CN108410550A - 防锈阻燃性能好的锻压机滑动轴承用润滑油及其制备方法 - Google Patents

防锈阻燃性能好的锻压机滑动轴承用润滑油及其制备方法 Download PDF

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CN108410550A
CN108410550A CN201810045587.6A CN201810045587A CN108410550A CN 108410550 A CN108410550 A CN 108410550A CN 201810045587 A CN201810045587 A CN 201810045587A CN 108410550 A CN108410550 A CN 108410550A
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parts
lubricating oil
antirust
flame retardant
sliding bearing
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杨继顺
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Ningguo Shun Xin Metal Products Co Ltd
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Abstract

本发明提供了防锈阻燃性能好的锻压机滑动轴承用润滑油及其制备方法，涉及润滑油技术领域，该防锈阻燃性能好的锻压机滑动轴承用润滑油，由以下原料制成：石蜡基基础油、三硬脂酸甘油酯、石油醚、2，6‑二叔丁基对甲酚、丁基羟基茴香醚、柠檬酸、棕榈酸、二异氰酸酯、三乙醇胺、二烷基二硫代氨基甲酸锌、氟表面活性剂、季戊四醇、聚磷酸铵、磷酸二氢钾、硼酸锌、降凝剂和防锈剂，其制备方法包括原料准备、脱水、预热、混合搅拌和冷却五个步骤，由本发明生产出的防锈阻燃性能好的锻压机滑动轴承用润滑油，不仅润滑效果好，使用时间长，而且，还具有阻燃、防锈和抗氧化的功效。

