CN114174380A - 多元醇嵌段共聚物、组合物及其方法 - Google Patents

多元醇嵌段共聚物、组合物及其方法 Download PDF

Info

Publication number
CN114174380A
CN114174380A CN202080047748.0A CN202080047748A CN114174380A CN 114174380 A CN114174380 A CN 114174380A CN 202080047748 A CN202080047748 A CN 202080047748A CN 114174380 A CN114174380 A CN 114174380A
Authority
CN
China
Prior art keywords
reaction
polyol
optionally
carbonate
block
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202080047748.0A
Other languages
English (en)
Chinese (zh)
Inventor
詹姆斯·里兰德
拉吉布尔·卡比尔
凯瑞·莱利
迈克尔·肯博
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Econic Technologies Ltd
Original Assignee
Econic Technologies Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Econic Technologies Ltd filed Critical Econic Technologies Ltd
Publication of CN114174380A publication Critical patent/CN114174380A/zh
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/18Block or graft polymers
    • C08G64/183Block or graft polymers containing polyether sequences
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44Polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20General preparatory processes
    • C08G64/32General preparatory processes using carbon dioxide
    • C08G64/34General preparatory processes using carbon dioxide and cyclic ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • C08G65/2606Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645Metals or compounds thereof, e.g. salts
    • C08G65/2663Metal cyanide catalysts, i.e. DMC's
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2650/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G2650/28Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
    • C08G2650/36Pre-polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/02Aliphatic polycarbonates
    • C08G64/0208Aliphatic polycarbonates saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyethers (AREA)
CN202080047748.0A 2019-05-02 2020-05-01 多元醇嵌段共聚物、组合物及其方法 Pending CN114174380A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB1906210.8A GB201906210D0 (en) 2019-05-02 2019-05-02 A polyol block copolymer, compositions and processes therefor
GB1906210.8 2019-05-02
PCT/GB2020/051082 WO2020222018A1 (en) 2019-05-02 2020-05-01 A polyol block copolymer, compositions and processes therefor

Publications (1)

Publication Number Publication Date
CN114174380A true CN114174380A (zh) 2022-03-11

Family

ID=67384906

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202080047748.0A Pending CN114174380A (zh) 2019-05-02 2020-05-01 多元醇嵌段共聚物、组合物及其方法

Country Status (7)

Country Link
US (2) US12351681B2 (https=)
EP (1) EP3994197A1 (https=)
JP (1) JP7588092B2 (https=)
KR (1) KR102921591B1 (https=)
CN (1) CN114174380A (https=)
GB (1) GB201906210D0 (https=)
WO (1) WO2020222018A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN119662279A (zh) * 2023-09-20 2025-03-21 大庆油田有限责任公司 二聚醇醚羧酸盐表面活性剂及其制备方法和压驱一体化体系及应用

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB202003003D0 (en) * 2020-03-02 2020-04-15 Econic Tech Ltd A polyol block copolymer
JP7845040B2 (ja) * 2021-05-27 2026-04-14 Agc株式会社 ポリオキシアルキレンポリカーボネートジオール及びその製造方法、ポリウレタン樹脂前駆体、ポリウレタン樹脂、ポリウレタン樹脂組成物、並びに物品
CN115650828A (zh) * 2022-12-15 2023-01-31 山东一诺威新材料有限公司 丁醇聚醚及其制备方法
GB2626546A (en) 2023-01-25 2024-07-31 Econic Tech Ltd Surface-active agent
GB2626989A (en) 2023-02-10 2024-08-14 Econic Tech Ltd Surface-active agent
KR102833474B1 (ko) * 2023-03-22 2025-07-14 한국화학연구원 폴리우레탄 경질폼용 폴리에테르 카보네이트 폴리올의 제조방법 및 이로부터 제조된 폴리에테르 카보네이트 폴리올

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103797045A (zh) * 2011-07-18 2014-05-14 拜耳知识产权有限责任公司 用于制备聚醚碳酸酯多元醇的双金属氰化物催化剂的活化方法
CN106471042A (zh) * 2014-07-03 2017-03-01 科思创德国股份有限公司 用于制备聚醚碳酸酯多元醇的方法及其设备
CN108291019A (zh) * 2015-08-28 2018-07-17 伊克尼克技术有限公司 用于制备多元醇的方法

Family Cites Families (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3427256A (en) 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanide complex compounds
US4500704A (en) 1983-08-15 1985-02-19 The Dow Chemical Company Carbon dioxide oxirane copolymers prepared using double metal cyanide complexes
GB8528071D0 (en) 1985-11-14 1985-12-18 Shell Int Research Polycarbonates
US4866143A (en) 1988-04-21 1989-09-12 Basf Corporation Novel surfactants based on poly(alkylene carbonate)s
US5158922A (en) 1992-02-04 1992-10-27 Arco Chemical Technology, L.P. Process for preparing metal cyanide complex catalyst
US5482908A (en) 1994-09-08 1996-01-09 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US5627122A (en) 1995-07-24 1997-05-06 Arco Chemical Technology, L.P. Highly active double metal cyanide complex catalysts
US5693584A (en) 1996-08-09 1997-12-02 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US5783513A (en) 1997-03-13 1998-07-21 Arco Chemical Technology, L.P. Process for making double metal cyanide catalysts
DE19810269A1 (de) 1998-03-10 2000-05-11 Bayer Ag Verbesserte Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
US6133402A (en) 1998-08-04 2000-10-17 Cornell Research Foundation, Inc. Polycarbonates made using high activity catalysts
DE19842383A1 (de) 1998-09-16 2000-03-23 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE19905611A1 (de) 1999-02-11 2000-08-17 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE19937114C2 (de) 1999-08-06 2003-06-18 Bayer Ag Verfahren zur Herstellung von Polyetherpolyolen
EP1276562B1 (en) 2000-03-30 2003-09-17 Shell Internationale Researchmaatschappij B.V. Dmc complex catalyst and process for its preparation
AU2001260217A1 (en) 2000-04-20 2001-11-07 Bayer Aktiengesellschaft Method for producing double metal cyanide (dmc) catalysts
DE10219028A1 (de) * 2002-04-29 2003-11-06 Bayer Ag Herstellung und Verwendung von hochmolekularen aliphatischen Polycarbonaten
US6716788B2 (en) 2002-06-14 2004-04-06 Shell Oil Company Preparation of a double metal cyanide catalyst
US6977236B2 (en) 2002-06-14 2005-12-20 Shell Oil Company Preparation of a double metal cyanide catalyst
US6855658B1 (en) 2003-08-26 2005-02-15 Bayer Antwerp, N.V. Hydroxide containing double metal cyanide (DMC) catalysts
US20050101477A1 (en) 2003-11-07 2005-05-12 George Combs Unsaturated tertiary alcohols as ligands for active dmc catalysts
US20050107643A1 (en) 2003-11-13 2005-05-19 Thomas Ostrowski Preparation of polyether alcohols
ES2298705T3 (es) 2004-02-27 2008-05-16 Repsol Quimica S.A. Catalizadores de cianuros dobles metalicos (dmc) con esteres-corona, procedimiento para su obtencion y aplicaciones.
US7304172B2 (en) 2004-10-08 2007-12-04 Cornell Research Foundation, Inc. Polycarbonates made using highly selective catalysts
DE102005011581A1 (de) 2005-03-10 2006-09-14 Basf Ag Verfahren zur Herstellung von DMC-Katalysatoren
US7977501B2 (en) 2006-07-24 2011-07-12 Bayer Materialscience Llc Polyether carbonate polyols made via double metal cyanide (DMC) catalysis
JP2008081518A (ja) 2006-09-25 2008-04-10 Tokyo Univ Of Science アルキレンオキシドと二酸化炭素の共重合体の製造方法、及び共重合体
KR101455878B1 (ko) 2006-11-15 2014-11-03 바스프 에스이 연질 폴리우레탄 발포체의 제조 방법
EP2573126B1 (en) 2007-05-04 2014-09-24 SK Innovation Co. Ltd. A process for producing polycarbonates and a coordination complex used therefor
CN101977965B (zh) 2008-03-25 2012-11-28 旭硝子株式会社 羟基化合物、其制备方法、使用了该羟基化合物的预聚物及聚氨酯
GB0807607D0 (en) 2008-04-25 2008-06-04 Imp Innovations Ltd Catalyst
KR102128706B1 (ko) 2008-08-22 2020-07-02 사우디 아람코 테크놀로지스 컴퍼니 촉매 및 중합체 합성방법
CN103333330A (zh) 2008-09-08 2013-10-02 诺沃梅尔公司 聚碳酸酯多元醇组合物和方法
US8580911B2 (en) 2008-11-01 2013-11-12 Novomer, Inc. Polycarbonate block copolymers
CN101412809B (zh) 2008-11-28 2011-04-27 大连理工大学 用于合成聚碳酸酯的单活性点催化剂
KR101503745B1 (ko) 2010-02-25 2015-03-19 에스케이이노베이션 주식회사 나이트레이트 음이온의 이산화탄소/에폭사이드 공중합 촉매 시스템
KR101805648B1 (ko) 2010-09-14 2017-12-14 사우디 아람코 테크놀로지스 컴퍼니 중합체 합성용의 촉매 및 방법
EP2530101A1 (de) 2011-06-01 2012-12-05 Bayer MaterialScience AG Verfahren zur Herstellung von Polyetherpolyolen
EP2548908A1 (de) 2011-07-18 2013-01-23 Bayer MaterialScience AG Verfahren zur Herstellung von Polyetherpolyolen
KR102024510B1 (ko) 2011-07-18 2019-11-14 사우디 아람코 테크놀로지스 컴퍼니 금속 착체
DE102011109541A1 (de) * 2011-08-03 2013-02-07 Evonik Goldschmidt Gmbh Verwendung von Polysiloxanen enthaltend verzweigte Polyetherreste zur Herstellung von Polyurethanschäumen
US9018318B2 (en) 2011-09-02 2015-04-28 BASF SE Corporation Catalysts for the preparation of carbonates from epoxides and CO2
GB201115565D0 (en) 2011-09-08 2011-10-26 Imp Innovations Ltd Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent
EP2703426A1 (de) 2012-08-27 2014-03-05 Bayer MaterialScience AG Verfahren zur Herstellung von Polyethercarbonatpolyolen
WO2014072336A1 (de) * 2012-11-09 2014-05-15 Bayer Materialscience Ag Verfahren zur herstellung von polyethercarbonatpolyolen
EP2730602A1 (de) 2012-11-09 2014-05-14 Bayer MaterialScience AG Verfahren zur Herstellung von Polyethercarbonatpolyolen
CN104968353B (zh) 2012-11-13 2017-12-22 博研医药开发股份有限公司 吉西他滨前药及其用途
KR101975036B1 (ko) 2013-03-21 2019-05-03 에스케이이노베이션 주식회사 신규 착화합물 존재 하에 이산화탄소/에폭사이드 공중합에 의한 폴리(알킬렌 카보네이트)의 제조방법
EP2837648A1 (en) 2013-08-12 2015-02-18 Repsol, S.A. Process for preparing polyether carbonate polyols
EP2865700A1 (de) 2013-10-23 2015-04-29 Bayer MaterialScience AG Verfahren zur Herstellung von Polyethercarbonatpolyolen
US9657135B2 (en) * 2014-02-26 2017-05-23 Covestro Deutschland Ag Method for producing polyether ester carbonate polyols
AU2015293702B2 (en) 2014-07-22 2018-11-01 Econic Technologies Ltd Catalysts
EP3538588B1 (en) 2016-11-11 2023-01-25 Dow Global Technologies LLC Polycarbonate based polyols
GB201703331D0 (en) * 2017-03-01 2017-04-12 Econic Tech Ltd Method for preparing polycarbonate ether polyols
GB201703323D0 (en) 2017-03-01 2017-04-12 Econic Tech Ltd Method for preparing polyols
GB201703324D0 (en) * 2017-03-01 2017-04-12 Econic Tech Ltd Method for preparing polyether carbonates
GB201714436D0 (en) 2017-09-07 2017-10-25 Econic Tech Ltd A polymerisation process
CN107868239B (zh) 2017-11-28 2019-11-15 中国科学院长春应用化学研究所 一种具有高伯羟基含量的聚(碳酸酯-醚)多元醇组合物及其制备方法
WO2019126221A1 (en) 2017-12-22 2019-06-27 Saudi Aramco Technologies Company Catalysts for polycarbonate production

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103797045A (zh) * 2011-07-18 2014-05-14 拜耳知识产权有限责任公司 用于制备聚醚碳酸酯多元醇的双金属氰化物催化剂的活化方法
CN106471042A (zh) * 2014-07-03 2017-03-01 科思创德国股份有限公司 用于制备聚醚碳酸酯多元醇的方法及其设备
CN108291019A (zh) * 2015-08-28 2018-07-17 伊克尼克技术有限公司 用于制备多元醇的方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN119662279A (zh) * 2023-09-20 2025-03-21 大庆油田有限责任公司 二聚醇醚羧酸盐表面活性剂及其制备方法和压驱一体化体系及应用

Also Published As

Publication number Publication date
US20220227925A1 (en) 2022-07-21
US20250304746A1 (en) 2025-10-02
EP3994197A1 (en) 2022-05-11
KR102921591B1 (ko) 2026-01-30
WO2020222018A1 (en) 2020-11-05
JP7588092B2 (ja) 2024-11-21
US12351681B2 (en) 2025-07-08
GB201906210D0 (en) 2019-06-19
KR20220003607A (ko) 2022-01-10
JP2022530910A (ja) 2022-07-04

Similar Documents

Publication Publication Date Title
KR102921591B1 (ko) 폴리올 블록 공중합체, 이의 조성물 및 방법
KR102918628B1 (ko) 폴리올 블록 공중합체, 이의 조성물 및 방법
US20250263516A1 (en) Rigid foams
CN116710504A (zh) (多元)醇嵌段共聚物
CN110603280A (zh) 制备聚碳酸酯醚多元醇的方法
CN115485317A (zh) 多元醇嵌段共聚物的制备方法
JP7735295B2 (ja) ポリオールブロックコポリマー

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information

Address after: Cheshire

Applicant after: Iconic Technology Co.,Ltd.

Address before: Cheshire

Applicant before: ECONIC TECHNOLOGIES Ltd.

CB02 Change of applicant information