CN112921640B - 一种阻燃织带的制备方法 - Google Patents

一种阻燃织带的制备方法 Download PDF

Info

Publication number
CN112921640B
CN112921640B CN202110135393.7A CN202110135393A CN112921640B CN 112921640 B CN112921640 B CN 112921640B CN 202110135393 A CN202110135393 A CN 202110135393A CN 112921640 B CN112921640 B CN 112921640B
Authority
CN
China
Prior art keywords
flame
retardant
parts
nano
drying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202110135393.7A
Other languages
English (en)
Other versions
CN112921640A (zh
Inventor
薛迪
薛翔翔
薛成
薛劲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shishi Jinliang Ribbon Co ltd
Original Assignee
Shishi Jinliang Ribbon Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shishi Jinliang Ribbon Co ltd filed Critical Shishi Jinliang Ribbon Co ltd
Priority to CN202110135393.7A priority Critical patent/CN112921640B/zh
Publication of CN112921640A publication Critical patent/CN112921640A/zh
Application granted granted Critical
Publication of CN112921640B publication Critical patent/CN112921640B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/06—Inorganic compounds or elements
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/16—Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B1/00—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
    • D06B1/02—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by spraying or projecting
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic System; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic System; Aluminates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/47—Oxides or hydroxides of elements of Groups 5 or 15 of the Periodic System; Vanadates; Niobates; Tantalates; Arsenates; Antimonates; Bismuthates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

Abstract

本发明涉及织带的制备领域，公开了一种阻燃织带的制备方法，包括如下步骤：(1)将氯化锂溶液在超声雾化箱进行雾化，将纺织纤维传送经过超声雾化箱，使得氯化锂溶液对纺织纤维的表面进行浸润、改性，之后进行烘干，得到改性纤维；(2)将阻燃溶液通过静电喷涂于步骤(1)得到的改性纤维的表面，之后进行烘干得到阻燃纤维，(3)将阻燃纤维编织成织带，得到阻燃织带，通过本发明制备的阻燃织带，织带表面形成的阻燃层，阻燃层与纺织纤维结合牢固，步骤简单方便，避免了传统方法大量污水的产生。

Description

一种阻燃织带的制备方法
技术领域
本发明涉及织带的制备领域，特别是一种阻燃织带的制备方法。
背景技术
随着人们生活水平的提高及消防意识的增强，对家庭装饰用纺织面料的阻燃要求也越来越高。阻燃纺织品在延缓火灾扩大的同时，还可使人们有时间撤离或采取措施灭火。因此，为阻止火灾的发生对纺织品进行阻燃整理变得尤为重要。
目前，多采用将阻燃剂与纤维分子链进行接枝、共聚等方法或对纤维或纺织成品进行浸渍、浸轧等方法进行改性，前者工艺较复杂，且影响织物的强度，而后者工艺虽简易却大量消耗水、热等能源，且使用设备占用较大的面积，并且排放出大量污水，阻燃剂也会有一定程度的浪费。
发明内容
为此，需要提供一种阻燃织带的制备方法，解决现有成品纺织面料浸渍、浸轧改性时，成本较高，污水排放量大的问题。
为实现上述目的，本发明提供了一种阻燃织带的制备方法，包括如下步骤：
(1)将氯化锂溶液在超声雾化箱进行雾化，将纺织纤维传送经过超声雾化箱，使得氯化锂溶液对纺织纤维的表面进行浸润、改性，之后进入烘干机进行烘干，得到改性纤维；
(2)将阻燃溶液通过静电喷涂于步骤(1)得到的改性纤维的表面，之后进入烘干机进行烘干，得到阻燃纤维；
(3)将阻燃纤维编织成织带，得到阻燃织带，所述阻燃溶液中按重量份数计包括：5-10份纳米氢氧化铝、3-5份纳米氢氧化镁、1-2份纳米三氧化二锑、 3-10份壳聚糖、20-30份去离子水。
进一步，步骤(1)中，氯化锂溶液的溶剂为乙醇，所述氯化锂溶液的浓度为1wt％-10wt％。
进一步，所述阻燃溶液按重量组分包括8份纳米氢氧化铝、5份纳米氢氧化镁、1份纳米三氧化二锑、8份壳聚糖、25份去离子水，所述氯化锂溶液的浓度为5wt％。
进一步，步骤(1)中，超声频率为50-70KHz，所述纺织纤维经过超声雾化箱的时间为2-10min。
进一步，纳米氢氧化铝的平均粒径为25-50nm，纳米氢氧化镁的平均粒径为25-50nm，纳米三氧化二锑的平均粒径为25-50nm。
进一步，步骤(2)中，进行静电喷涂时，喷涂间距为80-100mm，喷涂电压为150V-200V。
进一步，步骤(1)中，烘干机保持在惰性气体的氛围内进行烘干，烘干的温度为90-110℃，烘干时间为10-30s。
进一步，步骤(2)中，烘干的温度为120-150℃，烘干时间为30-60s。
进一步，所述阻燃织带为纬编结构。纬编结构包括平针织物、罗纹织物和畦编织物，纬编结构具有高能量吸收性，有较好的弹性和延伸形。
进一步，所述纺织纤维的材料为涤纶或锦纶。
上述技术方案具有以下有益效果：
(1)本发明中，在进行阻燃改性之前，使用氯化锂溶液对纺织纤维进行改性，且改性时，氯化锂溶液以雾滴的形式接触纺织纤维的表面，纺织纤维的表面更容易被雾化的氯化锂溶液浸润、改性，且超声对氯化锂与纺织纤维表面的结合具有一定的激励作用，氯化锂改性完之后，纺织纤维的表面粗糙度增加、表面活性基团也增加，另外，纺织纤维的力学性能也相应的增加。
(2)本发明中，纺织纤维进行改性时，阻燃溶液通过静电喷涂的方式，在纺织纤维的表面形成一层阻燃层，纺织纤维表面的活性基团能够与阻燃溶液的各种主要成分相结合，使得阻燃层结合牢固，另外，使用静电喷涂方式避免了大量废水的产生，整个生产过程绿色、环保、无污染。
具体实施方式
为详细说明技术方案的技术内容、构造特征、所实现目的及效果，以下结合具体实施例详予说明。
实施例1
一种阻燃织带的制备方法，包括如下步骤：
(1)将5wt％氯化锂乙醇溶液在超声雾化箱进行雾化，将纺织纤维传送经过超声雾化箱，超声频率为60KHz，所述纺织纤维经过超声雾化箱的时间为 8min，使得氯化锂乙醇溶液对纺织纤维的表面进行浸润、改性，之后通过烘干室进行烘干，烘干室保持在惰性气体的气体氛围内进行烘干，烘干的温度为100℃，烘干时间为20s，惰性气体为氮气，得到改性纤维；
(2)使用静电喷涂设备将阻燃溶液通过静电喷涂于步骤(1)得到的改性纤维的表面，进行静电喷涂时，阻燃溶液的喷涂出口与改性纤维表面的喷涂间距为90mm，喷涂电压为170V，之后改性纤维进入烘干机进行烘干，得到阻燃纤维，烘干的温度为130℃，烘干时间为40s；
(3)将阻燃纤维罗纹编织成织带，得到阻燃织带。
所述阻燃溶液中按重量份数计包括：8份纳米氢氧化铝、5份纳米氢氧化镁、1份纳米三氧化二锑、8份壳聚糖、25份去离子水。
纳米氢氧化铝的平均粒径为25nm，纳米氢氧化镁的平均粒径为25nm，纳米三氧化二锑的平均粒径为25nm。
本实施例中纺织纤维的材料为涤纶。
实施例2
一种阻燃织带的制备方法，包括如下步骤：
(1)将1％wt氯化锂乙醇溶液在超声雾化箱进行雾化，将纺织纤维传送经过超声雾化箱，超声频率为50KHz，所述纺织纤维经过超声雾化箱的时间为 10min，使得氯化锂乙醇溶液对纺织纤维的表面进行浸润、改性，之后通过烘干室进行烘干，烘干室保持在惰性气体的气体氛围内进行烘干，烘干的温度为90℃，烘干时间为30s，惰性气体为氮气，得到改性纤维；
(2)使用静电喷涂设备将阻燃溶液通过静电喷涂于步骤(1)得到的改性纤维的表面，进行静电喷涂时，阻燃溶液的喷涂出口与改性纤维表面的喷涂间距为80mm，喷涂电压为150V，之后改性纤维进入烘干机进行烘干，得到阻燃纤维，烘干的温度为120℃，烘干时间为60s；
(3)将阻燃纤维罗纹编织成织带，得到阻燃织带。
所述阻燃溶液中按重量份数计包括：5份纳米氢氧化铝、3份纳米氢氧化镁、1份纳米三氧化二锑、3份壳聚糖、20份去离子水。
纳米氢氧化铝的平均粒径为25nm，纳米氢氧化镁的平均粒径为25nm，纳米三氧化二锑的平均粒径为25nm。
本实施例中纺织纤维的材料为涤纶。
实施例3
一种阻燃织带的制备方法，包括如下步骤：
(1)将10％wt氯化锂乙醇溶液在超声雾化箱进行雾化，将纺织纤维传送经过超声雾化箱，超声频率为70KHz，所述纺织纤维经过超声雾化箱的时间为 2min，使得氯化锂乙醇溶液对纺织纤维的表面进行浸润、改性，之后通过烘干室进行烘干，烘干室保持在惰性气体的气体氛围内进行烘干，烘干的温度为110℃，烘干时间为10s，惰性气体为氮气，得到改性纤维；
(2)使用静电喷涂设备将阻燃溶液通过静电喷涂于步骤(1)得到的改性纤维的表面，进行静电喷涂时，喷涂间距为100mm，喷涂电压为200V，之后改性纤维进入烘干机进行烘干，得到阻燃纤维，烘干的温度为150℃，烘干时间为30s；
(3)将阻燃纤维罗纹编织成织带，得到阻燃织带。
所述阻燃溶液中按重量份数计包括：10份纳米氢氧化铝、5份纳米氢氧化镁、2份纳米三氧化二锑、10份壳聚糖、30份去离子水。
纳米氢氧化铝的平均粒径为50nm，纳米氢氧化镁的平均粒径为50nm，纳米三氧化二锑的平均粒径为50nm。
本实施例中纺织纤维的材料为涤纶。
实施例4
一种阻燃织带的制备方法，包括如下步骤：
(1)将5wt％氯化锂乙醇溶液在超声雾化箱进行雾化，将纺织纤维传送经过超声雾化箱，超声频率为60KHz，所述纺织纤维经过超声雾化箱的时间为 8min，使得氯化锂乙醇溶液对纺织纤维的表面进行浸润、改性，之后通过烘干室进行烘干，烘干室保持在惰性气体的气体氛围内进行烘干，烘干的温度为100℃，烘干时间为20s，惰性气体为氮气，得到改性纤维；
(2)使用静电喷涂设备将阻燃溶液通过静电喷涂于步骤(1)得到的改性纤维的表面，进行静电喷涂时，阻燃溶液的喷涂出口与改性纤维表面的喷涂间距为90mm，喷涂电压为170V，之后改性纤维进入烘干机进行烘干，得到阻燃纤维，烘干的温度为130℃，烘干时间为40s；
(3)将阻燃纤维罗纹编织成织带，得到阻燃织带。所述阻燃溶液中按重量份数计包括：8份纳米氢氧化铝、5份纳米氢氧化镁、1份纳米三氧化二锑、 8份壳聚糖、25份去离子水。
纳米氢氧化铝的平均粒径为25nm，纳米氢氧化镁的平均粒径为25nm，纳米三氧化二锑的平均粒径为25nm。
本实施例中纺织纤维的材料为锦纶。
实施例5
一种阻燃织带的制备方法，包括如下步骤：
(1)使用静电喷涂设备将阻燃溶液通过静电喷涂于纺织纤维的表面，进行静电喷涂时，阻燃溶液的喷涂出口与纺织纤维表面的喷涂间距为90mm，喷涂电压为170V，之后织带进入烘干机进行烘干，得到阻燃织带，烘干的温度为130℃，烘干时间为40s。
(2)将阻燃纤维罗纹编织成织带，得到阻燃织带。
所述阻燃溶液中按重量份数计包括：8份纳米氢氧化铝、5份纳米氢氧化镁、1份纳米三氧化二锑、8份壳聚糖、25份去离子水。
纳米氢氧化铝的平均粒径为25nm，纳米氢氧化镁的平均粒径为25nm，纳米三氧化二锑的平均粒径为25nm。本实施例中织带的材料为涤纶，织带为纬编结构。
对照组1：涤纶罗纹编织成织带，对照组2：锦纶罗纹编织成织带。
实施例1-5生产的阻燃织带和对照组1-2，通过GB/T5454-1997《纺织品燃烧性能测定-氧指数测定法》测定各个实施例生产的织带的氧指数，极限氧指数是判断材料阻燃性的常用指标，指在规定试验条件下，使材料恰好能保持燃烧状态所需氮氧混合气体中氧的最低浓度。根据，极限氧指数(LOI)大小，纺织品的燃烧性能可分为4级：易燃(LOI＜20％)、可燃(20％≤LOI ＜26％)、难燃(26％≤LOI＜30％)和不燃(LOI≥30％)。
实施1-4和对照组1-2生产织带还拉伸强度测试，
上述实验结果如表1所示
表1.检测数据。
纺织纤维材料 极限氧指数/％ 拉伸强度/kN
实施例1 涤纶 43 18.36
实施例2 涤纶 35 16.56
实施例3 涤纶 37 15.38
实施例4 锦纶 40 15.47
实施例5 涤纶 33 13.43
对照组1 涤纶 20 13.28
对照组2 锦纶 22 12.48
由表1表明，通过本发明制备的织带其燃烧性能均能够达到了“不燃”等级，且生产的织带具有较强的拉伸强度。
需要说明的是，在本文中，诸如第一和第二等之类的关系术语仅仅用来将一个实体或者操作与另一个实体或操作区分开来，而不一定要求或者暗示这些实体或操作之间存在任何这种实际的关系或者顺序。而且，术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含，从而使得包括一系列要素的过程、方法、物品或者终端设备不仅包括那些要素，而且还包括没有明确列出的其他要素，或者是还包括为这种过程、方法、物品或者终端设备所固有的要素。在没有更多限制的情况下，由语句“包括……”或“包含……”限定的要素，并不排除在包括所述要素的过程、方法、物品或者终端设备中还存在另外的要素。此外，在本文中，“大于”、“小于”、“超过”等理解为不包括本数；“以上”、“以下”、“以内”等理解为包括本数。
尽管已经对上述各实施例进行了描述，但本领域内的技术人员一旦得知了基本创造性概念，则可对这些实施例做出另外的变更和修改，所以以上所述仅为本发明的实施例，并非因此限制本发明的专利保护范围，凡是利用本发明说明书内容所作的等效结构或等效流程变换，或直接或间接运用在其他相关的技术领域，均同理包括在本发明的专利保护范围之内。

Claims (8)

1.一种阻燃织带的制备方法，其特征在于，包括如下步骤：
（1）将氯化锂溶液在超声雾化箱进行雾化，将纺织纤维传送经过超声雾化箱，使得氯化锂溶液对纺织纤维进行浸润、改性，之后进入烘干机进行烘干，得到改性纤维，超声频率为50-70KHz，所述纺织纤维经过超声雾化箱的时间为2-10min；
（2）将阻燃溶液通过静电喷涂于步骤（1）得到的改性纤维的表面，之后进入烘干机进行烘干，得到阻燃纤维，进行静电喷涂时，喷涂间距为80-100mm，喷涂电压为150V-200V；
(3)将阻燃纤维编织成织带，得到阻燃织带，
所述阻燃溶液中按重量份数计包括：5-10份纳米氢氧化铝、3-5份纳米氢氧化镁、1-2份纳米三氧化二锑、3-10份壳聚糖、20-30份去离子水。
2.如权利要求1所述的制备方法，其特征在于，步骤（1）中，氯化锂溶液的溶剂为乙醇，所述氯化锂溶液的浓度为1wt%-10wt%。
3.如权利要求2所述的制备方法，其特征在于,所述阻燃溶液按重量组分包括8份纳米氢氧化铝、5份纳米氢氧化镁、1份纳米三氧化二锑、8份壳聚糖、25份去离子水，所述氯化锂溶液的浓度为5wt%。
4.如权利要求1所述的制备方法，其特征在于，纳米氢氧化铝的平均粒径为25-50nm，纳米氢氧化镁的平均粒径为25-50nm，纳米三氧化二锑的平均粒径为25-50nm。
5.如权利要求1所述的制备方法，其特征在于，步骤（1）中，烘干机保持在惰性气体的氛围内进行烘干，烘干的温度为90-110℃，烘干时间为10-30s。
6.如权利要求1所述的制备方法，其特征在于，步骤（2）中，烘干的温度为120-150℃，烘干时间为30-60s。
7.如权利要求1所述的制备方法，其特征在于，所述阻燃织带为纬编结构。
8.如权利要求1所述的制备方法，其特征在于，所述纺织纤维的材料为涤纶或锦纶。
CN202110135393.7A 2021-02-01 2021-02-01 一种阻燃织带的制备方法 Active CN112921640B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110135393.7A CN112921640B (zh) 2021-02-01 2021-02-01 一种阻燃织带的制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110135393.7A CN112921640B (zh) 2021-02-01 2021-02-01 一种阻燃织带的制备方法

Publications (2)

Publication Number Publication Date
CN112921640A CN112921640A (zh) 2021-06-08
CN112921640B true CN112921640B (zh) 2022-07-29

Family

ID=76169198

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110135393.7A Active CN112921640B (zh) 2021-02-01 2021-02-01 一种阻燃织带的制备方法

Country Status (1)

Country Link
CN (1) CN112921640B (zh)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20100090566A (ko) * 2009-02-06 2010-08-16 웅진케미칼 주식회사 스프레이 코팅법 및 자외선 경화법을 이용한 직물 및 이의 제조방법
CN102002834A (zh) * 2010-12-01 2011-04-06 武汉纺织大学 一种纺织品染色方法
CN102936842A (zh) * 2012-10-29 2013-02-20 金猴集团威海鞋业有限公司 一种纳米阻燃中底鞋材
CN109208103A (zh) * 2018-08-31 2019-01-15 龙丝（上海）新材料科技有限公司 一种阻燃纤维素纤维的制备方法
CN110424150A (zh) * 2019-07-31 2019-11-08 山东大学 一种芳纶纤维表面改性方法
CN111712597A (zh) * 2018-02-13 2020-09-25 日本制纸株式会社 阻燃化的复合纤维及其制造方法
CN112251870A (zh) * 2020-09-07 2021-01-22 苏州贤辉新纺织科技有限公司 一种采用回收聚酯纤维再生阻燃聚酯纤维的工艺方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090031537A1 (en) * 2007-08-03 2009-02-05 Muscarella Nicholas V Safety Strap for Securing Trousers

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20100090566A (ko) * 2009-02-06 2010-08-16 웅진케미칼 주식회사 스프레이 코팅법 및 자외선 경화법을 이용한 직물 및 이의 제조방법
CN102002834A (zh) * 2010-12-01 2011-04-06 武汉纺织大学 一种纺织品染色方法
CN102936842A (zh) * 2012-10-29 2013-02-20 金猴集团威海鞋业有限公司 一种纳米阻燃中底鞋材
CN111712597A (zh) * 2018-02-13 2020-09-25 日本制纸株式会社 阻燃化的复合纤维及其制造方法
CN109208103A (zh) * 2018-08-31 2019-01-15 龙丝（上海）新材料科技有限公司 一种阻燃纤维素纤维的制备方法
CN110424150A (zh) * 2019-07-31 2019-11-08 山东大学 一种芳纶纤维表面改性方法
CN112251870A (zh) * 2020-09-07 2021-01-22 苏州贤辉新纺织科技有限公司 一种采用回收聚酯纤维再生阻燃聚酯纤维的工艺方法

Also Published As

Publication number Publication date
CN112921640A (zh) 2021-06-08

Similar Documents

Publication Publication Date Title
Lam et al. Effect of zinc oxide on flame retardant finishing of plasma pre-treated cotton fabric
Morent et al. Non-thermal plasma treatment of textiles
WO2020077695A1 (zh) 一种反应性阻燃剂及其对蛋白质纤维耐久阻燃整理的方法
CN109137467B (zh) 一锅法制备超疏水阻燃纺织物的方法
Li et al. Layer-by-layer self-assembly of organic-inorganic hybrid intumescent flame retardant on cotton fabrics
Shahidi et al. Effect of plasma pretreatment followed by nanoclay loading on flame retardant properties of cotton fabric
Lam et al. Effect of titanium dioxide on the flame‐retardant finishing of cotton fabric
CN104818607A (zh) 电子辐射技术制备阻燃纺织品的方法
CN111206411A (zh) 一种等离子改性防水防油防污纤维及其制备方法、应用
EP0663968B1 (de) Verfahren zur plasmabehandlung von antiballistisch wirksamen materialien
Lam et al. Effect of oxygen plasma pretreatment and titanium dioxide overlay coating on flame retardant finished cotton fabrics
CN111996798A (zh) 一种lbl法膨胀型阻燃棉织物涂层及其涂装方法
CN112921640B (zh) 一种阻燃织带的制备方法
CN106592221A (zh) 一种阻燃防静电面料的制备方法
KR20080112797A (ko) 난연성이 우수한 폴리프로필렌 장섬유 다층 복합 부직포
JP2836205B2 (ja) 炎中反応による高分子の表層改質方法および高分子成形品
CN101265660B (zh) 一种阻燃型涤纶工业长丝及其生产工艺
Vest et al. Polyelectrolyte complex for flame retardant silk
Šimor et al. The influence of surface DBD plasma treatment on the adhesion of coatings to high-tech textiles
Kale et al. A novel approach for functionalization of polyester and cotton textiles with continuous online deposition of plasma polymers
CN109423883B (zh) 一种阻燃超高分子量聚乙烯织物的制备方法
Palaskar et al. Plasma induced nano-finish for multifunctional properties on cotton fabric
CN114752096B (zh) 基于全生物基阻燃剂的高分子阻燃材料及其制备方法
Navik et al. Effect of dielectric barrier discharge parameters on certain properties of natural polymeric material (cotton) fiber
CN105088809A (zh) 一种防油针刺棉的制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: A preparation method of flame retardant ribbon

Effective date of registration: 20221117

Granted publication date: 20220729

Pledgee: Fujian Shishi Rural Commercial Bank Co.,Ltd. Jinshang Sub branch

Pledgor: SHISHI JINLIANG RIBBON Co.,Ltd.

Registration number: Y2022350000150

PE01 Entry into force of the registration of the contract for pledge of patent right