CN112204778B - 活性物质、负极活性物质和氟离子二次电池 - Google Patents
活性物质、负极活性物质和氟离子二次电池 Download PDFInfo
- Publication number
- CN112204778B CN112204778B CN201980036806.7A CN201980036806A CN112204778B CN 112204778 B CN112204778 B CN 112204778B CN 201980036806 A CN201980036806 A CN 201980036806A CN 112204778 B CN112204778 B CN 112204778B
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- China
- Prior art keywords
- active material
- fluoride
- negative electrode
- fluoride ion
- positive electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000011149 active material Substances 0.000 title claims abstract description 99
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 title claims description 160
- 239000007773 negative electrode material Substances 0.000 title description 22
- -1 fluorine ions Chemical class 0.000 claims abstract description 39
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 31
- 229910001512 metal fluoride Inorganic materials 0.000 claims abstract description 26
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 24
- 239000011737 fluorine Substances 0.000 claims abstract description 16
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims description 57
- 239000003792 electrolyte Substances 0.000 claims description 43
- 239000007774 positive electrode material Substances 0.000 claims description 21
- 239000013078 crystal Substances 0.000 claims description 13
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 239000013543 active substance Substances 0.000 claims description 7
- 239000002131 composite material Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 abstract description 43
- 239000002184 metal Substances 0.000 abstract description 41
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract description 15
- 229910052723 transition metal Inorganic materials 0.000 abstract description 15
- 150000001342 alkaline earth metals Chemical class 0.000 abstract description 13
- 229910052791 calcium Inorganic materials 0.000 abstract description 6
- 229910052712 strontium Inorganic materials 0.000 abstract description 4
- 239000002245 particle Substances 0.000 description 52
- 229910016569 AlF 3 Inorganic materials 0.000 description 50
- 239000010936 titanium Substances 0.000 description 29
- 239000000463 material Substances 0.000 description 28
- 238000000034 method Methods 0.000 description 18
- 150000001875 compounds Chemical class 0.000 description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 14
- 239000011230 binding agent Substances 0.000 description 14
- 239000006183 anode active material Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 12
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- 239000000956 alloy Substances 0.000 description 8
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- 150000004673 fluoride salts Chemical class 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 150000002500 ions Chemical class 0.000 description 7
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- 239000007787 solid Substances 0.000 description 7
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- 239000010409 thin film Substances 0.000 description 7
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- 238000004519 manufacturing process Methods 0.000 description 6
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- 239000002994 raw material Substances 0.000 description 5
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
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- 238000011156 evaluation Methods 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
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- 238000002156 mixing Methods 0.000 description 4
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- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- XROWMBWRMNHXMF-UHFFFAOYSA-J titanium tetrafluoride Chemical compound [F-].[F-].[F-].[F-].[Ti+4] XROWMBWRMNHXMF-UHFFFAOYSA-J 0.000 description 4
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 3
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 3
- 229920002943 EPDM rubber Polymers 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
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- 229910000077 silane Inorganic materials 0.000 description 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- 229910016036 BaF 2 Inorganic materials 0.000 description 2
- 229910004261 CaF 2 Inorganic materials 0.000 description 2
- 229910016509 CuF 2 Inorganic materials 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
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- 239000002033 PVDF binder Substances 0.000 description 2
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- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000012300 argon atmosphere Substances 0.000 description 2
- XJHCXCQVJFPJIK-UHFFFAOYSA-M caesium fluoride Chemical compound [F-].[Cs+] XJHCXCQVJFPJIK-UHFFFAOYSA-M 0.000 description 2
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- 238000000921 elemental analysis Methods 0.000 description 2
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- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 2
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- 239000000835 fiber Substances 0.000 description 2
- 150000002222 fluorine compounds Chemical group 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910001506 inorganic fluoride Inorganic materials 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 239000010416 ion conductor Substances 0.000 description 2
- 238000004255 ion exchange chromatography Methods 0.000 description 2
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000005289 physical deposition Methods 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 2
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- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- AHLATJUETSFVIM-UHFFFAOYSA-M rubidium fluoride Chemical compound [F-].[Rb+] AHLATJUETSFVIM-UHFFFAOYSA-M 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 2
- ZXMGHDIOOHOAAE-UHFFFAOYSA-N 1,1,1-trifluoro-n-(trifluoromethylsulfonyl)methanesulfonamide Chemical compound FC(F)(F)S(=O)(=O)NS(=O)(=O)C(F)(F)F ZXMGHDIOOHOAAE-UHFFFAOYSA-N 0.000 description 1
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 description 1
- FLVJYESYPAKKKQ-UHFFFAOYSA-M 1-methyl-1-propylpiperidin-1-ium;fluoride Chemical compound [F-].CCC[N+]1(C)CCCCC1 FLVJYESYPAKKKQ-UHFFFAOYSA-M 0.000 description 1
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 1
- AFZZDVXJZOLVKO-UHFFFAOYSA-M 2,2-dimethylpropyl(trimethyl)azanium;fluoride Chemical compound [F-].CC(C)(C)C[N+](C)(C)C AFZZDVXJZOLVKO-UHFFFAOYSA-M 0.000 description 1
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 description 1
- SBLRHMKNNHXPHG-UHFFFAOYSA-N 4-fluoro-1,3-dioxolan-2-one Chemical compound FC1COC(=O)O1 SBLRHMKNNHXPHG-UHFFFAOYSA-N 0.000 description 1
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
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- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
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- MOVBJUGHBJJKOW-UHFFFAOYSA-N methyl 2-amino-5-methoxybenzoate Chemical compound COC(=O)C1=CC(OC)=CC=C1N MOVBJUGHBJJKOW-UHFFFAOYSA-N 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
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- 229920005575 poly(amic acid) Polymers 0.000 description 1
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- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011698 potassium fluoride Substances 0.000 description 1
- 235000003270 potassium fluoride Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
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- 229940090181 propyl acetate Drugs 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
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- BJQWBACJIAKDTJ-UHFFFAOYSA-N tetrabutylphosphanium Chemical compound CCCC[P+](CCCC)(CCCC)CCCC BJQWBACJIAKDTJ-UHFFFAOYSA-N 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- VBHJAIGGLJOOLJ-UHFFFAOYSA-M tetramethylphosphanium;fluoride Chemical compound [F-].C[P+](C)(C)C VBHJAIGGLJOOLJ-UHFFFAOYSA-M 0.000 description 1
- GEPYJHDOGKHEMZ-UHFFFAOYSA-M tetraphenylphosphanium;fluoride Chemical compound [F-].C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 GEPYJHDOGKHEMZ-UHFFFAOYSA-M 0.000 description 1
- 238000002230 thermal chemical vapour deposition Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
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- KZEXVNKGDKTRPC-UHFFFAOYSA-N triethyl(2-methoxyethyl)phosphanium Chemical compound CC[P+](CC)(CC)CCOC KZEXVNKGDKTRPC-UHFFFAOYSA-N 0.000 description 1
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 description 1
- GLMLIFKQHOMAAP-UHFFFAOYSA-M trimethylsulfanium;fluoride Chemical compound [F-].C[S+](C)C GLMLIFKQHOMAAP-UHFFFAOYSA-M 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/582—Halogenides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0407—Methods of deposition of the material by coating on an electrolyte layer
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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| PCT/JP2019/039068 WO2020158051A1 (fr) | 2019-01-28 | 2019-10-03 | Matériau actif, matériau actif d'électrode négative et batterie secondaire au fluorure-ion |
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| WO2023238508A1 (fr) * | 2022-06-07 | 2023-12-14 | パナソニックＩｐマネジメント株式会社 | Matériau d'électrolyte solide et son procédé de production |
