CN114591693A - 防水型广告贴膜的制备方法 - Google Patents
防水型广告贴膜的制备方法 Download PDFInfo
- Publication number
- CN114591693A CN114591693A CN202210256132.5A CN202210256132A CN114591693A CN 114591693 A CN114591693 A CN 114591693A CN 202210256132 A CN202210256132 A CN 202210256132A CN 114591693 A CN114591693 A CN 114591693A
- Authority
- CN
- China
- Prior art keywords
- layer
- parts
- glue solution
- substrate layer
- waterproof
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000000758 substrate Substances 0.000 claims abstract description 24
- 239000003292 glue Substances 0.000 claims abstract description 22
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000011248 coating agent Substances 0.000 claims abstract description 13
- 238000000576 coating method Methods 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims abstract description 6
- VYZKQGGPNIFCLD-UHFFFAOYSA-N 3,3-dimethylhexane-2,2-diol Chemical compound CCCC(C)(C)C(C)(O)O VYZKQGGPNIFCLD-UHFFFAOYSA-N 0.000 claims abstract description 6
- MTPJEFOSTIKRSS-UHFFFAOYSA-N 3-(dimethylamino)propanenitrile Chemical compound CN(C)CCC#N MTPJEFOSTIKRSS-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 6
- WRXCBRHBHGNNQA-UHFFFAOYSA-N (2,4-dichlorobenzoyl) 2,4-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1Cl WRXCBRHBHGNNQA-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000008367 deionised water Substances 0.000 claims abstract description 5
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims abstract description 5
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 8
- YDVJBLJCSLVMSY-UHFFFAOYSA-N carbamoyl cyanide Chemical compound NC(=O)C#N YDVJBLJCSLVMSY-UHFFFAOYSA-N 0.000 claims description 3
- 239000000463 material Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 abstract description 48
- 239000000853 adhesive Substances 0.000 abstract description 11
- 230000001070 adhesive effect Effects 0.000 abstract description 11
- 239000012790 adhesive layer Substances 0.000 abstract description 7
- 230000007774 longterm Effects 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 7
- 230000002035 prolonged effect Effects 0.000 description 3
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000003857 carboxamides Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/062—Copolymers with monomers not covered by C09J133/06
- C09J133/064—Copolymers with monomers not covered by C09J133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/245—Vinyl resins, e.g. polyvinyl chloride [PVC]
