CN112313320B - 合成洗涤剂棒组合物 - Google Patents
合成洗涤剂棒组合物 Download PDFInfo
- Publication number
- CN112313320B CN112313320B CN201980033172.XA CN201980033172A CN112313320B CN 112313320 B CN112313320 B CN 112313320B CN 201980033172 A CN201980033172 A CN 201980033172A CN 112313320 B CN112313320 B CN 112313320B
- Authority
- CN
- China
- Prior art keywords
- composition
- weight
- alkyl
- synthetic detergent
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 106
- 239000000271 synthetic detergent Substances 0.000 title claims abstract description 59
- 239000004094 surface-active agent Substances 0.000 claims abstract description 33
- -1 alkyl sulfosuccinates Chemical class 0.000 claims abstract description 24
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims abstract description 20
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 16
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000004909 Moisturizer Substances 0.000 claims abstract description 15
- 230000001333 moisturizer Effects 0.000 claims abstract description 15
- 239000003906 humectant Substances 0.000 claims abstract description 14
- 150000004671 saturated fatty acids Chemical class 0.000 claims abstract description 13
- 239000000945 filler Substances 0.000 claims abstract description 10
- 150000008051 alkyl sulfates Chemical class 0.000 claims abstract description 9
- 150000004702 methyl esters Chemical class 0.000 claims abstract description 9
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 8
- 229960000541 cetyl alcohol Drugs 0.000 claims abstract description 8
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 6
- 229940012831 stearyl alcohol Drugs 0.000 claims abstract description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 19
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 238000005336 cracking Methods 0.000 claims description 11
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 10
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 claims description 10
- 239000000194 fatty acid Substances 0.000 claims description 10
- 229930195729 fatty acid Natural products 0.000 claims description 10
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 9
- 229920002472 Starch Polymers 0.000 claims description 8
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 8
- 235000011187 glycerol Nutrition 0.000 claims description 8
- 229940079886 disodium lauryl sulfosuccinate Drugs 0.000 claims description 7
- KHIQYZGEUSTKSB-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-3-sulfobutanoate Chemical group [Na+].[Na+].CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O.CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O KHIQYZGEUSTKSB-UHFFFAOYSA-L 0.000 claims description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 7
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 235000021314 Palmitic acid Nutrition 0.000 claims description 5
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 229940100445 wheat starch Drugs 0.000 claims description 5
- 229920002261 Corn starch Polymers 0.000 claims description 4
- 239000005639 Lauric acid Substances 0.000 claims description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical group [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 4
- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- 239000008120 corn starch Substances 0.000 claims description 4
- 239000008172 hydrogenated vegetable oil Substances 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 4
- 239000008117 stearic acid Substances 0.000 claims description 4
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 claims description 3
- 235000007319 Avena orientalis Nutrition 0.000 claims description 3
- 244000075850 Avena orientalis Species 0.000 claims description 3
- 240000005979 Hordeum vulgare Species 0.000 claims description 3
- 235000007340 Hordeum vulgare Nutrition 0.000 claims description 3
- 240000003183 Manihot esculenta Species 0.000 claims description 3
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 229940099112 cornstarch Drugs 0.000 claims description 3
- ONQDVAFWWYYXHM-UHFFFAOYSA-M potassium lauryl sulfate Chemical compound [K+].CCCCCCCCCCCCOS([O-])(=O)=O ONQDVAFWWYYXHM-UHFFFAOYSA-M 0.000 claims description 3
- 229940116985 potassium lauryl sulfate Drugs 0.000 claims description 3
- 229940100486 rice starch Drugs 0.000 claims description 3
- 239000001540 sodium lactate Substances 0.000 claims description 3
- 229940005581 sodium lactate Drugs 0.000 claims description 3
- 235000011088 sodium lactate Nutrition 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 239000000454 talc Substances 0.000 claims description 3
- 229910052623 talc Inorganic materials 0.000 claims description 3
- 235000012222 talc Nutrition 0.000 claims description 3
- 229940082500 cetostearyl alcohol Drugs 0.000 claims 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 10
- 229940081733 cetearyl alcohol Drugs 0.000 abstract description 5
- 238000004851 dishwashing Methods 0.000 abstract description 4
- 235000019387 fatty acid methyl ester Nutrition 0.000 abstract description 3
- 238000010412 laundry washing Methods 0.000 abstract description 2
- 239000004165 Methyl ester of fatty acids Substances 0.000 abstract 1
- 239000000344 soap Substances 0.000 description 37
- 210000003491 skin Anatomy 0.000 description 24
- 239000003599 detergent Substances 0.000 description 21
- 239000004615 ingredient Substances 0.000 description 16
- 238000012360 testing method Methods 0.000 description 14
- 230000000694 effects Effects 0.000 description 13
- 229940079776 sodium cocoyl isethionate Drugs 0.000 description 10
- 238000009472 formulation Methods 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- 230000007794 irritation Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000001134 F-test Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 241001465754 Metazoa Species 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 235000003441 saturated fatty acids Nutrition 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 235000019482 Palm oil Nutrition 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000004067 bulking agent Substances 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 230000003020 moisturizing effect Effects 0.000 description 3
- 239000002540 palm oil Substances 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000003974 emollient agent Substances 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 230000000887 hydrating effect Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 229940048106 sodium lauroyl isethionate Drugs 0.000 description 2
- BRMSVEGRHOZCAM-UHFFFAOYSA-M sodium;2-dodecanoyloxyethanesulfonate Chemical compound [Na+].CCCCCCCCCCCC(=O)OCCS([O-])(=O)=O BRMSVEGRHOZCAM-UHFFFAOYSA-M 0.000 description 2
