CN112176726B - 一种具有防皱功能的羊毛面料的制备方法 - Google Patents

一种具有防皱功能的羊毛面料的制备方法 Download PDF

Info

Publication number
CN112176726B
CN112176726B CN202011080786.4A CN202011080786A CN112176726B CN 112176726 B CN112176726 B CN 112176726B CN 202011080786 A CN202011080786 A CN 202011080786A CN 112176726 B CN112176726 B CN 112176726B
Authority
CN
China
Prior art keywords
parts
preparation
crease
wool
wool fabric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202011080786.4A
Other languages
English (en)
Other versions
CN112176726A (zh
Inventor
陈爱芳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Mengsen Clothing Co ltd
Original Assignee
Zhejiang Mengsen Clothing Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Mengsen Clothing Co ltd filed Critical Zhejiang Mengsen Clothing Co ltd
Priority to CN202011080786.4A priority Critical patent/CN112176726B/zh
Publication of CN112176726A publication Critical patent/CN112176726A/zh
Application granted granted Critical
Publication of CN112176726B publication Critical patent/CN112176726B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/21—Cyclic compounds having at least one ring containing silicon, but no carbon in the ring
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
    • D06M13/358—Triazines
    • D06M13/364—Cyanuric acid; Isocyanuric acid; Derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/13—Alginic acid or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00—Protein-based fibres, e.g. animal fibres
    • D10B2211/01—Natural animal fibres, e.g. keratin fibres
    • D10B2211/02—Wool
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00—Protein-based fibres, e.g. animal fibres
    • D10B2211/20—Protein-derived artificial fibres
    • D10B2211/26—Globulin, e.g. groundnut protein
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/10—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明涉及纺织品制备领域，具体关于一种具有防皱功能的强触感羊毛面料的制备方法；包括羊毛纤维，莱卡纤维，大豆蛋白纤维和聚氨酯纤维混纺后整理得到；所述的第一次浸扎液中含有质量份数为3.4%‑6.8%的亚硫酸氢钠和1.2%‑3.4%的柔软剂；所述的第二次浸扎液中含有0.3%‑0.8%的防皱剂。保持了织物良好的强力及柔软的手感。本发明的羊毛面料具有优异的防皱功能，其色泽柔和、手感柔软丰满、透气保暖的特点，是一款高品质的纺织品材料。

