyl sulfosuccinates, ether sulfates, alkyl sulfosuccinates, ether sulfates, alkyl sulfosuccinates, ether sulfates, ether sulfates, Any one or more materials may be used, and the amphoteric surfactant may be selected from the group consisting of alkylaminopropylbetaine, alkylmonoamphoacetate, and alkylamphodiacetate, and the nonionic surfactant may be an alkylpoly Characterized in that at least one substance selected from the group consisting of alkylene glycol, alkylaryl polyalkylene glycol, alkyldimethylamine oxide, di-alkylmethylamine oxide, alkylaminopropylamine oxide, alkylglucamide and alkylamine is used .

The proton (hydrogen ion) emission material of the present invention may be at least one selected from the group consisting of a carboxyl group, a sulfate group, a phosphate group, a sulfate group, a phosphate group, a sulfoethyl group, a phosphomethyl group and a carbomethyl group, Acrylamido-2-methylpropanesulfonic acid, and vinylsulfonic acid, styrenesulfonic acid and salts thereof, and 2-acrylamido-2-methylpropanesulfonic acid.

The substance having an anion dissociation group of the present invention may be at least one selected from the group consisting of vinylbenzyltrimethylammonium salt, diethylaminoethyl methacrylate, dimethylaminoethyl acrylate, dimethanoaminoethyl methacrylate, diethylaminoethyl acrylate, diethylaminomethyl methacrylate Acrylamide, diethylenetriamine, monoethanolamine, diethanolamine, triethanolamine, diethanolamine, triethanolamine, triethanolamine, triethanolamine, triethanolamine, triethanolamine, N, N'-bis (methylene) bis (N, N-dibutylamine) N, N-dimethylacrylamide, N, N-dimethylaminoethyl acrylate and N, N-dimethylaminopropylacrylamide are used.

As described above, the technical problem to be solved in the present invention is to solve the technical problem of the present invention by dissociating the oxygen molecules O2 in the air into oxygen atoms O, dissociating the nitrogen molecules N2 into nitrogen atoms N by an electrochemical method of high- (H ⁺ ) and hydroxyl group (OH ^- ) to dissolve the active gas in the washing water, and the washing water is made into a small-sized active water, the deodorant and the odor It is possible to improve the liquid contact efficiency with the contaminated gas containing the substance and improve the absorption rate of the hydrophilic odorous substance to improve the deodorization efficiency.

In addition, the present invention can improve the deodorization efficiency by oxidation reaction between the active gas and the functional active substance containing hydroxyl groups in the small-sized, active water and harmful gas and odorous substances.

In addition, the present invention can improve the deodorization efficiency by dissolving lipophilic pollutants by the insoluble active gas and lipophilic fluid in the small-sized activated water.

In addition, the present invention can improve the deodorization efficiency by reducing the proton (H ⁺ ) released from the proton-emitting substance and the odorous substance.

In addition, the present invention can improve deodorization efficiency by ion dissociation reaction between a substance anion dissociation unit having an anion dissociation group and a malodorous substance.

Further, the present invention improves the gas-liquid interface with contaminated air containing odorous substances by the active gas and the surfactant in the small-grouped water and the contaminated air is captured in the micro-foam produced by the surfactant, Since the reaction proceeds, the deodorization efficiency can be improved.

1 is a conceptual diagram showing a process for manufacturing a deodorant for the noxious gas and odor removing industry according to the present invention.
FIG. 2 is a view illustrating an example of a high-voltage discharge system for generating active gas, which is the first stage of FIG. 1;
Fig. 3 is an example of a system for pressurizing the active gas, which is the second step in Fig. 1, to dissolve in water and to subdivide water molecules.
FIG. 4 is an exemplary view showing mixing and filtering steps of supplying and stirring an additive to the active water, which is the third step of FIG. 1;
5 is an exemplary view showing a control panel for controlling facilities according to the present invention.
6 is an exemplary view showing a spray tower as a test test equipment for evaluating the deodorizing performance of the deodorant manufactured by the present invention.

Hereinafter, the production of a deodorant for the noxious gas and odor removing industry of the present invention will be described with reference to the accompanying drawings, but the present invention is not limited to the embodiments shown in the drawings.

FIG. 1 is a conceptual view illustrating a process for manufacturing a deodorant for the noxious gas and odor removing industry according to the present invention. As shown in FIG. 1, the deodorant preparation step for the noxious gas and odor removing industry of the present invention is formed on a single shaft of an independent housing, And a fan 102 for forcibly introducing clean air at a distance from the pre-processing filter 101 is provided in the front portion of the pre- And the clean air introduced by the air fan 102 is transferred to the discharge electrode 111. The clean air is supplied to the discharge electrode 111a and the ground electrode 111a by the high voltage generated by the high voltage generator 120, ) 111b by decomposing the covalent bonds of the clean air molecules through an electrochemical reaction such as dissociation, ionization, excitation, oxidation, and reduction, and ionizing A first step of generating an active gas and supplying it to the dissolving tank 200 using the pressurizing units 131, 132 and 133; a first step of supplying the active gas to the dissolving tank 200 using the pressurizing units 131, 132 and 133; And a circulation line 220 in which a water molecule small-scale grouping mechanism is installed. In the circulation line 220, an ejector-type active gas dissolution head 221, which dissolves the active gas, The circulation pump 222 is installed on the suction side and the circulation pipe is branched by a certain distance from the circulation pump 222 on the pump discharge side and the electronic toes 223 and 224 are installed in the branched pipes , And a water molecular small-scale grouping mechanism 225 spaced a certain distance, and the number of times corresponding to 88.5% by weight to 99.97% by weight of the total weight portion of the melting vessel body is opened and closed by the measurement value of the water level detecting sensor The active water is filled, The activated gas generated from the gas generator is pressurized by the air pump and is injected into the air intake pipe and injected into the water to partially dissolve the activated gas which is insufficiently sucked into the pump by the circulation pump, The water molecules are submerged into a small molecule pelletizing unit having a structure in which a plurality of pellets of fine pores provided on the pump discharge side are laminated, and a plurality of inflow pellets are passed through the fine pores of the pellet, A stirrer 302, an electric heater 303, a vent pipe 304, a sludge discharge pipe 305, a temperature detection sensor 305, and a temperature detection sensor 305. The second step is to produce activated water by atomizing the water molecules of the active water in which the active gas is dissolved and dissolved. A plurality of branch pipes of the main body 301 and the additive supply pipe 320 to which the water level sensor 340, the water level detection sensor 341, the active water supply pipe 310, the additive supply pipe 320, the product discharge pipe 330, A second storage tank 322 and an electronic foot 322a for storing the lipophilic fluid are provided in the other branch and a first storage tank 321 and an electronic foot 321a for storing substances are provided. A third storage tank 323 and an electron generating unit 323a are installed in the branch pipe and a fourth storage tank 324 and an electron generating unit 324a And a fifth storage tank 325 and an electronic toothed portion 325a in which a substance having an anion dissociation device is stored are installed in the other one of the first and second storage chambers 321 and 322. The transfer pump 331 and the transfer pump sucking and discharging An electronic toes 331a and 331b are provided in the piping and a filter housing 332 in which a filter is installed is provided with intervals therebetween and an electronic toes 332a are installed on a discharge tube at intervals from the filter housing 332 do.

First, when active water equivalent to 88.5% by weight to 99.97% by weight of the entire weight portion is supplied through the active water supply pipe 310, power is supplied from the control panel to the stirrer installed on the top of the main body, Is supplied to the mixer main body 301 through the additive supply pipe in an amount corresponding to 0.01 wt% to 5 wt% of the total weight of the functional active material having the hydroxyl group stored therein, and is melted by stirring for 10 minutes to 30 minutes, Is supplied to the mixer main body 301 through the additive supply pipe 320 by an amount corresponding to 0.02 wt% to 3 wt% of the total weight portion of the lipophilic liquid stored in the container 322, and is melted by stirring for 10 minutes to 30 minutes, The surfactant stored in the third storage container 323 is supplied to the mixer main body 301 through the additive supply pipe 320 by an amount corresponding to 0.01% by weight to 1% by weight of the total weight portion, stirred for 10 minutes to 30 minutes Dissolution And the substance releasing the protons stored in the fourth storage container 324 is supplied to the mixer main body 301 through the additive supply pipe 320 by an amount corresponding to 0.02 wt% to 1.5 wt% of the total weight portion, And the substance having an anion dissociation group stored in the fifth storage container 325 is added to the mixer main body 301 through the additive supply pipe 320 by an amount corresponding to 0.01 wt% to 1 wt% of the total weight portion, And a third step 300 of stirring the solution for 10 to 30 minutes to dissolve and then transferring the solution to a filter using a pump to remove foreign substances in the deodorizing solution.

FIG. 2 is a view illustrating an example of a high-voltage discharge system for generating active gas, which is the first stage of FIG. 1;

As shown in FIG. 2, the active gas generator 100 according to the present invention is formed in one side of an independent housing to receive external clean air, and the inlet of the active gas generator 100 has a pre- And a fan 102 is provided for forcibly introducing the purified air at a distance from the pre-processing filter 101. The clean air introduced by the air fan 102 is transferred to the discharge electrode 111 , A very high electric field energy is applied between the discharge electrode (+ electrode) 111a and the ground electrode (- electrode) 111b by applying the high voltage generated by the high voltage generator 120 to dissociate, ionize, , The reduction reaction, and the covalent bond of the clean air molecule is decomposed by an electrochemical reaction to generate an ionized active gas.

The discharge electrode 111 is connected to the discharge electrode (positive electrode) 111a, the ground electrode (negative electrode) 111b, and the discharge electrode (positive electrode) A permanent magnet 111c is attached to the rear surface of the discharge electrode (positive electrode) 111a, the ground electrode (negative electrode) 111b, and the discharge of the discharge electrode A combination of quartz, high purity alumina, a dielectric material of ceramic material (a negative electrode) 111b and a ground electrode (negative electrode) 111b is formed between a combination of the surface of which is coated with a catalyst material 111d such as TiO2, Or a combination in which any one of them is attached.

The discharge electrode 111a and the ground electrode 111b of the discharge electrode 111 are made of stainless steel (STS 304, (TiO2), platinum (Pt), manganese dioxide (MnO2), lithium hydroxide (LiOH), and lithium hydroxide (LiOH) to improve the discharge efficiency on the surface of the discharge electrode. Palladium (Pd), rhodium (Rh), or the like.

At this time, it is preferable that the discharge electrode 111 is located inside the selected cell 109 of insulating material such as PVC, PE, MC, bakelite, Teflon, FRP, ceramic sintered material, The diameter of the discharge electrode 111 and the size of the cell 109 are set to be within a range of 10 cm to 100 cm in the case of circular, double-tube, or multi-tubular shape so that the internal space of the cell 109 is minimized in order to densify the discharge density. It is desirable to increase the size in proportion to the volume.

The high voltage generator 120 is composed of a fixed type in which an input voltage, a frequency, and an output voltage are preset as appropriate values, a variable type in which an input voltage is fixed, and an output voltage, a frequency and a rated capacity are arbitrarily adjustable. (Ie, eV) capable of decomposing the covalent bond of oxygen molecule (OO2) in the air; An electric field electron energy (Ie, eV) capable of decomposing the covalent bond of the nitrogen molecule (N2) of 12.0857 eV or more; An electric field energy (Ie, eV) capable of decomposing the covalent bond of water molecules of not less than 15.58 eV; 12.621 eV or more.

Therefore, the high voltage generator 120 according to the present invention has a high voltage generator 120 in which the input side voltage is at least 12V DC, the alternating current voltage is at least 110V, the output voltage is at least one of DC voltage (AC) , And the output frequency (Hz) range is preferably in the range of 1 KHz to 500 KHz in the case of alternating current (AC).

To this end, the output voltage (V) of the high voltage generator 120 is in the range of 1 KV to 300 KV, the frequency is selected in the range of 1 KHz to 500 KHz, and the voltage and frequency are set. The rated capacity (W, A) A fixed high voltage generator arbitrarily selected as the capacity, or a variable high voltage generator capable of controlling voltage, frequency, and capacity can be used.

Since the pressure of the active gas generated by the active gas generator is insufficient to supply the active gas into the active gas dissolver by the pressure of the air fan 102 installed in the air intake tube, the pressurizer 130 is separated from the discharge electrode 111 by a certain distance And is supplied to the activated gas dissolving bath 201 after being sufficiently pressurized to inject the active gas into the interior of the dissolving tank.

Fig. 3 is an example of a system for pressurizing the active gas, which is the second step in Fig. 1, to dissolve in water and to subdivide water molecules.

3, the active water producing apparatus 200 according to the present invention includes a melting vessel body 201, a water supply pipe 202, an active gas supply pipe 210, a circulation pump 222, and a circulation line 220 .

In the circulation line 220, an ejector-type active gas dissolution head 221 for dissolving the active gas is installed on the suction side of the pump on the circulation line, a circulation pump 221 is installed at intervals, The water circulation pipe is branched to be spaced apart from each other and the branched water pipes 223 and 224 are installed in the branched pipes.

When the water is supplied to the melting tank 201 in an appropriate amount, the water level sensor 230 operates and the electromagnetic valve 203 And then the supply of water is stopped to stop the supply of water from the water supply tank 211. The pressure of the pressurizing pump 131 of the activated gas generator is then released to open the electronic feet 211 and 212 on the active gas supply pipe, Is supplied to the ejector-type dissolved head 221 provided at one side of the suction pipe of the circulation pump 222, while the active gas is injected into the water through the engine 213.

When the electronic pawl 223 of the circulation pipe 220 is opened and the circulation pump 222 is powered by the control panel 500 and activated, A plurality of holes having a pore diameter of 1 mm or less are punched in the dissolved head 221 during the process of passing through the ejector-type dissolved head 221 by the suction force of the piercing plate 202 The water molecules in the cleansing water are cleaved into fine molecules, and at the same time, the insoluble active gas is absorbed into the cleansing water by ultrafine bubble (micro size) cleavage and is dissolved first.

Subsequently, the active gas bubbles insoluble by the wing (not shown) of the circulating pump 222 rotating at a high speed are finely cleaved and dissolved secondarily, and the active gas is dissolved in the washing water by the pressing force generated by the pump, A plurality of holes having a pore diameter of not more than 1 mmm are supplied to the molecular small grouping mechanism 225 and the large water molecules are subdivided into fine water molecules while passing through the perforated plates laminated within 30 to 100 sheets, After the reflux process is continued for about 30 minutes to 1 hour, the electronic toes 211 and 212 of the active gas supply pipe 210 are turned off and closed, and then the power is turned off to the electronic toothed part 223 of the circulation pipe 220, The tube 220 is closed and power is supplied to the electron emitting portion 224 of the branch pipe to dissolve the active gas and the water molecules are broken into fine molecules to supply the cleaned water to the mixer 300.

FIG. 4 is an exemplary view showing mixing and filtering steps of supplying and stirring an additive to the active water, which is the third step of FIG. 1;

4, the mixer 300 according to the present invention includes a stirrer 302, an electric heater 303, a vent pipe 304, a sludge discharge pipe 305, a temperature detection sensor 340, An active water supply pipe 310, an additive supply pipe 320 and a product discharge pipe 330 in which a sensor 341 is installed.

A first storage tank 321 and an electronic foot portion 321a in which a functional active material is stored are installed in one branch of the additive supply pipe 320 and a second storage tank 322 And a third storage tank 323 in which a surfactant is stored and an electron emission portion 323a are provided in the other branch and a substance which emits a proton in the other branch is provided A fourth storage tank 324 and an electron emission unit 324a are installed and a fifth storage tank 325 and an electron emission unit 325a are installed in another branch so as to store a substance having an anion dissociation unit.

On the product discharge pipe 330, there are provided a feed pump 331 and electronic feed units 331a and 331b in the feed pump suction and discharge pipe, a filter housing 332 in which a filter is mounted, An electronic foot portion 332a is provided on the discharge tube at an interval from the housing 332. [

First, when electric power is supplied to the electric foot part 311 of the active water supply pipe 310 to open the electric foot part 311, the transfer pump 222 of the active water maker is activated, and the pre- .

The water level detection sensor 341 detects the water level and turns off the feed pump 222 and the electronic feet 224 and 310 to stop the supply of the active water and then supplies power to the electric heater 303 from the control panel 500 The temperature detection sensor 340 detects the temperature and transmits the detected data to the control panel 500 in real time and the control panel 500 controls the electric heater power source 303 ).

Next, power is supplied to the stirrer 302 in the control panel 500 to rotate the stirrer 302 at 30 to 60 rpm to open the electron emitting portion 321a of the branch pipe connected to the additive supply pipe 320, Isobornyl, isobornyl, 3-isocamphylcyclohexanol, 2-isopropenyl-5-methylcyclohexanol (isoprene), 1-isopropyl- 4-isopropylcyclohexylmethane, 4-methylcyclohex-3-enol (terpinenol), 4-isopropylcyclohexanol, 1- Methylphenol (menthol), 2-isopropyl-5-methylphenol (thymol), 5-isopropyl- Propanol (terpineol), 2- (4-methylcyclohexyl) -2-propanol (dihydroterpineol), 4-methoxybenzyl alcohol), 4- (5,5,6-trimethylbicyclo (2,2,1) hept-2-yl) cyclohexane- Trimethylcyclohexanol, 2,4,6-trimethyl-4-cyclohexen-1-ylmethanol, 5- (2,2,3-trimethyl-3-cyclopentenyl) Methylpentan-2-ol, 3,7,11-trimethyl-2,6,10-dodecatrien-3-ol (nerolitol), 3,5,5- Nonanol), 1-undecanol, 10-undecen-1-ol, betibellol, 2-phenoxyethanol and phenylethyl alcohol is selected and stored in a total weight of 0.01 The stirrer 302 is operated while opening the electron emitting portion 321a of the container 321 in which the functional active material is stored by an amount corresponding to 3 to 3% by weight and supplied to the mixer main body 301 by the gravity lag and stirred for 10 to 30 minutes Dissolve.

When the dissolution of the functional active material is completed, the second active ingredient is dissolved in the second storage tank 322 connected to the additive supply pipe 320, and the siloxane, octamethylcyclotetrasiloxane, dodecamethyl-cyclohexasiloxane (hexamer) Cyclopentasiloxane and mixtures thereof, diols, polyol esters, propylene glycol methyl ether, n-propyl ether, propylene glycol t-butyl ether, dipropylene glycol n-butyl ether, propylene glycol n-butyl ether, tripropylene glycol methyl ether , Glycol ether groups such as tripropylene glycol-propyl ether, tripropylene glycol n-propyl ether, tripropylene glycol t-butyl ether and tripropylene glycol n-butyl ether, glycerin derivative solvents such as 2,3- Propanol, 1-methoxy-2-propanol, 2-isopropyl-5-methylcyclohexanol (menthol), 2- (2-hydroxy-1-methoxymethyl) ethyl ester methyl ester, glycerol carbonate, methyl carbonate, ethylene carbonate, propylene carbonate, glycerin ether, hydrofluorine, ether solvent, low volatile nonfluorinated ester solvent, A lipophilic fluid containing any one or more substances from a substance such as methyl carbonate, ethyl carbonate, ethylene carbonate, propylene carbonate, glycerin carbonate, etc. is opened so that the electron emitting portion 322a of the additive supply pipe 320 is opened, %, The mixture is agitated for 10 to 30 minutes while being stirred by a moving stirrer and dissolved.

When the functional active material and the lipophilic fluid have been dissolved in the active water, the third container 323 connected to the additive supply pipe 320 may contain an alkyl ether sulfonate, a glycerol ether sulfonate, a sulfo fatty acid compound, (Ether) sulfate, mono or dialkyl sulfosuccinate, sulfotriglyceride, amide sulfoalkyl oligoglucoside sulfate, alkylamino sugarsulfate, and alkyl (ether) phosphate with ether sulfate, ether sulfate, At least one anionic surfactant selected from the group consisting of alkyl aminopropyl betaine, alkyl monoamphoacetate and alkyl amphodiacetate, or an alkyl polyalkylene glycol, alkylaryl Polyal At least one nonionic surfactant selected from the group consisting of alkylene oxide, alkylene oxide, alkylene oxide, alkylene oxide, alkylene oxide, alkylene oxide, alkylene oxide, alkylene oxide, alkylene oxide, The electron emitting portion 323a of the additive supply pipe 320 is opened by an amount corresponding to 0.01 to 1% by weight, and the stirrer is operated while supplying the mixture to the mixer by gravity. The mixture is stirred for 10 to 30 minutes to dissolve.

When the dissolution of the surfactant is completed, the carboxyl group, the sulfate group, the phosphate group, the sulfate group, the phosphate group, the sulfoethyl group, the phosphomethyl group and the carbomethyl group stored in the fourth storage tank 324 connected to the additive supply pipe 320 (Hydrogen ions) selected from the group consisting of acrylic acid, methacrylic acid, allylsulfonic acid, vinylsulfonic acid, styrenesulfonic acid and its salts and 2-acrylamido-2-methylpropanesulfonic acid group The electron emitting portion 324a of the additive supply pipe 320 is opened by an amount corresponding to 0.02 to 1.5% by weight of the emission material of any one or more protons (hydrogen ions) selected from the materials, and the stirrer is operated For 30 minutes to dissolve.

When the dissolution of the proton (hydrogen ion) is completed, the vinylbenzyltrimethylammonium salt, diethylaminoethyl methacrylate, dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate, and the like, which are stored in the fifth storage tank 325 connected to the additive supply pipe 320, Dimethylaminoethyl methacrylate, diethylaminoethyl methacrylate, diethylaminomethyl methacrylate, tertiary-butylaminoethyl acrylate, tertiary-butylaminoethyl methacrylate, dimethylaminopropylacrylamide, acrylic Amide, allylamine, diethylenetriamine, monoethanolamine, diethanolamine, triethanolamine, N, N'-oxybis (methylene) bis (N, N-dibutylamine) (N, N-diethylamine), N, N-dimethyl acrylamide, N, N-dimethylaminoethyl acrylate and N, N-dimethylaminopropylacrylamide groups that The electron emitting portion 325a of the additive supply pipe 320 is opened by an amount corresponding to 0.01 to 1% by weight of the substance having any one or more anion dissociating groups, and the mixture is supplied to the mixer by the gravity lane, And then the deodorant made in the filtration unit is conveyed by opening the electromagnetic foot part 330a connected to the discharge pipe 330 and the transfer pump 331 is operated to filter the foreign matter by the filter media, The deodorant for industrial use for removing noxious gas and odor is produced.

The lipophilic fluid means any liquid or mixture that is incompatible with water at a water content of 20% by weight and 50% or less, and generally suitable lipophilic fluids can be completely liquid at ambient temperature and pressure, Refers to a material that may be an easily fused solid such as being liquid at temperatures in the range of -60 < 0 > C, or may contain mixtures of liquid and vapor phases at ambient temperatures and pressures, e.g., 25 [deg.] C and 1 atm pressure. Quot; refers to a material in which the contaminant has a high solubility in a lipophilic fluid or a high affinity for a lipophilic fluid. Examples of the lipophilic contaminants include lipophilic substances such as monoglyceride, diglyceride, triglyceride, saturated and unsaturated fatty acids, non-polar hydrocarbons, waxes and wax esters, Is a well-soluble substance.

The anionic surfactant is an activator which dissociates in an aqueous solution and the anion moiety exhibits a surfactant, wherein the surfactant depends on the type of functional group and the number of carbon atoms which exhibit a hydrophilic group.

The amphoteric surfactant is an active agent that dissociates in an aqueous solution and exhibits both cationic and anionic moieties.

The nonionic surfactant is an active agent that does not dissociate ions in an aqueous solution, but a hydrophilic functional group such as a hydroxyl group exhibits a surfactant.

5 is an exemplary view showing a control panel for controlling facilities according to the present invention.

5, the control panel 500 according to the present invention controls the active gas generator 100, the active water generator 200, and the mixer 300

6 is an exemplary view showing a spray tower as a test test equipment for evaluating the deodorizing performance of the deodorant manufactured by the present invention.

As shown in FIG. 6, the spray tower 400, which is a test test equipment for evaluating the deodorization performance of the deodorant for the harmful gas and odor removing industry according to the present invention, includes a main body 401 having a three- 410), and a deodorant supply pipe (420).

The structure of the main body 401 includes a reservoir 401a filled with a deodorant at the lower end, a liquid contact portion 401b contacting the deodorant sprayed with contaminated air containing odorous substances at the middle end, And an upper end 401c for collecting contaminated air through the measuring hole.

The contaminated air suction pipe 410 is provided on the pipe with a measuring hole 411 spaced apart from the suction unit of the air fan 412 to measure the concentration of contaminated air containing odorous substances, The discharge portion is connected to the shock absorber connector 413 which isolates the vibration when the main body 401 and the air fan 412 are connected.

The deodorant supply pipe 420 is provided with a pump 421 for sucking and pressurizing the deodorant stored at the lower end of the main body, an electronic foot 422, and a nozzle 423 for spraying the deodorant.

An air compressor 431 and an electronic ear part 432 for sucking external air in a range of 3 to 8 kg / cm 2 are installed in the compressed air supply pipe 430 installed at a distance from the deodorant supply pipe 420, The compressed air supply pipe 430 is connected to a nozzle 423 for spraying the deodorant through the main body so as to spray the deodorizing liquid sprayed from the supply nozzle finer.

First, a spray tower 400, which is a test test equipment, is installed in the vicinity of contaminated air containing odorous substances. A suction pipe 410 is connected to a contaminated air source and a suction pipe is connected to the air pan 412 When the power is supplied, the air fan 412 is operated to suck the contaminated air discharged from the polluted air generating source by the suction force of the air fan 412 and supply the contaminated air into the liquid contact portion 401b of the spray tower 400, And the electromagnetic valve 432 of the compressed air supply pipe 430 is then opened to remove the contaminated air sample from the exhaust port 422 of the deodorant supply pipe 420, The pump 421 is operated to suck and store the deodorizing liquid and the outside air stored in the storage tank 401a of the main body 401. When the circulation pump 421 and the air compressor 431 are powered from a control panel (not shown) And is supplied to the injection nozzle 423 and supplied to the contaminated gas The odorous substance is removed by the deodorant by opening the measuring hole provided at the upper part of the body while the odorous substance is continuously removed by the absorption of contaminants due to the liquid contact by deodorization, dissolution of lipophilic contaminants, and oxidation reaction with hydroxyl groups Purified air is captured and analyzed by Tetra bag to analyze odorant removal rate.

- Field test of odor removal

Example 1

1, deodorant manufacturing

1) Supply of active water

70.8 to 79.97 liters of active water produced in the active water production step corresponding to 88.5 to 99.97% by weight of the total weight% is fed to the mixer 300 by means of a pump. Here, the 80 liters of active water is an appropriate capacity (level) for sucking and discharging by the pump in the spray tower 400.

2) Supply of functional active substance

Isobornyl, isobornyl, 3-isocamphylcyclohexanol, 2-isopropenyl-5-methylcyclohexanol (isoprene), 1-iso (4-isopropylcyclohexyl) ethanol, 4-isopropylcyclohexylmethanol, 2-isopropylcyclohexylmethane, 4-isopropylcyclohexylmethane, 5-methylphenol (menthol), 2-isopropyl-5-methylphenol (thymol), 5-isopropyl- 2-propanol (terpineol), 2- (4-methylcyclohexyl) -2-propanol (dihydroterpineol), 4-methoxybenzyl alcohol), 4- (5,5,6- Cyclohexan-1-ol, 3,5,5-trimethylcyclohexanol, 2,4,6-trimethyl-4-cyclohexen-1-ylmethanol , 5- (2,2,3-trimethyl-3-cyclopentenyl) -3-methylpentan-2-ol, 3,7,11-trimethyl-2,6,10-dodecatrien- Neroli ), 3,5-trimethyl-1-hexanol (isononanol), 1-undecanol, 10-undecen-1-ol, betibellol, 2-phenoxyethanol and phenylethyl alcohol (2-methylphenyl) ethanol is added in an amount corresponding to 0.01 to 3 parts by weight (0.008 to 2.4 Kg) of the total weight of the polyvinyl alcohol selected and stored in an amount corresponding to 1 to 2 parts by weight of the total weight of the polyvinyl alcohol, After stirring, the stirrer is operated.

3) lipophilic fluid supply

(Hexamer), decamethyl-cyclopentasiloxane, and mixtures thereof, diols, polyol esters, propylene oxide, and mixtures thereof in a second vessel installed on top of the mixer 300, such as siloxane, octamethylcyclotetrasiloxane, dodecamethylcyclohexasiloxane Propyleneglycol n-butyl ether, propylene glycol n-butyl ether, tripropylene glycol methyl ether, tripropylene glycol-propyl ether, tripropylene glycol n-propyl ether, Ether, tripropylene glycol t-butyl ether and tripropylene glycol n-butyl ether; glycerol derivative solvents such as 2,3-bis (1,1-dimethylethoxy) 1-propanol, 2-isopropyl-5-methylcyclohexanol (menthol), carbonic acid (2-hydroxy-1-methoxymethyl) ethyl A solvent such as methylene chloride, methyl ethyl ketone, ethylene carbonate, propylene carbonate, glycerin, methylene chloride, methylene carbonate, ethyl carbonate, ethylene carbonate, propylene carbonate, glycerin ether, hydrofluorine, ether solvent, low volatile nonfluoroester solvent, (0.016 to 4 kg) of tripropylene glycol-propyl ether in a total amount of 0.02 to 5% by weight of the total 1-methoxy-2-propanol selected from the group consisting of And stirred.

3) Surfactant supply

(Ether) sulphate mixed with a hydroxyl group, an ether sulfate (ether) sulphate mixed with a hydroxyl group, a monoethanolamine ether (sulphate) sulphate mixed with a hydroxyl group, and a mixture of the alkyl ether sulphonate, glycerol ether sulphonate, sulfo fatty acid compound, fatty acid alcohol ether sulphate, Or an anionic surfactant alkylaminopropyl betaine selected from the group consisting of dialkyl sulfosuccinate, sulfo triglyceride, amide sulfoalkyl oligoglucoside sulfate, alkyl amino sugarsulfate and alkyl (ether) phosphate, Alkyl aminopropyl betaine, alkyl monoamphoacetate, and alkyl amphodiacetate stored in a third container, or an amphoteric surfactant alkylaminopropyl betaine selected from the group consisting of alkyl aminopropyl acetate and alkyl amphodiacetate in an amount corresponding to 0.01% Input or Is selected from the group consisting of alkyl polyalkylene glycols, alkylaryl polyalkylene glycols, alkyldimethylamine oxides, di-alkylmethylamine oxides, alkylaminopropylamine oxides, alkylglucamides, and alkylamines, The stored nonionic surfactant alkylpolyalkylene glycol is added in an amount corresponding to 0.01 to 1% by weight (0.008 to 0.8 Kg) of the total weight of the nonionic surfactant, and then the stirrer is agitated.

4) Proton (H ⁺ ) emission material supply

A mixture of acrylic acid, methacrylic acid, and allylsulfonic acid, which is contained in a fourth container provided above the mixer 300 and contains a carboxyl group, a sulfate group, a phosphate group, a sulfate group, a phosphate group, a sulfoethyl group, a phosphomethyl group, (Hydrogen ions) selected from 2-acrylamido-2-methylpropanesulfonic acid group and from 0.02% to 1.5% by weight of the total weight of acrylic acid, After the appropriate amount (0.016 to 1.2 Kg) is added, the stirrer is actuated and stirred.

5) Material input with anion dissociation

The mixture of the vinyl benzyltrimethylammonium salt, diethylaminoethyl methacrylate, dimethylaminoethyl acrylate, dimethanoaminoethyl methacrylate, diethylaminoethyl acrylate, diethylaminoethyl methacrylate, Methyl methacrylate, tert-butylaminoethyl acrylate, tert-butylaminoethyl methacrylate, dimethylaminopropylacrylamide, acrylamide, allylamine, diethylenetriamine, monoethanolamine, diethanolamine, triethanol Amine, N, N'-oxybis (methylene) bis (N, N-dibutylamine), N, N`- (methylenebis N, N-dimethyl acrylamide, N, N-dimethylaminoethyl acrylate, and N, N-dimethylaminopropylacrylamide group. The vinylbenzyltrimethylammonium salt is added to the entire Part hayeoseo stirred to 0.01% to the amount corresponding to 1% by weight ((0.008 to 0.8Kg) movable one after the stirrer is added as a spray tower using a dissolved pump.

2. Field testing

1) Experiment to remove odor causing substance

The test bed described above was installed at the wastewater treatment plant of the product 00 (the same vegetable oil manufacturing industry) located at 00, Wonsi-dong, Danwon-gu, Ansan-si, Gyeonggi-do and the test bed was set up by the Siheung Green Environment Support Center (2121 Jeongwang- 00 Researchers at the Ansan branch of the Environmental Research Institute visited the test site to collect the two samples for the wastewater treatment and the spray tower exit in the tetra bag during the experiment to remove odor from the odor causing substances generated in the wastewater treatment plant, The results of analysis by air dilution sensory method showed that odor generated after spraying deodorant in spray tower at 10,000 times (dilution multiples) of waste water treatment plant is 3000 times (dilution multiples) .

* Test results
Sectors

Circle concentration
Deodorant spraying
Post-discharge concentration
Reduction rate
Reaction time
Process test method
Animal husbandry manufacturing industry
Waste water treatment plant odor
10,000 times
3,000 times
70%
Within 3 seconds
National Institute of Environmental Research
No. 2007-18 Chapter 3

 2) Experiment to remove harmful gas

The test bed described above was installed at the wastewater treatment plant of the product 00 (the same vegetable oil manufacturing industry) located at 00, Wonsi-dong, Danwon-gu, Ansan-si, Gyeonggi-do and the test bed was set up by the Siheung Green Environment Support Center (2121 Jeongwang- 00 Laboratory Ansan branch researcher visited the test site and visited the test site. During the process of removing the bad odor from harmful gas generated in the wastewater treatment plant, the sample was sampled in the tetra bag for the waste water treatment (odor source concentration), the spray tower exit The concentration of the harmful gas originating from the wastewater treatment plant was estimated by the analysis of the process test standard based on Article 4 (2) of the Notice No. 2007-18 (2007.10) of the National Institute of Environmental Research In the case of hydrogen sulfide, the concentration of the spray tower was reduced to 0.202 ppm by 74% at 0.803 ppm, and the concentration of methylmercaptane In the case of DMS, the concentration of the spray tower was reduced by 100% to 0 (nd) ppm at 0.018ppm and the concentration of DMDS was decreased from 0.008ppm to 0.007ppm at the spray tower In the case of propionaldehyde, the concentration of the passing tower was reduced to 0.017 ppm at 0.043 ppm. In the case of butyaldehyde, the concentration of the passing tower was reduced to 0.025 ppm at 0.120 ppm. 79.2%. In the case of Isovaleraldehyde, the concentration of spray tower was reduced to 0.048ppm by 63.9% at 0.133ppm, while that of valeraldehyde was reduced from 0.022ppm to 0.012ppm by 45.5%.

* Test results
Sectors

Name of harmful gas
Circle concentration
Deodorant spraying
Post-discharge concentration
Reduction rate
Reaction time
Process test method
Animal
Maintenance manufacturing industry
Waste water treatment plant odor
Hydrogen sulfide
0.803 ppm
0.202 ppm
74%
Within 3 seconds
National Environment
Notification No. 2007-18
Chapter 4, Section 2
Methyl mercaptan
0.273 ppm
0.002 ppm
99.2%
DMS
0.018 ppm
0 (nd) ppm
100%
DMDS
0.008 ppm
0 (nd) ppm
100%
Propionaldehyde
0.043 ppm
0.017 ppm
60%
Butyaldehyde
0.120 ppm
0.025 ppm
79.2%
Isovaleraldehyde
0.133 ppm
0.048 ppm
63.9%
Valeraldehyde
0.022 ppm
0.012 ppm
45.5%

3. Ammonia Removal Experiment

The test bed described above was installed at the wastewater treatment plant of the product 00 (the same vegetable oil manufacturing industry) located at 00, Wonsi-dong, Danwon-gu, Ansan-si, Gyeonggi-do and the Siheung Green Support Center During the experiment, the researchers collect two samples for the waste water treatment (odor source concentration) and the spray tower outlet (after the deodorant spraying) in the tetra bag during the process of removing the odor from the ammonia generated in the wastewater treatment plant. As a result of analysis of the process test standard set forth in Chapter 4, paragraph 2 of the Korea Institute of Science and Technology (No. 2007-18) (2007.10), the concentration of ammonia in the wastewater treatment plant was reduced from 125 ppb to 27.5 ppb by 78%. (Pass speed within 3 seconds)

* Ammonia test results
Sectors
Circle concentration
Deodorant spraying
Post-discharge concentration
Rate
Reaction time
Process test method
Animal
Maintenance manufacturing industry
Waste water treatment plant odor
25 ppb
27.5 ppb
78%
Within 3 seconds
National Institute of Environmental Research
2007-18 Chapter 4 Section 2

Example 2

2. Field testing

1) Experiment to remove odor causing substance

The test bed described above was installed in the wastewater treatment plant of the product 00 (Wastewater Treatment Plant), 00, Wonsi-dong, Danwon-gu, Danwon-gu, Gyeonggi-do, Korea and the researcher of 00 Engineering Co., During the process of conducting the odor removal test on the odor causing substances generated in the wastewater treatment plant in the presence of a visiting person, two samples were collected in the tetra bag for the wastewater discharge and the spray tower exit, (2007.10) Chapter 3 Analysis by air dilution sensory method The odor generated at the wastewater treatment plant was reduced by 96% to 173 times (dilution factor) after spraying deodorant at spray tower at 4481 times (dilution multiples).

* Test results
Sectors
Circle concentration
Deodorant spraying
Post-discharge concentration
Reduction rate
Reaction time
Process test method
Animal
Maintenance manufacturing industry
Waste water treatment plant odor
4,481 times
173 times
96%
Within 3 seconds
National Institute of Environmental Research
No. 2007-18 Chapter 3

Example 3

1. Field Testing

1) Experiment to remove odor causing substance

A test bed was installed in the compost tank (B) of Ansan City Food Waste Recycling Facility at 00 Haebongno, Danwon-ro, Danwon-gu, Danwon-gu, Ansan-si, Gyeonggi-do, and a research institute of 00 Environmental Research Institute During the process of removing odors from the smell-causing substances generated in the compost tank (B), two samples were collected for tetrasuberosity (B) and for the spray tower outlet, 2007-18 Chapter 3 Analysis by air dilution sensory method Reduced odor after spraying deodorant at spray tower at 10,000 times (dilution multiples) of wastewater treatment plant Reduce by 55.2% by 4481 times (dilution multiples) (Passing speed within 3 seconds)

* Test results
Sectors
Circle concentration
Deodorant spraying
Post-discharge concentration
Reduction rate
Reaction time
Process test method
Food waste
Public treatment
10,000 times
4,481 times
55.2%
Within 3 seconds
National Institute of Environmental Research
No. 2007-18 Chapter 3

Example 4

(SCRUBBER: Capacity 400m3) installed at the wastewater treatment plant of 00 home (food processing and wholesale industry), 00, Wonhyo-dong, Danwon-gu, Ansan-si, Gyeonggi-do, (dilution ratio: 25: 1) of deodorant of the present invention was added to 2000 liters of washing water of 2000 g / min.

The researcher of Siheung Green Support Center directly collects 2 pieces of each of the entrance and exit specimens of odor pollution prevention facilities on a tetra bag and reports them to the Ministry of Environment in accordance with Article 4, Paragraph 2 of the Notification No. 2007-18 (2007.10) of the National Institute of Environmental Research As a result of analyzing the complex odor concentration on the basis of the process test, the concentration of the complex odor at the entrance of the odor pollution prevention facility was 650 times, and the complex odor concentration at the exit side was reduced to 300 times (within 3 seconds)

* Test results
Sectors
Circle concentration
Deodorant spraying
Post-discharge concentration
Reduction rate
Reaction time
Process test method
Food processing and wholesaling
650 times
300 times
53.8%
Within 3 seconds
National Institute of Environmental Research
No. 2007-18 Chapter 3

Example 5

(SCRUBBER: Capacity of 650m3 / day) installed in the meat processing of 00 home (food processing and wholesale) in 00, Wonsi-dong, Danwon-gu, Ansan-si, Gyeonggi-do, (dilution ratio: 25: 1) of the deodorant of the present invention was added to 3000 liters of washing water of 3,000 liters / min to perform a complex odor reduction test.

The researcher of Siheung Green Support Center directly collects the entrance and exit samples of the odor pollution prevention facility into two each one in the tetra bag and reports it to the National Institute of Environmental Research 2007-08 (2007.10) As a result of analyzing the complex odor concentration based on the process test standard, the concentration of the complex odor at the entrance of the odor pollution prevention facility was 1000 times, and the complex odor concentration at the exit side was reduced to 448 times (passing speed within 3 seconds).

* Test results
Sectors
Circle concentration
Deodorant spraying
Post-discharge concentration
Reduction rate
Reaction time
Process test method
Food processing and wholesaling
1000 times
448 times
55.2%
Within 3 seconds
National Institute of Environmental Research
No. 2007-18 Chapter 3

Example 6

It was commissioned by the Siheung Green Environment Support Center (located in 2121 Jungwang-dong, Jungwang-dong, Korea) to be equipped with an odor pollution prevention facility (SCRUBBER, capacity: 250m3 / min) installed in the leather processing process of 00, Sunggok-dong, 40 liters (dilution ratio: 25: 1) of the deodorant of the present invention was injected into 1000 liters of washing water to carry out the complex odor reduction test.

The researcher of Siheung Green Support Center directly collects the entrance and exit samples of the odor pollution prevention facility into two each one in the tetra bag and reports it to the National Institute of Environmental Research 2007-08 (2007.10) As a result of analyzing the complex odor concentration on the basis of the process test, the concentration of the complex odor at the entrance of the odor pollution prevention facility was 600 times, and the complex odor concentration at the exit side was reduced to 300 times (within 3 seconds)

* Test results
Sectors
Circle concentration
Deodorant spraying
Post-discharge concentration
Reduction rate
Reaction time
Process test method
Food processing and wholesaling
1000 times
448 times
55.2%
Within 3 seconds
National Institute of Environmental Research
No. 2007-18 Chapter 3

Example 7

The amount of liquid jet was 5.4 liters / minute in the exhaust port (diameter: 1400 mm) of the drying process of the 000 paper (manufactured by box) of 00 munna-dong, Danwon-gu, Ansan-si, Gyeonggi-do, h. Compressed air injection quantity 37 liters / min. Three hundred nozzles with a spray angle of 120 degrees were installed, and 2000 liters of washing water was filled in a separately installed tank. Then, 40 liters of the deodorant of the present invention (dilution magnification: 50: 1) Odor reduction test was conducted.

The researcher of Siheung Green Support Center directly collects two samples, one for each of the spray inlet nozzle and the spray nozzle outlet, in the tetra bag, and reports to the National Institute of Environmental Research 2007-18 (2007.10) Chapter 4 As a result of analyzing the complex odor concentration according to the process test standard described in the item 2, the concentration of the complex odor at the entrance of the odor pollution prevention facility was 448 times, and the complex odor concentration at the exit side was reduced to 250 times (within 3 seconds)

* Test results
Sectors
Circle concentration
Deodorant spraying
Post-discharge concentration
Reduction rate
Reaction time
Process test method
Food processing and wholesaling
448 times
250 times
44.2%
Within 3 seconds
National Institute of Environmental Research
No. 2007-18 Chapter 3

A high voltage generated in a high voltage generator is applied to a discharge electrode and a ground electrode which are provided in a discharge chamber facing each other while sucking and pressurizing external air by using an air fan and introducing the external air into a discharge chamber of a high voltage discharge unit, (O2) into oxygen atoms (O) by electrochemical methods such as dissociation, excitation, ionization oxidation and reduction reaction by applying a very high electric field electron energy generated between the electrodes (Step 1) of dissociating water molecules (H2O) of water vapor in air into hydrogen protons (H ⁺ ) and hydroxyl groups (OH ^& lt ^{; - &} gt ^; ) to generate active gas, : The active gas generated by the activated gas generating means is pressurized with an air pump and supplied to an air diffuser and sprayed in water to dissolve the dissolved active gas, and the dissolved active gas is pumped into a water molecule refining apparatus (Step 2): a step of preparing an active water which is supplied with a small amount of activated active water produced by flushing and supplied to a mixer by using a transfer pump; Step 2: a step of mixing the functional active substance having a hydroxyl group in the active water supplied to the mixer, , A proton-releasing substance, and an anion dissociating group are sequentially added, and the mixture is stirred and mixed (Step 3). It is also possible to remove complex odor substances such as hydrophilic, hydrophobic and lipophilic contaminants simultaneously Lt; / RTI >

), 수증기의 물분자(H2O)는 수산기이온(OH

)을 생성한다.The active gas generating step (step 1) includes a pre-treatment filter for removing dust from outside air introduced into an inlet of the inside of the housing, the fresh air being formed at one side of the independent housing, A high voltage generated by a high voltage generator is applied to a discharge electrode (+ pole) and a ground electrode (- pole) provided opposite to each other in an intake tube installed to face the air fan discharge port, An electric field energy band which is generated by the discharge is formed. When fresh ambient air sucked by the air fan is passed through this energy band, the electric field energy is applied to the outside air to dissociate, excite, ionize, oxidize, In the electrochemical reaction, the nitrogen molecule (N2) is the nitrogen ion [N], the oxygen molecule (O2) is the oxygen ion (O, O

), The water molecule of water vapor (H2O) is a hydroxyl ion (OH

).

The active water producing step (step 2) includes a water storage tank for storing the water and an active gas supply unit for supplying the active gas generated in the active gas generating step to the air diffusing pipe, A means for supplying an active gas to the acid orifice and sucking and pressurizing the fluid mixed with the active gas in the seawater and connected to the water molecule sub-grouping mechanism having a plurality of micro-aperture perforated plates connected to the discharge side of the pump, Circulation means.

When the active gas generated in the active gas generating step is pressurized with an air pump and supplied to an air diffuser installed at an interval from the bottom of the storage tank, the active gas is injected into the stored water, a part of which is dissolved in the water, The gas is sucked into the circulation pump at the time of the pump and is sucked by the wing of the pump rotating at a high speed to be pressurized and dissolved in the water. The pressurized water passes through the water molecule small- As the insoluble active gas passes through the perforated plate, it dissolves in the water and the water molecules in the water are subdivided. This process is continuously repeated so that the water molecules are subdivided and active water in which active gas is dissolved in water is produced.

The composition of the mixer in the mixing step (step 3) includes a storage tank main body for storing active water, a stirrer provided on the top of the main body, a functional active material having a hydroxyl group connected to the tank main body on one side of the main body, An additive supply part composed of an active agent, a proton-emitting substance, and an anion dissociation device, and an electric heater installed at one side of the storage tank, and the process of mixing the functional active material, the lipophilic fluid and the surfactant The activated water produced in the active water production step is filled in the mixer tank by an amount corresponding to 88.5% by weight to 99.97% by weight of the total weight portion by using a transfer pump, and then the functional active material having the hydroxyl group of the additive supply portion is filled The electron emitting portion of the container storing the functional active material is opened by an amount corresponding to 0.01 to 5% by weight, While stirring, the stirrer is operated to dissolve by stirring for 10 minutes to 30 minutes. The electric heater is used when heating the active water to a range of 20 to 60 degrees when the temperature of the electric heater is low and the functional active material having the hydroxyl group is not dissolved well or the time is delayed.

Next, the electron emission portion of the tank storing the lipophilic liquid was opened by an amount corresponding to 0.02 to 5% by weight of the lipophilic liquid in the additive supply portion, and the stirrer was operated for 10 minutes To 30 minutes with stirring. Next, the electron emitting portion of the tank, in which the surfactant is stored in an amount corresponding to 0.01 to 1% by weight of the surfactant in the additive supplying portion, is opened to the solution containing the hydroxyl functional group-containing functional substance and the lipophilic liquid, The mixture is stirred and stirred for 10 to 30 minutes while the stirrer is being operated.

Next, the electron emitting portion of the tank storing the proton-emitting material was opened by an amount corresponding to 0.02 to 1.5% by weight of the proton-emitting material in the additive supplying portion, and the stirrer was operated for 10 minutes To 30 minutes with stirring.

Next, the electron emitting portion of the tank storing the proton-emitting material is opened by an amount corresponding to 0.01 to 1.0 wt% of the total weight portion of the substance having the anion dissociating group of the additive supplying portion, and the stirrer is operated while supplying an appropriate amount to the mixer by the gravity difference Deg.] C for 10 minutes to 30 minutes to prepare a deodorant for industrial use in the noxious gas and odor removing process of the present invention.

As described above, the present invention dissociates oxygen molecules (O2) in the air into oxygen atoms (O) by dissociation of nitrogen molecules (N2) into nitrogen atoms (N) by an electrochemical method of high- Since active water is dissociated into cleansing water by dissociating water molecule of water vapor (H2O) with hydrogen proton (H ⁺ ) and hydroxyl group (OH ^- ) and activated water is made small, cleansing water containing deodorant and odorous substance It is possible to improve the contact efficiency of the liquid body with the gas, and the water absorption efficiency of the hydrophilic odorous substance can be improved and the deodorization efficiency can be improved. In addition, the present invention can improve the deodorization efficiency by oxidation reaction between the active gas and the functional active substance containing hydroxyl groups in the small-sized, active water and harmful gas and odorous substances.

It will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims. It will be possible. Therefore, the embodiments disclosed in the present invention and the accompanying drawings are intended to illustrate and not to limit the technical spirit of the present invention, and the scope of the technical idea of the present invention is not limited by these embodiments and the accompanying drawings . The scope of protection of the present invention should be construed according to the following claims, and all technical ideas within the scope of equivalents thereof should be construed as being included in the scope of the present invention.

100: Activated gas generator 101: Pretreatment filter for dust removal
102: air fan 109: cell
111: discharge electrode 111a: discharge electrode
111b: ground electrode 111c: permanent magnet
111d: catalyst layer
120: High voltage generator
130: pressurizer 130, 132, 133:
200: active water generator 201: melting vessel main body
202: water supply pipe 203:
210: active gas supply pipe 213:
220: circulation line
221: active gas ejector type active gas dissolution head
222: circulation pump 223, 224:
225: Water molecule small grouping mechanism 230: Water level detection sensor
300: mixer 301: main body
302: stirrer 303: electric heater
304: Vent tube
305: sludge discharge pipe 305a:
340: Temperature detection sensor 341: Water level detection sensor
310: active water supply pipe 320: additive supply pipe
330: Product discharge pipe
400: spray tower 401a: storage tank
401b: liquid contact portion 410: contaminated air suction pipe
411: Measuring ball 412: Air fan
420: deodorant supply pipe 421: pump
422: electronic pawl 423: nozzle
430: compressed air supply pipe 431: air compressor
432:
500: control panel

Claims (6)

From 0.01 to 3% by weight, based on the total weight of the functional active material,
0.0 > 5% < / RTI > by weight of the total lipophilic fluid,
The surfactant may be present in an amount of from 0.01 to 1% by weight,
Proton (hydrogen ion) releasing material in an amount of 0.02 to 1.5 wt%
0.0 > 1% < / RTI > by weight <
The active gas is dissolved in an amount of 88.5 to 99.93 wt%
By weight based on the weight of the deodorant.
The method according to claim 1,
The functional active material may be,
But are not limited to, carboxaldehyde having at least one hydroxyl group, isoborneyol, 3-isocamphylcyclohexanol, 2-isopropenyl-5-methylcyclohexanol (isoprene) Isopropylcyclohexanol, 3-enol (terpinenol), 4-isopropylcyclohexanol, 1- (4-isopropylcyclohexyl) ethanol, 4-isopropylcyclohexylmethanol, ), 2-isopropyl-5-methylphenol (thymol), 5-isopropyl-2-methylphenol (carbacol), 2- (4- 2- (4-methylcyclohexyl) -2-propanol (dihydroterpineol), 4-methoxybenzyl alcohol), 4- (5,5,6-trimethylbicyclo Cyclohexan-1-ol, 3,5,5-trimethylcyclohexanol, 2,4,6-trimethyl-4-cyclohexen-1-ylmethanol, 5- (2,2,2- 3-methylpentan-2-ol, 3,7,11-trimethyl-2,6,10-dodecatrien-3-ol (nerolitol) 5-trimethyl-1-hexyl Characterized in that at least one substance selected from the group consisting of norbornene (isononanol), 1-undecanol, 10-undecen-1-ol, betibrole, 2-phenoxyethanol and phenylethyl alcohol is used. And odor removal industrial deodorant.
The method according to claim 1,
The lipophilic fluid may contain,
Diols, polyol esters, propylene glycol methyl ethers, n-propyl ethers, propylene glycol t-butyl hydroxysiloxanes, and mixtures thereof. Butyl ether, dipropylene glycol n-butyl ether, propylene glycol n-butyl ether, tripropylene glycol methyl ether, tripropylene glycol-propyl ether, tripropylene glycol n-propyl ether, tripropylene glycol t- n-butyl ether, glycerin derivative solvents such as 2,3-bis (1,1-dimethylethoxy) -1-propanol, 2,3- dimethoxy- (2-hydroxy-1-methoxymethyl) ethyl ester methyl ester, glycerol carbonate, methyl carbonate, Any one or more substances selected from the group consisting of tilene carbonate, propylene carbonate, glycerin ether, hydrofluorine, ether solvent, low volatile non-fluoroester solvent, dimethylenate, methyl carbonate, ethyl carbonate, ethylene carbonate, propylene carbonate and glycerin carbonate is used Wherein the deodorizing agent is a deodorant for industrial harmful gases and odors.
The method according to claim 1,
The surfactant,
An anionic surfactant, an amphoteric surfactant, and a nonionic surfactant,
The anionic surfactant may be at least one selected from the group consisting of alkyl ether sulfonates, glycerol ether sulfonates, sulfo fatty acid compounds, fatty acid alcohol ether sulfates, ether sulfates mixed with hydroxyl groups, petiexamide amide (ether) sulfates, mono or dialkyl sulfosuccinates, Any one or more substances selected from the group consisting of sulfo triglyceride, amide sulfoalkyl oligoglucoside sulfate, alkyl amino sugarsulfate and alkyl (ether) phosphate are used,
Wherein the amphoteric surfactant is selected from the group consisting of alkylaminopropyl betaine, alkylmonoammonium acetate and alkylamphodiacetate,
Wherein the nonionic surfactant is selected from the group consisting of alkyl polyalkylene glycols, alkylaryl polyalkylene glycols, alkyldimethylamine oxides, di-alkylmethylamine oxides, alkylaminopropylamine oxides, alkylglucamides, and alkylamines Wherein said material is used as a deodorant for deodorizing harmful gas and odor.
The method according to claim 1,
The proton (hydrogen ion)
Methacrylic acid, allylsulfonic acid, vinylsulfonic acid, styrenesulfonic acid and salts thereof containing a carboxyl group, a sulfate group, a phosphate group, a sulfate group, a phosphate group, a sulfoethyl group, a phosphomethyl group and a carbomethyl group and - acrylamido-2-methylpropanesulfonic acid is used as the deodorant for deodorizing harmful gases and odors.
The method according to claim 1,
The substance having an anion dissociation group may be,
Dimethylaminoethyl methacrylate, diethylaminoethyl methacrylate, diethylaminoethyl acrylate, diethylaminomethyl methacrylate, tert-butylaminoethyl acrylate, diethylaminoethyl methacrylate, diethylaminoethyl methacrylate, , N, N'-oxybis (methylene) bis, N, N'-oxybis (methylene) bismaleimide, triethylamine, (N, N-dibutylamine), N, N`- (methylenebis (oxy) bis (methylene) Aminoethyl acrylate, and N, N-dimethylaminopropylacrylamide is used as the deodorant for deodorizing harmful gas and odor.

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