CN113677662B - 特定的脱氢方法(i) - Google Patents

特定的脱氢方法(i) Download PDF

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Publication number
CN113677662B
CN113677662B CN202080028170.4A CN202080028170A CN113677662B CN 113677662 B CN113677662 B CN 113677662B CN 202080028170 A CN202080028170 A CN 202080028170A CN 113677662 B CN113677662 B CN 113677662B
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formula
compound
carried out
compounds
present
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Chinese (zh)
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CN113677662A (zh
Inventor
维尔纳·邦拉蒂
马克-安德烈·米勒
贝蒂娜·乌斯特伯格
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DSM IP Assets BV
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DSM IP Assets BV
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/06—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms
    • C07C403/12—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms by esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/14—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by doubly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/44—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with halogen or a halogen-containing compound as an acceptor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/02—Preparation of carboxylic acid esters by interreacting ester groups, i.e. transesterification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/44—Preparation of carboxylic acid esters by oxidation-reduction of aldehydes, e.g. Tishchenko reaction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/14—Acetic acid esters of monohydroxylic compounds
    • C07C69/145—Acetic acid esters of monohydroxylic compounds of unsaturated alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Steroid Compounds (AREA)
CN202080028170.4A 2019-04-15 2020-04-03 特定的脱氢方法(i) Active CN113677662B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP19169206.0 2019-04-15
EP19169206 2019-04-15
PCT/EP2020/059477 WO2020212163A1 (en) 2019-04-15 2020-04-03 Specific dehydrogenation process (i)

Publications (2)

Publication Number Publication Date
CN113677662A CN113677662A (zh) 2021-11-19
CN113677662B true CN113677662B (zh) 2024-07-16

Family

ID=66182394

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202080028170.4A Active CN113677662B (zh) 2019-04-15 2020-04-03 特定的脱氢方法(i)

Country Status (5)

Country Link
US (1) US11851402B2 (https=)
EP (1) EP3956304B1 (https=)
JP (1) JP2022529573A (https=)
CN (1) CN113677662B (https=)
WO (1) WO2020212163A1 (https=)

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1254613B (de) * 1966-05-17 1967-11-23 Basf Ag Verfahren zur Herstellung von Vitamin A-Aldehyd
DE3578169D1 (de) * 1985-01-10 1990-07-19 Kuraray Co Verfahren zur herstellung von vitamin a oder seinen carbonsaeureestern und zwischenprodukte und ihre verwendung in diesem verfahren.
JPS6289657A (ja) * 1985-10-16 1987-04-24 Kuraray Co Ltd ビタミンａ又はそのカルボン酸エステルの製造方法
JP6064264B2 (ja) * 2011-12-27 2017-01-25 ディーエスエム アイピー アセッツ ビー．ブイ． ビタミンａ中間体の触媒合成
BR112015027922B1 (pt) * 2013-05-08 2021-02-02 Dsm Ip Assets B.V processo de produção de acetato de dehidrolinalil (ii)

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
（synthetic investigations in the chemistry of polyene compounds LII.*Synthesis of retinoic and dihdroretinoic esters by the reformatskii reaction;O.O.Tutorskaya等;《Journal of organic chemistr of the USSR》;19911231;第27卷(第7期);P1237-1240 *
the necessity of an intact polyene for the biological isomerization of vitamin A;Wing C.LAW等;《J.AM.Chem.Soc.》;19881231;第110卷;第5961页table1 *

Also Published As

Publication number Publication date
US11851402B2 (en) 2023-12-26
WO2020212163A1 (en) 2020-10-22
US20220194891A1 (en) 2022-06-23
CN113677662A (zh) 2021-11-19
JP2022529573A (ja) 2022-06-23
EP3956304B1 (en) 2026-03-25
EP3956304A1 (en) 2022-02-23
BR112021020268A2 (pt) 2021-12-07

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