Description

防锈阻燃性能好的锻压机滑动轴承用润滑油及其制备方法
技术领域
本发明涉及润滑油技术领域，具体涉及防锈阻燃性能好的锻压机滑动轴承用润滑油及其制备方法。
背景技术
润滑油是用在各种类型汽车、机械设备上以减少摩擦，保护机械及加工件的液体或半固体润滑剂，主要起润滑、冷却、防锈、清洁、密封和缓冲等作用。润滑油主要用于减少运动部件表面间的摩擦，同时对机器设备具有冷却、密封、防腐、防锈、绝缘、功率传送、清洗杂质等作用。
生锈是一种化学反应，本质上是金属的氧化反应。最常见的生锈现象是铁制品长期暴露在空气中和氧气发生了氧化反应，或者是被水中的氧元素侵蚀成为氧化物，生锈后会给我们带来工业和生活的很多麻烦，所以人们想出很多措施来预防生锈，高效防锈润滑油将是市场的一种需求，减少生锈带来的经济损失。
发明内容
针对现有技术的不足，本发明提供了防锈阻燃性能好的锻压机滑动轴承用润滑油及其制备方法，使得润滑油不仅润滑效果好，还具有防锈和阻燃的功效。
为实现以上目的，本发明通过以下技术方案予以实现：
防锈阻燃性能好的锻压机滑动轴承用润滑油，由以下重量份数的原料制成：
石蜡基基础油80-100份、三硬脂酸甘油酯8-12份、石油醚5-10份、2，6-二叔丁基对甲酚0.5-1份、丁基羟基茴香醚0.5-1份、柠檬酸2-3份、棕榈酸5-10份、二异氰酸酯5-8份、三乙醇胺8-12份、二烷基二硫代氨基甲酸锌1-2份、氟表面活性剂1-3份、季戊四醇5-10份、聚磷酸铵3-5份、磷酸二氢钾4-8份、硼酸锌3-5份、降凝剂10-20份、防锈剂8-12份。
优选地，所述防锈阻燃性能好的锻压机滑动轴承用润滑油，由以下重量份数的原料制成：石蜡基基础油90份、三硬脂酸甘油酯10份、石油醚8份、2，6-二叔丁基对甲酚0.7份、丁基羟基茴香醚0.7份、柠檬酸2.5份、棕榈酸7.5份、二异氰酸酯6.5份、三乙醇胺10份、二烷基二硫代氨基甲酸锌1.5份、氟表面活性剂2份、季戊四醇9份、聚磷酸铵4份、磷酸二氢钾6份、硼酸锌4份、降凝剂15份、防锈剂10份。
优选地，所述降凝剂由甲基丙烯酸高碳酯、马来酸酐和醋酸乙烯酯按照质量比3：1：1共聚而成。
优选地，所述硼酸锌的粒径小于30nm。
优选地，所述2，6-二叔丁基对甲酚和丁基羟基茴香醚的质量比为1：1。
上述防锈阻燃性能好的锻压机滑动轴承用润滑油的制备方法，包括以下步骤：
(1)原料准备：按照配方量准备好各原料，备用；
(2)脱水：将三硬脂酸甘油酯、石油醚、2，6-二叔丁基对甲酚、丁基羟基茴香醚、柠檬酸、棕榈酸、二异氰酸酯，三乙醇胺、二烷基二硫代氨基甲酸锌、氟表面活性剂、季戊四醇、聚磷酸铵、磷酸二氢钾、硼酸锌、胺解后的降凝剂和防锈剂混合均匀后，送入脱水机进行脱水，得混合料；
(3)预热：将石蜡基基础油放在反应釜中，在100-120℃的温度下预热5-10min；
(4)混合搅拌：向反应釜中加入混合料，搅拌20-30min后，边搅拌边降温至50-80℃，2-3h后得到润滑油；
(5)冷却：将润滑油用冷凝管冷凝处理，降温到室温后送入成品罐储存。
有益效果：
本发明提供了防锈阻燃性能好的锻压机滑动轴承用润滑油及其制备方法，本发明中阻燃剂为聚磷酸铵、季戊四醇和硼酸锌，在阻燃的过程中，聚磷酸铵、季戊四醇和硼酸锌不仅具有复合阻燃效应，而且具有非常强的抑制烟雾和毒气的作用；本发明中降凝剂由甲基丙烯酸高碳酯、马来酸酐和醋酸乙烯酯共聚而成，生成的三元共聚物对润滑油基础油的降凝效果好，特别是胺解后的三元共聚物对石蜡基基础油的降凝幅度最大；本发明中2，6-二叔丁基对甲酚作为抗氧化剂使用，其与丁基羟基茴香醚配合使用后，再以柠檬酸为增效剂，比单一使用2，6-二叔丁基对甲酚的抗氧化作用更强，抗氧化效果更好。
具体实施方式
为使本发明实施例的目的、技术方案和优点更加清楚，下面将结合本发明实施例，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1：
防锈阻燃性能好的锻压机滑动轴承用润滑油，由以下重量份数的原料制成：
石蜡基基础油80份、三硬脂酸甘油酯12份、石油醚5份、2，6-二叔丁基对甲酚0.5份、丁基羟基茴香醚0.5份、柠檬酸3份、棕榈酸10份、二异氰酸酯5份、三乙醇胺12份、二烷基二硫代氨基甲酸锌1份、氟表面活性剂3份、季戊四醇5份、聚磷酸铵3份、磷酸二氢钾4份、硼酸锌5份、降凝剂10份、防锈剂8份。
其中，降凝剂由甲基丙烯酸高碳酯、马来酸酐和醋酸乙烯酯按照质量比3：1：1共聚而成；硼酸锌的粒径小于30nm。
实施例2：
防锈阻燃性能好的锻压机滑动轴承用润滑油，由以下重量份数的原料制成：
石蜡基基础油100份、三硬脂酸甘油酯8份、石油醚10份、2，6-二叔丁基对甲酚1份、丁基羟基茴香醚1份、柠檬酸2份、棕榈酸5份、二异氰酸酯8份、三乙醇胺8份、二烷基二硫代氨基甲酸锌2份、氟表面活性剂1份、季戊四醇10份、聚磷酸铵5份、磷酸二氢钾8份、硼酸锌3份、降凝剂20份、防锈剂12份。
其中，降凝剂由甲基丙烯酸高碳酯、马来酸酐和醋酸乙烯酯按照质量比3：1：1共聚而成；硼酸锌的粒径小于30nm。
实施例3：
防锈阻燃性能好的锻压机滑动轴承用润滑油，由以下重量份数的原料制成：
石蜡基基础油90份、三硬脂酸甘油酯10份、石油醚8份、2，6-二叔丁基对甲酚0.7份、丁基羟基茴香醚0.7份、柠檬酸2.5份、棕榈酸7.5份、二异氰酸酯6.5份、三乙醇胺10份、二烷基二硫代氨基甲酸锌1.5份、氟表面活性剂2份、季戊四醇9份、聚磷酸铵4份、磷酸二氢钾6份、硼酸锌4份、降凝剂15份、防锈剂10份。
其中，降凝剂由甲基丙烯酸高碳酯、马来酸酐和醋酸乙烯酯按照质量比3：1：1共聚而成；硼酸锌的粒径小于30nm。
实施例4：
防锈阻燃性能好的锻压机滑动轴承用润滑油，由以下重量份数的原料制成：
石蜡基基础油95份、三硬脂酸甘油酯11份、石油醚8.5份、2，6-二叔丁基对甲酚0.6份、丁基羟基茴香醚0.6份、柠檬酸3份、棕榈酸9份、二异氰酸酯6份、三乙醇胺11份、二烷基二硫代氨基甲酸锌1.5份、氟表面活性剂2.5份、季戊四醇8.5份、聚磷酸铵4份、磷酸二氢钾6.5份、硼酸锌4份、降凝剂17份、防锈剂11份。
其中，降凝剂由甲基丙烯酸高碳酯、马来酸酐和醋酸乙烯酯按照质量比3：1：1共聚而成；硼酸锌的粒径小于30nm。
实施例5：
防锈阻燃性能好的锻压机滑动轴承用润滑油，由以下重量份数的原料制成：
石蜡基基础油85份、三硬脂酸甘油酯9份、石油醚6份、2，6-二叔丁基对甲酚0.8份、丁基羟基茴香醚0.8份、柠檬酸2.5份、棕榈酸6.5份、二异氰酸酯7份、三乙醇胺9份、二烷基二硫代氨基甲酸锌1.5份、氟表面活性剂1.5份、季戊四醇6份、聚磷酸铵3.5份、磷酸二氢钾5份、硼酸锌3份、降凝剂12份、防锈剂9份。
其中，降凝剂由甲基丙烯酸高碳酯、马来酸酐和醋酸乙烯酯按照质量比3：1：1共聚而成；硼酸锌的粒径小于30nm。
实施例6：
防锈阻燃性能好的锻压机滑动轴承用润滑油，由以下重量份数的原料制成：
石蜡基基础油90份、三硬脂酸甘油酯10份、石油醚8.5份、2，6-二叔丁基对甲酚1份、丁基羟基茴香醚1份、柠檬酸2.5份、棕榈酸10份、二异氰酸酯5份、三乙醇胺10份、二烷基二硫代氨基甲酸锌1份、氟表面活性剂3份、季戊四醇5份、聚磷酸铵3份、磷酸二氢钾7份、硼酸锌4.5份、降凝剂16份、防锈剂9份。
其中，降凝剂由甲基丙烯酸高碳酯、马来酸酐和醋酸乙烯酯按照质量比3：1：1共聚而成；硼酸锌的粒径小于30nm。
上述实施例1-6防锈阻燃性能好的锻压机滑动轴承用润滑油的制备方法，包括以下步骤：
(1)原料准备：按照配方量准备好各原料，备用；
(2)脱水：将三硬脂酸甘油酯、石油醚、2，6-二叔丁基对甲酚、丁基羟基茴香醚、柠檬酸、棕榈酸、二异氰酸酯，三乙醇胺、二烷基二硫代氨基甲酸锌、氟表面活性剂、季戊四醇、聚磷酸铵、磷酸二氢钾、硼酸锌、胺解后的降凝剂和防锈剂混合均匀后，送入脱水机进行脱水，得混合料；
(3)预热：将石蜡基基础油放在反应釜中，在100-120℃的温度下预热5-10min；
(4)混合搅拌：向反应釜中加入混合料，搅拌20-30min后，边搅拌边降温至50-80℃，2-3h后得到润滑油；
(5)冷却：将润滑油用冷凝管冷凝处理，降温到室温后送入成品罐储存。
综上，本发明实施例具有如下有益效果：由本发明实施例1-6生产出的防锈阻燃性能好的锻压机滑动轴承用润滑油，不仅润滑效果好，使用时间长，而且，还具有阻燃、防锈和抗氧化的功效。
需要说明的是，在本文中，诸如第一和第二等之类的关系术语仅仅用来将一个实体或者操作与另一个实体或操作区分开来，而不一定要求或者暗示这些实体或操作之间存在任何这种实际的关系或者顺序。而且，术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含，从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素，而且还包括没有明确列出的其他要素，或者是还包括为这种过程、方法、物品或者设备所固有的要素。在没有更多限制的情况下，由语句“包括一个……”限定的要素，并不排除在包括所述要素的过程、方法、物品或者设备中还存在另外的相同要素。
以上实施例仅用以说明本发明的技术方案，而非对其限制；尽管参照前述实施例对本发明进行了详细的说明，本领域的普通技术人员应当理解：其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换；而这些修改或者替换，并不使相应技术方案的本质脱离本发明各实施例技术方案的精神和范围。

Claims (6)

1.防锈阻燃性能好的锻压机滑动轴承用润滑油，其特征在于，由以下重量份数的原料制成：石蜡基基础油80-100份、三硬脂酸甘油酯8-12份、石油醚5-10份、2，6-二叔丁基对甲酚0.5-1份、丁基羟基茴香醚0.5-1份、柠檬酸2-3份、棕榈酸5-10份、二异氰酸酯5-8份、三乙醇胺8-12份、二烷基二硫代氨基甲酸锌1-2份、氟表面活性剂1-3份、季戊四醇5-10份、聚磷酸铵3-5份、磷酸二氢钾4-8份、硼酸锌3-5份、降凝剂10-20份、防锈剂8-12份。
2.如权利要求1所述的防锈阻燃性能好的锻压机滑动轴承用润滑油，其特征在于，由以下重量份数的原料制成：石蜡基基础油90份、三硬脂酸甘油酯10份、石油醚8份、2，6-二叔丁基对甲酚0.7份、丁基羟基茴香醚0.7份、柠檬酸2.5份、棕榈酸7.5份、二异氰酸酯6.5份、三乙醇胺10份、二烷基二硫代氨基甲酸锌1.5份、氟表面活性剂2份、季戊四醇9份、聚磷酸铵4份、磷酸二氢钾6份、硼酸锌4份、降凝剂15份、防锈剂10份。
3.如权利要求1所述的防锈阻燃性能好的锻压机滑动轴承用润滑油，其特征在于，所述降凝剂由甲基丙烯酸高碳酯、马来酸酐和醋酸乙烯酯按照质量比3：1：1共聚而成。
4.如权利要求1所述的防锈阻燃性能好的锻压机滑动轴承用润滑油，其特征在于，所述硼酸锌的粒径小于30nm。
5.如权利要求1所述的防锈阻燃性能好的锻压机滑动轴承用润滑油，其特征在于，所述2，6-二叔丁基对甲酚和丁基羟基茴香醚的质量比为1：1。
6.如权利要求1所述的防锈阻燃性能好的锻压机滑动轴承用润滑油的制备方法，其特征在于，包括以下步骤：
(1)原料准备：按照配方量准备好各原料，备用；
(2)脱水：将三硬脂酸甘油酯、石油醚、2，6-二叔丁基对甲酚、丁基羟基茴香醚、柠檬酸、棕榈酸、二异氰酸酯，三乙醇胺、二烷基二硫代氨基甲酸锌、氟表面活性剂、季戊四醇、聚磷酸铵、磷酸二氢钾、硼酸锌、胺解后的降凝剂和防锈剂混合均匀后，送入脱水机进行脱水，得混合料；
(3)预热：将石蜡基基础油放在反应釜中，在100-120℃的温度下预热5-10min；
(4)混合搅拌：向反应釜中加入混合料，搅拌20-30min后，边搅拌边降温至50-80℃，2-3h后得到润滑油；
(5)冷却：将润滑油用冷凝管冷凝处理，降温到室温后送入成品罐储存。
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