CN112646309A - 一种阻燃abs塑料及制备方法及其在焊机外壳、电焊辅助塑料工具中的应用 - Google Patents
一种阻燃abs塑料及制备方法及其在焊机外壳、电焊辅助塑料工具中的应用 Download PDFInfo
- Publication number
- CN112646309A CN112646309A CN202011514184.5A CN202011514184A CN112646309A CN 112646309 A CN112646309 A CN 112646309A CN 202011514184 A CN202011514184 A CN 202011514184A CN 112646309 A CN112646309 A CN 112646309A
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- Prior art keywords
- parts
- flame
- hollow glass
- resin
- retardant
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 124
- 239000003063 flame retardant Substances 0.000 title claims abstract description 124
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title claims abstract description 119
- 238000003466 welding Methods 0.000 title claims abstract description 48
- 229920003023 plastic Polymers 0.000 title claims abstract description 25
- 239000004033 plastic Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000011521 glass Substances 0.000 claims abstract description 80
- 239000011324 bead Substances 0.000 claims abstract description 76
- 229920005989 resin Polymers 0.000 claims abstract description 66
- 239000011347 resin Substances 0.000 claims abstract description 66
- 239000000463 material Substances 0.000 claims abstract description 43
- 239000003822 epoxy resin Substances 0.000 claims abstract description 39
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 39
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000002994 raw material Substances 0.000 claims abstract description 28
- OXDXXMDEEFOVHR-CLFAGFIQSA-N (z)-n-[2-[[(z)-octadec-9-enoyl]amino]ethyl]octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCCNC(=O)CCCCCCC\C=C/CCCCCCCC OXDXXMDEEFOVHR-CLFAGFIQSA-N 0.000 claims abstract description 11
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 24
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 22
- 238000002156 mixing Methods 0.000 claims description 17
- SWSBIGKFUOXRNJ-CVBJKYQLSA-N ethene;(z)-octadec-9-enamide Chemical compound C=C.CCCCCCCC\C=C/CCCCCCCC(N)=O.CCCCCCCC\C=C/CCCCCCCC(N)=O SWSBIGKFUOXRNJ-CVBJKYQLSA-N 0.000 claims description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 9
- -1 pentabromobiphenyl ether Chemical compound 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims description 2
- 230000008901 benefit Effects 0.000 abstract description 8
- 229920000915 polyvinyl chloride Polymers 0.000 description 47
- 239000004800 polyvinyl chloride Substances 0.000 description 47
- 230000000052 comparative effect Effects 0.000 description 29
- 239000011159 matrix material Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 12
- 238000001514 detection method Methods 0.000 description 8
- 239000011257 shell material Substances 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000000956 alloy Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- 239000004005 microsphere Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000002195 synergetic effect Effects 0.000 description 4
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- ACRQLFSHISNWRY-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-phenoxybenzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=CC=CC=C1 ACRQLFSHISNWRY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 229910000679 solder Inorganic materials 0.000 description 2
- MXJJJAKXVVAHKI-WRBBJXAJSA-N (9z,29z)-octatriaconta-9,29-dienediamide Chemical compound NC(=O)CCCCCCC\C=C/CCCCCCCCCCCCCCCCCC\C=C/CCCCCCCC(N)=O MXJJJAKXVVAHKI-WRBBJXAJSA-N 0.000 description 1
- 241000233805 Phoenix Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN202011514184.5A CN112646309B (zh) | 2020-12-21 | 2020-12-21 | 一种阻燃abs塑料及制备方法及其在焊机外壳、电焊辅助塑料工具中的应用 |
Applications Claiming Priority (1)
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CN202011514184.5A CN112646309B (zh) | 2020-12-21 | 2020-12-21 | 一种阻燃abs塑料及制备方法及其在焊机外壳、电焊辅助塑料工具中的应用 |
Publications (2)
Publication Number | Publication Date |
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CN112646309A true CN112646309A (zh) | 2021-04-13 |
CN112646309B CN112646309B (zh) | 2021-09-14 |
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CN202011514184.5A Active CN112646309B (zh) | 2020-12-21 | 2020-12-21 | 一种阻燃abs塑料及制备方法及其在焊机外壳、电焊辅助塑料工具中的应用 |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1090670A (en) * | 1965-08-10 | 1967-11-15 | Geigy Uk Ltd | Chemical compositions |
JPS61233035A (ja) * | 1985-04-08 | 1986-10-17 | Kanegafuchi Chem Ind Co Ltd | 難燃樹脂組成物 |
CN109096725A (zh) * | 2018-07-17 | 2018-12-28 | 江苏兆维塑料科技有限公司 | 一种轻量化pc/abs减重复合材料及其制备方法 |
CN110894335A (zh) * | 2018-09-12 | 2020-03-20 | 珠海格力电器股份有限公司 | 高抗冲阻燃abs-pvc复合材料及其制备方法 |
CN111218086A (zh) * | 2020-03-02 | 2020-06-02 | 台州市安安焊接设备有限公司 | 电焊机塑件用高耐热阻燃abs材料及其注塑工艺 |
-
2020
- 2020-12-21 CN CN202011514184.5A patent/CN112646309B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1090670A (en) * | 1965-08-10 | 1967-11-15 | Geigy Uk Ltd | Chemical compositions |
JPS61233035A (ja) * | 1985-04-08 | 1986-10-17 | Kanegafuchi Chem Ind Co Ltd | 難燃樹脂組成物 |
CN109096725A (zh) * | 2018-07-17 | 2018-12-28 | 江苏兆维塑料科技有限公司 | 一种轻量化pc/abs减重复合材料及其制备方法 |
CN110894335A (zh) * | 2018-09-12 | 2020-03-20 | 珠海格力电器股份有限公司 | 高抗冲阻燃abs-pvc复合材料及其制备方法 |
CN111218086A (zh) * | 2020-03-02 | 2020-06-02 | 台州市安安焊接设备有限公司 | 电焊机塑件用高耐热阻燃abs材料及其注塑工艺 |
Non-Patent Citations (4)
Title |
---|
欧育湘: "《阻燃剂》", 30 September 2009 * |
裴涛: "环氧树脂对PVC/ABS合金性能的影响", 《塑料工业》 * |
裴涛: "玻璃微珠对PVC/ABS合金材料性能的影响", 《塑料科技》 * |
郑晓晨: "耐老化阻燃ABS/PVC合金的研究", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 * |
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CN112646309B (zh) | 2021-09-14 |
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Denomination of invention: A flame retardant ABS plastic and its preparation method and its application in welding machine shell and welding auxiliary plastic tools Effective date of registration: 20220721 Granted publication date: 20210914 Pledgee: Bank of Taizhou Co.,Ltd. Luqiao New Street sub branch Pledgor: TAIZHOU ANN WELDING EQUIPMENT CO.,LTD. Registration number: Y2022330001488 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20231120 Granted publication date: 20210914 Pledgee: Bank of Taizhou Co.,Ltd. Luqiao New Street sub branch Pledgor: TAIZHOU ANN WELDING EQUIPMENT CO.,LTD. Registration number: Y2022330001488 |