- 238000005482 strain hardening Methods 0.000 description 2
- 210000000434 stratum corneum Anatomy 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- GJJVAFUKOBZPCB-ZGRPYONQSA-N (r)-3,4-dihydro-2-methyl-2-(4,8,12-trimethyl-3,7,11-tridecatrienyl)-2h-1-benzopyran-6-ol Chemical class OC1=CC=C2OC(CC/C=C(C)/CC/C=C(C)/CCC=C(C)C)(C)CCC2=C1 GJJVAFUKOBZPCB-ZGRPYONQSA-N 0.000 description 1
- WMCMCZTWKQMHBE-UHFFFAOYSA-N 1-decoxydecane;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCOCCCCCCCCCC WMCMCZTWKQMHBE-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- PHIIYDSPMYGDAF-UHFFFAOYSA-N S(=O)(=O)(O)O.C(CCCCCCCCCCC)[K] Chemical compound S(=O)(=O)(O)O.C(CCCCCCCCCCC)[K] PHIIYDSPMYGDAF-UHFFFAOYSA-N 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 238000000540 analysis of variance Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229940093797 bioflavonoids Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000008406 cosmetic ingredient Substances 0.000 description 1
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 1
- 235000018417 cysteine Nutrition 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000004299 exfoliation Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000012041 food component Nutrition 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000000135 prohibitive effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000000528 statistical test Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 125000002640 tocopherol group Chemical class 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- 229930003802 tocotrienol Natural products 0.000 description 1
- 239000011731 tocotrienol Substances 0.000 description 1
- 229940068778 tocotrienols Drugs 0.000 description 1
- 235000019148 tocotrienols Nutrition 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/006—Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/002—Surface-active compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
- C11D3/2013—Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
本发明涉及一种合成洗涤剂棒组合物，该合成洗涤剂棒组合物包含具有16个至18个碳原子(C16‑C18)的链长度的脂肪酸的磺化甲酯，其中磺化甲酯以组合物的按重量计5％至30％的量存在；助表面活性剂，所述助表面活性剂选自由烷基磺基琥珀酸盐、烷基硫酸盐、烷基醚硫酸盐、烷基聚葡萄糖苷或其组合组成的组；脂肪醇，所述脂肪醇选自由鲸蜡醇、硬脂醇或鲸蜡硬脂醇组成的组；饱和脂肪酸；填充剂；和湿润剂/保湿剂。合成洗涤剂棒组合物可用作个人清洁、洗衣或洗碗棒。
Description
发明领域
本发明涉及合成洗涤剂棒(syndet bar)(合成的洗涤剂棒(synthetic detergentbar))组合物。更具体地，本发明涉及一种含有天然来源的磺化甲酯的合成洗涤剂棒组合物，其可以用作个人清洁或洗衣棒。
发明背景
回到公元前2500年自从在美索不达米亚文明时期皂的存在或发明以来，皂在个人卫生中发挥重要作用。除了个人卫生之外，皂现在也用于许多家庭和工业清洁过程。在目前的技术中，皂棒通过甘油三酯的连续皂化或脂肪酸与碱的中和被工业化生产。
在最近几十年中，皂的作用随着时间的推移而演变，其中皂不仅用于清洁的目的，而且还用作皮肤护理。预期皂产生丰富和乳脂状的泡沫，因此提供了优异的清洁效果。同时，消费者还预期皂能提供保湿或补水效果，以便防止皮肤在清洁后变干，以及保护皮肤免受对皮肤有害的外部影响。因此，皂棒的制造商持续寻找满足消费者这些增加的需求和期望的新的成分。
市场上可获得的具有高pH的碱性皂，其仅含有脂肪酸盐和任选的游离脂肪酸，不能提供预期的皮肤护理和清洁性质。由于碱性皂在化学上是苛刻的(高pH)，它们可能对消费者的皮肤造成刺激和开裂影响。因此，另一种类型的皂棒，即复合棒(combination bar)或复合皂(combo soap)在工业上被引入，以使清洁效果最大化，同时使刺激最小化。除了脂肪酸盐，复合皂还使用合成表面活性剂的组合，例如椰油酰羟乙基磺酸钠(sodium cocoylisethionate)或磺基琥珀酸盐，以促进用于皮肤的温和性。复合皂包含脂肪酸盐，它们比传统的皂刺激较小，但不如合成洗涤剂棒温和。
合成洗涤剂棒或合成的洗涤剂棒是一种新类型的无皂清洁棒，它由不同的表面活性剂(surfactant)或具有去污性质的表面活性剂(tensioactive agent)的组合制成。除了杂质之外，合成洗涤剂棒也不含脂肪酸盐，并且仅含有合成的表面活性剂。合成的表面活性剂通常来源于天然来源的矿物油、植物油或动物脂肪，因此所生产的合成洗涤剂棒已知是温和的，并且作为个人清洁棒或皮肤用品棒(dermatological bar)是有益的。此外，合成洗涤剂棒通常具有中性pH，这可以防止皮肤刺激。
工业上可获得的合成洗涤剂棒通常由椰油酰羟乙基磺酸钠制成。由于椰油酰羟乙基磺酸钠在合成洗涤剂棒的生产中的广泛使用，这种成分的价格在工业上也变得过高。在本领域中存在许多与由椰油酰羟乙基磺酸钠制成的合成洗涤剂棒组合物相关的技术。例如，美国专利第US 5691287号公开了一种低刺激的清洁棒组合物，该组合物包含以清洁棒的按重量计20％至35％的量的椰油酰羟乙基磺酸钠。该组合物还包含含有相对较低量的脂肪酸的脂肪醇。除了低刺激效果之外，在该文献中没有关于清洁棒组合物在其去污力或软化效果方面的性能的公开内容。由于椰油酰羟乙基磺酸钠被用作主要成分，因此该清洁棒的制造成本是相对高的。此外，椰油酰羟乙基磺酸钠也被认为是一种温和的表面活性剂，并且可能不产生期望的去污力。
SME，其还被称为α-磺基脂肪酸甲酯或甲酯磺酸盐(MES)，近年来已经被越来越多地用作表面活性剂。SME代表一类阴离子型表面活性剂，其适合应用在多种工业应用，包括衣物洗涤剂(laundry detergent)和餐具洗涤剂(dish washing detergent)中。已知由于来源于天然的可再生资源诸如棕榈油，SME是可生物降解的，并且被认为是绿色可选择的表面活性剂。由于这样的可再生性质，SME已经逐渐成为更有吸引力的选项，以作为表面活性剂被包含在某些合成的洗涤剂制剂(formulation)中。因此，有限数量的皂棒制造技术已经开始使用SME代替椰油酰羟乙基磺酸钠作为棒组合物的主要成分。
作为实例，美国专利公布第2007004611号公开了一种适合于在个人清洁或洗涤剂皂棒中使用的组合物，该个人清洁或洗涤剂皂棒也被称为“皂条(soap noodle)”，其含有SME作为主要表面活性剂。该组合物还包含次级表面活性剂，诸如磺基琥珀酸盐和烷基硫酸盐。然而，所公开的组合物包含皂，优选地动物脂皂和/或椰子皂作为主要成分。在该文献中还陈述了该组合物是前体清洁或洗衣棒，在消费者使用期间具有改善的硬度、改善的抗擦伤性、降低的磨损率和减少的糊状物形成。该文献没有公开任何改善的保湿或软化效果。这种含动物脂皂和/或椰子皂的皂棒组合物被认为是复合棒组合物。在该文献中还陈述了合成洗涤剂棒通常具有差的物理性质，并且大部分由难以制造的温和表面活性剂制成。
在现有技术中没有提供关于任何特定的含有长碳链SME作为基本成分的合成洗涤剂棒组合物的教导，该组合物可以产生具有改善的软化效果以及相当的清洁性能的合成洗涤剂棒。因此，一种改善的基于SME的合成洗涤剂棒组合物是期望的。
发明概述
本发明的目的之一是提供一种合成洗涤剂棒组合物，该合成洗涤剂棒组合物包含SME作为基本成分，提供具有改善的软化效果的天然且温和的清洁产品，该产品可用作用于个人清洁、洗衣或洗碗的清洁和皮肤护理产品。
本发明旨在提供一种基于SME的合成洗涤剂棒组合物，该组合物与基于椰油酰羟乙基磺酸钠的合成洗涤剂棒相比提供了改善的软化效果以及相当的清洁性能。基于SME的合成洗涤剂棒组合物还应该在生产成本上是较低的并且对消费者是成本有效的。
前述目的中的至少一个通过本发明来全部或部分满足，其中本发明的实施方案之一描述了一种合成洗涤剂棒或合成的洗涤剂棒组合物，其包含：具有16个至18个碳原子(C16-C18)的链长度的脂肪酸的SME，其中SME以组合物的按重量计5％至30％的量存在；助表面活性剂，所述助表面活性剂选自由烷基磺基琥珀酸盐、烷基硫酸盐、烷基醚硫酸盐或其组合组成的组；脂肪醇，所述脂肪醇选自由鲸蜡醇、硬脂醇或鲸蜡硬脂醇组成的组；饱和脂肪酸；填充剂；和湿润剂/保湿剂(humectant/moisturiser)。
在本说明书中，以下术语具有被指定它们作为阴离子型表面活性剂的以下含义：
“烷基磺基琥珀酸盐”是磺基琥珀酸盐型阴离子型表面活性剂，其包括具有式M+(O3SCH(CO2R1)CH2CO2R2)-的磺基琥珀酸酯，其中M+是阳离子，包括碱金属阳离子诸如钠Na+，并且其中R1是氢H且R2是烷基，或者其中R1和R2均是烷基。
“烷基硫酸盐”是具有官能团结构R-O-SO3 -的有机硫酸盐，其中R是有机残基，包括烷基。
“烷基醚硫酸盐”(AES)是具有通式RO(CH2CH2O)nSO3M的烷基硫酸盐的特定基团，其中R代表具有8个-18个碳原子的烷基基团，n代表平均加成摩尔数，诸如约2-10，并且M代表产生水溶性盐的阳离子，其包括在国际化妆品成分命名(International Nomenclature ofCosmetic Ingredient，INCI)名称下已知的化合物，诸如月桂醇聚醚硫酸钠(sodiumlaureth sulfate)(SLES)、月桂基醚硫酸钠(SLES)、癸基醚硫酸铵等的公认缩写。
根据本发明的优选的实施方案，SME是包含化合物的按重量计55％至99％的C16SME和45％至1％的C18 SME的化合物。
根据本发明的另一种实施方案，助表面活性剂以组合物的按重量计1％至40％的量存在。在某些实施方案中，助表面活性剂可以是烷基磺基琥珀酸盐，诸如月桂基磺基琥珀酸二钠；或烷基硫酸盐，诸如月桂基硫酸钠(SLS)、月桂基硫酸钾或其组合；或烷基醚硫酸盐，诸如月桂基醚硫酸钠(SLES)。
本发明的另一种实施方案公开了脂肪醇以组合物的按重量计1％至30％的量存在。
本发明的还另一种实施方案公开了饱和脂肪酸以组合物的按重量计1％至30％的量存在。优选地，饱和脂肪酸可以是硬脂酸、棕榈酸、月桂酸或其任何两种或更多种的组合。
在本发明的另一种实施方案中公开了填充剂以组合物的按重量计1％至40％的量存在。在某些实施方案中，填充剂是小麦淀粉、玉米淀粉、大米淀粉、大麦淀粉、燕麦、木薯、滑石、硫酸钠或其任何两种或更多种的组合。
根据本发明的实施方案，湿润剂/保湿剂以组合物的按重量计1％至10％的量存在。优选地，湿润剂/保湿剂是甘油、水、脲、乳酸钠或其任何两种或更多种的组合。为了方便，在此处将水归为一类，尽管它更多的是一种溶剂并且被添加到制剂中以达到100％。
本发明的另外的实施方案公开了，合成洗涤剂棒组合物还包含以组合物的按重量计1％至15％的量的抗裂剂(anti-cracking agent)。例如，抗裂剂可以是氢化植物油、聚乙二醇或其组合。
本发明的目前的优选实施方案包括新颖的特征和部分的组合，其在下文中在附图中充分地描述或图示出并且在所附的权利要求中特别地指出；应理解，本领域技术人员可以实现细节的多种改变，但不偏离本发明的范围或不牺牲本发明的任何优点。
发明详述
在下文中，将根据本发明的优选的实施方案并且通过参考所附的描述和附图来描述本发明。然而，应理解，将描述限制于本发明的优选的实施方案和附图仅仅是为了便于本发明的讨论，并且设想，本领域技术人员可以在不偏离所附权利要求的范围的情况下设计多种修改。
本发明公开了一种合成洗涤剂棒组合物，该合成洗涤剂棒组合物包含具有16个至18个碳原子(C16-C18)的链长度的脂肪酸的SME，其中SME以组合物的按重量计5％至30％的量存在；助表面活性剂，所述助表面活性剂选自由烷基磺基琥珀酸盐、烷基硫酸盐、烷基醚硫酸盐或其组合组成的组；脂肪醇，所述脂肪醇选自由鲸蜡醇、硬脂醇或鲸蜡硬脂醇组成的组；饱和脂肪酸；填充剂；和湿润剂/保湿剂。
SME在合成洗涤剂棒组合物中用作表面活性剂，其提供去污力以及对皮肤的有益效果，例如天然效果、温和效果和软化效果。术语“表面活性剂”或“表面活性剂体系”指的是能够降低液体和气体之间或者两种液体之间或者液体和固体之间的表面张力或界面张力的一种或更多种化合物。因此，表面活性剂可用作润湿剂、乳化剂或洗涤剂。
根据本发明的实施方案，在合成洗涤剂棒组合物中使用的SME是脂肪酸的长碳链SME，具有16个至18个碳原子的链长度(即C16-C18 SME)。C16 SME和C18 SME分别具有如在以下式(I)和式(II)中示出的分子结构：
C16 SME和C18 SME两者均可以来源于天然来源，诸如植物油(plant oil)(植物油(vegetable oil))或动物脂肪，包括棕榈油。具体地，C16 SME可以从棕榈酸获得；而C18SME可以从棕榈油的硬脂酸获得。这两种SME均经由甲酯的磺化获得。
如在前述描述中阐述的，SME以组合物的按重量计约5％至30％的量存在于合成洗涤剂棒组合物中。例如，它可以以组合物的按重量计5％至25％、或10％至25％、或15％至20％的量存在。
在某些实施方案中，在合成洗涤剂棒组合物中使用的SME是含有以特定组合比率的C16 SME和C18 SME的化合物(共混物或混合物)。优选地，本发明的SME化合物可以包含化合物的按重量计约55％至99％的C16 SME和约1％至45％的C18 SME。例如，SME化合物可以是60％至90％的C16 SME和10％至40％的C18 SME的共混物，或者65％至85％的C16 SME和15％至35％的C18 SME的共混物。可选择地，SME化合物还可以是90％至99％的C16 SME和1％至10％的C18 SME的共混物。
除了具有SME作为主要表面活性剂之外，本发明的合成洗涤剂棒组合物还包含助表面活性剂，该助表面活性剂可以以组合物的按重量计约1％至40％的量存在。在某些实施方案中，助表面活性剂可以是烷基磺基琥珀酸盐，诸如月桂基磺基琥珀酸二钠；或烷基硫酸盐，诸如SLS、月桂基硫酸钾或其组合；或烷基醚硫酸盐，诸如SLES；或烷基聚葡萄糖苷。不希望受理论的束缚，在助表面活性剂的存在下，预期SME在合成洗涤剂棒的去污力方面产生协同作用。应理解，SLES，如果添加的话，应该以少量(例如，组合物的按重量计2％至3％)使用，以便防止所生产的合成洗涤剂棒的任何不期望的性质，例如，以防止棒在使用时变油和变粘。
助表面活性剂被添加至组合物中以提供良好的去污力和发泡性质。在某些实施方案中，主要表面活性剂和助表面活性剂的组合也能够减少皮肤刺激。例如，将绿色表面活性剂诸如烷基聚葡萄糖苷(APG)添加至直链烷基苯磺酸盐(LAS)中可以减少LAS的刺激。可选择地，APG和SLES之间以特定比率的组合也可以减少SLES的刺激。
根据本发明的另一种实施方案，合成洗涤剂棒组合物还包含脂肪醇，脂肪醇以组合物的按重量计约1％至30％的量存在。例如，脂肪醇可以以组合物的按重量计5％至20％的量存在。如在前述描述中阐述的，本发明中使用的脂肪醇可以是鲸蜡醇、硬脂醇或鲸蜡硬脂醇(即鲸蜡醇和硬脂醇的混合物)。脂肪醇在合成洗涤剂棒组合物中发挥结构剂和润肤剂的作用。由于脂肪醇还起抗裂剂的作用，脂肪醇(例如鲸蜡硬脂醇)和SME之间的组合能够为合成洗涤剂棒提供改善的软化以及抗开裂效果。
除了脂肪醇之外，本发明的合成洗涤剂棒组合物还包含饱和脂肪酸，饱和脂肪酸也起结构剂和润肤剂的作用，这增强脂肪醇的作用。在某些实施方案中，包含长链脂肪酸也可以帮助硬化合成洗涤剂棒。优选地，饱和脂肪酸以组合物的按重量计约1％至30％的量存在。根据本发明的一种实施方案，饱和脂肪酸可以是硬脂酸、棕榈酸、月桂酸或其任何两种或更多种的组合。可以在合成洗涤剂棒组合物中使用的优选的饱和脂肪酸中的一种是三压硬脂酸(triple pressed stearic acid)。在某些实施方案中，三压硬脂酸可以以组合物的按重量计5％至20％的量存在。
根据本发明的另一种实施方案，合成洗涤剂棒组合物还包含填充剂。填充剂可以以组合物的按重量计约1％至40％的量存在。具体地，填充剂可以以组合物的按重量计10％至30％的量存在。在某些实施方案中，填充剂是小麦淀粉、玉米淀粉、大米淀粉、大麦淀粉、燕麦、木薯、滑石、硫酸钠或其任何两种或更多种的组合。
根据本发明的另一种实施方案，湿润剂/保湿剂以组合物的按重量计约1％至10％的量存在。例如，湿润剂/保湿剂可以以组合物的按重量计约1％至10％的量存在。优选地，湿润剂/保湿剂是甘油、水、脲、乳酸钠或其任何两种或更多种的组合。湿润剂/保湿剂诸如甘油和水也可以用作粘合剂，其将合成洗涤剂棒组合物的组成成分粘结性地结合以形成皂棒。
本发明的另外的实施方案公开了，合成洗涤剂棒组合物还包含以组合物的按重量计1％至15％的量的抗裂剂。例如，抗裂剂可以是氢化植物油、聚乙二醇或其组合。优选地，抗裂剂可以是氢化蓖麻油。合成洗涤剂棒有时可能难以成型。为了增加用于不同应用的合成洗涤棒的硬度，可以增加氢化植物油的重量百分比。
成分的组合不需要调整二盐含量，但由于特定的配方和成分的特定掺混，它能够提供硬皂棒。本发明的合成洗涤剂棒是大体上无皂的、温和的并且产生乳脂状泡沫。因此，它适合被消费者用作个人清洁棒。由于它的低pH和对皮肤温和，它还可以用作动物(例如宠物)的清洁剂。在某些实施方案中，另外的成分，诸如抗菌剂和半胱氨酸可以被添加至动物清洁产品中。它还可以在工业上或在家庭中用于洗衣、洗碗或硬表面清洁。
在本发明的某些实施方案中，合成洗涤剂棒组合物还可以包含防腐剂、稳定剂、调味剂、着色剂或其任何两种或更多种的组合。作为还提供皮肤护理效果的个人清洁棒，合成洗涤剂棒组合物还可以包含添加剂，诸如皮肤调理剂、皮肤保湿剂(skin moisturizingagent)、皮肤保湿剂(skin hydrating agent)、控油剂、舒缓剂或增白剂。
根据本发明的另一种实施方案，合成洗涤剂棒组合物还可以包含营养组分，诸如维生素和矿物质、天然来源的精油、生物类黄酮和抗氧化剂，所述营养组分保护皮肤免于由于去污力作用而变干，通过给皮肤留下保护层来防止皮肤免受外部损伤，或者改善皮肤的整体卫生和健康。例如，维生素和矿物质可以是维生素E(生育三烯酚、生育酚或其组合)、维生素A、二氧化硅、镁、钙、钾、锌、铜、硒、铬以及硫。在某些实施方案中，二氧化钛可以被添加以增加合成洗涤剂棒的白度，并且为棒提供均匀的颜色外观。
合成洗涤剂棒组合物可以被制备成固体皂棒的形式或者任何其他合适的固体形式，诸如皂粒(soap pellet)或皂片(soap flake)。这种基于SME的合成洗涤剂棒的示例性制剂在实施例中进一步详述。合成洗涤剂棒可以经由粉末和液体成分的简单的混合工艺由多种成分产生。该工艺包括在冷加工中混合液体成分的步骤。液体成分包括湿润剂/保湿剂(例如甘油和水)和聚乙二醇。随后在高温熔化固体成分，包括SME、助表面活性剂、脂肪醇、饱和脂肪酸和填充剂。熔化的成分的热液体和来自冷加工的冷液体可以在螺杆混合单元中在高温(hot temperature)混合以形成糊状物，该糊状物在冷滚筒上经历剥落过程。获得的片可以被包装以形成皂棒。
基于SME的合成洗涤剂棒的性能可以与商业上获得的合成洗涤剂棒或复合棒相比进行测试。在实施例2中进一步详述了对皂棒性能的比较测试的实例，即F-检验和T-检验。如表4和表5中的比较数据所示，基于SME的合成洗涤剂棒被示出提供与商业上获得的合成洗涤剂棒或商业上获得的基于月桂酰羟乙基磺酸钠的复合皂的清洁相当的清洁，同时与这些商业上获得的皂棒相比产生改善的软化效果。通过实验数据可以示出，本发明的合成洗涤剂棒是温和的并且具有低刺激。在使用合成洗涤剂棒后且在洗涤后，皮肤不会感觉干燥，并且角质层(皮肤的最上层)是完好的。不希望受理论的束缚，据信合成洗涤剂棒中活性成分的组合可以帮助角质层保留水分，因此示出皮肤软化的效果。
实施例
实施例1合成洗涤剂棒制剂
基于SME的合成洗涤剂棒可以基于如表1-表3中所示的配方制备。
表1
| 成分 | 重量百分比范围(％wt) |
| C16-C18 SME | 10-30 |
| 月桂基磺基琥珀酸二钠 | 5-20 |
| 月桂基硫酸钾 | 5-20 |
| 鲸蜡醇 | 5-15 |
| 三压硬脂酸 | 5-15 |
| 氢化蓖麻油 | 1-10 |
| 小麦淀粉 | 10-30 |
| 甘油 | 1-10 |
| 水 | 至100％ |
表2
| 成分 | 重量百分比范围(％wt) |
| C16-C18 SME | 10-30 |
| 月桂基磺基琥珀酸二钠 | 5-20 |
| 月桂基硫酸钾 | 5-20 |
| 硬脂醇 | 5-15 |
| 棕榈酸 | 5-15 |
| 聚乙二醇 | 1-10 |
| 玉米淀粉 | 10-30 |
| 甘油 | 1-10 |
| 水 | 至100％ |
表3
| 成分 | 重量百分比范围(％wt) |
| C16-C18 SME | 10-30 |
| 月桂基磺基琥珀酸二钠 | 5-20 |
| 月桂基硫酸钾 | 5-20 |
| 鲸蜡醇 | 5-15 |
| 月桂酸 | 5-15 |
| 氢化蓖麻油 | 1-10 |
| 小麦淀粉 | 10-30 |
| 甘油 | 1-10 |
| 二氧化钛 | 0.1-0.5 |
| 水 | 至100％ |
实施例2用于合成洗涤剂棒制剂的F-检验和T-检验
进行了包括F-检验和T-检验的统计测试，以评估基于SME的合成洗涤剂棒组合物的性能。将基于表1的配方制备的SME合成洗涤剂棒用作测试样品，与商业上获得的合成洗涤剂棒(其包含月桂基磺基琥珀酸二钠作为主要成分)和复合皂(其包含月桂酰羟乙基磺酸钠作为主要成分)相比。商业上获得的合成洗涤剂棒和复合棒两者均不包含SME。这些测试样品基于皂性能参数进行评估，所述皂性能参数包括漂洗性、光滑性、软化性、润滑性和起泡性。特别地，要求所有受试者(即参与小组测试的参与者)填写一份包含所有这些性能参数的问卷，并且要求他们以定量方式评估不同的样品。基于SME的合成洗涤剂棒和商业合成洗涤剂棒之间的F-检验和T-检验两者的比较数据在表4中展示；而基于SME的合成洗涤剂棒和商业复合棒之间的F-检验和T-检验两者的比较数据在表5中展示。
表4
表5
F-检验聚焦于样品数据的方差分析，而T-检验指的是测试样品平均值的假设，以评估样品集是否显著不同。基于表4和表5中所示的测试结果，基于SME的合成洗涤剂棒展示出与商业上获得的复合皂表现一样好，同时与商业上获得的合成洗涤剂棒相比提供了改善的软化效果。软化效果的这样的改善通过T-检验结果显示出是显著的。
Claims (14)
1.一种合成洗涤剂棒组合物，包含：
具有16个至18个碳原子(C16-C18)的链长度的脂肪酸的磺化甲酯，其中所述磺化甲酯以所述组合物的按重量计5%至30%的量存在，其中所述磺化甲酯是包含化合物的按重量计60%至90%的C16磺化甲酯和10%至40%的C18磺化甲酯的化合物；
助表面活性剂，所述助表面活性剂选自由烷基磺基琥珀酸盐、烷基硫酸盐、烷基醚硫酸盐或其组合组成的组；
脂肪醇，所述脂肪醇是以所述组合物的按重量计5%至20%的量，选自由鲸蜡醇、硬脂醇或鲸蜡硬脂醇组成的组；
饱和脂肪酸；
填充剂；和
湿润剂/保湿剂，
其中所述合成洗涤剂棒组合物是无皂的。
2.根据权利要求1所述的组合物，其中所述助表面活性剂以所述组合物的按重量计1%至40%的量存在。
3.根据权利要求1或2所述的组合物，其中所述烷基磺基琥珀酸盐是月桂基磺基琥珀酸二钠。
4.根据权利要求1或2所述的组合物，其中所述烷基硫酸盐是月桂基硫酸钠、月桂基硫酸钾或其组合。
5.根据权利要求1或2所述的组合物，其中所述烷基醚硫酸盐是月桂基醚硫酸钠。
6.根据权利要求1或2所述的组合物，其中所述饱和脂肪酸以所述组合物的按重量计1%至30%的量存在。
7.根据权利要求1或2所述的组合物，其中所述饱和脂肪酸是硬脂酸、棕榈酸、月桂酸或其任何两种或更多种的组合。
8.根据权利要求1或2所述的组合物，其中所述填充剂以所述组合物的按重量计1%至40%的量存在。
9.根据权利要求1或2所述的组合物，其中所述填充剂是小麦淀粉、玉米淀粉、大米淀粉、大麦淀粉、燕麦、木薯、滑石、硫酸钠或其任何两种或更多种的组合。
10.根据权利要求1或2所述的组合物，其中所述湿润剂/保湿剂以所述组合物的按重量计1%至10%的量存在。
11.根据权利要求1或2所述的组合物，其中所述湿润剂/保湿剂是甘油、水、脲、乳酸钠或其任何两种或更多种的组合。
12.根据权利要求1或2所述的组合物，还包含以所述组合物的按重量计1%至15%的量的抗裂剂。
13.根据权利要求12所述的组合物，其中所述抗裂剂是氢化植物油、聚乙二醇或其组合。
14.根据权利要求1所述的组合物，其中所述助表面活性剂的组还包括烷基聚葡萄糖苷。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MYPI2018702242A MY186674A (en) | 2018-06-07 | 2018-06-07 | A syndet bar composition |
| MYPI2018702242 | 2018-06-07 | ||
| PCT/MY2019/050029 WO2019235911A1 (en) | 2018-06-07 | 2019-04-24 | A syndet bar composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN112313320A CN112313320A (zh) | 2021-02-02 |
| CN112313320B true CN112313320B (zh) | 2022-06-07 |
Family
ID=68770407
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201980033172.XA Active CN112313320B (zh) | 2018-06-07 | 2019-04-24 | 合成洗涤剂棒组合物 |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US11932826B2 (zh) |
| EP (1) | EP3810738B1 (zh) |
| JP (1) | JP7263399B2 (zh) |
| KR (1) | KR20210019458A (zh) |
| CN (1) | CN112313320B (zh) |
| AU (1) | AU2019283637B2 (zh) |
| CA (1) | CA3102239A1 (zh) |
| EC (1) | ECSP20079152A (zh) |
| IL (1) | IL278738B2 (zh) |
| MX (1) | MX2020012983A (zh) |
| MY (1) | MY186674A (zh) |
| NZ (1) | NZ771582A (zh) |
| PH (1) | PH12020552057A1 (zh) |
| SG (1) | SG11202011457WA (zh) |
| TW (1) | TW202000883A (zh) |
| WO (1) | WO2019235911A1 (zh) |
| ZA (1) | ZA202007644B (zh) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4565647A (en) * | 1982-04-26 | 1986-01-21 | The Procter & Gamble Company | Foaming surfactant compositions |
| CN1090887A (zh) * | 1992-11-30 | 1994-08-17 | 普罗格特-甘布尔公司 | 含有特选皂的高泡洗涤剂组合物 |
| CN1137286A (zh) * | 1993-10-12 | 1996-12-04 | 斯蒂潘公司 | 含α磺化脂肪酸甲酯和阴离子表面活性剂的液体洗涤剂组合物 |
| US5965508A (en) * | 1997-10-21 | 1999-10-12 | Stepan Company | Soap bar compositions comprising alpha sulfonated fatty acid alkyl esters and long chain fatty acids |
| CN1270627A (zh) * | 1997-08-21 | 2000-10-18 | 帝国化学工业公司 | 合成洗涤剂制剂 |
| CN1784202A (zh) * | 2002-01-31 | 2006-06-07 | 斯特潘公司 | 含α－磺化脂肪酸烷基酯和多元醇的皂条组合物及其生产工艺 |
| CN101111593A (zh) * | 2004-12-08 | 2008-01-23 | 斯蒂潘公司 | 含有α磺化烷基酯或磺化脂肪酸的肥皂条 |
| CN102712563A (zh) * | 2009-11-03 | 2012-10-03 | 斯特潘公司 | 磺甲基琥珀酸(或其盐)、其制备方法及包含其的组合物 |
| CN103242992A (zh) * | 2013-05-02 | 2013-08-14 | 广州立白企业集团有限公司 | 一种含功能有色粒子洗衣皂及其生产方法 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5984995A (ja) * | 1982-11-04 | 1984-05-16 | 味の素株式会社 | 洗浄剤組成物 |
| US5017302A (en) | 1989-08-15 | 1991-05-21 | Colgate-Palmolive Company | Bar soap having improved resistance to cracking |
| CZ283033B6 (cs) * | 1990-09-28 | 1997-12-17 | The Procter And Gamble Company | Detergenční kompozice aktivovaná zeolitem a/nebo vrstevnatým silikátem a způsob zlepšování její schopnosti čištění textilie |
| US5227086A (en) * | 1992-03-20 | 1993-07-13 | The Procter & Gamble Company | Framed skin pH cleansing bar |
| US5691287A (en) | 1995-12-21 | 1997-11-25 | S. C. Johnson & Son, Inc. | Low irritation cleansing bar |
| US6458751B1 (en) | 2001-07-23 | 2002-10-01 | Unilever Home & Personal Care Usa | Skin cleansing bar comprising a fatty alcohol with low mush |
| JP2003096489A (ja) * | 2001-09-25 | 2003-04-03 | Tsumura & Co | 固形石鹸 |
| MY148956A (en) | 2002-01-31 | 2013-06-14 | Stepan Co | Soap bar compositions comprising alpha sulfonated alkyl esters or sulfonated fatty acid and process for producing the same |
| ES2295906T3 (es) * | 2003-08-27 | 2008-04-16 | Unilever N.V. | Detergente en pastilla mejorado y procedimiento de fabricacion. |
| US7109154B2 (en) * | 2004-04-13 | 2006-09-19 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Combination toilet bar composition |
| US20060003908A1 (en) * | 2004-07-01 | 2006-01-05 | Brennan Michael A | Mild synthetic detergent toilet bar composition |
| WO2009060312A2 (en) | 2007-08-17 | 2009-05-14 | Rhodia Asia Pacific Pte, Limited | Structured soap compositions |
| EP2751240B1 (en) * | 2011-09-20 | 2019-07-24 | Henkel IP & Holding GmbH | Cleaning formulations with improved surfactant solubility and use thereof |
| DE102014224216A1 (de) * | 2014-11-27 | 2016-06-02 | Henkel Ag & Co. Kgaa | Kosmetische Stückseifen enthaltend Seife und Mikroemulsionen |
| MY179544A (en) * | 2017-07-19 | 2020-11-10 | Kl Kepong Oleomas Sdn Bhd | A surfactant system |
-
2018
- 2018-06-07 MY MYPI2018702242A patent/MY186674A/en unknown
-
2019
- 2019-04-24 SG SG11202011457WA patent/SG11202011457WA/en unknown
- 2019-04-24 NZ NZ771582A patent/NZ771582A/en unknown
- 2019-04-24 KR KR1020207037225A patent/KR20210019458A/ko not_active Application Discontinuation
- 2019-04-24 IL IL278738A patent/IL278738B2/en unknown
- 2019-04-24 WO PCT/MY2019/050029 patent/WO2019235911A1/en active Search and Examination
- 2019-04-24 CA CA3102239A patent/CA3102239A1/en active Pending
- 2019-04-24 EP EP19816126.7A patent/EP3810738B1/en active Active
- 2019-04-24 AU AU2019283637A patent/AU2019283637B2/en active Active
- 2019-04-24 US US15/734,802 patent/US11932826B2/en active Active
- 2019-04-24 JP JP2020567851A patent/JP7263399B2/ja active Active
- 2019-04-24 MX MX2020012983A patent/MX2020012983A/es unknown
- 2019-04-24 CN CN201980033172.XA patent/CN112313320B/zh active Active
- 2019-06-06 TW TW108119680A patent/TW202000883A/zh unknown
-
2020
- 2020-12-01 PH PH12020552057A patent/PH12020552057A1/en unknown
- 2020-12-08 ZA ZA2020/07644A patent/ZA202007644B/en unknown
- 2020-12-09 EC ECSENADI202079152A patent/ECSP20079152A/es unknown
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4565647A (en) * | 1982-04-26 | 1986-01-21 | The Procter & Gamble Company | Foaming surfactant compositions |
| US4565647B1 (en) * | 1982-04-26 | 1994-04-05 | Procter & Gamble | Foaming surfactant compositions |
| CN1090887A (zh) * | 1992-11-30 | 1994-08-17 | 普罗格特-甘布尔公司 | 含有特选皂的高泡洗涤剂组合物 |
| CN1137286A (zh) * | 1993-10-12 | 1996-12-04 | 斯蒂潘公司 | 含α磺化脂肪酸甲酯和阴离子表面活性剂的液体洗涤剂组合物 |
| CN1270627A (zh) * | 1997-08-21 | 2000-10-18 | 帝国化学工业公司 | 合成洗涤剂制剂 |
| US5965508A (en) * | 1997-10-21 | 1999-10-12 | Stepan Company | Soap bar compositions comprising alpha sulfonated fatty acid alkyl esters and long chain fatty acids |
| CN1784202A (zh) * | 2002-01-31 | 2006-06-07 | 斯特潘公司 | 含α－磺化脂肪酸烷基酯和多元醇的皂条组合物及其生产工艺 |
| CN101111593A (zh) * | 2004-12-08 | 2008-01-23 | 斯蒂潘公司 | 含有α磺化烷基酯或磺化脂肪酸的肥皂条 |
| CN102712563A (zh) * | 2009-11-03 | 2012-10-03 | 斯特潘公司 | 磺甲基琥珀酸(或其盐)、其制备方法及包含其的组合物 |
| CN103242992A (zh) * | 2013-05-02 | 2013-08-14 | 广州立白企业集团有限公司 | 一种含功能有色粒子洗衣皂及其生产方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| MX2020012983A (es) | 2021-02-16 |
| IL278738B2 (en) | 2024-08-01 |
| MY186674A (en) | 2021-08-05 |
| IL278738B1 (en) | 2024-04-01 |
| PH12020552057A1 (en) | 2021-05-31 |
| ZA202007644B (en) | 2022-04-28 |
| EP3810738B1 (en) | 2024-08-28 |
| US20210230507A1 (en) | 2021-07-29 |
| TW202000883A (zh) | 2020-01-01 |
| ECSP20079152A (es) | 2021-01-29 |
| BR112020024845A2 (pt) | 2021-03-02 |
| SG11202011457WA (en) | 2020-12-30 |
| CN112313320A (zh) | 2021-02-02 |
| WO2019235911A1 (en) | 2019-12-12 |
| CA3102239A1 (en) | 2019-12-12 |
| NZ771582A (en) | 2023-07-28 |
| KR20210019458A (ko) | 2021-02-22 |
| AU2019283637B2 (en) | 2021-10-14 |
| EP3810738A1 (en) | 2021-04-28 |
| US11932826B2 (en) | 2024-03-19 |
| AU2019283637A1 (en) | 2021-01-21 |
| EP3810738A4 (en) | 2022-03-09 |
| JP7263399B2 (ja) | 2023-04-24 |
| JP2021527144A (ja) | 2021-10-11 |
| IL278738A (zh) | 2021-03-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0569773B1 (en) | Anhydrous foaming composition containing low concentrations of detergents and high levels of glycerin and emollients such as oils and esters | |
| US4198311A (en) | Skin conditioning toilet bar | |
| CA2930724C (en) | Soap bar formulations with improved skin softness comprising nonionic polymer structuring system | |
| US5547602A (en) | Moisturizing soap bar | |
| US2175285A (en) | Detergent for toilet use containing incompletely esterified polyhydric alcohol | |
| GB2317396A (en) | Personal cleansing bar | |
| US5952276A (en) | Soap bar composition | |
| CN112313320B (zh) | 合成洗涤剂棒组合物 | |
| FI86556B (fi) | Tvaolkomposition. | |
| RU2800638C2 (ru) | Композиция кускового синдета | |
| JP2930671B2 (ja) | 臭気相容性嵩高アミン陽イオン重合体を有するパーソナルクレンジング製品 | |
| US6228822B1 (en) | Synthetic detergent base material and synthetic detergent bar produced therefrom | |
| JP2008094812A (ja) | 洗浄剤組成物 | |
| JPH08183730A (ja) | 固形洗浄剤組成物及びその製造方法 | |
| JP2000169879A (ja) | モノグリセリドスルフォン酸塩を含有する複合石鹸組成物及びその製造方法 | |
| KR100469770B1 (ko) | 약산성 인체세정용 비누 제조방법 및 그 제품 | |
| JP2005171219A (ja) | 米糠油由来化粧品原料組成物 | |
| BR112020024845B1 (pt) | Composição de barra syndet | |
| JPH03277698A (ja) | 固形洗浄剤 | |
| JPH0816240B2 (ja) | パ−ル様外観を呈する液体洗浄剤組成物 | |
| WO2005017087A1 (en) | Toilet soap composition | |
| JP2002114994A (ja) | 機械練り石鹸組成物 | |
| JP3472776B2 (ja) | 固形洗浄剤組成物 | |
| CN107002001B (zh) | 具有苯氧乙醇的清洁条 | |
| JPH03277699A (ja) | 固形洗浄剤 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: DE Ref document number: 40037566 Country of ref document: HK |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |