CN114051517A - 隔离材料及其制造方法 - Google Patents

隔离材料及其制造方法 Download PDF

Info

Publication number
CN114051517A
CN114051517A CN202080048468.1A CN202080048468A CN114051517A CN 114051517 A CN114051517 A CN 114051517A CN 202080048468 A CN202080048468 A CN 202080048468A CN 114051517 A CN114051517 A CN 114051517A
Authority
CN
China
Prior art keywords
water glass
weight
mixture
silicate solution
material according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202080048468.1A
Other languages
English (en)
Inventor
加布里埃拉·赫兰多娃
彼得·什帕涅尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
First Point Co ltd
Original Assignee
First Point Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by First Point Co ltd filed Critical First Point Co ltd
Publication of CN114051517A publication Critical patent/CN114051517A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/04—Silica-rich materials; Silicates
    • C04B14/22—Glass ; Devitrified glass
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/04—Silica-rich materials; Silicates
    • C04B14/22—Glass ; Devitrified glass
    • C04B14/24—Glass ; Devitrified glass porous, e.g. foamed glass
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/30—Oxides other than silica
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00—Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04—Macromolecular compounds
    • C04B16/08—Macromolecular compounds porous, e.g. expanded polystyrene beads or microballoons
    • C04B16/082—Macromolecular compounds porous, e.g. expanded polystyrene beads or microballoons other than polystyrene based, e.g. polyurethane foam
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/0016—Granular materials, e.g. microballoons
    • C04B20/002—Hollow or porous granular materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24—Macromolecular compounds
    • C04B24/28—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/282—Polyurethanes; Polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26—Silicates of the alkali metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3271—Hydroxyamines
    • C08G18/3278—Hydroxyamines containing at least three hydroxy groups
    • C08G18/3284—Hydroxyamines containing at least three hydroxy groups containing four hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/40—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • C08K7/28—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482—Coating or impregnation materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00844—Uses not provided for elsewhere in C04B2111/00 for electronic applications
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/2084—Thermal shock resistance
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/005—Additives being defined by their particle size in general

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Fireproofing Substances (AREA)
  • Thermal Insulation (AREA)

Abstract

一种隔离材料，特别是一种不可燃隔热材料，其含有水玻璃和塑料组分的不可燃，该隔离材料由含有43至57.5重量％的塑料组分、30至47重量％的硅酸盐水溶液、9至11.5重量％的中空玻璃微球和0.1至1重量％的水玻璃稳定剂的混合物组成。生产隔离材料的方法，尤其是生产不可燃隔热材料的方法，事实上作为第一步，将水玻璃稳定剂加入到硅酸盐水溶液中，同时制备苯基甲基二异氰酸酯和支化多元醇的混合物，然后将硅酸盐水溶液与苯基甲基二异氰酸酯和支化多元醇的混合物混合，之后将中空玻璃球加入到所得的混合物中，然后再次彻底混合全部物质。

Description

隔离材料及其制造方法
技术领域
本发明涉及一种隔离材料，特别是一种含有水玻璃和塑料组分的不可燃隔热材料，并且涉及其生产方法。
背景技术
从现有技术已知许多方法，其中塑将料被用作隔离材料，特别是在建筑行业中。它们的缺点是耐火性较低。
例如，泡沫隔离材料是广泛用于隔热的材料之一。最常用的材料是发泡和挤出聚苯乙烯。这种材料具有良好的隔离能力，但高度易燃且不透蒸汽。
聚氨酯泡沫和聚异氰脲酸酯泡沫也是建筑行业广泛使用的材料。这些材料的缺点是其应用要求、UV降解以及在一些情况下可能的吸水。
所有常用隔离材料的共同特性是它们的可燃性，这在很大程度上有助于火势蔓延。当加热和燃烧时，这些材料会产生大量有毒气体，其因此比火灾本身更危险。
专利文献CA1064200A描述了聚氨酯泡沫的生产，其中在发泡前加入苏打水玻璃以降低可燃性。这种材料的缺点仍然是高可燃性。
另一份专利文献CN105924942描述了用珍珠岩或中空玻璃球和磷胺缓凝剂生产聚氨酯泡沫。所述球体是为了增加这种再次高度易燃的材料的刚度。
从专利文献CN 106220819中获知另一种易燃塑料材料。将由添加了球体的聚氨酯和聚丙二醇组成的材料用于制造板。
从现有技术可以明显看出，上述所有材料的主要缺点是迄今为止已知的塑料隔离材料几乎总是易燃的。
本发明的目的是配制一种具有高耐火性并同时具有抗降解性的隔离材料。
发明内容
通过一种隔离材料，尤其是通过根据本发明的一种含有水玻璃和塑料组分的不可燃隔热材料，在很大程度上消除了上述缺点并且实现了本发明的目标，其性质在于事实上该材料是一种混合物，含有43至57.6重量％的塑料组分、30至47重量％的硅酸盐水溶液、9至11.5重量％的中空玻璃微球和0.1至1重量％的水玻璃稳定剂。所述隔离材料的一个优点是其高热稳定性、高耐火性和相当高的抗降解性。同时，该隔离材料具有优良的杀菌效果、环境友好、对健康无害、能很好地反射UV辐射并且不释放任何有机有毒物质。
有利的是，所使用的塑料组分是聚氨酯，并且在最有利的选项中，聚氨酯由60至70重量％的苯基甲基二异氰酸酯和30至40重量％的支化多元醇的混合物组成。这是有利的，因为聚氨酯为所得隔离材料提供了弹性和柔韧性。
如果所述中空玻璃球是0.05至0.08mm的微球，则是非常有利的。这些球体的壁很薄。它们在单独的点上相互接触，并且大量尖锐的材料界面(边界)代表了热量通过的阻力。这种多孔系统的特点是传热系数低，并且是一种极好的隔热材料。
根据第一变型例，在一些应用中，如果上述第一变型例中提到的硅酸盐水溶液是硅酸钠水溶液，则是有利的。
根据第二变型例，如果上述第二变型例中提到的硅酸盐水溶液是硅酸钾水溶液，则也是有利的。
如果所述隔离材料进一步含有水玻璃硬化剂，例如甘油单到三乙酸酯或它们的混合物，则是非常有利的。
如果使用亲水性烷氧基烷基氨盐作为水玻璃稳定剂，则更有利。
通过一种生产隔离材料的方法，尤其是一种生产含有水玻璃和塑料组分的不可燃隔热材料的方法，在很大程度上进一步消除了上述缺点并且实现了本发明的目的，其性质在于，作为第一步，将水玻璃稳定剂加入到硅酸盐水溶液中，同时制备苯基甲基二异氰酸酯和支化多元醇的混合物。然后，作为第二步，将硅酸盐水溶液与苯基甲基二异氰酸酯和支链多元醇的混合物混合，作为第三步，将中空玻璃球加入到所得混合物中，然后将所有物质充分混合。该方法的一个优点是便于制造固体产品，例如隔离板、成型件等，也便于进行液体应用。
如果将水玻璃硬化剂加入到硅酸盐和水玻璃稳定剂的水溶液中是有利的。优点在于可以优化硬化速率。
如果然后将所得混合物倒入模具中并保持原样直至硬化，则是有利的。
根据本发明的隔离材料及其生产方法的主要优点是它高度不可燃。另一个优点是材料中使用的水玻璃减缓了聚合物的分解，同时确保了混合物整体的不可燃性，同时不影响聚氨酯的积极性能，尤其是其可塑性。聚氨酯、水玻璃和球体的混合物形成了一种不可燃的隔热塑料组分，它质轻、足够柔软、有弹性、可成型、易于倒入模具中且对健康无害。也可用普通无机颜料染色。在液态时，它非常粘稠，可在各种底层表面上用作保护层。该层然后以机械和化学方式保护表面免受水、霉菌、发霉、腐蚀等的影响。
具体实施方式
实施例1
不可燃隔离材料由一种混合物组成，该混合物含有45重量％的塑料组分、43重量％的硅酸钠水溶液、9.6重量％的中空玻璃微球、0.1重量％的水玻璃稳定剂和2.3重量％的水玻璃硬化剂。
所述塑料组分是聚氨酯，它由67重量％的苯基甲基二异氰酸酯和33重量％的支化多元醇的混合物组成。
所述中空玻璃球是尺寸为0.05mm的微球。
所述水玻璃硬化剂是纯甘油二乙酸/三乙酸酯按体积份7:3比例、浓度相对于纯水玻璃为0.5至5重量％的混合物。
将98％N,N,N',N'-四(2-羟丙基)乙二胺水溶液形式的亲水性烷氧基烷基氨盐用作水玻璃稳定剂。
生产方法：作为第一步，将水玻璃稳定剂加入到硅酸钠水溶液中。作为第二步，将水玻璃硬化剂加入到所述溶液中，并且全部物质搅拌10分钟。同时，制备苯基甲基二异氰酸酯和支化多元醇的混合物。之后，将硅酸钠水溶液与苯基甲基二异氰酸酯和支化多元醇的混合物混合。然后将中空玻璃球加入所得混合物中，再次彻底混合全部物质。
之后，将所得混合物倒入硅酮模具中并保持原样直至硬化。
实施例2
不可燃隔离材料由一种混合物组成，该混合物含有54重量％的塑料组分、34.9重量％的硅酸钾水溶液、11重量％的中空玻璃微球和0.1重量％的水玻璃稳定剂。
所述塑料组分是聚氨酯，由66重量％的苯基甲基二异氰酸酯和33重量％的支化多元醇的混合物组成。
所述中空玻璃球是尺寸为0.065mm的微球。
所述水玻璃硬化剂是纯甘油二乙酸/三乙酸酯按体积份7:3比例、浓度相对于纯水玻璃为0.5至5重量％的混合物。
将98％N,N,N',N'-四(2-羟基丙基)乙二胺水溶液形式的亲水性烷氧基烷基氨盐用作水玻璃稳定剂。
生产方法：作为第一步，将水玻璃稳定剂加入到硅酸钠水溶液中。同时，制备苯基甲基二异氰酸酯和支化多元醇的混合物。然后将硅酸钠水溶液与苯基甲基二异氰酸酯和支化多元醇的混合物混合。然后将中空玻璃球加入到所得混合物中，再次彻底混合全部物质。
之后，将所得混合物倒入到硅桐模具中并保持原样直至硬化。
实施例3
不可燃隔离材料由一种混合物组成，该混合物含有57.5重量％的塑料组分、30重量％的硅酸钠水溶液、11.5重量％的中空玻璃微球、和0.8重量％的水玻璃稳定剂、以及0.2重量％的水玻璃硬化剂。
所述塑料组分是聚氨酯，由60重量％的苯基甲基二异氰酸酯和40重量％的支链多元醇组成。
所述中空玻璃球是尺寸为0.08mm的微球。
所述水玻璃硬化剂是纯甘油二乙酸/三乙酸酯按体积份7:3比例、浓度相对于纯水玻璃为0.5至5重量％的混合物。
将98％N,N,N',N'-四(2-羟基丙基)乙二胺水溶液形式的亲水性烷氧基烷基氨盐用作水玻璃稳定剂。
生产方法：作为第一步，将水玻璃稳定剂和水玻璃硬化剂加入到硅酸钠水溶液中，并且将全部物质搅拌10分钟。同时，制备苯基甲基二异氰酸酯和支化多元醇的混合物。然后，将硅酸钠水溶液与苯基甲基二异氰酸酯和支化多元醇的混合物混合。然后，将中空玻璃球加入所得混合物中，再次彻底混合全部物质。
之后，将所得混合物倒入硅酮模具中并保持原样直至硬化。
实施例4
不可燃隔离材料由一种混合物组成，该混合物含有43重量％的塑料组分、47重量％的硅酸钾水溶液、9重量％的中空玻璃微球和1重量％的水玻璃稳定剂。
所述塑料组分是聚氨酯，由70重量％的苯基甲基二异氰酸酯和30重量％的支链多元醇组成。
所述中空玻璃球是尺寸为0.065mm的微球。
所述水玻璃硬化剂是纯甘油二乙酸/三乙酸酯按体积份7:3比例、浓度相对于纯水玻璃为0.5至5重量％的混合物。
将98％N,N,N',N'-四(2-羟丙基)乙二胺水溶液形式的亲水性烷氧基烷基氨盐用作水玻璃稳定剂。
生产方法：作为第一步，将水玻璃稳定剂加入到硅酸钠水溶液中。同时，制备苯基甲基二异氰酸酯和支化多元醇的混合物。然后将硅酸钠水溶液与苯基甲基二异氰酸酯和支化多元醇的混合物混合。然后将中空玻璃球加入到所得混合物中，再次彻底混合全部物质。
之后，将所得混合物倒入硅酮模具中并保持原样直至硬化。
工业应用
根据本发明的隔离材料不仅在建筑行业中具有广泛的用途，而且在汽车和电子技术工业中具有广泛的用途，因为它可以用于制备单独的隔离产品或者它可以直接施加到要被保护的单独表面(例如金属)上。

Claims (11)

1.一种隔离材料，特别是一种含有水玻璃和塑料组分的不可燃隔热材料，其特征在于所述材料由含有43至57.5重量％的塑料组分、30至47重量％的硅酸盐水溶液、9至11.5重量％的中空玻璃微球和0.1至1重量％的水玻璃稳定剂的混合物组成。
2.根据权利要求1所述的隔离材料，其特征在于所述塑料组分是聚氨酯。
3.根据前述权利要求中的一些所述的隔离材料，其特征在于所述塑料组分是聚氨酯，所述聚氨酯由60至70重量％的苯基甲基二异氰酸酯和30至40重量％的支化多元醇的混合物组成。
4.根据前述权利要求中的一些所述的隔离材料，其特征在于所述中空玻璃球是尺寸为0.05至0.08mm的微球。
5.根据前述权利要求中的一些所述的隔离材料，其特征在于所述硅酸盐水溶液是硅酸钠水溶液。
6.根据权利要求1至4中的一些所述的隔离材料，其特征在于所述硅酸盐水溶液是硅酸钾水溶液。
7.根据前述权利要求中的一些所述的隔离材料，其特征在于所述材料还含有水玻璃硬化剂。
8.根据前述权利要求中的一些所述的隔离材料，其特征在于所述水玻璃稳定剂是亲水性烷氧基烷基铵盐。
9.一种生产根据权利要求1至8中的一些所述的隔离材料的方法，尤其是一种生产不可燃隔热材料的方法，其特征在于，作为第一步，将水玻璃稳定剂加入到硅酸盐水溶液中，同时制备苯基甲基二异氰酸酯和支链多元醇的混合物，然后将硅酸盐水溶液与苯基甲基二异氰酸酯和支化多元醇的混合物混合，之后将中空玻璃球加入到所得混合物中，然后再次彻底混合全部物质。
10.根据权利要求9所述的生产隔离材料的方法，其特征在于将水玻璃硬化剂加入到硅酸盐和水玻璃稳定剂的水溶液中。
11.根据权利要求9或权利要求10所述的生产隔离材料的方法，其特征在于然后将所得混合物倒入硅酮模具中并保持原样直至硬化。
CN202080048468.1A 2019-08-06 2020-06-09 隔离材料及其制造方法 Pending CN114051517A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CZPV2019-507 2019-08-06
CZ2019-507A CZ2019507A3 (cs) 2019-08-06 2019-08-06 Izolační materiál a způsob jeho výroby
PCT/CZ2020/000023 WO2021023317A1 (en) 2019-08-06 2020-06-09 Insulating material and method of its production

Publications (1)

Publication Number Publication Date
CN114051517A true CN114051517A (zh) 2022-02-15

Family

ID=71670015

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202080048468.1A Pending CN114051517A (zh) 2019-08-06 2020-06-09 隔离材料及其制造方法

Country Status (13)

Country Link
US (1) US20220274873A1 (zh)
EP (1) EP4010391A1 (zh)
JP (1) JP2022543386A (zh)
KR (1) KR20220061961A (zh)
CN (1) CN114051517A (zh)
AU (1) AU2020325425A1 (zh)
BR (1) BR112022002221A2 (zh)
CA (1) CA3140945A1 (zh)
CL (1) CL2022000283A1 (zh)
CZ (1) CZ2019507A3 (zh)
EA (1) EA202100277A1 (zh)
SK (1) SK288967B6 (zh)
WO (1) WO2021023317A1 (zh)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CZ202294A3 (cs) * 2022-02-28 2022-12-14 Technická univerzita v Liberci Odlehčený tepelně izolační geopolymerní kompozit pro speciální aplikace a způsob jeho výroby

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4129696A (en) * 1975-03-20 1978-12-12 Bayer Aktiengesellschaft Process for the production of inorganic-organic plastic composites
US4447561A (en) * 1982-07-23 1984-05-08 Basf Aktiengesellschaft Stable water glass solutions, process for their preparation and use for organosilicate foams as well as a production process therefor
US20030153635A1 (en) * 2002-02-13 2003-08-14 Spitler Kieth G. Process for making cellular composites using polymeric isocyanates as binders for hollow filler particles
CN1511798A (zh) * 2002-12-21 2004-07-14 B��K������ 水玻璃体系的稳定剂
US20130015389A1 (en) * 2011-07-13 2013-01-17 Torres-Aranda Jr Francisco Jose Fire resistant foam insulation compositions
CN103408923A (zh) * 2013-07-26 2013-11-27 北京仁创科技集团有限公司 一种聚氨酯泡沫体及其制备方法
CN103923295A (zh) * 2014-03-19 2014-07-16 中国建筑科学研究院 一种阻燃防水复合保温材料及其制备方法
CN104876629A (zh) * 2015-04-27 2015-09-02 深圳市新纶科技股份有限公司 一种硅酸盐防火保温材料及其制备方法
CN110041505A (zh) * 2019-04-30 2019-07-23 青岛科技大学 一种发泡型杂化高分子堵漏材料及其制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2325090C3 (de) * 1973-05-17 1980-11-06 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von als kolloides Xerosol vorliegendem anorganischorganischem Polymer-Polykieselsäure-Verbundmaterial
RU2439024C1 (ru) * 2010-04-30 2012-01-10 Государственное образовательное учреждение высшего профессионального образования "Национальный исследовательский Томский политехнический университет" Состав смеси для получения теплоизоляционного материала
CZ29941U1 (cs) * 2016-09-13 2016-11-03 paniel Petr Ĺ Směs pro tenkovrstvou termoizolační termoreflexní úpravu žhavých povrchů
CZ30925U1 (cs) * 2017-03-09 2017-08-21 Gabriela Chlandová Smčs pro tenkovrstvou termoizolační termoreflexní úpravu žhavých povrchů s vlákny
CN107352549B (zh) * 2017-08-30 2020-07-03 张振 一种空心玻璃微珠的制备方法
CZ31269U1 (cs) * 2017-09-19 2017-12-04 Ĺ paniel Petr Směs pro tepelně izolační protipožární protiplísňovou sanační ekologickou úpravu povrchů

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4129696A (en) * 1975-03-20 1978-12-12 Bayer Aktiengesellschaft Process for the production of inorganic-organic plastic composites
US4447561A (en) * 1982-07-23 1984-05-08 Basf Aktiengesellschaft Stable water glass solutions, process for their preparation and use for organosilicate foams as well as a production process therefor
US20030153635A1 (en) * 2002-02-13 2003-08-14 Spitler Kieth G. Process for making cellular composites using polymeric isocyanates as binders for hollow filler particles
CN1511798A (zh) * 2002-12-21 2004-07-14 B��K������ 水玻璃体系的稳定剂
US20130015389A1 (en) * 2011-07-13 2013-01-17 Torres-Aranda Jr Francisco Jose Fire resistant foam insulation compositions
CN103408923A (zh) * 2013-07-26 2013-11-27 北京仁创科技集团有限公司 一种聚氨酯泡沫体及其制备方法
CN103923295A (zh) * 2014-03-19 2014-07-16 中国建筑科学研究院 一种阻燃防水复合保温材料及其制备方法
CN104876629A (zh) * 2015-04-27 2015-09-02 深圳市新纶科技股份有限公司 一种硅酸盐防火保温材料及其制备方法
CN110041505A (zh) * 2019-04-30 2019-07-23 青岛科技大学 一种发泡型杂化高分子堵漏材料及其制备方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
XD HONG, 等: "Study on Structure and Performance of Reactive Silicate Reinforced Polyurethane Composite", 《POLYMER ENGINEERING AND SCIENCE》, vol. 55, no. 10, pages 2322 - 2327 *
程家骥: "矿用硅酸盐-多异氰酸酯杂化高分子复合材料安全性能的研究和膨胀传热过程分析", 《中国博士学位论文全文数据库工程科技Ⅰ辑》, no. 1, pages 14 *

Also Published As

Publication number Publication date
WO2021023317A1 (en) 2021-02-11
EP4010391A1 (en) 2022-06-15
CA3140945A1 (en) 2021-02-11
CL2022000283A1 (es) 2022-10-21
AU2020325425A1 (en) 2021-11-25
WO2021023317A8 (en) 2021-12-09
SK1152019A3 (sk) 2021-02-10
KR20220061961A (ko) 2022-05-13
BR112022002221A2 (pt) 2022-06-07
CZ308477B6 (cs) 2020-09-09
EA202100277A1 (ru) 2022-02-03
US20220274873A1 (en) 2022-09-01
CZ2019507A3 (cs) 2020-09-09
JP2022543386A (ja) 2022-10-12
SK288967B6 (sk) 2022-06-30

Similar Documents

Publication Publication Date Title
EP1907461B1 (en) Method for manufacturing fire retardant composite and composite thus obtained
CN101781396B (zh) 壳聚糖复合聚氨酯的硬质闭孔泡沫材料及其制备方法
JP2013500364A5 (zh)
CN114051517A (zh) 隔离材料及其制造方法
US4207113A (en) Inorganic foam and preparation thereof
CN110117349A (zh) 一种超强阻燃海绵及其制备方法
CN103923295B (zh) 一种阻燃防水复合保温材料及其制备方法
KR101693369B1 (ko) 발포 폴리스타이렌 난연성 접착제 조성물
KR20080072877A (ko) 발포 플라스틱의 제조를 위한 발포성 조성물
KR101644786B1 (ko) 산성 경화제가 포함되지 않은 페놀수지 발포체의 제조방법, 이에 의해 제조되는 페놀수지 발포체, 및 이를 위한 페놀수지 발포체용 조성물
KR20090010543A (ko) 발포수지용 난연 코팅제
WO2016170469A1 (en) Fireproof additive to polyurethanes, fireproof polyurethane, method of production of fireproof additive
DE69631232T2 (de) Polyurethanschaumstoff
CN103554893B (zh) 一种用于硬质聚氨酯泡沫的复合阻燃剂
EA046364B1 (ru) Изолирующий материал и способ его получения
AT391466B (de) Anorganische thermoisolationsmasse
US20110021648A1 (en) Silicone foam with added thermal agent and uses of the foam
WO2002062916A1 (fr) Accelerateur de dissolution inorganique pour rendre une substance metallique ou inorganique soluble dans l'eau
CN101747525A (zh) 聚氨酯发泡剂
EP3168245B1 (en) Composition for producing fire-resistant polyurethane foam
WO2007013791A1 (en) Method for manufacturing a fire retardant composite and composite thus obtained
WO2014106867A1 (en) Process for the production of rigid foamed objects made of polymer materials
RU2026844C1 (ru) Состав для изготовления теплоизоляционного материала
NL2006018C2 (en) Method for manufacturing a fire retardant composite and composite thus obtained.
KR100646038B1 (ko) 수발포 폴리우레아 폼 및 그 제조방법

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination