CN1146579C - 由连续本体聚合制备水溶性苯乙烯/丙烯酸树脂的方法 - Google Patents
由连续本体聚合制备水溶性苯乙烯/丙烯酸树脂的方法 Download PDFInfo
- Publication number
- CN1146579C CN1146579C CNB998147737A CN99814773A CN1146579C CN 1146579 C CN1146579 C CN 1146579C CN B998147737 A CNB998147737 A CN B998147737A CN 99814773 A CN99814773 A CN 99814773A CN 1146579 C CN1146579 C CN 1146579C
- Authority
- CN
- China
- Prior art keywords
- weight
- water
- molecular weight
- monomer component
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000012662 bulk polymerization Methods 0.000 title claims abstract description 20
- 239000011347 resin Substances 0.000 title abstract description 38
- 229920005989 resin Polymers 0.000 title abstract description 38
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 62
- 239000000178 monomer Substances 0.000 claims abstract description 37
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 30
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229920000642 polymer Polymers 0.000 claims abstract description 17
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000001816 cooling Methods 0.000 claims abstract description 13
- KTADTTCBDAMZIR-UHFFFAOYSA-N 2-(2-hydroxypropoxy)propan-1-ol;hydrate Chemical compound O.CC(O)COC(C)CO KTADTTCBDAMZIR-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 28
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 26
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical group CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 23
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 15
- 238000006116 polymerization reaction Methods 0.000 claims description 14
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 13
- 239000012046 mixed solvent Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 4
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 2
- 238000009826 distribution Methods 0.000 abstract description 26
- 239000002253 acid Substances 0.000 abstract description 21
- -1 acryl Chemical group 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 3
- 239000011877 solvent mixture Substances 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 14
- 239000002904 solvent Substances 0.000 description 14
- 238000000576 coating method Methods 0.000 description 13
- 239000000976 ink Substances 0.000 description 13
- 239000011248 coating agent Substances 0.000 description 12
- 238000007639 printing Methods 0.000 description 11
- 230000000704 physical effect Effects 0.000 description 10
- 239000007788 liquid Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 230000032050 esterification Effects 0.000 description 5
- 238000005886 esterification reaction Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 230000008859 change Effects 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 210000000689 upper leg Anatomy 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/02—Polymerisation in bulk
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019980056434A KR100301126B1 (ko) | 1998-12-19 | 1998-12-19 | 연속벌크중합에 의한 스티렌/아크릴계 수용성 수지의 제조방법 |
| KR1998/056434 | 1998-12-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1331704A CN1331704A (zh) | 2002-01-16 |
| CN1146579C true CN1146579C (zh) | 2004-04-21 |
Family
ID=19563948
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB998147737A Expired - Lifetime CN1146579C (zh) | 1998-12-19 | 1999-03-04 | 由连续本体聚合制备水溶性苯乙烯/丙烯酸树脂的方法 |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JP3570624B2 (ja) |
| KR (1) | KR100301126B1 (ja) |
| CN (1) | CN1146579C (ja) |
| HK (1) | HK1043800B (ja) |
| ID (1) | ID29615A (ja) |
| WO (1) | WO2000037506A1 (ja) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100560622C (zh) * | 2008-02-27 | 2009-11-18 | 广东天龙油墨集团股份有限公司 | 连续法本体聚合制备高分散性水溶性的丙烯酸树脂和制备方法及其在油墨中的应用 |
| FR2928227B1 (fr) * | 2008-02-29 | 2010-04-02 | Commissariat Energie Atomique | Procede de fabrication d'une membrane polymerique a conduction ionique pour pile a combustible. |
| WO2012018242A2 (ko) | 2010-08-05 | 2012-02-09 | 한화케미칼 주식회사 | 탄소소재를 이용한 고효율 방열도료 조성물 |
| KR101495211B1 (ko) | 2013-01-08 | 2015-02-24 | 한화케미칼 주식회사 | 블리스터 포장용 수지 및 이의 제조 방법 |
| KR102687446B1 (ko) * | 2020-08-31 | 2024-07-23 | 한화솔루션 주식회사 | 연속중합을 통한 스티렌 무수 말레인산 수지의 제조방법 및 이에 의해 제조된 스티렌 무수 말레인산 수지 |
| CN113384489B (zh) * | 2021-06-16 | 2022-06-17 | 宇虹颜料股份有限公司 | 水性指甲油制备物的加工方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4451612A (en) * | 1980-09-22 | 1984-05-29 | Mobil Oil Corporation | Continuous process for the preparation of rubber modified polymers |
| US4414370A (en) * | 1981-01-09 | 1983-11-08 | S. C. Johnson & Son, Inc. | Process for continuous bulk copolymerization of vinyl monomers |
| WO1982002387A1 (en) * | 1981-01-09 | 1982-07-22 | & Son Inc S C Johnson | Process for continuous bulk copolymerization of vinyl monomers and product thereof |
| JPS6058773B2 (ja) * | 1981-06-30 | 1985-12-21 | 日立金属株式会社 | 高温疲労強度を改善したＮｉ−Ｃｒ−Ｗ合金とその製造方法 |
| DE68903655T2 (de) * | 1988-03-17 | 1993-04-08 | Dainippon Ink & Chemicals | Verfahren zur herstellung eines styrol/methacrylsaeurecopolymers. |
| DE19524181A1 (de) * | 1995-07-03 | 1997-01-09 | Basf Ag | Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Polymeren |
-
1998
- 1998-12-19 KR KR1019980056434A patent/KR100301126B1/ko not_active IP Right Cessation
-
1999
- 1999-03-04 ID IDW00200101329A patent/ID29615A/id unknown
- 1999-03-04 WO PCT/KR1999/000103 patent/WO2000037506A1/en active Search and Examination
- 1999-03-04 JP JP2000589575A patent/JP3570624B2/ja not_active Expired - Lifetime
- 1999-03-04 CN CNB998147737A patent/CN1146579C/zh not_active Expired - Lifetime
-
2002
- 2002-07-16 HK HK02105247.8A patent/HK1043800B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| WO2000037506A1 (en) | 2000-06-29 |
| HK1043800B (zh) | 2005-02-18 |
| CN1331704A (zh) | 2002-01-16 |
| KR100301126B1 (ko) | 2001-09-06 |
| ID29615A (id) | 2001-09-06 |
| KR20000040715A (ko) | 2000-07-05 |
| HK1043800A1 (en) | 2002-09-27 |
| JP3570624B2 (ja) | 2004-09-29 |
| JP2002533480A (ja) | 2002-10-08 |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| REG | Reference to a national code |
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Granted publication date: 20040421 |