| WO2023238509A1 (fr) * | 2022-06-07 | 2023-12-14 | パナソニックＩｐマネジメント株式会社 | Matériau d'électrolyte solide et procédé de production de celui-ci |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4040846A (en) * | 1975-03-29 | 1977-08-09 | Ernst Leitz G.M.B.H. | Optical fluorophosphate glass and process of making same |
| CN101510608A (zh) * | 2008-02-13 | 2009-08-19 | Tdk株式会社 | 活性物质以及电极的制造方法、活性物质以及电极 |
| WO2013066582A1 (fr) * | 2011-11-03 | 2013-05-10 | Johnson Controls Technology Llc | Batterie secondaire au lithium-ion présentant des caractéristiques de sécurité améliorées |
| CN103650219A (zh) * | 2011-06-24 | 2014-03-19 | 旭硝子株式会社 | 锂离子二次电池用正极活性物质的制造方法、锂离子二次电池用正极及锂离子二次电池 |
| WO2014076946A1 (fr) * | 2012-11-13 | 2014-05-22 | Ｊｘ日鉱日石エネルギー株式会社 | Matériau d'électrode positive, procédé de fabrication de matériau d'électrode positive, et batterie à électrolyte non aqueux |
| CN105742583A (zh) * | 2014-12-31 | 2016-07-06 | 三星电子株式会社 | 复合负极活性材料、包括其的负极和锂二次电池 |
| CN107086302A (zh) * | 2016-02-12 | 2017-08-22 | 丰田自动车株式会社 | 活性物质及氟化物离子电池 |
| CN108172828A (zh) * | 2016-12-07 | 2018-06-15 | 丰田自动车株式会社 | 氟化物离子全固体电池 |
| CN109216781A (zh) * | 2017-07-03 | 2019-01-15 | 松下电器产业株式会社 | 氟化物穿梭二次电池 |
| CN109216780A (zh) * | 2017-07-03 | 2019-01-15 | 松下电器产业株式会社 | 氟化物穿梭二次电池 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8377586B2 (en) * | 2005-10-05 | 2013-02-19 | California Institute Of Technology | Fluoride ion electrochemical cell |
| CN101467287B (zh) | 2006-03-03 | 2012-09-05 | 加州理工学院 | 氟离子电化学电池 |
| KR20100007236A (ko) * | 2008-07-11 | 2010-01-22 | 주식회사 에너세라믹 | 리튬 이차 전지용 양극 활물질, 이의 제조방법 및 이를포함하는 리튬 이차 전지 |
| KR101490406B1 (ko) * | 2013-01-25 | 2015-02-05 | 경북대학교 산학협력단 | 불소 화합물이 코팅된 리튬 이차 전지용 양극 활물질 및 이의 제조 방법 |
| WO2014144179A1 (fr) * | 2013-03-15 | 2014-09-18 | Wildcat Discovery Technologies, Inc. | Matières de haute énergie pour une batterie et procédés de réalisation et d'utilisation |
| US10177365B2 (en) * | 2015-03-05 | 2019-01-08 | Uchicago Argonne, Llc | Metal fluoride passivation coatings prepared by atomic layer deposition for Li-ion batteries |
| US10903483B2 (en) * | 2015-08-27 | 2021-01-26 | Wildcat Discovery Technologies, Inc | High energy materials for a battery and methods for making and use |
| JP6563856B2 (ja) * | 2016-05-30 | 2019-08-21 | トヨタ自動車株式会社 | 二次電池システム |
| JP6487375B2 (ja) * | 2016-06-03 | 2019-03-20 | トヨタ自動車株式会社 | 二次電池システム |
| WO2019187943A1 (fr) * | 2018-03-27 | 2019-10-03 | 本田技研工業株式会社 | Matériau actif d'électrode négative pour batteries secondaires au fluorure-ion, électrode négative utilisant ledit matériau actif, batterie secondaire au fluorure-ion et procédé de production dudit matériau actif |
-
2019
- 2019-10-03 EP EP19912721.8A patent/EP3920284B1/fr active Active
- 2019-10-03 WO PCT/JP2019/039068 patent/WO2020158051A1/fr unknown
- 2019-10-03 CN CN201980036806.7A patent/CN112204778B/zh active Active
- 2019-10-03 JP JP2020511402A patent/JP6862608B2/ja active Active
-
2021
- 2021-05-21 US US17/326,384 patent/US20210273222A1/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4040846A (en) * | 1975-03-29 | 1977-08-09 | Ernst Leitz G.M.B.H. | Optical fluorophosphate glass and process of making same |
| CN101510608A (zh) * | 2008-02-13 | 2009-08-19 | Tdk株式会社 | 活性物质以及电极的制造方法、活性物质以及电极 |
| CN103650219A (zh) * | 2011-06-24 | 2014-03-19 | 旭硝子株式会社 | 锂离子二次电池用正极活性物质的制造方法、锂离子二次电池用正极及锂离子二次电池 |
| WO2013066582A1 (fr) * | 2011-11-03 | 2013-05-10 | Johnson Controls Technology Llc | Batterie secondaire au lithium-ion présentant des caractéristiques de sécurité améliorées |
| WO2014076946A1 (fr) * | 2012-11-13 | 2014-05-22 | Ｊｘ日鉱日石エネルギー株式会社 | Matériau d'électrode positive, procédé de fabrication de matériau d'électrode positive, et batterie à électrolyte non aqueux |
| CN105742583A (zh) * | 2014-12-31 | 2016-07-06 | 三星电子株式会社 | 复合负极活性材料、包括其的负极和锂二次电池 |
| CN107086302A (zh) * | 2016-02-12 | 2017-08-22 | 丰田自动车株式会社 | 活性物质及氟化物离子电池 |
| CN108172828A (zh) * | 2016-12-07 | 2018-06-15 | 丰田自动车株式会社 | 氟化物离子全固体电池 |
| CN109216781A (zh) * | 2017-07-03 | 2019-01-15 | 松下电器产业株式会社 | 氟化物穿梭二次电池 |
| CN109216780A (zh) * | 2017-07-03 | 2019-01-15 | 松下电器产业株式会社 | 氟化物穿梭二次电池 |
Non-Patent Citations (3)
| Title |
|---|
| Half-metallic TiF3: a potential anode material for Liion spin batteries;Junru Wang等;J. Mater. Chem. A;第5卷;21486–21490 * |
| J. GUELIN 等.New A0.5A’0.5F3 Ferroelastic Phases with VF3 Structure (A, A' = Al, Ti, Cr, In, TI).Z. anorg. allg. Chem.1988,第557卷225-233. * |
| NH4F 溶液化学处理对γ-TiAl 抗高温氧化性能的影响;唐光泽等;中国有色金属学报(第7期);1535-1540 * |
Also Published As
| Publication number | Publication date |
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| CN112204778A (zh) | 2021-01-08 |
| JPWO2020158051A1 (ja) | 2021-02-18 |
| EP3920284B1 (fr) | 2023-04-19 |
| EP3920284A4 (fr) | 2022-03-23 |
| US20210273222A1 (en) | 2021-09-02 |
| WO2020158051A1 (fr) | 2020-08-06 |
| EP3920284A1 (fr) | 2021-12-08 |
| JP6862608B2 (ja) | 2021-04-21 |
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