CN1138736C - 同时制备乙二醇和碳酸酯的方法 - Google Patents
同时制备乙二醇和碳酸酯的方法 Download PDFInfo
- Publication number
- CN1138736C CN1138736C CNB011030399A CN01103039A CN1138736C CN 1138736 C CN1138736 C CN 1138736C CN B011030399 A CNB011030399 A CN B011030399A CN 01103039 A CN01103039 A CN 01103039A CN 1138736 C CN1138736 C CN 1138736C
- Authority
- CN
- China
- Prior art keywords
- ethylene glycol
- carbonic ether
- ethylene carbonate
- ethylene
- carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 title claims abstract description 232
- 238000000034 method Methods 0.000 title claims abstract description 35
- 150000002148 esters Chemical class 0.000 title description 6
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims abstract description 71
- 238000000746 purification Methods 0.000 claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 claims abstract description 18
- 238000005809 transesterification reaction Methods 0.000 claims abstract description 18
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 63
- 238000006243 chemical reaction Methods 0.000 claims description 54
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 45
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 30
- 238000004821 distillation Methods 0.000 claims description 19
- 235000011089 carbon dioxide Nutrition 0.000 claims description 14
- 239000002994 raw material Substances 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000001569 carbon dioxide Substances 0.000 claims description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 7
- 230000003301 hydrolyzing effect Effects 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 238000000926 separation method Methods 0.000 claims description 6
- 239000006227 byproduct Substances 0.000 claims description 5
- 125000005911 methyl carbonate group Chemical group 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 4
- SXXGBDASYFEMSO-UHFFFAOYSA-N 1,3-dioxolan-2-one;ethane-1,2-diol Chemical compound OCCO.O=C1OCCO1 SXXGBDASYFEMSO-UHFFFAOYSA-N 0.000 claims 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 10
- 230000007062 hydrolysis Effects 0.000 abstract description 9
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract description 5
- 230000015572 biosynthetic process Effects 0.000 abstract description 4
- CXHHBNMLPJOKQD-UHFFFAOYSA-M methyl carbonate Chemical compound COC([O-])=O CXHHBNMLPJOKQD-UHFFFAOYSA-M 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 8
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 238000009835 boiling Methods 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 238000011084 recovery Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910052728 basic metal Inorganic materials 0.000 description 2
- 150000003818 basic metals Chemical class 0.000 description 2
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 101150034459 Parpbp gene Proteins 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- DOSPXNJPDHTNGN-UHFFFAOYSA-M [P].[I-].C(CCC)[P+](C)(CCCC)CCCC Chemical compound [P].[I-].C(CCC)[P+](C)(CCCC)CCCC DOSPXNJPDHTNGN-UHFFFAOYSA-M 0.000 description 1
- ZIFSPRTXKPJXJI-UHFFFAOYSA-N [Y].[Co](=O)=O Chemical compound [Y].[Co](=O)=O ZIFSPRTXKPJXJI-UHFFFAOYSA-N 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 229910052915 alkaline earth metal silicate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 239000002815 homogeneous catalyst Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- CUXQLKLUPGTTKL-UHFFFAOYSA-M microcosmic salt Chemical compound [NH4+].[Na+].OP([O-])([O-])=O CUXQLKLUPGTTKL-UHFFFAOYSA-M 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- FDRCDNZGSXJAFP-UHFFFAOYSA-M sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 description 1
- HSFQBFMEWSTNOW-UHFFFAOYSA-N sodium;carbanide Chemical group [CH3-].[Na+] HSFQBFMEWSTNOW-UHFFFAOYSA-N 0.000 description 1
- 150000003476 thallium compounds Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C68/00—Preparation of esters of carbonic or haloformic acids
- C07C68/06—Preparation of esters of carbonic or haloformic acids from organic carbonates
- C07C68/065—Preparation of esters of carbonic or haloformic acids from organic carbonates from alkylene carbonates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
- C07C29/12—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of mineral acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/128—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by alcoholysis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP009865/2000 | 2000-01-19 | ||
| JP2000009865A JP3659109B2 (ja) | 2000-01-19 | 2000-01-19 | エチレングリコールと炭酸エステルの併産方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1308046A CN1308046A (zh) | 2001-08-15 |
| CN1138736C true CN1138736C (zh) | 2004-02-18 |
Family
ID=18537957
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011030399A Expired - Fee Related CN1138736C (zh) | 2000-01-19 | 2001-01-19 | 同时制备乙二醇和碳酸酯的方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6380419B2 (enExample) |
| EP (1) | EP1125915B1 (enExample) |
| JP (1) | JP3659109B2 (enExample) |
| CN (1) | CN1138736C (enExample) |
| DE (1) | DE60110947T2 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9656943B2 (en) | 2015-10-20 | 2017-05-23 | Chang Chun Plastics Co. Ltd. | Process for producing dimethyl carbonate |
| US10131620B2 (en) | 2015-10-20 | 2018-11-20 | Chang Chun Plastics Co., Ltd. | Process for producing dimethyl carbonate |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6774256B2 (en) | 2001-06-22 | 2004-08-10 | Exxonmobil Chemical Patents Inc. | Low corrosive integrated process for preparing dialkyl carbonates |
| US7084292B2 (en) | 2001-06-22 | 2006-08-01 | Exxonmobil Chemical Patents Inc. | Integrated process for preparing dialkyl carbonates with a circulating catalyst |
| WO2003006418A1 (en) * | 2001-07-10 | 2003-01-23 | Mitsubishi Chemical Corporation | Method for producing dialkylcarbonate |
| US20040220433A1 (en) * | 2003-03-28 | 2004-11-04 | Evert Van Der Heide | Process for the preparation of propylene glycol |
| EP1622857B1 (en) * | 2003-04-09 | 2011-10-05 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of alkanediol |
| CN1946660B (zh) * | 2004-06-17 | 2012-11-14 | 旭化成化学株式会社 | 生产碳酸二烷基酯和二醇的方法 |
| CN100354244C (zh) * | 2004-07-28 | 2007-12-12 | 华东理工大学 | C2~c3的二元醇的制备方法 |
| CN100364956C (zh) * | 2004-08-09 | 2008-01-30 | 华东理工大学 | 反应精馏酯交换联产碳酸二甲酯和二元醇的方法 |
| BRPI0618334B1 (pt) * | 2005-11-25 | 2016-01-05 | Asahi Kasei Chemicals Corp | processo para a produção industrial de um carbonato de dialquila e de um diol, e, coluna de destilação contínua de estágios múltiplos |
| US20070197801A1 (en) * | 2005-12-22 | 2007-08-23 | Bolk Jeroen W | Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitables for such a process |
| US7750170B2 (en) * | 2005-12-22 | 2010-07-06 | Shell Oil Company | Process for mixing an oxidant having explosive potential with a hydrocarbon |
| US20070203350A1 (en) * | 2005-12-22 | 2007-08-30 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US20070203352A1 (en) * | 2005-12-22 | 2007-08-30 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| BE1017793A3 (fr) * | 2005-12-22 | 2009-07-07 | Shell Int Research | Procede de preparation d'un oxyde d'olefine ou d'un produit chimique pouvant provenir d'un oxyde d'olefine. |
| US20070154377A1 (en) * | 2005-12-22 | 2007-07-05 | Rekers Dominicus M | Process for the removal of combustible volatile contaminant materials from a process stream |
| US20070213545A1 (en) * | 2005-12-22 | 2007-09-13 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US7459589B2 (en) * | 2005-12-22 | 2008-12-02 | Shell Oil Company | Process for the preparation of an alkylene glycol |
| US20070197808A1 (en) * | 2005-12-22 | 2007-08-23 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US20070151451A1 (en) * | 2005-12-22 | 2007-07-05 | Rekers Dominicus M | Process for the cooling, concentration or purification of ethylene oxide |
| TW200740749A (en) * | 2006-02-22 | 2007-11-01 | Shell Int Research | Process for the preparation of an alkanediol and a dialkyl carbonate |
| TWI378087B (en) * | 2006-02-22 | 2012-12-01 | Shell Int Research | Process for the preparation of an alkanediol and a dialkyl carbonate |
| TWI383976B (zh) * | 2006-02-22 | 2013-02-01 | Shell Int Research | 製備碳酸二烷酯及烷二醇的方法 |
| TWI382979B (zh) * | 2006-02-22 | 2013-01-21 | Shell Int Research | 碳酸伸烷酯之生產方法及由此生產的碳酸伸烷酯於烷二醇及碳酸二烷酯之製造中的用途 |
| TW200740731A (en) * | 2006-02-22 | 2007-11-01 | Shell Int Research | Process for the preparation of alkanediol |
| TWI387584B (zh) * | 2006-03-13 | 2013-03-01 | Shell Int Research | 碳酸伸烷酯之生產方法及由此生產之碳酸伸烷酯於烷二醇及碳酸二烷酯之製造中之用途 |
| US20080154051A1 (en) * | 2006-12-20 | 2008-06-26 | Jeroen Willem Bolk | Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process |
| US20080154052A1 (en) * | 2006-12-20 | 2008-06-26 | Jeroen Willem Bolk | Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process |
| TW200906774A (en) * | 2007-04-23 | 2009-02-16 | Shell Int Research | Process for the preparation of an 1,2-alkylene diol and a dialkylcarbonate |
| EP2493850B1 (de) * | 2009-10-27 | 2014-07-16 | Basf Se | Verfahren zur koppelproduktion von di- und/oder polyisocyanaten und glykolen |
| BR112012012895B1 (pt) * | 2009-11-30 | 2018-01-02 | Mitsubishi Chemical Corporation | Método para produzir o carbonato de etileno e etileno glicol. |
| JP5511979B2 (ja) | 2010-06-07 | 2014-06-04 | 中国科学院過程工程研究所 | イオン液体触媒によるエチレングリコールの製造方法 |
| WO2012052363A1 (en) * | 2010-10-19 | 2012-04-26 | Shell Internationale Research Maatschappij B.V. | Process for the production of alkylene glycol |
| US8802900B2 (en) * | 2010-11-29 | 2014-08-12 | Shell Oil Company | Process for the preparation of ethylene glycol |
| US8829206B2 (en) | 2011-06-24 | 2014-09-09 | Eastman Chemical Company | Production of cyclic acetals or ketals using solid acid catalysts |
| US9388105B2 (en) | 2011-06-24 | 2016-07-12 | Eastman Chemical Company | Production of hydroxy ether hydrocarbons by liquid phase hydrogenolysis of cyclic acetals or cyclic ketals |
| US9000229B2 (en) | 2011-06-24 | 2015-04-07 | Eastman Chemical Company | Production of hydroxy ether hydrocarbons by vapor phase hydrogenolysis of cyclic acetals and ketals |
| US8969598B2 (en) | 2011-06-24 | 2015-03-03 | Eastman Chemical Company | Production of cyclic acetals or ketals using liquid-phase acid catalysts |
| US8785697B2 (en) | 2011-06-24 | 2014-07-22 | Eastman Chemical Company | Nickel modified catalyst for the production of hydroxy ether hydrocarbons by vapor phase hydrogenolysis of cyclic acetals and ketals |
| US9056313B2 (en) | 2011-06-24 | 2015-06-16 | Eastman Chemical Company | Catalysts for the production of hydroxy ether hydrocarbons by vapor phase hydrogenolysis of cyclic acetals and ketals |
| US8829207B2 (en) | 2011-06-24 | 2014-09-09 | Eastman Chemical Company | Production of cyclic acetals by reactive distillation |
| US8809569B2 (en) | 2012-02-28 | 2014-08-19 | Saudi Basic Industries Corporation | Process for preparing dialkyl carbonate and diol products |
| US8735608B2 (en) | 2012-02-28 | 2014-05-27 | Saudi Basic Industries Corporation | Process for preparing carbonate and diol products |
| CN102603477A (zh) * | 2012-02-29 | 2012-07-25 | 南京工业大学 | 一种碳酸乙烯酯法制备乙二醇的方法 |
| EP2650278A1 (de) | 2012-04-11 | 2013-10-16 | Bayer MaterialScience AG | Verfahren zur Herstellung von Diarylcarbonaten aus Dialkylcarbonaten |
| BR112021009797B1 (pt) | 2018-12-10 | 2024-03-12 | Shell Internationale Research Maatschappij B.V | Processo para a preparação de etilenoglicol a partir de etileno |
| CA3150254C (en) * | 2019-09-17 | 2024-01-02 | Hao HONG | Method for addition reaction of acetylene and ketone compound |
| CN114539025A (zh) * | 2022-03-11 | 2022-05-27 | 广西科技大学 | 一种通过酯交换反应分离二元醇的方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4661609A (en) * | 1986-07-31 | 1987-04-28 | Texaco Inc. | Process for cosynthesis of ethylene glycol and dimethyl carbonate |
| US4734518A (en) * | 1987-01-12 | 1988-03-29 | Texaco Inc. | Process for cosynthesis of ethylene glycol and dimethyl carbonate |
| US5214182A (en) | 1987-01-12 | 1993-05-25 | Texaco Chemical Company | Process for cogeneration of ethylene glycol and dimethyl carbonate |
| DE69620470T2 (de) * | 1995-12-22 | 2002-11-21 | Asahi Kasei Kabushiki Kaisha, Osaka | Verfahren zur kontinuierlichen herstellung von dialkylcarbonaten und diolen |
| US6080897A (en) | 1998-03-19 | 2000-06-27 | Mitsubishi Chemical Corporation | Method for producing monoethylene glycol |
| JP3788019B2 (ja) * | 1998-03-19 | 2006-06-21 | 三菱化学株式会社 | モノエチレングリコールの製造方法 |
| US6346638B1 (en) * | 1998-06-10 | 2002-02-12 | Asahi Kasel Kabushiki Kaisha | Process for continuous production of dialkyl carbonate and diol |
| SG77264A1 (en) | 1998-08-10 | 2000-12-19 | Mitsubishi Chem Corp | Process for producing an alkylene glycol |
| US6207850B1 (en) * | 1999-11-03 | 2001-03-27 | Mobil Oil Corporation | Process for co-production of dialkyl carbonate and alkanediol |
| US6162940A (en) * | 1999-12-14 | 2000-12-19 | Mobil Oil Corporation | Process for co-production of dialkyl carbonate and alkanediol |
| US6166240A (en) * | 2000-02-22 | 2000-12-26 | Mobil Oil Corporation | Process for co-production of dialkyl carbonate and alkanediol |
-
2000
- 2000-01-19 JP JP2000009865A patent/JP3659109B2/ja not_active Expired - Lifetime
-
2001
- 2001-01-17 US US09/760,785 patent/US6380419B2/en not_active Expired - Fee Related
- 2001-01-17 DE DE60110947T patent/DE60110947T2/de not_active Expired - Fee Related
- 2001-01-17 EP EP01100972A patent/EP1125915B1/en not_active Expired - Lifetime
- 2001-01-19 CN CNB011030399A patent/CN1138736C/zh not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9656943B2 (en) | 2015-10-20 | 2017-05-23 | Chang Chun Plastics Co. Ltd. | Process for producing dimethyl carbonate |
| US10131620B2 (en) | 2015-10-20 | 2018-11-20 | Chang Chun Plastics Co., Ltd. | Process for producing dimethyl carbonate |
Also Published As
| Publication number | Publication date |
|---|---|
| DE60110947D1 (de) | 2005-06-30 |
| US6380419B2 (en) | 2002-04-30 |
| DE60110947T2 (de) | 2006-04-27 |
| JP2001199913A (ja) | 2001-07-24 |
| JP3659109B2 (ja) | 2005-06-15 |
| EP1125915B1 (en) | 2005-05-25 |
| CN1308046A (zh) | 2001-08-15 |
| US20010020102A1 (en) | 2001-09-06 |
| EP1125915A1 (en) | 2001-08-22 |
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