CN114620676A - 一种含钛物质催化改性镁基储氢材料及其制备方法与应用 - Google Patents
一种含钛物质催化改性镁基储氢材料及其制备方法与应用 Download PDFInfo
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- CN114620676A CN114620676A CN202011459328.1A CN202011459328A CN114620676A CN 114620676 A CN114620676 A CN 114620676A CN 202011459328 A CN202011459328 A CN 202011459328A CN 114620676 A CN114620676 A CN 114620676A
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- Prior art keywords
- titanium
- magnesium
- hydrogen storage
- storage material
- based hydrogen
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- 239000001257 hydrogen Substances 0.000 title claims abstract description 115
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 115
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 113
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 103
- 239000010936 titanium Substances 0.000 title claims abstract description 97
- 239000000463 material Substances 0.000 title claims abstract description 94
- 229910052719 titanium Inorganic materials 0.000 title claims abstract description 93
- 239000011232 storage material Substances 0.000 title claims abstract description 68
- 150000002680 magnesium Chemical class 0.000 title claims abstract description 17
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 94
- 239000011777 magnesium Substances 0.000 claims abstract description 80
- 239000000126 substance Substances 0.000 claims abstract description 69
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 64
- 229910012375 magnesium hydride Inorganic materials 0.000 claims abstract description 52
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 23
- 238000000034 method Methods 0.000 claims abstract description 22
- 230000009467 reduction Effects 0.000 claims abstract description 19
- 229910000861 Mg alloy Inorganic materials 0.000 claims abstract description 13
- 150000004678 hydrides Chemical class 0.000 claims abstract description 13
- 238000000498 ball milling Methods 0.000 claims description 78
- 239000011261 inert gas Substances 0.000 claims description 24
- 239000007789 gas Substances 0.000 claims description 19
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 18
- 238000000227 grinding Methods 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 17
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 16
- 238000001354 calcination Methods 0.000 claims description 14
- 239000007787 solid Substances 0.000 claims description 14
- 239000002994 raw material Substances 0.000 claims description 13
- 229910052700 potassium Inorganic materials 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 11
- 229910052783 alkali metal Inorganic materials 0.000 claims description 10
- 150000001340 alkali metals Chemical class 0.000 claims description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 229910052791 calcium Inorganic materials 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 9
- 229910052744 lithium Inorganic materials 0.000 claims description 9
- 229910052748 manganese Inorganic materials 0.000 claims description 9
- 229910052701 rubidium Inorganic materials 0.000 claims description 9
- 229910052725 zinc Inorganic materials 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 6
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical group [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 6
- 239000008117 stearic acid Substances 0.000 claims description 6
- 229910052712 strontium Inorganic materials 0.000 claims description 6
- 229910052727 yttrium Inorganic materials 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 5
- 229910000102 alkali metal hydride Inorganic materials 0.000 claims description 5
- 150000008046 alkali metal hydrides Chemical class 0.000 claims description 5
- 229910052788 barium Inorganic materials 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- 238000006467 substitution reaction Methods 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 4
- 238000013329 compounding Methods 0.000 claims description 4
- 239000012279 sodium borohydride Substances 0.000 claims description 4
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 4
- 239000011780 sodium chloride Substances 0.000 claims description 4
- 239000011343 solid material Substances 0.000 claims description 4
- 229910052684 Cerium Inorganic materials 0.000 claims description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 3
- 229910010252 TiO3 Inorganic materials 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 239000001110 calcium chloride Substances 0.000 claims description 3
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 3
- 239000003638 chemical reducing agent Substances 0.000 claims description 3
- 229910052738 indium Inorganic materials 0.000 claims description 3
- 229910052746 lanthanum Inorganic materials 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 239000001103 potassium chloride Substances 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- 239000012448 Lithium borohydride Substances 0.000 claims description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 3
- 238000010521 absorption reaction Methods 0.000 abstract description 18
- 238000003795 desorption Methods 0.000 abstract description 15
- 239000000203 mixture Substances 0.000 abstract description 10
- 238000003860 storage Methods 0.000 abstract description 10
- 230000004913 activation Effects 0.000 abstract description 2
- 238000006356 dehydrogenation reaction Methods 0.000 description 41
- 229910002113 barium titanate Inorganic materials 0.000 description 19
- 239000000843 powder Substances 0.000 description 16
- 238000012360 testing method Methods 0.000 description 16
- 238000005303 weighing Methods 0.000 description 11
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 8
- 229910003122 ZnTiO3 Inorganic materials 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 229910002971 CaTiO3 Inorganic materials 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 238000000634 powder X-ray diffraction Methods 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229910019096 CoTiO3 Inorganic materials 0.000 description 1
- 229910005451 FeTiO3 Inorganic materials 0.000 description 1
- 229910007848 Li2TiO3 Inorganic materials 0.000 description 1
- -1 MgCl)2 Chemical compound 0.000 description 1
- 229910017676 MgTiO3 Inorganic materials 0.000 description 1
- 229910020264 Na2TiO3 Inorganic materials 0.000 description 1
- 229910002367 SrTiO Inorganic materials 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N chromium(III) oxide Inorganic materials O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000713 high-energy ball milling Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Inorganic materials O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0078—Composite solid storage mediums, i.e. coherent or loose mixtures of different solid constituents, chemically or structurally heterogeneous solid masses, coated solids or solids having a chemically modified surface region
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
Abstract
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CN202011459328.1A CN114620676B (zh) | 2020-12-11 | 2020-12-11 | 一种含钛物质催化改性镁基储氢材料及其制备方法与应用 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN117430082A (zh) * | 2023-12-11 | 2024-01-23 | 烟台大学 | 一种镁基储氢材料及其制备方法 |
CN118083910A (zh) * | 2024-04-24 | 2024-05-28 | 大连金煜新能源有限公司 | 一种镁基储氢材料及碱金属还原二氧化钛催化剂辅助合成镁基储氢材料的方法 |
Citations (9)
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CN1570175A (zh) * | 2004-05-12 | 2005-01-26 | 浙江大学 | 一种低温可逆储氢镁基复合材料 |
JP2006130375A (ja) * | 2004-11-02 | 2006-05-25 | Bridgestone Corp | 水素貯蔵及び発生用触媒構造体並びにそれを用いた水素の貯蔵及び発生方法 |
JP2007169708A (ja) * | 2005-12-21 | 2007-07-05 | Osaka Prefecture Univ | 水素吸蔵合金の製造方法 |
JP2008156148A (ja) * | 2006-12-22 | 2008-07-10 | Mitsubishi Heavy Ind Ltd | 水素発生方法 |
JP2014181344A (ja) * | 2013-03-16 | 2014-09-29 | Zenji Hotta | TiFe水素貯蔵合金、及びTiFe水素貯蔵合金の製造方法 |
US20140332726A1 (en) * | 2013-05-09 | 2014-11-13 | Sabic Global Technologies B.V. | Alkaline earth metal/metal oxide supported catalysts |
CN108394860A (zh) * | 2018-02-05 | 2018-08-14 | 安泰科技股份有限公司 | 碳载镍催化剂掺杂的Mg(BH4)2基储氢材料及其制备方法 |
CN108588455A (zh) * | 2018-04-08 | 2018-09-28 | 安徽工业大学 | 一种改善Mg2Ni合金储氢性能的方法 |
CN111167440A (zh) * | 2020-01-07 | 2020-05-19 | 郑州大学 | 一种氨硼烷水解析氢用催化剂及其制备方法 |
-
2020
- 2020-12-11 CN CN202011459328.1A patent/CN114620676B/zh active Active
Patent Citations (9)
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CN1570175A (zh) * | 2004-05-12 | 2005-01-26 | 浙江大学 | 一种低温可逆储氢镁基复合材料 |
JP2006130375A (ja) * | 2004-11-02 | 2006-05-25 | Bridgestone Corp | 水素貯蔵及び発生用触媒構造体並びにそれを用いた水素の貯蔵及び発生方法 |
JP2007169708A (ja) * | 2005-12-21 | 2007-07-05 | Osaka Prefecture Univ | 水素吸蔵合金の製造方法 |
JP2008156148A (ja) * | 2006-12-22 | 2008-07-10 | Mitsubishi Heavy Ind Ltd | 水素発生方法 |
JP2014181344A (ja) * | 2013-03-16 | 2014-09-29 | Zenji Hotta | TiFe水素貯蔵合金、及びTiFe水素貯蔵合金の製造方法 |
US20140332726A1 (en) * | 2013-05-09 | 2014-11-13 | Sabic Global Technologies B.V. | Alkaline earth metal/metal oxide supported catalysts |
CN108394860A (zh) * | 2018-02-05 | 2018-08-14 | 安泰科技股份有限公司 | 碳载镍催化剂掺杂的Mg(BH4)2基储氢材料及其制备方法 |
CN108588455A (zh) * | 2018-04-08 | 2018-09-28 | 安徽工业大学 | 一种改善Mg2Ni合金储氢性能的方法 |
CN111167440A (zh) * | 2020-01-07 | 2020-05-19 | 郑州大学 | 一种氨硼烷水解析氢用催化剂及其制备方法 |
Non-Patent Citations (1)
Title |
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王家盛等: "MgH2+20%(w)MgTiO3复合材料的吸/放氢性能", 《物理化学学报》 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN117430082A (zh) * | 2023-12-11 | 2024-01-23 | 烟台大学 | 一种镁基储氢材料及其制备方法 |
CN118083910A (zh) * | 2024-04-24 | 2024-05-28 | 大连金煜新能源有限公司 | 一种镁基储氢材料及碱金属还原二氧化钛催化剂辅助合成镁基储氢材料的方法 |
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Application publication date: 20220614 Assignee: Dalian Jinyu New Energy Co.,Ltd. Assignor: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES Contract record no.: X2023210000296 Denomination of invention: A titanium containing catalytic modified magnesium based hydrogen storage material and its preparation method and application Granted publication date: 20230606 License type: Common License Record date: 20231211 |
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