CN114196468A - 一种通用型冲压成型油及其制备方法 - Google Patents

一种通用型冲压成型油及其制备方法 Download PDF

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CN114196468A
CN114196468A CN202111643242.9A CN202111643242A CN114196468A CN 114196468 A CN114196468 A CN 114196468A CN 202111643242 A CN202111643242 A CN 202111643242A CN 114196468 A CN114196468 A CN 114196468A
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oil
percent
stamping forming
forming oil
ester
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李清华
汪小龙
谢宗生
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Amer Technology Co Ltd
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Abstract

本发明提供一种通用型冲压成型油及其制备方法,涉及冲压成型油技术领域,所述通用型冲压成型油的制备材料是由二烃基五硫化物莱茵RC2541、非活性硫化猪油、超碱值磺酸钙、抗磨剂、不干性油、合成酯、氧化石蜡丁酯、噻二唑衍生物、矿物油、抗氧化剂、防腐剂、分散剂和润滑性添加剂构成。本发明,通过采用二烃基五硫化物莱茵RC2541,可提供很好的极压性,且对有色金属腐蚀较低,使成品冲压成型油可用于有色金属的加工,且具有极好的极压性,使成品冲压成型油适宜于加工不锈钢、合金钢等难加工金属,且成品冲压成型油具有优良的防锈性,适用于铸铁、碳钢等易生锈金属,以便使成品冲压成型油能够具有更广的使用范围,以便达到更好的使用效果。

Description

一种通用型冲压成型油及其制备方法
技术领域
本发明涉及冲压成型油技术领域,尤其涉及一种通用型冲压成型油及其制备方法。
背景技术
在对不锈钢、合金钢等难加工材质加工时,往往需要油品具备很好的极压性,但常用的活性硫、含氯极压剂等又会对铜、铁等金属材质产生腐蚀,含磷极压剂又和许多添加剂的兼容性有冲突,这导致现有的冲压成型油在使用时,使用范围往往较为局限,难以达到较好的使用效果。
中国专利号CN102965177B公开了一种冲压油,其原料组分及重量百分比如下:蓖麻油88-92%、大豆油6-9%、猪脂肪1.5-3%,该冲压油虽然具有润滑性、且较为环保,同时不会对铜、铁等金属材质产生腐蚀,但其极压性较差,在加工不锈钢、合金钢的过程中,难以形成均匀连续、完整的液体介质膜,难以达到较好的润滑效果,需要进行改进。
中国专利号CN105296085B公开了一种冲压油组合物及其用途,其原料组分及重量份数比如下:精制矿物油60-85份、油性剂5-25份、防锈剂0.5-10份、表面活性剂2-10份、极压剂2-10份,该冲压油组合物虽然具有良好的极压性,且清洗工件表面的污渍,但其会对对铜、铁等金属材质产生腐蚀,难以达到较好的使用效果,需要进行改进。
发明内容
本发明的目的是为了解决现有技术中存在的缺点,而提出的一种通用型冲压成型油及其制备方法。
为了实现上述目的,本发明采用了如下技术方案:一种通用型冲压成型油,所述通用型冲压成型油的制备材料是由二烃基五硫化物莱茵RC2541、非活性硫化猪油、超碱值磺酸钙、抗磨剂、不干性油、合成酯、氧化石蜡丁酯、噻二唑衍生物、矿物油、抗氧化剂、防腐剂、分散剂和润滑性添加剂构成,且由以下重量百分数的组分组成:二烃基五硫化物莱茵RC2541 0.1-1%,非活性硫化猪油0.5-10%,超碱值磺酸钙1-5%,抗磨剂0.1-5%,不干性油1-10%,合成酯1-20%,氧化石蜡丁酯0.1-1%,噻二唑衍生物0.05-0.5%,矿物油40-90%,抗氧化剂0.5-1%,防腐剂0.1-0.5%,分散剂0.4-1%,润滑性添加剂1-5%。
为了使成品冲压成型油能够达到较好的抗磨效果,本发明的改进有,所述抗磨剂为硫代氨基甲酸酯与烷基硫代磷酸锌中的一种或两种。
为了使成品冲压成型油能够达到更好的润滑效果,本发明的改进有,所述润滑性添加剂为异氰尿酸三聚氰胺,油酸异辛酯、三羟甲基丙烷油酸酯、偏苯三酸酯、多元醇酯、季戊四醇油酸酯、双季戊四醇油酸酯、中的一种或多种任意比例混合物。
为了防止成品冲压成型油干燥,本发明的改进有,所述不干性油为碘值为100以下的脂肪酸三甘油酯,优选棕榈油、蓖麻油与橄榄油中的一种。
为了使成品冲压成型油能够具有更长保存时间,本发明的改进有,所述合成酯为单酯、双酯与多元醇酯的任意比例混合物。
为了使制备材料能够充分分散,本发明的改进有,所述分散剂为单烯基二酰亚胺、双烯基丁二酰亚胺、多烯基丁二酰亚胺聚与异丁烯丁二酰亚胺中的一种或多种,所述防腐剂为硫磷丁辛基锌盐、硫磷烷基酚锌盐、硫磷二烷基锌盐中的一种或多种,所述抗氧化剂为2,6二叔丁基对甲酚、2,6-二叔丁基混合酯、丁基羟基茴香醚与叔丁基对苯二酚中的一种。
为了达到不同的效果,本发明的改进有,由以下重量百分数的组分组成:二烃基五硫化物莱茵RC2541 0.1%,非活性硫化猪油10%,超碱值磺酸钙1%,抗磨剂5%,不干性油10%,合成酯5%,氧化石蜡丁酯1%,噻二唑衍生物0.05%,矿物油63.15%,抗氧化剂0.6%,防腐剂0.5%,分散剂0.6%,润滑性添加剂3%。
为了达到不同的效果,本发明的改进有,由以下重量百分数的组分组成:二烃基五硫化物莱茵RC2541 1%,非活性硫化猪油0.5%,超碱值磺酸钙5%,抗磨剂2%,不干性油1%,合成酯20%,氧化石蜡丁酯0.1%,噻二唑衍生物0.5%,矿物油65%,抗氧化剂0.8%,防腐剂0.4%,分散剂0.7%,润滑性添加剂3%。
为了达到不同的效果,本发明的改进有,由以下重量百分数的组分组成:二烃基五硫化物莱茵RC2541 0.5%,非活性硫化猪油5%,超碱值磺酸钙3%,抗磨剂3%,不干性油5%,合成酯10%,氧化石蜡丁酯0.5%,噻二唑衍生物0.2%,矿物油66.5%,抗氧化剂1%,防腐剂0.3%,分散剂1%,润滑性添加剂4%。
一种通用型冲压成型油的制备方法,包括以下步骤:
S1:将矿物油、非活性硫化猪油、不干性油与氧化石蜡丁酯一同倒入调合釜内,然后将调合釜的温度调节至40-60℃,进行搅拌,搅拌时间为15-30分钟,从而得到初始混合物;
S2:将硫化烯烃、超碱值磺酸钙、抗磨剂、合成酯与噻二唑衍生物一种倒入调合釜内,保持调合釜的温度进行搅拌,搅拌时间为10-20分钟,从而得到次混合物;
S3:将抗氧化剂、防腐剂、分散剂与润滑性添加剂一同倒入调合釜内,然后将调合釜的温度调节至30-40℃,进行搅拌,搅拌时间为20-30分钟,从而得到成品冲压成型油。
与现有技术相比,本发明的优点和积极效果在于,
本发明中,通过采用二烃基五硫化物莱茵RC2541,该添加剂含高活硫(活性硫含量约38%),可提供很好的极压性,同时该添加剂铜片腐蚀为1b,并且加入噻二唑衍生物进行补强,保证成品冲压成型油对铜、铝等有色金属不产生腐蚀,可用于有色金属的加工,且加入超碱值磺酸钙,使成品冲压成型油具有极好的极压性,使成品冲压成型油适宜于加工不锈钢、合金钢等难加工金属,且超碱值磺酸钙本身也有极佳的防锈性,同时加入氧化石蜡丁酯进行协同增效,使成品冲压成型油具有优良的防锈性,可提供工序间防锈,适用于铸铁、碳钢等易生锈金属,以便使成品冲压成型油能够具有更广的使用范围,以便达到更好的使用效果,同时润滑性添加剂能够使成品具有良好的润滑效果,以便成品冲压成型油能够达到更好加工使用效果,同时加入抗氧化剂防止氧化,加入防腐剂防止变质,使成品冲压成型油能够具有更长的保存时间,而分散剂能够使成品冲压成型油内的各种材料不易分层,以便成品冲压成型油能够具有更好的使用效果。
附图说明
图1为本发明提出一种通用型冲压成型油及其制备方法的流程图;
图2为本发明提出一种通用型冲压成型油及其制备方法的俯视的检测结果图。
具体实施方式
为了能够更清楚地理解本发明的上述目的、特征和优点,下面结合附图和实施例对本发明做进一步说明。需要说明的是,在不冲突的情况下,本申请的实施例及实施例中的特征可以相互组合。
在本发明的描述中,需要理解的是,术语“长度”、“宽度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。此外,在本发明的描述中,“多个”的含义是两个或两个以上,除非另有明确具体的限定。
请参阅图1-2,本发明提供一种通用型冲压成型油,通用型冲压成型油的制备材料是由二烃基五硫化物莱茵RC2541、非活性硫化猪油、超碱值磺酸钙、抗磨剂、不干性油、合成酯、氧化石蜡丁酯、噻二唑衍生物、矿物油、抗氧化剂、防腐剂、分散剂和润滑性添加剂构成,且由以下重量百分数的组分组成:二烃基五硫化物莱茵RC2541 0.1-1%,非活性硫化猪油0.5-10%,超碱值磺酸钙1-5%,抗磨剂0.1-5%,不干性油1-10%,合成酯1-20%,氧化石蜡丁酯0.1-1%,噻二唑衍生物0.05-0.5%,矿物油40-90%,抗氧化剂0.5-1%,防腐剂0.1-0.5%,分散剂0.4-1%,润滑性添加剂1-5%,二烃基五硫化物莱茵RC2541可提供很好的极压性,同时该添加剂铜片腐蚀为1b,并且加入噻二唑衍生物进行补强,保证成品冲压成型油对铜、铝等有色金属不产生腐蚀,可用于有色金属的加工,超碱值磺酸钙,使成品冲压成型油具有极好的极压性,使成品冲压成型油适宜于加工不锈钢、合金钢等难加工金属,且超碱值磺酸钙本身也有极佳的防锈性,同时加入氧化石蜡丁酯进行协同增效,使成品冲压成型油具有优良的防锈性,可提供工序间防锈,适用于铸铁、碳钢等易生锈金属,以便使成品冲压成型油能够具有更广的使用范围,以便达到更好的使用效果。
抗磨剂为硫代氨基甲酸酯与烷基硫代磷酸锌中的一种或两种,润滑性添加剂为异氰尿酸三聚氰胺,油酸异辛酯、三羟甲基丙烷油酸酯、偏苯三酸酯、多元醇酯、季戊四醇油酸酯、双季戊四醇油酸酯、中的一种或多种任意比例混合物,润滑性添加剂能够使成品具有良好的润滑效果,以便成品冲压成型油能够达到更好加工使用效果。
不干性油为碘值为100以下的脂肪酸三甘油酯,优选棕榈油、蓖麻油与橄榄油中的一种,合成酯为单酯、双酯与多元醇酯的任意比例混合物。
分散剂为单烯基二酰亚胺、双烯基丁二酰亚胺、多烯基丁二酰亚胺聚与异丁烯丁二酰亚胺中的一种或多种,防腐剂为硫磷丁辛基锌盐、硫磷烷基酚锌盐、硫磷二烷基锌盐中的一种或多种,抗氧化剂为2,6二叔丁基对甲酚、2,6-二叔丁基混合酯、丁基羟基茴香醚与叔丁基对苯二酚中的一种,加入抗氧化剂防止氧化,加入防腐剂防止变质,使成品冲压成型油能够具有更长的保存时间,而分散剂能够使成品冲压成型油内的各种材料不易分层,以便成品冲压成型油能够具有更好的使用效果。
实施例一
由以下重量百分数的组分组成:二烃基五硫化物莱茵RC2541 0.1%,非活性硫化猪油10%,超碱值磺酸钙1%,抗磨剂5%,不干性油10%,合成酯5%,氧化石蜡丁酯1%,噻二唑衍生物0.05%,矿物油63.15%,抗氧化剂0.6%,防腐剂0.5%,分散剂0.6%,润滑性添加剂3%。
一种通用型冲压成型油的制备方法,包括以下步骤:
S1:将矿物油、非活性硫化猪油、不干性油与氧化石蜡丁酯一同倒入调合釜内,然后将调合釜的温度调节至58℃,进行搅拌,搅拌时间为25分钟,从而得到初始混合物;
S2:将硫化烯烃、超碱值磺酸钙、抗磨剂、合成酯与噻二唑衍生物一种倒入调合釜内,保持调合釜的温度进行搅拌,搅拌时间为13分钟,从而得到次混合物;
S3:将抗氧化剂、防腐剂、分散剂与润滑性添加剂一同倒入调合釜内,然后将调合釜的温度调节至35℃,进行搅拌,搅拌时间为26分钟,从而得到成品冲压成型油。
实施例二
由以下重量百分数的组分组成:二烃基五硫化物莱茵RC2541 1%,非活性硫化猪油0.5%,超碱值磺酸钙5%,抗磨剂2%,不干性油1%,合成酯20%,氧化石蜡丁酯0.1%,噻二唑衍生物0.5%,矿物油65%,抗氧化剂0.8%,防腐剂0.4%,分散剂0.7%,润滑性添加剂3%。
一种通用型冲压成型油的制备方法,包括以下步骤:
S1:将矿物油、非活性硫化猪油、不干性油与氧化石蜡丁酯一同倒入调合釜内,然后将调合釜的温度调节至55℃,进行搅拌,搅拌时间为22分钟,从而得到初始混合物;
S2:将硫化烯烃、超碱值磺酸钙、抗磨剂、合成酯与噻二唑衍生物一种倒入调合釜内,保持调合釜的温度进行搅拌,搅拌时间为16分钟,从而得到次混合物;
S3:将抗氧化剂、防腐剂、分散剂与润滑性添加剂一同倒入调合釜内,然后将调合釜的温度调节至36℃,进行搅拌,搅拌时间为24分钟,从而得到成品冲压成型油。
实施例三
由以下重量百分数的组分组成:二烃基五硫化物莱茵RC2541 0.5%,非活性硫化猪油5%,超碱值磺酸钙3%,抗磨剂3%,不干性油5%,合成酯10%,氧化石蜡丁酯0.5%,噻二唑衍生物0.2%,矿物油66.5%,抗氧化剂1%,防腐剂0.3%,分散剂1%,润滑性添加剂4%。
一种通用型冲压成型油的制备方法,包括以下步骤:
S1:将矿物油、非活性硫化猪油、不干性油与氧化石蜡丁酯一同倒入调合釜内,然后将调合釜的温度调节至48℃,进行搅拌,搅拌时间为24分钟,从而得到初始混合物;
S2:将硫化烯烃、超碱值磺酸钙、抗磨剂、合成酯与噻二唑衍生物一种倒入调合釜内,保持调合釜的温度进行搅拌,搅拌时间为18分钟,从而得到次混合物;
S3:将抗氧化剂、防腐剂、分散剂与润滑性添加剂一同倒入调合釜内,然后将调合釜的温度调节至32℃,进行搅拌,搅拌时间为25分钟,从而得到成品冲压成型油。
对实施例一、实施例二、实施例三得到的成品冲压成型油进行检测,检测结果如说明书附图所示,由此可知本发明的成品冲压成型油是一种极压性好,且对有色金属不产生腐蚀的冲压成型油产品。
本发明,通过采用二烃基五硫化物莱茵RC2541,该添加剂含高活硫(活性硫含量约38%),可提供很好的极压性,同时该添加剂铜片腐蚀为1b,并且加入噻二唑衍生物进行补强,保证成品冲压成型油对铜、铝等有色金属不产生腐蚀,可用于有色金属的加工,且加入超碱值磺酸钙,使成品冲压成型油具有极好的极压性,使成品冲压成型油适宜于加工不锈钢、合金钢等难加工金属,且超碱值磺酸钙本身也有极佳的防锈性,同时加入氧化石蜡丁酯进行协同增效,使成品冲压成型油具有优良的防锈性,可提供工序间防锈,适用于铸铁、碳钢等易生锈金属,以便使成品冲压成型油能够具有更广的使用范围,以便达到更好的使用效果,同时润滑性添加剂能够使成品具有良好的润滑效果,以便成品冲压成型油能够达到更好加工使用效果,同时加入抗氧化剂防止氧化,加入防腐剂防止变质,使成品冲压成型油能够具有更长的保存时间,而分散剂能够使成品冲压成型油内的各种材料不易分层,以便成品冲压成型油能够具有更好的使用效果。
以上,仅是本发明的较佳实施例而已,并非是对本发明作其它形式的限制,任何熟悉本专业的技术人员可能利用上述揭示的技术内容加以变更或改型为等同变化的等效实施例应用于其它领域,但是凡是未脱离本发明技术方案内容,依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化与改型,仍属于本发明技术方案的保护范围。

Claims (10)

1.一种通用型冲压成型油,其特征在于:所述通用型冲压成型油的制备材料是由二烃基五硫化物莱茵RC2541、非活性硫化猪油、超碱值磺酸钙、抗磨剂、不干性油、合成酯、氧化石蜡丁酯、噻二唑衍生物、矿物油、抗氧化剂、防腐剂、分散剂和润滑性添加剂构成,且由以下重量百分数的组分组成:二烃基五硫化物莱茵RC2541 0.1-1%,非活性硫化猪油0.5-10%,超碱值磺酸钙1-5%,抗磨剂0.1-5%,不干性油1-10%,合成酯1-20%,氧化石蜡丁酯0.1-1%,噻二唑衍生物0.05-0.5%,矿物油40-90%,抗氧化剂0.5-1%,防腐剂0.1-0.5%,分散剂0.4-1%,润滑性添加剂1-5%。
2.根据权利要求1所述的通用型冲压成型油,其特征在于:所述抗磨剂为硫代氨基甲酸酯与烷基硫代磷酸锌中的一种或两种。
3.根据权利要求1所述的通用型冲压成型油,其特征在于:所述润滑性添加剂为异氰尿酸三聚氰胺,油酸异辛酯、三羟甲基丙烷油酸酯、偏苯三酸酯、多元醇酯、季戊四醇油酸酯、双季戊四醇油酸酯、中的一种或多种任意比例混合物。
4.根据权利要求1所述的通用型冲压成型油,其特征在于:所述不干性油为碘值为100以下的脂肪酸三甘油酯,优选棕榈油、蓖麻油与橄榄油中的一种。
5.根据权利要求1所述的通用型冲压成型油,其特征在于:所述合成酯为单酯、双酯与多元醇酯的任意比例混合物。
6.根据权利要求1所述的通用型冲压成型油,其特征在于:所述分散剂为单烯基二酰亚胺、双烯基丁二酰亚胺、多烯基丁二酰亚胺聚与异丁烯丁二酰亚胺中的一种或多种,所述防腐剂为硫磷丁辛基锌盐、硫磷烷基酚锌盐、硫磷二烷基锌盐中的一种或多种,所述抗氧化剂为2,6二叔丁基对甲酚、2,6-二叔丁基混合酯、丁基羟基茴香醚与叔丁基对苯二酚中的一种。
7.根据权利要求1所述的通用型冲压成型油,其特征在于:由以下重量百分数的组分组成:二烃基五硫化物莱茵RC2541 0.1%,非活性硫化猪油10%,超碱值磺酸钙1%,抗磨剂5%,不干性油10%,合成酯5%,氧化石蜡丁酯1%,噻二唑衍生物0.05%,矿物油63.15%,抗氧化剂0.6%,防腐剂0.5%,分散剂0.6%,润滑性添加剂3%。
8.根据权利要求1所述的通用型冲压成型油,其特征在于:由以下重量百分数的组分组成:二烃基五硫化物莱茵RC2541 1%,非活性硫化猪油0.5%,超碱值磺酸钙5%,抗磨剂2%,不干性油1%,合成酯20%,氧化石蜡丁酯0.1%,噻二唑衍生物0.5%,矿物油65%,抗氧化剂0.8%,防腐剂0.4%,分散剂0.7%,润滑性添加剂3%。
9.根据权利要求1所述的通用型冲压成型油,其特征在于:由以下重量百分数的组分组成:二烃基五硫化物莱茵RC2541 0.5%,非活性硫化猪油5%,超碱值磺酸钙3%,抗磨剂3%,不干性油5%,合成酯10%,氧化石蜡丁酯0.5%,噻二唑衍生物0.2%,矿物油66.5%,抗氧化剂1%,防腐剂0.3%,分散剂1%,润滑性添加剂4%。
10.一种通用型冲压成型油的制备方法,其特征在于,包括以下步骤:
S1:将矿物油、非活性硫化猪油、不干性油与氧化石蜡丁酯一同倒入调合釜内,然后将调合釜的温度调节至40-60℃,进行搅拌,搅拌时间为15-30分钟,从而得到初始混合物;
S2:将硫化烯烃、超碱值磺酸钙、抗磨剂、合成酯与噻二唑衍生物一种倒入调合釜内,保持调合釜的温度进行搅拌,搅拌时间为10-20分钟,从而得到次混合物;
S3:将抗氧化剂、防腐剂、分散剂与润滑性添加剂一同倒入调合釜内,然后将调合釜的温度调节至30-40℃,进行搅拌,搅拌时间为20-30分钟,从而得到成品冲压成型油。
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