CN114729108B - 环氧树脂组合物、预浸料及纤维增强复合材料 - Google Patents

环氧树脂组合物、预浸料及纤维增强复合材料 Download PDF

Info

Publication number
CN114729108B
CN114729108B CN202080079172.6A CN202080079172A CN114729108B CN 114729108 B CN114729108 B CN 114729108B CN 202080079172 A CN202080079172 A CN 202080079172A CN 114729108 B CN114729108 B CN 114729108B
Authority
CN
China
Prior art keywords
epoxy resin
resin composition
molecular weight
epoxy
component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202080079172.6A
Other languages
English (en)
Chinese (zh)
Other versions
CN114729108A (zh
Inventor
古川浩司
佐野健太郎
川崎顺子
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Publication of CN114729108A publication Critical patent/CN114729108A/zh
Application granted granted Critical
Publication of CN114729108B publication Critical patent/CN114729108B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22Di-epoxy compounds
    • C08G59/24Di-epoxy compounds carbocyclic
    • C08G59/245Di-epoxy compounds carbocyclic aromatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32Epoxy compounds containing three or more epoxy groups
    • C08G59/3227Compounds containing acyclic nitrogen atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/5033Amines aromatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/042Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with carbon fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/10Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/243Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/05Alcohols; Metal alcoholates
    • C08K5/053Polyhydroxylic alcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/07Aldehydes; Ketones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/17Amines; Quaternary ammonium compounds
    • C08K5/18Amines; Quaternary ammonium compounds with aromatically bound amino groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/20Carboxylic acid amides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00Characterised by the use of epoxy resins; Derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Epoxy Resins (AREA)
  • Reinforced Plastic Materials (AREA)
CN202080079172.6A 2019-11-15 2020-11-05 环氧树脂组合物、预浸料及纤维增强复合材料 Active CN114729108B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2019-206896 2019-11-15
JP2019206896 2019-11-15
PCT/JP2020/041333 WO2021095627A1 (ja) 2019-11-15 2020-11-05 エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料

Publications (2)

Publication Number Publication Date
CN114729108A CN114729108A (zh) 2022-07-08
CN114729108B true CN114729108B (zh) 2024-12-13

Family

ID=75912890

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202080079172.6A Active CN114729108B (zh) 2019-11-15 2020-11-05 环氧树脂组合物、预浸料及纤维增强复合材料

Country Status (6)

Country Link
US (1) US12338315B2 (https=)
EP (1) EP4059975A4 (https=)
JP (1) JP7647102B2 (https=)
CN (1) CN114729108B (https=)
TW (1) TWI861279B (https=)
WO (1) WO2021095627A1 (https=)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014227473A (ja) * 2013-05-23 2014-12-08 東レ株式会社 複合材料用エポキシ樹脂組成物、繊維強化複合材料およびそれらの製造方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008095013A (ja) * 2006-10-13 2008-04-24 Fujikura Ltd エポキシ系接着剤、カバーレイ、プリプレグ、金属張積層板、プリント配線基板
JP2009155431A (ja) * 2007-12-26 2009-07-16 Sumitomo Bakelite Co Ltd 液状封止樹脂組成物、半導体装置および半導体装置の製造方法
JP2010077176A (ja) * 2008-09-24 2010-04-08 Fuji Kasei Kogyo Co Ltd 氷点下で硬化可能な水性エマルションエポキシド組成物
JP2014167103A (ja) * 2013-01-29 2014-09-11 Toray Ind Inc エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料
JP6723238B2 (ja) * 2014-11-20 2020-07-15 ダウ グローバル テクノロジーズ エルエルシー 促進剤組成物
RU2726406C2 (ru) * 2016-01-26 2020-07-14 Торэй Индастриз, Инк. Композиция эпоксидной смолы, препрег и композитный материал, армированный волокном
JP6950174B2 (ja) 2016-12-08 2021-10-13 三菱ケミカル株式会社 エポキシ樹脂組成物、並びにこれを用いた成形品、プリプレグ及び繊維強化プラスチック
CA3081351A1 (en) * 2017-11-08 2019-10-24 Cytec Industries Inc. Composites with interlaminar toughening particles and method of making the same
JP7172995B2 (ja) 2018-03-20 2022-11-16 東レ株式会社 プリプレグおよび繊維強化複合材料
CN109265655B (zh) * 2018-09-04 2020-12-25 北京化工大学 一种快速固化树脂体系及制备方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014227473A (ja) * 2013-05-23 2014-12-08 東レ株式会社 複合材料用エポキシ樹脂組成物、繊維強化複合材料およびそれらの製造方法

Also Published As

Publication number Publication date
TWI861279B (zh) 2024-11-11
US12338315B2 (en) 2025-06-24
JP7647102B2 (ja) 2025-03-18
CN114729108A (zh) 2022-07-08
EP4059975A1 (en) 2022-09-21
US20230037333A1 (en) 2023-02-09
WO2021095627A1 (ja) 2021-05-20
TW202128815A (zh) 2021-08-01
EP4059975A4 (en) 2023-11-29
JPWO2021095627A1 (https=) 2021-05-20

Similar Documents

Publication Publication Date Title
JP5768893B2 (ja) エポキシ樹脂組成物及びこれを用いたフィルム、プリプレグ、繊維強化プラスチック
WO2014030638A1 (ja) エポキシ樹脂組成物、及びこれを用いたフィルム、プリプレグ、繊維強化プラスチック
CN107001586B (zh) 环氧树脂组合物、以及使用其的膜、预浸料和纤维增强塑料
CN114729108B (zh) 环氧树脂组合物、预浸料及纤维增强复合材料
JP7823570B2 (ja) エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料
CN115210318B (zh) 环氧树脂组合物、预浸料及纤维增强复合材料
CN114729107B (zh) 环氧树脂组合物、预浸料及纤维增强复合材料
CN114729106B (zh) 环氧树脂组合物、预浸料及纤维增强复合材料
JP6421897B1 (ja) エポキシ樹脂組成物、プリプレグ、繊維強化複合材料およびその製造方法
JP7707805B2 (ja) プリプレグおよび繊維強化複合材料
JP7622436B2 (ja) エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料
TWI914487B (zh) 環氧樹脂組成物、預浸體及纖維強化複合材料
CN117043217A (zh) 环氧树脂组合物、预浸料及纤维增强复合材料

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant