CN113230188A - A herba Lycopodii pine needle polysaccharide facial mask with moisturizing and antioxidant effects, and its preparation method - Google Patents

Abstract

The invention relates to the field of cosmetics, and discloses a slash pine needle polysaccharide facial mask with moisturizing and anti-oxidation effects and a preparation method thereof. The facial mask comprises a facial mask solution and a facial mask cloth, wherein the facial mask component comprises a pinus elliottii needle extract, a dendrobium officinale extract, a cherry blossom extract, a black tea extract, allantoin, nicotinamide, sodium hyaluronate, glycerol, squalane, dipotassium glycyrrhizinate, panthenol, betaine, 1, 3-propylene glycol, hydroxymethyl cellulose, acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, triethanolamine, methyl hydroxybenzoate, propyl hydroxybenzoate and EDTA-2 Na. The skin-care cream is particularly suitable for sensitive skin, has small irritation to the skin, can play an effective antioxidant and moisturizing role, and is also suitable for other various skins.

Description

A herba Lycopodii pine needle polysaccharide facial mask with moisturizing and antioxidant effects, and its preparation method

Technical Field

The invention relates to the field of cosmetics, in particular to a slash pine needle polysaccharide facial mask with moisturizing and anti-oxidation effects and a preparation method thereof.

Background

When scientific and efficient skin care is pursued, the moisture retention of the skin is the most important basis for maintaining the skin balance, and the water-oil balance of the skin is the basis for maintaining the water-oil metabolism of the skin and is also the first prerequisite for skin care. With age, the metabolism of the skin gradually slows down, the stratum corneum becomes thinner, and the external stimulus easily increases the free radical content of the skin, and a proper amount of free radicals are beneficial to the human body, can help to transfer energy for maintaining life vitality, can be used for killing bacteria and parasites, and can also participate in toxin elimination. However, when the free radicals in the human body exceed a certain amount, the control is lost, so that the skin is damaged, collagen of the skin is lost, wrinkles are generated, and the elasticity is lost.

The plants are rich in flavonoid, organic acid, polyphenol and other substances, and the substances are proved to have certain whitening effect. The plant extract with the whitening effect is added into the facial mask, and the safe and effective other whitening and relieving components are added, so that the advantages of the products such as the plant extract and the facial mask can be fully exerted, and better skin care experience is brought to people. Nowadays, the concept of 'natural skin care and plant skin care' is gradually paid attention to by the public, and effective antioxidant ingredients extracted from plants are applied to cosmetics, so that the cosmetics have the efficacy of resisting aging and the like.

Can promote skin metabolism through basic moisture retention, and is beneficial to absorption of subsequent skin care products.

Disclosure of Invention

The invention aims to provide a slash pine needle polysaccharide mask with moisturizing and anti-oxidation effects and a preparation method thereof.

The mask with the antioxidant moisturizing effect comprises mask liquid and mask cloth, wherein the mask comprises the following components in parts by weight:

5 to 10 percent of slash pine needle extract, 2 to 4 percent of dendrobium officinale extract, 0.5 to 1 percent of oriental cherry extract, 2 to 4 percent of black tea extract, 2 to 4 percent of allantoin, 0.5 to 3 percent of nicotinamide, 0.01 to 0.1 percent of sodium hyaluronate, 5 to 7 percent of glycerol, 2 to 3 percent of squalane, 2 to 4 percent of dipotassium glycyrrhizinate, 2 to 3 percent of panthenol, 2 to 4 percent of betaine, 1 to 3 percent of 1, 3-propanediol, 0.05 to 0.1 percent of hydroxymethyl cellulose, 0.05 to 0.1 percent of acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, 0.05 to 0.1 percent of triethanolamine, 0.05 to 1 percent of methyl hydroxybenzoate, 0.05 to 1 percent of propyl hydroxybenzoate, 1 to 5 percent of PEG-40 hydrogenated castor oil, 0.03 to 0.05 percent of EDTA-2Na, and purified water which is added to 100 percent.

Preferably, the facial mask comprises, by weight, 7% -10% of a pinus elliottii needle extract, 2% -4% of a dendrobium officinale extract, 0.8% -1% of a cherry blossom extract, 1% -3% of a black tea extract, 2% -3% of allantoin, 0.5% -1% of nicotinamide, 0.06% -0.08% of sodium hyaluronate, 5% -6% of glycerin, 2% -3% of squalane, 2% -4% of dipotassium glycyrrhizinate, 2% -3% of panthenol, 2% -4% of betaine, 1% -2% of 1, 3-propanediol, 0.08% -0.1% of hydroxymethyl cellulose, 0.08% -0.1% of acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, 0.08% -0.1% of triethanolamine, 0.5% -1% of methyl hydroxybenzoate, 0.05% -1% of propyl hydroxybenzoate, 2% -4% of PEG-40 hydrogenated castor oil, 0.03% -0.05% of EDTA-2Na and purified water which are added to 100%.

The mask cloth is eucalyptus velvet film cloth.

The invention relates to a mask with antioxidant moisturizing effect, which is characterized in that: the preparation method of the facial mask comprises the following steps:

the method comprises the following steps: uniformly spreading acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer and hydroxymethyl cellulose on a purified water surface, fully soaking, and stirring for 15 minutes to be uniform;

step two: mixing glycerol, PEG-40 hydrogenated castor oil, betaine, allantoin, sodium hyaluronate, nicotinamide and a proper amount of purified water, adding the mixture obtained in the step one, and stirring at 85 ℃ to obtain a uniform mixture;

step three: cooling the mixture obtained in the second step to 40-45 ℃, adding dipotassium glycyrrhizinate, panthenol, methyl hydroxybenzoate, propyl hydroxybenzoate, triethanolamine, EDTA-2Na and 1, 3-propylene glycol, and uniformly stirring;

step four: cooling the mixture obtained in the third step to room temperature, adding the slash pine needle polysaccharide, the oriental cherry extract, the black tea extract and the dendrobium officinale extract, and stirring uniformly to obtain a finished product;

step five: and (4) inspecting the physical and chemical indexes of the product, discharging after the product is qualified, inspecting, and filling into a mask bag filled with mask cloth after each index is qualified.

Pine needles are widely distributed in the south of China, and because the pine needles contain rich conventional nutritional ingredients such as crude protein, crude fat and crude fiber, and also contain bioactive substances such as amino acids, vitamins, carotene, polyphenols, pigments, flavones, terpenoids, various trace elements and the like, the research on the pine needles is mainly focused on the daily use aspect and the traditional Chinese medicine aspect at present, and the reports on the aspect of skin care products are few. Researches show that the pine needles have high polysaccharide content and can achieve good effects of resisting oxidation and preserving moisture.

According to previous reports, the cherry blossom contains abundant natural vitamin A, B, E, has good whitening and moisturizing effects, has the effects of shrinking pores and balancing grease, can effectively remove redundant free radicals generated after ultraviolet irradiation, and has a good antioxidant effect on skin. Meanwhile, Japanese late flowering cherry is also known as 'youthful flowers' for keeping skin young, so that the flowering cherry extract has certain effects on daily moisturizing and repairing of skin.

According to previous researches, the black tea extract has an inhibiting effect on caspase, the caspase is a core molecule for controlling apoptosis, the inhibiting effect on the caspase can prolong the service life of cells, and meanwhile, the black tea extract can eliminate free radicals in a human body, so that the two aspects achieve the anti-aging effect of the skin.

Herba Dendrobii is an Orchidaceae herb, and its stem can be used as medicine to enhance qi and blood, nourish yin and tonify kidney. According to previous reports, the dendrobium officinale has an inhibiting effect on B-16 melanocytes, can remove free radicals in human skin and achieves an anti-aging effect.

The provitamin B5, also known as panthenol, has good hygroscopicity similar to water-based moisturizers such as hyaluronic acid, can absorb moisture in air, and can promote the penetration of water molecules into skin, thereby keeping skin moisture for a long time. Can effectively inhibit inflammatory reaction of skin and has the effect of repairing skin injury.

The ingredients such as the slash pine needle extract, the oriental cherry extract, the black tea extract and the dendrobium officinale extract with the antioxidant effect and the ingredients such as panthenol, squalane and betaine with the moisturizing effect are added together through a proper process, so that the mask has the antioxidant and moisturizing effects at the same time, and the antioxidant effect of the skin is realized under the condition of ensuring that the skin is not irritated as far as possible.

Drawings

FIG. 1 shows the moisture absorption rate of pine needle polysaccharide under the conditions of (A) saturated potassium carbonate (43% relative humidity) and (B) ammonium sulfate solution (81% relative humidity)

FIG. 2 shows the moisture retention rate of pine needle polysaccharide under the conditions of (A) saturated potassium carbonate (43% relative humidity) and (B) ammonium sulfate solution (81% relative humidity)

FIG. 3 shows the scavenging ability of pine needle polysaccharides to DPPH free radicals

FIG. 4 shows the scavenging ability of pine needle polysaccharide to ABTS free radical

Detailed Description

The present invention is further illustrated by the following examples, which are not intended to limit the invention in any way.

Example 1:

the invention provides a composition of a facial mask with antioxidant moisturizing effect, which comprises facial mask cloth and facial mask liquid, wherein the facial mask cloth is eucalyptus velvet membrane cloth, and the facial mask liquid comprises the following components:

slash pine needle extract: 8 percent of

Cherry extract: 0.8 percent

The dendrobium officinale extract: 2 percent of

Black tea extract: 1 percent of

Allantoin: 2 percent of

Nicotinamide: 0.8 percent

Sodium hyaluronate: 0.06 percent

Glycerol: 5 percent of

Dipotassium glycyrrhizinate: 2 percent of

Squalane: 2 percent of

Panthenol: 2 percent of

1, 3-propanediol: 1 percent of

Hydroxymethyl cellulose: 0.08 percent

acrylic/C10-30 alkanol acrylate crosspolymer: 0.08 percent

Triethanolamine: 0.08 percent

Methyl hydroxybenzoate: 0.5 percent

Propyl hydroxybenzoate: 0.5 percent

ETDA-2Na：0.05％

PEG-40 hydrogenated castor oil: 2 percent of

A preparation method of a mask with antioxidant moisturizing effect is characterized by comprising the following steps:

the method comprises the following steps: uniformly spreading acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer and hydroxymethyl cellulose on a purified water surface, fully soaking, and stirring for 15 minutes to be uniform;

step two: mixing glycerol, PEG-40 hydrogenated castor oil, betaine, allantoin, sodium hyaluronate, nicotinamide and a proper amount of purified water, adding the mixture obtained in the step one, and stirring at 85 ℃ to obtain a uniform mixture;

step three: cooling the mixture obtained in the second step to 40-45 ℃, adding dipotassium glycyrrhizinate, panthenol, methyl hydroxybenzoate, propyl hydroxybenzoate, triethanolamine, EDTA-2Na and 1, 3-propylene glycol, and uniformly stirring;

step four: cooling the mixture obtained in the third step to room temperature, adding the slash pine needle polysaccharide, the oriental cherry extract, the black tea extract and the dendrobium officinale extract, and stirring uniformly to obtain a finished product;

step five: and (4) inspecting the physical and chemical indexes of the product, discharging after the product is qualified, inspecting, and filling into a mask bag filled with mask cloth after each index is qualified.

Example 2:

the invention provides a composition of a facial mask with antioxidant moisturizing effect, which comprises facial mask cloth and facial mask liquid, wherein the facial mask cloth is eucalyptus velvet membrane cloth, and the facial mask liquid comprises the following components:

slash pine needle extract: 8 percent of

Cherry extract: 1 percent of

The dendrobium officinale extract: 3 percent of

Black tea extract: 2 percent of

Allantoin: 3 percent of

Nicotinamide: 0.08 percent

Sodium hyaluronate: 0.08 percent

Glycerol: 5 percent of

Dipotassium glycyrrhizinate: 3 percent of

Squalane: 3 percent of

Panthenol: 3 percent of

1, 3-propanediol: 2 percent of

Hydroxymethyl cellulose: 0.1 percent of

acrylic/C10-30 alkanol acrylate crosspolymer: 0.1 percent of

Triethanolamine: 0.1 percent of

Methyl hydroxybenzoate: 0.5 percent

Propyl hydroxybenzoate: 0.5 percent

ETDA-2Na：0.05％

A preparation method of a mask with antioxidant moisturizing effect is characterized by comprising the following steps:

the method comprises the following steps: uniformly spreading acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer and hydroxymethyl cellulose on a purified water surface, fully soaking, and stirring for 15 minutes to be uniform;

step two: mixing glycerol, PEG-40 hydrogenated castor oil, betaine, allantoin, sodium hyaluronate, nicotinamide and a proper amount of purified water, adding the mixture obtained in the step one, and stirring at 85 ℃ to obtain a uniform mixture;

step three: cooling the mixture obtained in the second step to 40-45 ℃, adding dipotassium glycyrrhizinate, panthenol, methyl hydroxybenzoate, propyl hydroxybenzoate, triethanolamine, EDTA-2Na and 1, 3-propylene glycol, and uniformly stirring;

step four: cooling the mixture obtained in the third step to room temperature, adding the slash pine needle polysaccharide, the oriental cherry extract, the black tea extract and the dendrobium officinale extract, and stirring uniformly to obtain a finished product;

step five: and (4) inspecting the physical and chemical indexes of the product, discharging after the product is qualified, inspecting, and filling into a mask bag filled with mask cloth after each index is qualified.

Example 3:

the invention provides a composition of a facial mask with antioxidant moisturizing effect, which comprises facial mask cloth and facial mask liquid, wherein the facial mask cloth is eucalyptus velvet membrane cloth, and the facial mask liquid comprises the following components:

slash pine needle extract: 10 percent of

Cherry extract: 1 percent of

The dendrobium officinale extract: 2 percent of

Black tea extract: 3 percent of

Allantoin: 3 percent of

Nicotinamide: 0.08 percent

Sodium hyaluronate: 0.08 percent

Glycerol: 6 percent of

Dipotassium glycyrrhizinate: 4 percent of

Squalane: 3 percent of

Panthenol: 3 percent of

1, 3-propanediol: 1 percent of

Hydroxymethyl cellulose: 0.08 percent

acrylic/C10-30 alkanol acrylate crosspolymer: 0.08 percent

Triethanolamine: 0.08 percent

Methyl hydroxybenzoate: 0.5 percent

Propyl hydroxybenzoate: 0.5 percent

ETDA-2Na：0.05％

A preparation method of a mask with antioxidant moisturizing effect is characterized by comprising the following steps:

the method comprises the following steps: uniformly spreading acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer and hydroxymethyl cellulose on a purified water surface, fully soaking, and stirring for 15 minutes to be uniform;

step two: mixing glycerol, PEG-40 hydrogenated castor oil, betaine, allantoin, sodium hyaluronate, nicotinamide and a proper amount of purified water, adding the mixture obtained in the step one, and stirring at 85 ℃ to obtain a uniform mixture;

step three: cooling the mixture obtained in the second step to 40-45 ℃, adding dipotassium glycyrrhizinate, panthenol, methyl hydroxybenzoate, propyl hydroxybenzoate, triethanolamine, EDTA-2Na and 1, 3-propylene glycol, and uniformly stirring;

step four: cooling the mixture obtained in the third step to room temperature, adding the slash pine needle polysaccharide, the oriental cherry extract, the black tea extract and the dendrobium officinale extract, and stirring uniformly to obtain a finished product;

step five: and (4) inspecting the physical and chemical indexes of the product, discharging after the product is qualified, inspecting, and filling into a mask bag filled with mask cloth after each index is qualified.

Example 4: moisture absorption and retention capacity analysis of slash pine needle polysaccharide

The moisture absorption and moisture retention capacity of the slash pine needle polysaccharide is tested by a weighing method. Putting the pine needle polysaccharide, the reference glycerol and the hyaluronic acid into a allochroic silica gel, saturated potassium carbonate (relative humidity of 43%) and ammonium sulfate solution (relative humidity of 81%) dryer at 20 ℃, recording the mass of 0, 5, 12, 25 and 50h, performing parallel operation for 3 times at each time point, taking the average mass, and calculating the moisture absorption rate and the moisture retention rate.

Example 5: scavenging effect of slash pine needle polysaccharide on DPPH and ABTS free radicals

The excessive free radicals in the body react with unsaturated fatty acids in the body, resulting in abnormal function of cell membranes and abnormal state of the body. When it is expressed on the skin, the skin becomes dry, wrinkles are generated, collagen is lost, the skin elasticity is reduced, and skin pigmentation and black spots are formed.

ABTS free radical clearance detection:

ABTS is easily oxidized into green by an oxidant, and after the antioxidant is added, free radicals can be eliminated, so that the color is lightened, and the eliminating effect of the antioxidant can be judged by a colorimetric method. The ABTS reaction stock solution and a potassium persulfate solution are fully and uniformly mixed 12 hours before use, and then are diluted by a PBS solution, and the absorbance at 734nm is adjusted to be 0.70 +/-0.05. Adding folium Pini extract sample solutions with different concentrations, measuring absorbance at 734nm wavelength after 5min, using distilled water as blank control, and VC as positive control.

Clearance (%) - (1- (a)_j-A_i)/A_o)×100

In the formula: a. the_jBlank absorbance;

A_iis the absorbance of the sample;

A_oabsorbance was taken as the control.

DPPH free radical clearance detection:

collecting folium Pini extract samples with different concentrations and 2 × 10^-4mixing the mol/L DPPH solution uniformly, reacting for 30min in the dark, measuring the absorbance at 517nm, and recording as A₁(ii) a Mixing distilled water and DPPH solution at the same volume, mixing anhydrous ethanol and sample at the same volume, reacting in dark for 30min, measuring absorbance at 517nm, and recording as A₂And A₃。

DPPH radical scavenging ratio (A)₂+A₃-A₁)/A₂×100％

Example 6: sensory testing

When the facial mask liquid sample in the example 3 is smeared on the back of hands, the skin feel is comfortable and not sticky, the current skin dryness is obviously relieved when the facial mask liquid sample is used, and the using effect is better.

Claims (4)

1. A herba Lycopodii pine needle polysaccharide facial mask with moisturizing and antioxidant effects and its preparation method are provided.

2. The mask pack according to claim 1, wherein the mask pack comprises, in parts by weight, 5% to 10% pine needle extract of slash pine, 2% to 4% dendrobium officinale extract, 0.5% to 1% cherry blossom extract, 2% to 4% black tea extract, 2% to 4% allantoin, 0.5% to 3% niacinamide, 0.01% to 0.1% sodium hyaluronate, 5% to 7% glycerin, 2% to 3% squalane, 2% to 4% dipotassium glycyrrhizinate, 2% to 3% panthenol, 2% to 4% betaine, 1% to 3% 1, 3-propanediol, 0.05% to 0.1% hydroxymethyl cellulose, 0.05% to 0.1% acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, 0.05% to 0.1% triethanolamine, 0.05% to 1% methylparaben, 0.05% to 1% propylparaben, 1% to 5% PEG-40 hydrogenated castor oil, 0.05% to 0.03% EDTA-2Na, purified water is made up to 100%.

3. The mask pack according to claim 2, wherein the mask solution comprises, in parts by weight, 7% to 10% of pinus elliottii needle extract, 2% to 4% of dendrobium officinale extract, 0.8% to 1% of oriental cherry extract, 1% to 3% of black tea extract, 2% to 3% of allantoin, 0.5% to 1% of nicotinamide, 0.06% to 0.08% of sodium hyaluronate, 5% to 6% of glycerin, 2% to 3% of squalane, 2% to 4% of dipotassium glycyrrhizinate, 2% to 3% of panthenol, 2% to 4% of betaine, 1% to 2% of 1, 3-propanediol, 0.08 to 0.1% of hydroxymethyl cellulose, 0.08 to 0.1% of acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, 0.08 to 0.1% of triethanolamine, 0.5% to 1% of methylparaben, 0.05% to 1% of propylparaben, 2% to 4% of PEG-40 hydrogenated castor oil, 0.03 to 0.05 percent of EDTA-2Na and purified water to 100 percent.

4. The mask according to claim 2, wherein the preparation method comprises the steps of:

the method comprises the following steps: uniformly spreading acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer and hydroxymethyl cellulose on a purified water surface, fully soaking, and stirring for 15 minutes to be uniform;

step two: mixing glycerol, PEG-40 hydrogenated castor oil, betaine, allantoin, sodium hyaluronate, nicotinamide and a proper amount of purified water, adding the mixture obtained in the step one, and stirring at 85 ℃ to obtain a uniform mixture;

step three: cooling the mixture obtained in the second step to 40-45 ℃, adding dipotassium glycyrrhizinate, panthenol, methyl hydroxybenzoate, propyl hydroxybenzoate, triethanolamine, EDTA-2Na and 1, 3-propylene glycol, and uniformly stirring;

step four: cooling the mixture obtained in the third step to room temperature, adding the slash pine needle polysaccharide, the oriental cherry extract, the black tea extract and the dendrobium officinale extract, and stirring uniformly to obtain a finished product;

step five: and (4) inspecting the physical and chemical indexes of the product, discharging after the product is qualified, inspecting, and filling into a mask bag filled with mask cloth after each index is qualified.

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