Description

一种具有防皱功能的羊毛面料的制备方法
技术领域
本发明涉及纺织品制备领域，尤其是一种具有防皱功能的羊毛面料的制备方法。
背景技术
羊毛面料时具有弹性好、耐穿耐磨、保暖性强的优点，满足了人们多方位的需求。与此同时人们还在不断地对羊毛面料进行改进。
CN102899792A公开了一种羊毛绒内衣面料，所述羊毛绒内衣面料是由面纱、底纱和连结纱交织而成的，所述面纱包括羊毛混纺纤维和覆盖于所述羊毛混纺纤维上的氨纶，所述连结纱为DTY长纤，所述底纱为DTY长纤蒸纱，其中，所述羊毛混纺纤维占总成分的26％-35％，所述氨纶占总成分的3％-5％，所述DTY长纤占总成分的13％-20％，所述DTY长纤蒸纱总成分的40％-58％。通过上述方式，该发明的面料具有膨松、柔软，弹性好，吸湿透气，保暖性好等优点。
CN102747496A公开了一种腈纶羊毛面料，由经纬纱交织而成，所述腈纶羊毛面料的经纬纱均由腈纶纱线和羊毛纤维纱线构成，所述腈纶纱线和羊毛纤维纱线的百分比为35-40％∶60-65％，所述羊毛的纱支为60-90s，所述蚕丝的纱支为7-45s。该发明将腈纶和羊毛混纺，弥补了普通羊毛面料弹性差、成本高的缺点，提供的腈纶羊毛面料厚实保暖、弹性好、成本低，主要用于制作服装、家纺用品等。
CN107489026A涉及一种羊毛面料，包括羊毛纤维和维纶纤维，所述羊毛纤维的规格为细度85s～150s、长度95～115mm；所述维纶纤维的规格为3.5～4.5dtex×50～75mm；其特征在于，羊毛纤维和维纶纤维内含有柔软剂，所述羊毛纤维和维纶纤维的重量百分比为：60～95:50～85。该发明所具有的优点是：在羊毛纤维和维纶纤维内添加柔软剂，从而可以使羊毛面料更加柔软舒适。
随着人们对美的不断追求，衣料的质感和防皱性能越来越受到人们的重视，但是羊毛面料因为其自身材料的特点，一直都不尽如人意。
发明内容
为了解决上述问题，本发明提供了一种具有防皱功能的羊毛面料的制备方法。
一种具有防皱功能的羊毛面料的制备方法，其具体方案为：
一种具有防皱功能的羊毛面料的制备方法，其特征在于：
按照质量份数，将75-90份的羊毛纤维，15-32份的莱卡纤维，5-12份的大豆蛋白纤维和14-26份的聚氨酯纤维混纺后得到羊毛混纺纱线，然后将得到的纱线进行第一次浸轧，轧液率为68％-75％，完成后在80-90℃烘2-6min，然后进行第二次浸轧，轧液率为70％-85％，完成后在80-90℃烘1-3min，然后在110-130℃烘干3-6min，完成后再安装到织机上，由织机制成面料即可；所述的第一次浸轧液中含有质量百分比为3.4％-6.8％的亚硫酸氢钠和1.2％-3.4％的柔软剂；所述的第二次浸轧液中含有0.3％-0.8％的防皱剂；
所述的防皱剂按照质量百分比，包括23％-31％的二羟甲基二羟基乙烯脲，4.6％-8.2％的海藻糖，5％-14％的三羟甲基三聚氰胺，12％-18％的二氯异氰尿酸钠，2％-6％的褐藻胶和1％-5％的甘氨酸的原料；将其加入到1.5-4倍的乙醇中，搅拌混合均匀后控温60-80℃，反应1-5h后蒸干溶剂后得到。所述的柔软剂为一种环氧改性甜菜碱柔软剂，其制备方法如下：按质量份，在高压搅拌釜中,通入氮气,加入10-15份油基甜菜碱,3.1-4.7份3,4-环氧-1-丁烯,2-5份质量百分比为6-12％的氯铂酸的异丙醇溶液，再加入100-150份的200#溶剂油，6-12份2,4,6,8-四甲基环四硅氧烷,0.5-2.1份N-烯丙基-N'-乙基脲，控温55-65℃，搅拌反应2-5h，减压蒸馏除去200#溶剂油，得到环氧改性甜菜碱柔软剂；
所述油基甜菜碱,3,4-环氧-1-丁烯,2,4,6,8-四甲基环四硅氧烷,N-烯丙基-N'-乙基脲发生硅氢加成反应，得到环氧改性甜菜碱柔软剂，其部分反应示意如下：
Figure GDA0003931226820000021
所述的第一次浸扎时间为30-60s。
所述的第二次浸扎时间为1-5min。
所述的第一次浸轧液中还含有0.3％-0.6％的硅油精。
所述的第二次浸轧液中还含有0.1％-0.5％的十八烷基异氰酸酯。
本发明的一种具有防皱功能的羊毛面料的制备方法，本发明提供的油基甜菜碱,3,4-环氧-1-丁烯,2,4,6,8-四甲基环四硅氧烷,N-烯丙基-N'-乙基脲发生硅氢加成反应，得到环氧改性甜菜碱柔软剂，能够和羊毛面料表面的氨基和羟基等活性基团反应，赋予整理真丝织物良好的抗皱性能，并符合环保要求；并配合使用抗皱剂进行抗皱整理，经其整理后的羊毛面料获得了良好的抗皱性能，分子中的聚硅氧烷还可赋予整理织物优良的柔滑性，消除整理织物应力集中，减少强力损伤，保持了织物良好的强力及柔软的手感。本发明的羊毛面料具有优异的防皱功能，其色泽柔和、手感柔软丰满、透气保暖的特点，是一款高品质的纺织品材料。
附图说明
图1为实施例1制备的环氧改性甜菜碱柔软剂产品所做的傅立叶红外光谱图；
在2960cm-1附近存在碳氢的伸缩吸收峰，在677cm-1附近存在硅碳的伸缩吸收峰，在1094/1017cm-1附近存在硅氧的反对称伸缩吸收峰，在802cm-1附近存在硅氧的对称伸缩吸收峰，说明2,4,6,8-四甲基环四硅氧烷参与了反应；在916cm-1附近存在碳氧键的对称伸缩吸收峰，说明3,4-环氧-1-丁烯参与了反应；在1590cm-1附近存在羧酸根离子的反对称伸缩吸收峰，在1054cm-1附近存在碳氮单键的伸缩吸收峰，说明油基甜菜碱参与了反应；在1656cm-1附近存在羰基的伸缩吸收峰，在3352cm-1附近存在氮氢键的伸缩吸收峰，说明N-烯丙基-N'-乙基脲参与了反应。
具体实施方式
下面通过具体实施例对该发明作进一步说明：
织物的干折皱回复角(DCRA)测定：按照GB/T3819-1997《纺织品织物折痕回复性的测定》标准测定整理后织物的回复角，经、纬向各测5次，取各自平均值相加。
织物的硬挺度测定按照GB/T18318.1-2009《纺织品弯曲性能的测定：斜面法》标准测定整理后织物的硬挺度(径向与纬向的平均值)，硬挺度值越小，织物越柔软。
实施例1
一种具有防皱功能的羊毛面料的制备方法，其具体方案为：
将75kg羊毛纤维，15kg莱卡纤维，5kg大豆蛋白纤维和14kg聚氨酯纤维混纺后得到羊毛混纺纱线，然后将得到的纱线进行第一次浸扎，轧液率为68％，完成后在80℃烘2min，然后进行第二次浸扎，轧液率为70％，完成后在80℃烘1min，然后在110℃烘干3min，完成后再安装到织机上，由织机制成面料即可；其特征在于所述的第一次浸轧液中含有质量百分比为3.4％的亚硫酸氢钠和1.2％的柔软剂；所述的第二次浸轧液中含有0.3％的防皱剂。所述的防皱剂按照质量百分比，包括23％的二羟甲基二羟基乙烯脲，4.6％的海藻糖，5％的三羟甲基三聚氰胺，12％的二氯异氰尿酸钠，2％的褐藻胶和1％的甘氨酸的原料；将其加入到1.5倍的乙醇中，搅拌混合均匀后控温60℃，反应1h后蒸干溶剂后得到。
所述的柔软剂为一种环氧改性甜菜碱柔软剂，其制备方法如下：
在高压搅拌釜中,通入氮气,加入10kg油基甜菜碱,3.1kg3,4-环氧-1-丁烯,2kg质量百分比为6％的氯铂酸的异丙醇溶液，再加入100kg的200#溶剂油，6kg2,4,6,8-四甲基环四硅氧烷,0.5kgN-烯丙基-N'-乙基脲，控温55℃，搅拌反应2h，减压蒸馏除去200#溶剂油，得到环氧改性甜菜碱柔软剂。
所述的第一次浸扎时间为30s。
所述的第二次浸扎时间为1min。
所述的第一次浸轧液中还含有0.3％的硅油精。
所述的第二次浸轧液中还含有0.1％的十八烷基异氰酸酯。
实施例2
一种具有防皱功能的羊毛面料的制备方法，其具体方案为：
将85kg羊毛纤维，24kg莱卡纤维，8kg大豆蛋白纤维和20kg聚氨酯纤维混纺后得到羊毛混纺纱线，然后将得到的纱线进行第一次浸扎，轧液率为72％，完成后在85℃烘2min，然后进行第二次浸扎，轧液率为75％，完成后在85℃烘2min，然后在120℃烘干4min，完成后再安装到织机上，由织机制成面料即可；其特征在于所述的第一次浸轧液中含有质量百分比为4.2％的亚硫酸氢钠和2.4％的柔软剂；所述的第二次浸轧液中含有0.5％的防皱剂。所述的防皱剂按照质量百分比，包括27％的二羟甲基二羟基乙烯脲，6.2％的海藻糖，8％的三羟甲基三聚氰胺，15％的二氯异氰尿酸钠，4％的褐藻胶和3％的甘氨酸的原料；将其加入到2.4倍的乙醇中，搅拌混合均匀后控温70℃，反应3h后蒸干溶剂后得到。
所述的柔软剂为一种环氧改性甜菜碱柔软剂，其制备方法如下：
在高压搅拌釜中,通入氮气,加入12kg油基甜菜碱,3.6kg3,4-环氧-1-丁烯,3kg质量百分比为10％的氯铂酸的异丙醇溶液，再加入145kg的200#溶剂油，9kg2,4,6,8-四甲基环四硅氧烷,1kgN-烯丙基-N'-乙基脲，控温58℃，搅拌反应3h，减压蒸馏除去200#溶剂油，得到环氧改性甜菜碱柔软剂。
所述的第一次浸扎时间为40s。
所述的第二次浸扎时间为3min。
所述的第一次浸轧液中还含有0.4％的硅油精。
所述的第二次浸轧液中还含有0.2％的十八烷基异氰酸酯。
实施例3
一种具有防皱功能的羊毛面料的制备方法，其具体方案为：
将90kg羊毛纤维，32kg莱卡纤维，12kg大豆蛋白纤维和26kg聚氨酯纤维混纺后得到羊毛混纺纱线，然后将得到的纱线进行第一次浸扎，轧液率为75％，完成后在90℃烘6min，然后进行第二次浸扎，轧液率为85％，完成后在90℃烘3min，然后在130℃烘干6min，完成后再安装到织机上，由织机制成面料即可；其特征在于所述的第一次浸轧液中含有质量百分比为6.8％的亚硫酸氢钠和3.4％的柔软剂；所述的第二次浸轧液中含有0.8％的防皱剂。
所述的防皱剂按照质量百分比，包括31％的二羟甲基二羟基乙烯脲，8.2％的海藻糖，14％的三羟甲基三聚氰胺，18％的二氯异氰尿酸钠，6％的褐藻胶和5％的甘氨酸的原料；将其加入到4倍的乙醇中，搅拌混合均匀后控温80℃，反应5h后蒸干溶剂后得到。
所述的柔软剂为一种环氧改性甜菜碱柔软剂，其制备方法如下：
在高压搅拌釜中,通入氮气,加入15kg油基甜菜碱,4.7kg3,4-环氧-1-丁烯,5kg质量百分比为12％的氯铂酸的异丙醇溶液，再加入150kg的200#溶剂油，12kg2,4,6,8-四甲基环四硅氧烷,2.1kgN-烯丙基-N'-乙基脲，控温65℃，搅拌反应5h，减压蒸馏除去200#溶剂油，得到环氧改性甜菜碱柔软剂。
所述的第一次浸扎时间为60s。
所述的第二次浸扎时间为5min。
所述的第一次浸轧液中还含有0.6％的硅油精。
所述的第二次浸轧液中还含有0.5％的十八烷基异氰酸酯。
以上实施例制备的织物的回复角和硬挺度，其结果统计结果如下：
编号 回复角(°) 硬挺度(cm)
实施例1 274 3.86
实施例2 281 3.51
实施例3 285 3.25
对比例1
所述的柔软剂为一种环氧改性甜菜碱柔软剂，其制备方法如下：
在高压搅拌釜中,通入氮气,加入10kg油基甜菜碱,2kg质量百分比为6％的氯铂酸的异丙醇溶液，再加入100kg的200#溶剂油，6kg2,4,6,8-四甲基环四硅氧烷,0.5kgN-烯丙基-N'-乙基脲，控温55℃，搅拌反应2h，减压蒸馏除去200#溶剂油，得到环氧改性甜菜碱柔软剂。其它技术方案与实施例1相同。
对比例2
所述的柔软剂为一种环氧改性甜菜碱柔软剂，其制备方法如下：
在高压搅拌釜中,通入氮气,加入10kg油基甜菜碱,3.1kg3,4-环氧-1-丁烯,2kg质量百分比为6％的氯铂酸的异丙醇溶液，再加入100kg的200#溶剂油，6kg2,4,6,8-四甲基环四硅氧烷,控温55℃，搅拌反应2h，减压蒸馏除去200#溶剂油，得到环氧改性甜菜碱柔软剂。
其它技术方案与实施例1相同。
对比例3
一种具有防皱功能的羊毛面料的制备方法，其具体方案为：
将75kg羊毛纤维，15kg莱卡纤维，5kg大豆蛋白纤维和14kg聚氨酯纤维混纺后得到羊毛混纺纱线，然后将得到的纱线进行第一次浸扎，轧液率为68％，完成后在80℃烘2min，然后进行第二次浸扎，轧液率为70％，完成后在80℃烘1min，然后在110℃烘干3min，完成后再安装到织机上，由织机制成面料即可；其特征在于所述的第一次浸轧液中含有质量百分比为3.4％的亚硫酸氢钠；所述的第二次浸轧液中含有0.3％的防皱剂。
所述的防皱剂按照质量百分比，包括23％的二羟甲基二羟基乙烯脲，4.6％的海藻糖，5％的三羟甲基三聚氰胺，12％的二氯异氰尿酸钠，2％的褐藻胶和1％的甘氨酸的原料；将其加入到1.5倍的乙醇中，搅拌混合均匀后控温60℃，反应1h后蒸干溶剂后得到。
所述的第一次浸扎时间为30s。
所述的第二次浸扎时间为1min。
所述的第一次浸轧液中还含有0.3％的硅油精。
所述的第二次浸轧液中还含有0.1％的十八烷基异氰酸酯。
以上对比例制备的织物的回复角和硬挺度，其结果统计结果如下：
Figure GDA0003931226820000051
Figure GDA0003931226820000061

Claims (5)

1.一种具有防皱功能的羊毛面料的制备方法，其特征在于：
按照质量份数，将75-90份的羊毛纤维，15-32份的莱卡纤维，5-12份的大豆蛋白纤维和14-26份的聚氨酯纤维混纺后得到羊毛混纺纱线，然后将得到的纱线进行第一次浸轧，轧液率为68%-75%，完成后在80-90℃烘2-6min，然后进行第二次浸轧，轧液率为70%-85%，完成后在80-90℃烘1-3min，然后在110-130℃烘干3-6min，完成后再安装到织机上，由织机制成面料即可；所述的第一次浸轧液中含有质量百分比为3.4%-6.8%的亚硫酸氢钠和1.2%-3.4%的柔软剂；所述的第二次浸轧液中含有0.3%-0.8%的防皱剂；
所述的柔软剂为一种环氧改性甜菜碱柔软剂，其制备方法如下：
按质量份，在高压搅拌釜中,通入氮气,加入10-15份油基甜菜碱, 3.1-4.7份3,4-环氧-1-丁烯,2-5份质量百分比浓度为6-12%的氯铂酸的异丙醇溶液，再加入100-150份的200#溶剂油，6-12份2,4,6,8-四甲基环四硅氧烷, 0.5-2.1份N-烯丙基-N'-乙基脲，控温55-65℃，搅拌反应2-5h，减压蒸馏除去200#溶剂油，得到环氧改性甜菜碱柔软剂；
所述的防皱剂按照质量百分比，包括23%-31%的二羟甲基二羟基乙烯脲，4.6%-8.2%的海藻糖，5%-14%的三羟甲基三聚氰胺，12%-18%的二氯异氰尿酸钠，2%-6%的褐藻胶和1%-5%的甘氨酸的原料；将其加入到1.5-4倍的乙醇中，搅拌混合均匀后控温60-80℃，反应1-5h后蒸干溶剂后得到。
2.根据权利要求1所述的一种具有防皱功能的羊毛面料的制备方法，其特征在于：所述的第一次浸轧时间为30-60s。
3.根据权利要求1所述的一种具有防皱功能的羊毛面料的制备方法，其特征在于：所述的第二次浸轧时间为1-5min。
4.根据权利要求1所述的一种具有防皱功能的羊毛面料的制备方法，其特征在于：所述的第一次浸轧液中还含有0.3%-0.6%的硅油精。
5.根据权利要求1所述的一种具有防皱功能的羊毛面料的制备方法，其特征在于：所述的第二次浸轧液中还含有0.1%-0.5%的十八烷基异氰酸酯。
CN202011080786.4A 2020-10-11 2020-10-11 一种具有防皱功能的羊毛面料的制备方法 Active CN112176726B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011080786.4A CN112176726B (zh) 2020-10-11 2020-10-11 一种具有防皱功能的羊毛面料的制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011080786.4A CN112176726B (zh) 2020-10-11 2020-10-11 一种具有防皱功能的羊毛面料的制备方法

Publications (2)

Publication Number Publication Date
CN112176726A CN112176726A (zh) 2021-01-05
CN112176726B true CN112176726B (zh) 2023-02-10

Family

ID=73949105

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011080786.4A Active CN112176726B (zh) 2020-10-11 2020-10-11 一种具有防皱功能的羊毛面料的制备方法

Country Status (1)

Country Link
CN (1) CN112176726B (zh)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3521997A (en) * 1966-04-15 1970-07-28 Iws Nominee Co Ltd Continuous process for treating wool with chlorocyanurate
WO1996015309A2 (en) * 1994-11-10 1996-05-23 The Procter & Gamble Company Wrinkle reducing composition
WO2012040131A2 (en) * 2010-09-20 2012-03-29 The Procter & Gamble Company Fabric care formulations and methods
CN107287905A (zh) * 2017-06-26 2017-10-24 苏州威尔德工贸有限公司 一种蚕丝织物抗皱抗菌整理方法
CN110016749A (zh) * 2019-04-30 2019-07-16 相里海霞 一种具有抗皱功能的羊毛制面料

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3521997A (en) * 1966-04-15 1970-07-28 Iws Nominee Co Ltd Continuous process for treating wool with chlorocyanurate
WO1996015309A2 (en) * 1994-11-10 1996-05-23 The Procter & Gamble Company Wrinkle reducing composition
WO2012040131A2 (en) * 2010-09-20 2012-03-29 The Procter & Gamble Company Fabric care formulations and methods
CN107287905A (zh) * 2017-06-26 2017-10-24 苏州威尔德工贸有限公司 一种蚕丝织物抗皱抗菌整理方法
CN110016749A (zh) * 2019-04-30 2019-07-16 相里海霞 一种具有抗皱功能的羊毛制面料

Also Published As

Publication number Publication date
CN112176726A (zh) 2021-01-05

Similar Documents

Publication Publication Date Title
CN105862204B (zh) 一种防护服混纺面料的制备方法
EP3589779A1 (en) Natural fabrics comprising rose fiber
CN103174016A (zh) 一种复配整理剂及其制备方法
CN110356059B (zh) 一种抗菌防紫外线面料
CN110774683B (zh) 一种水洗缩水率低的面料及其制备工艺
CN101956322A (zh) 一种无甲醛织物免烫整理剂及其制备方法和应用
WO2021243941A1 (zh) 抗起球石墨烯混纺纱纤维复合面料及其制造方法
CN110424160A (zh) 一种成衣免烫三防整理方法
CN110904687B (zh) 一种纯棉缎纹面料仿真丝整理剂及制备方法
CN112176726B (zh) 一种具有防皱功能的羊毛面料的制备方法
CN111893630B (zh) 一种易透气排汗的亲肤面料及其制备方法
TWI723914B (zh) 抗污樹脂、抗污織物及其製造方法
CN113604934A (zh) 一种吸湿快干单向导湿高弹面料的生产工艺
CN111270521A (zh) 一种蚕丝织物柔软整理剂及制备方法
CN110499566A (zh) 一种亲肤抗皱的高端定制衬衫面料及其加工方法
CN113122991A (zh) 一种吸湿速干织物的制备方法
CN112877851A (zh) 一种抗皱混纺面料的制备工艺
KR101921231B1 (ko) 활동성이 향상된 아웃도어 웨어용 직물 및 이의 제조방법
CN115449950B (zh) 无弹力丝经纬双弹面料及其制备方法
CN115045126B (zh) 一种多功能户外运动面料的生产工艺
CN114959994B (zh) 一种毛涤珍珠纤维衬衫面料的制备工艺
CN111188186A (zh) 一种抗皱抗菌校服面料及其制备方法
CN115464954B (zh) 一种抗起球棉服面料及其生产工艺
KR102717419B1 (ko) 와이드고어 드레이핑 기반의 컨투어링 심리스 브라
CN118147806B (zh) 锦棉色织四向高弹梭织面料的生产工艺

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant