CN112774712B - 一种用于降解抗生素的光催化材料及其制备方法和应用 - Google Patents
一种用于降解抗生素的光催化材料及其制备方法和应用 Download PDFInfo
- Publication number
- CN112774712B CN112774712B CN202110094114.7A CN202110094114A CN112774712B CN 112774712 B CN112774712 B CN 112774712B CN 202110094114 A CN202110094114 A CN 202110094114A CN 112774712 B CN112774712 B CN 112774712B
- Authority
- CN
- China
- Prior art keywords
- photocatalytic material
- photocatalytic
- levofloxacin
- melamine
- antibiotics
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000463 material Substances 0.000 title claims abstract description 65
- 230000001699 photocatalysis Effects 0.000 title claims abstract description 64
- 230000000593 degrading effect Effects 0.000 title claims abstract description 15
- 239000003242 anti bacterial agent Substances 0.000 title claims description 20
- 229940088710 antibiotic agent Drugs 0.000 title claims description 18
- 238000002360 preparation method Methods 0.000 title claims description 8
- 229910015902 Bi 2 O 3 Inorganic materials 0.000 claims abstract description 23
- GSDSWSVVBLHKDQ-JTQLQIEISA-N Levofloxacin Chemical compound C([C@@H](N1C2=C(C(C(C(O)=O)=C1)=O)C=C1F)C)OC2=C1N1CCN(C)CC1 GSDSWSVVBLHKDQ-JTQLQIEISA-N 0.000 claims abstract description 21
- 229960003376 levofloxacin Drugs 0.000 claims abstract description 21
- 239000002131 composite material Substances 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims description 11
- 229920000877 Melamine resin Polymers 0.000 claims description 9
- 230000003115 biocidal effect Effects 0.000 claims description 9
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 claims description 8
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims description 8
- 229940068041 phytic acid Drugs 0.000 claims description 8
- 235000002949 phytic acid Nutrition 0.000 claims description 8
- 239000000467 phytic acid Substances 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 239000004570 mortar (masonry) Substances 0.000 claims description 4
- 239000010431 corundum Substances 0.000 claims description 3
- 229910052593 corundum Inorganic materials 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- FBXVOTBTGXARNA-UHFFFAOYSA-N bismuth;trinitrate;pentahydrate Chemical compound O.O.O.O.O.[Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FBXVOTBTGXARNA-UHFFFAOYSA-N 0.000 claims 1
- 238000006731 degradation reaction Methods 0.000 abstract description 18
- 230000015556 catabolic process Effects 0.000 abstract description 16
- 238000002474 experimental method Methods 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 abstract 2
- 229960002685 biotin Drugs 0.000 abstract 1
- 235000020958 biotin Nutrition 0.000 abstract 1
- 239000011616 biotin Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 238000001514 detection method Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000031700 light absorption Effects 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000000634 powder X-ray diffraction Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000005215 recombination Methods 0.000 description 2
- 230000006798 recombination Effects 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004098 Tetracycline Substances 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000000589 high-performance liquid chromatography-mass spectrometry Methods 0.000 description 1
- 238000000024 high-resolution transmission electron micrograph Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- 238000002186 photoelectron spectrum Methods 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- LISFMEBWQUVKPJ-UHFFFAOYSA-N quinolin-2-ol Chemical compound C1=CC=C2NC(=O)C=CC2=C1 LISFMEBWQUVKPJ-UHFFFAOYSA-N 0.000 description 1
- 150000007660 quinolones Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 229940043267 rhodamine b Drugs 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 235000019364 tetracycline Nutrition 0.000 description 1
- 150000003522 tetracyclines Chemical class 0.000 description 1
- 229940040944 tetracyclines Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 150000003952 β-lactams Chemical class 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/38—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110094114.7A CN112774712B (zh) | 2021-01-22 | 2021-01-22 | 一种用于降解抗生素的光催化材料及其制备方法和应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110094114.7A CN112774712B (zh) | 2021-01-22 | 2021-01-22 | 一种用于降解抗生素的光催化材料及其制备方法和应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN112774712A CN112774712A (zh) | 2021-05-11 |
CN112774712B true CN112774712B (zh) | 2022-11-11 |
Family
ID=75758826
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202110094114.7A Active CN112774712B (zh) | 2021-01-22 | 2021-01-22 | 一种用于降解抗生素的光催化材料及其制备方法和应用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN112774712B (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114471628A (zh) * | 2022-03-10 | 2022-05-13 | 重庆邮电大学 | 一种钙钛矿光催化剂及其制备方法和应用 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5157561B2 (ja) * | 2007-03-20 | 2013-03-06 | 新日鐵住金株式会社 | 可視光応答型光触媒とその製造方法 |
CN104549406B (zh) * | 2014-12-19 | 2017-01-25 | 华南理工大学 | 一种g‑C3N4/铋系氧化物复合可见光催化剂及其制备方法与应用 |
CN107029699A (zh) * | 2017-06-23 | 2017-08-11 | 闽南师范大学 | 一种含有α和β晶型的氧化铋光催化剂及其制备方法与应用 |
CN108793312B (zh) * | 2018-06-25 | 2020-07-03 | 湖南大学 | 利用氮化碳/氮掺中空介孔碳/三氧化二铋三元z型光催化剂催化去除抗生素的方法 |
CN109735963B (zh) * | 2019-01-16 | 2021-12-21 | 江苏理工学院 | 一种氮化碳纳米纤维的制备方法及其应用 |
CN110694660B (zh) * | 2019-10-11 | 2021-01-12 | 力行氢能科技股份有限公司 | 异质元素掺杂的氮化碳光催化材料及其制备方法和应用 |
-
2021
- 2021-01-22 CN CN202110094114.7A patent/CN112774712B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
CN112774712A (zh) | 2021-05-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US11192093B2 (en) | Two-dimensional nitrogen-doped carbon-based titanium dioxide composite material, and preparation method and application thereof for degrading and removing organic pollutants in water | |
CN108325555B (zh) | 氮自掺杂石墨化氮化碳纳米片光催化剂及其制备方法和应用 | |
Hu et al. | LaMnO3 nanoparticles supported on N doped porous carbon as efficient photocatalyst | |
CN105148964B (zh) | 一种三维还原氧化石墨烯‑Mn3O4/MnCO3纳米复合材料及其制备方法 | |
Guo et al. | Boron-and europium-co-doped g-C3N4 nanosheets: Enhanced photocatalytic activity and reaction mechanism for tetracycline degradation | |
CN112774712B (zh) | 一种用于降解抗生素的光催化材料及其制备方法和应用 | |
CN113663732A (zh) | 一种ZIF-67(Co)/空心微球状β-Bi2O3/g-C3N4可见光催化剂 | |
CN112007679A (zh) | 一种Co/V双金属掺杂g-C3N4光催化剂及其制备方法和应用 | |
CN104148100B (zh) | 一种新型的钒磷酸盐光催化材料及其制备方法和应用 | |
CN113578363A (zh) | 一种可见光响应的含氮缺陷g-C3N4/MoS2二元复合光催化剂、制备方法及应用 | |
CN117582977A (zh) | 一种用于降解四环素的LCQDs/Bi2MoO6球花状复合光催化剂的制备方法与应用 | |
Wang et al. | The visible-light photocatalytic activity for enhancing RhB degradation and hydrogen evolution from SrTiO3 nanoparticles decorated red phosphorus nanorods as photocatalysts | |
CN108927182B (zh) | 一种Eu掺杂Bi4O5I2复合纳米光催化剂及其制备方法 | |
CN115041212B (zh) | 一种氯化银-氮化碳复合光催化剂及其制备方法与应用 | |
CN111215069A (zh) | 一种生物介孔碳载铁氧化物及其应用 | |
CN114308015B (zh) | 一种硅负载钨酸铋复合光催化剂的制备方法及其应用 | |
CN113871631B (zh) | 一种处理偶氮染料废水的光催化燃料电池及其制备方法 | |
CN113578296A (zh) | 一种片层状灰色TiO2光催化材料及其制备方法 | |
CN109589963B (zh) | 一种铌酸锂型氧化物/凹凸棒石非线性光学复合光催化材料及其制备方法与应用 | |
Wang et al. | Ni0. 6Fe0. 4Se2/rGO Heterogenous Nanocubes Anode for Stable and Efficient Na/K‐Ion Storage | |
CN111054401A (zh) | 一种钒酸铋/碘氧化铋/钨酸铋双z型光催化材料的制备方法 | |
CN117504892B (zh) | 一种La-Fe共掺杂SrTiO3/TiO2复合材料及其制备方法和应用 | |
CN114768871B (zh) | PANI/NH2-MIL-101(Fe)复合材料及其制备方法和应用 | |
CN112547096B (zh) | 一种碳基硫化物复合光催化剂及制备方法以及其在降解重金属中的应用 | |
CN114100658B (zh) | 氮化碳/三氧化钨/硫掺杂氯氧化锑双z型复合光催化剂及其制备方法和应用 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB03 | Change of inventor or designer information | ||
CB03 | Change of inventor or designer information |
Inventor after: Zhang Yuan Inventor after: Zhang Xinfei Inventor after: Cai Yanpeng Inventor after: Yang Zhifeng Inventor after: Jia Xiaobo Inventor after: Wang Ziwei Inventor after: Zhang Nan Inventor after: Li Feilong Inventor before: Zhang Yuan Inventor before: Zhang Xinfei Inventor before: Cai Yanpeng Inventor before: Yang Zhifeng Inventor before: Jia Xiaobo Inventor before: Wang Ziwei Inventor before: Zhang Nan Inventor before: Li Feilong |
|
GR01 | Patent grant | ||
GR01 | Patent grant |