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2427/00—Presence of halogenated polymer
- C09J2427/006—Presence of halogenated polymer in the substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Abstract
本发明公开了一种防水型广告贴膜的制备方法，所述防水型广告贴膜包括基材层、背胶层和离型层，所述基材层的一面上涂覆于背胶层，所述背胶层相背于基材层的一面设有离型层，所述背胶层由胶液涂覆烘干获得，此胶液由以下步骤制得：S1、将甲基丙烯酸甲酯、苯乙烯、丙烯酸‑2‑乙基己酯、三甲基戊二醇、二甲氨基丙腈1~5份和去离子水混合均匀，升温至75~80℃，向该混合体系中滴加偶氮异丁氰基甲酰胺和丙烯酸；冷却至室温，加入过氧化双2，4一二氯苯甲酰、固化剂、乳化剂和对苯二酚，混合均匀得到胶液；将胶液均匀涂覆于基材层上，烘干得到背胶层。本发明使得防水型广告贴膜的制备方法在环境湿度较大的情况下，粘着力基本不变，使得粘接稳定，从而适合长期室外使用。
Description
技术领域
本发明属于广告贴膜技术领域，尤其涉及一种防水型广告贴膜的制备方法。
背景技术
现有的部分广告贴，例如车贴、水性高亮PVC，都具有PVC膜、粘接层和离型纸，其中离型纸由硅油层、淋膜层和底纸构成，硅油层与广告贴的粘接层连接，在使用时剥离离型纸，以将粘接层暴露，进而将广告贴贴于指定位置。
目前市面上及国内生产的广告贴使用的是油性体系压敏胶，胶水有溶剂残留，VOC排放不达标，只能应用于室外环境。因此环保型水基胶粘剂已成为胶粘剂的发展方向，而环保型胶粘剂的研制成果相对较少，防水性能不尽人意，且制造工艺比较复杂。因此，如何开发一种防水性能优良、可长期室外使用的车身贴成为本领域技术人员的研究方向。
发明内容
本发明目的在于提供一种防水型广告贴膜的制备方法，该防水型广告贴膜的制备方法既提高了防水性能，也使得防水型广告贴膜的制备方法在环境湿度较大的情况下，粘着力基本不变，使得粘接稳定，不会出现脱落的情况，从而适合长期室外使用，大大延长了车身贴的使用寿命。
为达到上述目的，本发明采用的技术方案是：一种防水型广告贴膜的制备方法，所述防水型广告贴膜包括基材层、背胶层和离型层，所述基材层的一面上涂覆于背胶层，所述背胶层相背于基材层的一面设有离型层，所述背胶层由胶液涂覆烘干获得，此胶液由以下步骤制得：
S1、将甲基丙烯酸甲酯15份、苯乙烯15份、丙烯酸-2-乙基己酯20份、三甲基戊二醇1份、二甲氨基丙腈2份和去离子水70份混合均匀，升温至75~80℃，向该混合体系中滴加偶氮异丁氰基甲酰胺0.5份和丙烯酸6份，反应3~4h；
S2、冷却至室温，加入过氧化双2，4一二氯苯甲酰2份、固化剂1.5份、乳化剂0.2份和对苯二酚0.1份，混合均匀得到胶液；
S3、将胶液均匀涂覆于基材层上，烘干得到背胶层。
上述技术方案中进一步改进的技术方案如下：
1. 上述方案中：所述甲基丙烯酸甲酯与苯乙烯的添加比例为2：1~1：1。
2. 上述方案中：所述基材层为PVC层。
3. 上述方案中：所述基材层的厚度为50~150μm。
由于上述技术方案的运用，本发明与现有技术相比具有下列优点：
本发明防水型广告贴膜的制备方法，其通过在甲基丙烯酸甲酯、苯乙烯、丙烯酸-2-乙基己酯、丙烯酸和偶氮异丁氰基甲酰胺中添加三甲基戊二醇、二甲氨基丙腈，既提高了防水性能，也使得防水型广告贴膜的制备方法在环境湿度较大的情况下，粘着力基本不变，使得粘接稳定，从而适合长期室外使用，不会出现脱落的情况，大大延长了车身贴的使用寿命。
具体实施方式
在本专利的描述中，需要说明的是，术语“中心”、“上”、“下”、“左”、“右”、“竖直”、“水平”、“内”、“外”等指示的方位或位置关系为基于技术方案所示的方位或位置关系，仅是为了便于描述本专利和简化描述，而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作，因此不能理解为对专利的限制；术语“第一”、“第二”、“第三”仅用于描述目的，而不能理解为指示或暗示相对重要性；此外，除非另有明确的规定和限定，术语“安装”、“相连”、“连接”应做广义理解，例如，可以是固定连接，也可以是可拆卸连接，或一体地连接；可以是机械连接，也可以是电连接；可以是直接相连，也可以通过中间媒介间接相连，可以是两个元件内部的连通。对于本领域的普通技术人员而言，可以具体情况理解上述术语在本专利的具体含义。
下面结合实施例对本发明作进一步描述：
实施例：一种防水型广告贴膜的制备方法，所述防水型广告贴膜包括基材层、背胶层和离型层，所述基材层的一面上涂覆于背胶层，所述背胶层相背于基材层的一面设有离型层，所述背胶层由胶液涂覆烘干获得，此胶液由以下步骤制得：
S1、将甲基丙烯酸甲酯15份、苯乙烯15份、丙烯酸-2-乙基己酯20份、三甲基戊二醇1份、二甲氨基丙腈2份和去离子水70份混合均匀，升温至75~80℃，向该混合体系中滴加偶氮异丁氰基甲酰胺0.5份和丙烯酸6份，反应3~4h；
S2、冷却至室温，加入过氧化双2，4一二氯苯甲酰2份、固化剂1.5份、乳化剂0.2份和对苯二酚0.1份，混合均匀得到胶液；
S3、将胶液均匀涂覆于基材层上，烘干得到背胶层。
甲基丙烯酸甲酯与苯乙烯的添加比例为1:1，上述固化剂选自固化剂S01-5，上述乳化剂选自乙氧基化C16-18-醇。
上述基材层为PVC层，上述基材层的厚度为70μm，上述背胶层厚度为15μm。
对比例1~2：一种户外用广告车贴的制备方法，包括基材层、背胶层和离型层，所述基材层的一面上涂覆于背胶层，所述背胶层相背于基材层的一面设有离型层，所述背胶层由胶液涂覆烘干获得，此胶液由以下重量份组分组成，如表1所示：
表1
| 组分 | 对比例1 | 对比例2 |
| 甲基丙烯酸甲酯 | 18份 | 20份 |
| 苯乙烯 | 15份 | 10份 |
| 丙烯酸-2-乙基己酯 | 15份 | 16份 |
| 丙烯酸 | 3份 | 1份 |
| 过氧化双2，4一二氯苯甲酰 | 2份 | 3份 |
| 偶氮异丁氰基甲酰胺 | 0.5份 | 0.8份 |
| 三甲基戊二醇 | - | 1.1份 |
| 二甲氨基丙腈 | 2份 | - |
| 固化剂 | 1.5份 | 1份 |
| 去离子水 | 75份 | 60份 |
| 乳化剂 | 0.2份 | 0.5份 |
| 对苯二酚 | 0.1份 | 0.5份 |
对比例制备方法同实施例。
上述实施例和对比例1~2制得的抗静电膜的性能如表2所示：
表2
测试方法：
耐水试验测定方法：所制得试样在沸水(100℃)条件下蒸煮，经过1H、10H和24H分别测试粘着力情况。
如表2的评价结果所示，实施例防水型广告贴膜的制备方法防水性能优良，在水中浸泡长时间粘着力几乎不会发生变化，而对比例1防水性能相对差，对比例2粘着力随着浸泡时间变化，粘着力快速下降；可知，本发明既提高了防水性能，也使得防水型广告贴膜的制备方法在水中浸泡时间较长的情况下，粘着力变化很小，防水性能稳定，不会产生脱落的现象，从而适合长期室外使用，大大延长了车身贴的使用寿命。
上述实施例只为说明本发明的技术构思及特点，其目的在于让熟悉此项技术的人士能够了解本发明的内容并据以实施，并不能以此限制本发明的保护范围。凡根据本发明精神实质所作的等效变化或修饰，都应涵盖在本发明的保护范围之内。
Claims (4)
1.一种防水型广告贴膜的制备方法，其特征在于：所述防水型广告贴膜包括基材层、背胶层和离型层，所述基材层的一面上涂覆于背胶层，所述背胶层相背于基材层的一面设有离型层，所述背胶层由胶液涂覆烘干获得，此胶液由以下步骤制得：
S1、将甲基丙烯酸甲酯15份、苯乙烯15份、丙烯酸-2-乙基己酯20份、三甲基戊二醇1份、二甲氨基丙腈2份和去离子水70份混合均匀，升温至75~80℃，向该混合体系中滴加偶氮异丁氰基甲酰胺0.5份和丙烯酸6份，反应3~4h；
S2、冷却至室温，加入过氧化双2，4一二氯苯甲酰2份、固化剂1.5份、乳化剂0.2份和对苯二酚0.1份，混合均匀得到胶液；
S3、将胶液均匀涂覆于基材层上，烘干得到背胶层。
2.根据权利要求1所述的防水型广告贴膜的制备方法，其特征在于：所述甲基丙烯酸甲酯与苯乙烯的添加比例为2：1~1：1。
3.根据权利要求1所述的防水型广告贴膜的制备方法，其特征在于：所述基材层（1）为PVC层。
4.根据权利要求1所述的防水型广告贴膜的制备方法，其特征在于：所述基材层（1）的厚度为50~150μm。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210256132.5A CN114591693B (zh) | 2019-07-22 | 2019-07-22 | 广告车贴的制备方法 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210256132.5A CN114591693B (zh) | 2019-07-22 | 2019-07-22 | 广告车贴的制备方法 |
| CN201910659481.XA CN112251155B (zh) | 2019-07-22 | 2019-07-22 | 户外用耐气候广告车贴的制备方法 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910659481.XA Division CN112251155B (zh) | 2019-07-22 | 2019-07-22 | 户外用耐气候广告车贴的制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114591693A true CN114591693A (zh) | 2022-06-07 |
| CN114591693B CN114591693B (zh) | 2024-02-20 |
Family
ID=74224407
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910659481.XA Active CN112251155B (zh) | 2019-07-22 | 2019-07-22 | 户外用耐气候广告车贴的制备方法 |
| CN202210256132.5A Active CN114591693B (zh) | 2019-07-22 | 2019-07-22 | 广告车贴的制备方法 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910659481.XA Active CN112251155B (zh) | 2019-07-22 | 2019-07-22 | 户外用耐气候广告车贴的制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN112251155B (zh) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5756569A (en) * | 1996-12-19 | 1998-05-26 | Carver; Bobby Carroll | Use of alkyl 3-alkoxypropionates as coalescing agents in aqueous coating compositions |
| CN102352196A (zh) * | 2011-10-13 | 2012-02-15 | 上海嘉华广告有限公司 | 广告喷绘用冷裱膜 |
| CN105860625A (zh) * | 2016-05-25 | 2016-08-17 | 褚红芬 | 一种快速凝胶堵漏剂 |
| CN109476942A (zh) * | 2016-07-04 | 2019-03-15 | 东洋油墨Sc控股株式会社 | 非水系印刷油墨组合物 |
| CN109913141A (zh) * | 2019-01-21 | 2019-06-21 | 苏州义铠轩电子科技有限公司 | 制程用可重工热失粘胶带及其制备方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997031982A1 (en) * | 1996-03-01 | 1997-09-04 | Eastman Chemical Company | The use of alkyl 3-alkoxypropionates as coalescing agents in aqueous coating compositions |
| CN105400464B (zh) * | 2015-12-24 | 2017-02-08 | 广州市金万正印刷材料有限公司 | 一种耐冻丙烯酸酯压敏胶粘剂及其制备方法和其在制备耐冻丙烯酸酯压敏标签中的应用 |
-
2019
- 2019-07-22 CN CN201910659481.XA patent/CN112251155B/zh active Active
- 2019-07-22 CN CN202210256132.5A patent/CN114591693B/zh active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5756569A (en) * | 1996-12-19 | 1998-05-26 | Carver; Bobby Carroll | Use of alkyl 3-alkoxypropionates as coalescing agents in aqueous coating compositions |
| CN102352196A (zh) * | 2011-10-13 | 2012-02-15 | 上海嘉华广告有限公司 | 广告喷绘用冷裱膜 |
| CN105860625A (zh) * | 2016-05-25 | 2016-08-17 | 褚红芬 | 一种快速凝胶堵漏剂 |
| CN109476942A (zh) * | 2016-07-04 | 2019-03-15 | 东洋油墨Sc控股株式会社 | 非水系印刷油墨组合物 |
| CN109913141A (zh) * | 2019-01-21 | 2019-06-21 | 苏州义铠轩电子科技有限公司 | 制程用可重工热失粘胶带及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN112251155B (zh) | 2022-03-15 |
| CN114591693B (zh) | 2024-02-20 |
| CN112251155A (zh) | 2021-01-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110527464B (zh) | 高粘耐黄变防爆膜胶水，胶带及其制备方法 | |
| CN104210195B (zh) | 一种高密着性防静电离型膜 | |
| CN105683320B (zh) | 导电性粘合片和电子设备 | |
| CN112646515A (zh) | 一种耐高温溶剂型丙烯酸酯压敏胶及其制备方法 | |
| CN102703002A (zh) | 一种环保耐高温易剥离的电子工业用压敏胶及其制备方法 | |
| CN113930195A (zh) | 水性丙烯酸压敏胶、制备方法以及泡棉胶带 | |
| CN110938394A (zh) | 一种胶黏剂及其制备方法、由其制得的胶黏剂层以及热减粘胶带 | |
| CN113698892A (zh) | 一种双面热熔压敏胶带及其制备方法 | |
| CN112251162B (zh) | 耐水性户外广告车身贴 | |
| CN111748292A (zh) | 一种柔性双面胶带及其制备工艺 | |
| CN114015056B (zh) | 一种耐电压耐电解液共聚物、极耳胶黏剂及极耳胶带 | |
| CN112251155B (zh) | 户外用耐气候广告车贴的制备方法 | |
| CN109337597A (zh) | 一种防震发泡型的双面胶材料及其制备方法 | |
| CN107236477B (zh) | 一种无残留型临时固定粘合剂及其制备方法 | |
| WO2024032382A1 (zh) | 耐热型uv减粘胶水及其在制备燃料电池中的应用 | |
| CN111073558A (zh) | 一种高抗剪切的丙烯酸酯压敏胶、压敏胶带及其制备方法 | |
| CN111073548A (zh) | 柔性oled模组用哑光胶带离型膜、哑光双面胶带及制备方法 | |
| CN113881365B (zh) | 一种薄涂高粘溶剂丙烯酸压敏胶及其合成方法 | |
| CN112194988B (zh) | 户外广告车身贴的制备方法 | |
| CN114163950A (zh) | 一种单组分亚克力胶粘剂及其制备方法和应用 | |
| CN112194987B (zh) | 易剥离户外广告车身贴 | |
| KR102267537B1 (ko) | 전극 | |
| CN105441009A (zh) | 一种双重响应性复合粘胶剂 | |
| CN111100578A (zh) | 一种胶粘剂制品 | |
| US20240034911A1 (en) | Composition for self-suction adhering foam sheet and self-suction adhering foam laminate sheet |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |