CN1146382C - 托牙底垫 - Google Patents
托牙底垫 Download PDFInfo
- Publication number
- CN1146382C CN1146382C CNB00107038XA CN00107038A CN1146382C CN 1146382 C CN1146382 C CN 1146382C CN B00107038X A CNB00107038X A CN B00107038XA CN 00107038 A CN00107038 A CN 00107038A CN 1146382 C CN1146382 C CN 1146382C
- Authority
- CN
- China
- Prior art keywords
- methyl
- acrylate
- dental
- polymerization
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/30—Compositions for temporarily or permanently fixing teeth or palates, e.g. primers for dental adhesives
- A61K6/35—Preparations for stabilising dentures in the mouth
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P41/00—Drugs used in surgical methods, e.g. surgery adjuvants for preventing adhesion or for vitreum substitution
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Epidemiology (AREA)
- Polymers & Plastics (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Pharmacology & Pharmacy (AREA)
- General Chemical & Material Sciences (AREA)
- Surgery (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Engineering & Computer Science (AREA)
- Dental Preparations (AREA)
Abstract
Description
氟代甲基丙烯酸酯 | 溶液粘度(cps) | 多功能团甲基丙烯酸酯 | 着色(用姜黄)ΔE* | 甲硫醇浓度(ppm) | 水吸收μg/mm3 | 溶解度μg/mm3 | 断裂韧性MPa·m1/2 | |
实施例1 | 6FMA | 305 | 1,10-DD | 9.8 | 14 | 3.0 | 1.0 | 1.09 |
实施例2 | 8FMA | 315 | 1,10-DD | 8.3 | 14 | 2.9 | 0.6 | 1.15 |
实施例3 | 10FMA | 326 | 1,10-DD | 7.0 | 11 | 1.8 | 0.2 | 1.18 |
实施例4 | 12FMA | 370 | 1,10-DD | 6.8 | 10 | 1.9 | 0.5 | 1.01 |
实施例5 | 16FMA | 410 | 1,10-DD | 5.6 | 13 | 3.2 | 0.4 | 0.92 |
实施例6 | 5F/4H-BMA | 300 | 1,10-DD | 15.3 | 16 | 4.2 | 1.1 | 1.08 |
比较实施例1 | 5FMA | 290 | 1,10-DD | 16.2 | 20 | 7.7 | 1.5 | 0.91 |
比较实施例2 | 19FMA | 420 | 1,10-DD | 6.8 | 18 | 5.0 | 1.0 | 0.60 |
比较实施例3 | 7F/12H-NMA | 380 | 1,10-DD | 28.1 | 24 | 4.2 | 0.9 | 0.98 |
比较实施例4 | BMA | 267 | 1,10-DD | 43.7 | 23 | 5.9 | 1.5 | 1.01 |
比较实施例5 | NMA | 377 | 1,10-DD | 46.2 | 28 | 6.2 | 1.3 | 0.92 |
比较实施例6 | α-FMA | 120 | 1,10-DD | 38.0 | 26 | 3.2 | 0.9 | 0.76 |
实施例7 | 16FMA | 390 | 3G | 12.9 | 18 | 4.1 | 0.9 | 0.91 |
比较实施例7 | 5FMA | 290 | 3G | 20.4 | 20 | 7.9 | 2.1 | 0.69 |
比较实施例8 | 19FMA | 420 | 3G | 13.8 | 19 | 4.1 | 0.9 | 0.61 |
比较实施例9 | 无(EHMA) | 350 | 3G | 42.9 | 26 | 10.4 | 3.9 | 1.08 |
氟代甲基丙烯酸酯 | 氟代甲基丙烯酸酯的含量(g) | 多功能团甲基丙烯酸酯的含量 | 丙烯酸类树脂含量(g) | 着色(用姜黄)ΔE* | 甲硫醇浓度(ppm) | 水吸收μg/mm3 | 溶解度μg/mm3 | 断裂韧性MPa·m1/2 | |
比较实施例10 | 16FMA | 40 | 0 | 60(PMMA) | 14.5 | 22 | 8.9 | 2.7 | 0.89 |
比较实施例11 | 6FMA | 40 | 0 | 60(PMMA) | 19.6 | 24 | 9.0 | 2.6 | 0.71 |
实施例8 | 6FMA | 39.9 | 0.1 | 60(PMMA) | 12.1 | 18 | 5.3 | 1.3 | 1.03 |
实施例9 | 6FMA | 35 | 5 | 60(PMMA) | 8.5 | 12 | 3.9 | 0.8 | 1.10 |
实施例10 | 6FMA | 30 | 10 | 60(PMMA) | 7.6 | 14 | 3.1 | 0.8 | 1.08 |
实施例11 | 6FMA | 25 | 15 | 60(PMMA) | 10.2 | 16 | 4.1 | 0.4 | 1.26 |
实施例12 | 6FMA | 20 | 20 | 60(PMMA) | 16.6 | 16 | 3.5 | 1.0 | 1.17 |
实施例13 | 6FMA | 20 | 30 | 50(PMMA) | 35.7 | 18 | 3.8 | 0.7 | 1.20 |
实施例14 | 6FMA | 10 | 30 | 60(PMMA) | 21.5 | 17 | 4.0 | 0.9 | 1.13 |
比较实施例12 | 6FMA | 0 | 40 | 60(PMMA) | 41.5 | 15 | 3.2 | 0.3 | 1.23 |
氟代甲基丙烯酸酯 | 丙烯酸类树脂 | 多功能团甲基丙烯酸酯 | 着色(用姜黄)ΔE* | 甲硫醇浓度(ppm) | 水吸收μg/mm3 | 溶解度μg/mm3 | 断裂韧性MPa·m1/2 | 备注 | |
实施例15 | 6FMA | PEMA | 3G | 8.0 | 14 | 3.9 | 0.9 | 0.96 | |
实施例16 | 8FMA | PEMA | 3G | 6.4 | 14 | 4.2 | 0.8 | 0.94 | |
实施例17 | 6FMA | PMMA/PEMA | 1,10-DD | 5.9 | 10 | 1.8 | 0.2 | 1.28 | |
实施例18 | 6FMA | PMMA/PEMA | 1,10-DD | 6.2 | 11 | 2.1 | 0.3 | 1.24 | |
实施例19 | 6FMA | PMMA/PEMA | 1,6-HD | 7.2 | 12 | 1.7 | 0.4 | 1.34 | |
实施例20 | 6FMA | PMMA/PEMA | 1,6-HD | 7.5 | 10 | 2.0 | 0.5 | 1.21 | |
实施例21 | 6FMA | PMMA/PEMA | 1,6-HD | 6.9 | 12 | 1.4 | 0.6 | 1.39 | |
实施例22 | 6FMA | PMMA/PBMA | 1,6-HD | 6.4 | 11 | 2.1 | 0.8 | 1.31 | |
比较实施例13 | - | - | - | 35.7 | 28 | 12.9 | 2.6 | 1.19 | TOKUSO REBASE |
比较实施例14 | - | - | - | 40.1 | 26 | 10.8 | 3.4 | 0.84 | MILD REBARON |
氟代甲基丙烯酸酯 | 阴性 | 阳性 | |
实施例23 | 6FMA | 5 | 0 |
实施例24 | 5F/4H-BMA | 4 | 1 |
比较实施例15 | BMA | 0 | 5 |
实施例25 | 8FMA | 5 | 0 |
实施例26 | 10FMA | 5 | 0 |
实施例27 | 12FMA | 5 | 0 |
实施例28 | 16FMA | 5 | 0 |
比较实施例16 | 7F/12H-NMA | 2 | 3 |
比较实施例17 | NMA | 1 | 4 |
比较实施例18 | α-FMA | 0 | 5 |
Claims (6)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5484799 | 1999-03-03 | ||
JP54847/1999 | 1999-03-03 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1270016A CN1270016A (zh) | 2000-10-18 |
CN1146382C true CN1146382C (zh) | 2004-04-21 |
Family
ID=12982006
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB00107038XA Expired - Lifetime CN1146382C (zh) | 1999-03-03 | 2000-03-03 | 托牙底垫 |
Country Status (9)
Country | Link |
---|---|
US (1) | US6410612B1 (zh) |
EP (1) | EP1033125B1 (zh) |
KR (1) | KR100583212B1 (zh) |
CN (1) | CN1146382C (zh) |
AU (1) | AU767256B2 (zh) |
CA (1) | CA2299938C (zh) |
DE (1) | DE60005423T2 (zh) |
HK (1) | HK1032006A1 (zh) |
TW (1) | TW567070B (zh) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003095838A (ja) * | 2001-09-21 | 2003-04-03 | Gc Corp | 光重合性歯科用コーティング組成物 |
US20030073961A1 (en) * | 2001-09-28 | 2003-04-17 | Happ Dorrie M. | Medical device containing light-protected therapeutic agent and a method for fabricating thereof |
US7217426B1 (en) | 2002-06-21 | 2007-05-15 | Advanced Cardiovascular Systems, Inc. | Coatings containing polycationic peptides for cardiovascular therapy |
DE60335037D1 (de) | 2003-03-14 | 2010-12-30 | Depuy Spine Inc | Hydraulische vorrichtung zur knochenzementeinspritzung bei perkutaner vertebroplastie |
US8066713B2 (en) | 2003-03-31 | 2011-11-29 | Depuy Spine, Inc. | Remotely-activated vertebroplasty injection device |
US8791171B2 (en) * | 2003-05-01 | 2014-07-29 | Abbott Cardiovascular Systems Inc. | Biodegradable coatings for implantable medical devices |
US8415407B2 (en) | 2004-03-21 | 2013-04-09 | Depuy Spine, Inc. | Methods, materials, and apparatus for treating bone and other tissue |
WO2006011152A2 (en) | 2004-06-17 | 2006-02-02 | Disc-O-Tech Medical Technologies, Ltd. | Methods for treating bone and other tissue |
US8579908B2 (en) | 2003-09-26 | 2013-11-12 | DePuy Synthes Products, LLC. | Device for delivering viscous material |
US7244443B2 (en) | 2004-08-31 | 2007-07-17 | Advanced Cardiovascular Systems, Inc. | Polymers of fluorinated monomers and hydrophilic monomers |
US9381024B2 (en) | 2005-07-31 | 2016-07-05 | DePuy Synthes Products, Inc. | Marked tools |
US9918767B2 (en) | 2005-08-01 | 2018-03-20 | DePuy Synthes Products, Inc. | Temperature control system |
US8360629B2 (en) | 2005-11-22 | 2013-01-29 | Depuy Spine, Inc. | Mixing apparatus having central and planetary mixing elements |
US9028859B2 (en) | 2006-07-07 | 2015-05-12 | Advanced Cardiovascular Systems, Inc. | Phase-separated block copolymer coatings for implantable medical devices |
EP2068898A4 (en) | 2006-09-14 | 2011-07-20 | Depuy Spine Inc | BONE CEMENT AND APPLICATION METHOD THEREFOR |
WO2008047371A2 (en) | 2006-10-19 | 2008-04-24 | Depuy Spine, Inc. | Fluid delivery system |
CN101239024B (zh) * | 2008-03-20 | 2010-06-23 | 吉林省登泰克牙科材料有限公司 | 纳米银含氟自酸蚀单瓶牙科粘接剂 |
EP2668156B1 (en) | 2011-01-28 | 2018-10-31 | Basf Se | Polymerizable composition comprising an oxime sulfonate as thermal curing agent |
KR20160019444A (ko) * | 2013-06-14 | 2016-02-19 | 코베스트로 도이칠란트 아게 | 방향-독립적 내충격성 3-d 성형물 |
JP6403691B2 (ja) * | 2014-01-10 | 2018-10-10 | 株式会社トクヤマデンタル | 義歯床用裏装材 |
WO2016030790A1 (en) | 2014-08-29 | 2016-03-03 | Basf Se | Oxime sulfonate derivatives |
WO2021251302A1 (ja) * | 2020-06-10 | 2021-12-16 | ダイキン工業株式会社 | 含フッ素化合物 |
TWI785846B (zh) * | 2021-10-15 | 2022-12-01 | 明基材料股份有限公司 | 用於牙體修復之成型裝置的樹脂組合物 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60146810A (ja) * | 1984-01-05 | 1985-08-02 | Kureha Chem Ind Co Ltd | 軟質義歯床裏装材料 |
JPS6233110A (ja) * | 1985-08-02 | 1987-02-13 | Daikin Ind Ltd | 歯科用材料 |
DE3886868T2 (de) * | 1987-09-28 | 1994-04-28 | Daikin Ind Ltd | Adhäsivzusammensetzung für Biomaterialien. |
EP0358195A3 (en) * | 1988-09-06 | 1990-10-17 | Daikin Industries, Limited | Solid high polymer substance, process and use thereof |
DE3844619A1 (de) * | 1988-12-10 | 1990-07-12 | Goldschmidt Ag Th | Verwendung von perfluoroalkylgruppen aufweisenden (meth-)acrylsaeureestern in der dentaltechnik |
JPH05155729A (ja) * | 1991-12-03 | 1993-06-22 | Nippon Oil & Fats Co Ltd | 歯科用コーティング剤 |
-
2000
- 2000-02-28 DE DE60005423T patent/DE60005423T2/de not_active Expired - Lifetime
- 2000-02-28 EP EP00103437A patent/EP1033125B1/en not_active Expired - Lifetime
- 2000-03-01 TW TW089103600A patent/TW567070B/zh not_active IP Right Cessation
- 2000-03-01 AU AU19562/00A patent/AU767256B2/en not_active Ceased
- 2000-03-03 CA CA002299938A patent/CA2299938C/en not_active Expired - Fee Related
- 2000-03-03 CN CNB00107038XA patent/CN1146382C/zh not_active Expired - Lifetime
- 2000-03-03 KR KR1020000010683A patent/KR100583212B1/ko not_active IP Right Cessation
- 2000-03-03 US US09/518,137 patent/US6410612B1/en not_active Expired - Lifetime
-
2001
- 2001-04-12 HK HK01102663A patent/HK1032006A1/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE60005423D1 (de) | 2003-10-30 |
CN1270016A (zh) | 2000-10-18 |
CA2299938C (en) | 2008-12-02 |
HK1032006A1 (en) | 2001-07-06 |
KR20000062734A (ko) | 2000-10-25 |
TW567070B (en) | 2003-12-21 |
EP1033125B1 (en) | 2003-09-24 |
CA2299938A1 (en) | 2000-09-03 |
EP1033125A1 (en) | 2000-09-06 |
DE60005423T2 (de) | 2004-07-22 |
AU767256B2 (en) | 2003-11-06 |
KR100583212B1 (ko) | 2006-05-24 |
US6410612B1 (en) | 2002-06-25 |
AU1956200A (en) | 2000-09-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
REG | Reference to a national code |
Ref country code: HK Ref legal event code: GR Ref document number: 1032006 Country of ref document: HK |
|
ASS | Succession or assignment of patent right |
Owner name: KURARAY NORITAKE DENTAL INC. Free format text: FORMER OWNER: KURARAY CO. LTD. Effective date: 20120821 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20120821 Address after: Okayama City, Kurashiki, Japan, 1621 times the wine Jin Patentee after: Kuraray Noritake Dental Inc Address before: Okayama County, Japan Patentee before: Kuraray Co., Ltd. |
|
CX01 | Expiry of patent term |
Granted publication date: 20040421 |
|
CX01 | Expiry of patent term |