CN112176726A - 一种具有防皱功能的强触感羊毛面料的制备方法 - Google Patents
一种具有防皱功能的强触感羊毛面料的制备方法 Download PDFInfo
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Abstract
本发明涉及纺织品制备领域，具体关于一种具有防皱功能的强触感羊毛面料的制备方法；包括羊毛纤维，莱卡纤维，大豆蛋白纤维和聚氨酯纤维混纺后整理得到；所述的第一次浸扎液中含有质量份数为3.4%‑6.8%的亚硫酸氢钠和1.2%‑3.4%的柔软剂；所述的第二次浸扎液中含有0.3%‑0.8%的防皱剂。保持了织物良好的强力及柔软的手感。本发明的羊毛面料具有优异的防皱功能，其色泽柔和、手感柔软丰满、透气保暖的特点，是一款高品质的纺织品材料。
Description
技术领域
本发明涉及纺织品制备领域，尤其是一种具有防皱功能的强触感羊毛面料的制备方法。
背景技术
羊毛面料时具有弹性好、耐穿耐磨、保暖性强的优点，满足了人们多方位的需求。与此同时人们还在不断地对羊毛面料进行改进。
CN102899792A公开了一种羊毛绒内衣面料，所述羊毛绒内衣面料是由面纱、底纱和连结纱交织而成的，所述面纱包括羊毛混纺纤维和覆盖于所述羊毛混纺纤维上的氨纶，所述连结纱为DTY长纤，所述底纱为DTY长纤蒸纱，其中，所述羊毛混纺纤维占总成分的26%-35%，所述氨纶占总成分的3%-5%，所述DTY长纤占总成分的13%-20%，所述DTY长纤蒸纱总成分的40%-58%。通过上述方式，该发明的面料具有膨松、柔软，弹性好，吸湿透气，保暖性好等优点。
CN102747496A公开了一种腈纶羊毛面料，由经纬纱交织而成，所述腈纶羊毛面料的经纬纱均由腈纶纱线和羊毛纤维纱线构成，所述腈纶纱线和羊毛纤维纱线的百分比为35-40％∶60-65％，所述羊毛的纱支为60-90s，所述蚕丝的纱支为7-45s。该发明将腈纶和羊毛混纺，弥补了普通羊毛面料弹性差、成本高的缺点，提供的腈纶羊毛面料厚实保暖、弹性好、成本低，主要用于制作服装、家纺用品等。
CN107489026A涉及一种羊毛面料，包括羊毛纤维和维纶纤维，所述羊毛纤维的规格为细度85s～150s、长度95～115mm；所述维纶纤维的规格为3.5～4.5dtex×50～75mm；其特征在于，羊毛纤维和维纶纤维内含有柔软剂，所述羊毛纤维和维纶纤维的重量百分比为：60～95:50～85。该发明所具有的优点是：在羊毛纤维和维纶纤维内添加柔软剂，从而可以使羊毛面料更加柔软舒适。
随着人们对美的不断追求，衣料的质感和防皱性能越来越受到人们的重视，但是羊毛面料因为其自身材料的特点，一直都不尽如人意。
发明内容
为了解决上述问题，本发明提供了一种具有防皱功能的强触感羊毛面料的制备方法。
一种具有防皱功能的强触感羊毛面料的制备方法，其具体方案为：
按照质量份数，将75-90份的羊毛纤维，15-32份的莱卡纤维，5-12份的大豆蛋白纤维和14-26份的聚氨酯纤维混纺后得到羊毛混纺纱线，然后将得到的纱线进行第一次浸扎，轧液率为68%-75%，完成后在80-90℃烘2-6min，然后进行第二次浸扎，轧液率为70%-85%，完成后在80-90℃烘1-3min，然后在110-130℃烘干3-6min，完成后再安装到织机上，由织机制成面料即可；其特征在于所述的第一次浸扎液中含有质量份数为3.4%-6.8%的亚硫酸氢钠和1.2%-3.4%的柔软剂；所述的第二次浸扎液中含有0.3%-0.8%的防皱剂。
所述的防皱剂按照质量份，包括23%-31%的二羟甲基二羟基乙烯脲，4.6%-8.2%的海藻糖，5%-14%的三羟甲基三聚氰胺，12%-18%的二氯异氰尿酸钠，2%-6%的褐藻胶和1%-5%的甘氨酸的原料；将其加入到1.5-4倍的乙醇中，搅拌混合均匀后控温60-80℃，反应1-5h后蒸干溶剂后得到。
所述的柔软剂为一种环氧改性甜菜碱柔软剂，其制备方法如下：
按质量份，在高压搅拌釜中,通入氮气,加入10-15份油基甜菜碱, 3.1-4.7份3,4-环氧-1-丁烯,2-5份质量百分比浓度为6-12%的氯铂酸的异丙醇溶液，再加入100-150份的200#溶剂油，6-12份2,4,6,8-四甲基环四硅氧烷, 0.5-2.1份N-烯丙基-N'-乙基脲，控温55-65℃，搅拌反应2-5h，减压蒸馏除去200#溶剂油，得到环氧改性甜菜碱柔软剂。
所述油基甜菜碱, 3,4-环氧-1-丁烯, 2,4,6,8-四甲基环四硅氧烷, N-烯丙基-N'-乙基脲发生硅氢加成反应，得到环氧改性甜菜碱柔软剂，其部分反应示意如下：
所述的第一次浸扎时间为30-60s。
所述的第二次浸扎时间为1-5min。
所述的第一次浸扎液中还含有0.3%-0.6%的硅油精。
所述的第二次浸扎液中还含有0.1%-0.5%的十八烷基异氰酸酯。
本发明的一种具有防皱功能的强触感羊毛面料的制备方法，本发明提供的油基甜菜碱, 3,4-环氧-1-丁烯, 2,4,6,8-四甲基环四硅氧烷, N-烯丙基-N'-乙基脲发生硅氢加成反应，得到环氧改性甜菜碱柔软剂，能够和羊毛面料表面的氨基和羟基等活性基团反应，赋予整理真丝织物良好的抗皱性能，并符合环保要求；并配合使用抗皱剂进行抗皱整理，经其整理后的羊毛面料获得了良好的抗皱性能，分子中的聚硅氧烷还可赋予整理织物优良的柔滑性，消除整理织物应力集中，减少强力损伤，保持了织物良好的强力及柔软的手感。本发明的羊毛面料具有优异的防皱功能，其色泽柔和、手感柔软丰满、透气保暖的特点，是一款高品质的纺织品材料。
附图说明
图1为实施例1制备的环氧改性甜菜碱柔软剂产品所做的傅立叶红外光谱图；
在2960cm-1附近存在碳氢的伸缩吸收峰，在677cm-1附近存在硅碳的伸缩吸收峰，在1094/1017cm-1附近存在硅氧的反对称伸缩吸收峰，在802cm-1附近存在硅氧的对称伸缩吸收峰，说明2,4,6,8-四甲基环四硅氧烷参与了反应；在916cm-1附近存在碳氧键的对称伸缩吸收峰，说明3,4-环氧-1-丁烯参与了反应；在1590cm-1附近存在羧酸根离子的反对称伸缩吸收峰，在1054cm-1附近存在碳氮单键的伸缩吸收峰，说明油基甜菜碱参与了反应；在1656cm-1附近存在羰基的伸缩吸收峰，在3352cm-1附近存在氮氢键的伸缩吸收峰，说明N-烯丙基-N'-乙基脲参与了反应。
具体实施方式
下面通过具体实施例对该发明作进一步说明：
织物的干折皱回复角(DCRA)测定：按照GB/T3819-1997《纺织品织物折痕回复性的测定》标准测定整理后织物的回复角，经、纬向各测5次，取各自平均值相加。
织物的硬挺度测定按照GB/T18318.1-2009《纺织品弯曲性能的测定：斜面法》标准测定整理后织物的硬挺度（径向与纬向的平均值），硬挺度值越小，织物越柔软。
实施例1
一种具有防皱功能的强触感羊毛面料的制备方法，其具体方案为：
将75kg羊毛纤维，15kg莱卡纤维，5kg大豆蛋白纤维和14kg聚氨酯纤维混纺后得到羊毛混纺纱线，然后将得到的纱线进行第一次浸扎，轧液率为68%，完成后在80℃烘2min，然后进行第二次浸扎，轧液率为70%，完成后在80℃烘1min，然后在110℃烘干3min，完成后再安装到织机上，由织机制成面料即可；其特征在于所述的第一次浸扎液中含有质量kg数为3.4%的亚硫酸氢钠和1.2%的柔软剂；所述的第二次浸扎液中含有0.3%的防皱剂。
所述的防皱剂按照质量百分比含量，包括23%的二羟甲基二羟基乙烯脲，4.6%的海藻糖，5%的三羟甲基三聚氰胺，12%的二氯异氰尿酸钠，2%的褐藻胶和1%的甘氨酸的原料；将其加入到1.5倍的乙醇中，搅拌混合均匀后控温60℃，反应1h后蒸干溶剂后得到。
所述的柔软剂为一种环氧改性甜菜碱柔软剂，其制备方法如下：
在高压搅拌釜中,通入氮气,加入10kg油基甜菜碱, 3.1kg3,4-环氧-1-丁烯,2kg质量百分比浓度为6%的氯铂酸的异丙醇溶液，再加入100kg的200#溶剂油，6kg2,4,6,8-四甲基环四硅氧烷, 0.5kgN-烯丙基-N'-乙基脲，控温55℃，搅拌反应2h，减压蒸馏除去200#溶剂油，得到环氧改性甜菜碱柔软剂。
所述的第一次浸扎时间为30s。
所述的第二次浸扎时间为1min。
所述的第一次浸扎液中还含有0.3%的硅油精。
所述的第二次浸扎液中还含有0.1%的十八烷基异氰酸酯。
实施例2
一种具有防皱功能的强触感羊毛面料的制备方法，其具体方案为：
将85kg羊毛纤维，24kg莱卡纤维，8kg大豆蛋白纤维和20kg聚氨酯纤维混纺后得到羊毛混纺纱线，然后将得到的纱线进行第一次浸扎，轧液率为72%，完成后在85℃烘2min，然后进行第二次浸扎，轧液率为75%，完成后在85℃烘2min，然后在120℃烘干4min，完成后再安装到织机上，由织机制成面料即可；其特征在于所述的第一次浸扎液中含有质量kg数为4.2%的亚硫酸氢钠和2.4%的柔软剂；所述的第二次浸扎液中含有0.5%的防皱剂。
所述的防皱剂按照质量百分比含量，包括27%的二羟甲基二羟基乙烯脲，6.2%的海藻糖，8%的三羟甲基三聚氰胺，15%的二氯异氰尿酸钠，4%的褐藻胶和3%的甘氨酸的原料；将其加入到2.4倍的乙醇中，搅拌混合均匀后控温70℃，反应3h后蒸干溶剂后得到。
所述的柔软剂为一种环氧改性甜菜碱柔软剂，其制备方法如下：
在高压搅拌釜中,通入氮气,加入12kg油基甜菜碱, 3.6kg3,4-环氧-1-丁烯,3kg质量百分比浓度为10%的氯铂酸的异丙醇溶液，再加入145kg的200#溶剂油，9kg2,4,6,8-四甲基环四硅氧烷, 1kgN-烯丙基-N'-乙基脲，控温58℃，搅拌反应3h，减压蒸馏除去200#溶剂油，得到环氧改性甜菜碱柔软剂。
所述的第一次浸扎时间为40s。
所述的第二次浸扎时间为3min。
所述的第一次浸扎液中还含有0.4%的硅油精。
所述的第二次浸扎液中还含有0.2%的十八烷基异氰酸酯。
实施例3
一种具有防皱功能的强触感羊毛面料的制备方法，其具体方案为：
将90kg羊毛纤维，32kg莱卡纤维，12kg大豆蛋白纤维和26kg聚氨酯纤维混纺后得到羊毛混纺纱线，然后将得到的纱线进行第一次浸扎，轧液率为75%，完成后在90℃烘6min，然后进行第二次浸扎，轧液率为85%，完成后在90℃烘3min，然后在130℃烘干6min，完成后再安装到织机上，由织机制成面料即可；其特征在于所述的第一次浸扎液中含有质量kg数为6.8%的亚硫酸氢钠和3.4%的柔软剂；所述的第二次浸扎液中含有0.8%的防皱剂。
所述的防皱剂按照质量百分比含量，包括31%的二羟甲基二羟基乙烯脲，8.2%的海藻糖，14%的三羟甲基三聚氰胺，18%的二氯异氰尿酸钠，6%的褐藻胶和5%的甘氨酸的原料；将其加入到4倍的乙醇中，搅拌混合均匀后控温80℃，反应5h后蒸干溶剂后得到。
所述的柔软剂为一种环氧改性甜菜碱柔软剂，其制备方法如下：
在高压搅拌釜中,通入氮气,加入15kg油基甜菜碱, 4.7kg3,4-环氧-1-丁烯, 5kg质量百分比浓度为12%的氯铂酸的异丙醇溶液，再加入150kg的200#溶剂油，12kg2,4,6,8-四甲基环四硅氧烷, 2.1kgN-烯丙基-N'-乙基脲，控温65℃，搅拌反应5h，减压蒸馏除去200#溶剂油，得到环氧改性甜菜碱柔软剂。
所述的第一次浸扎时间为60s。
所述的第二次浸扎时间为5min。
所述的第一次浸扎液中还含有0.6%的硅油精。
所述的第二次浸扎液中还含有0.5%的十八烷基异氰酸酯。
以上实施例制备的织物的回复角和硬挺度，其结果统计结果如下：
| 编号 | 回复角(°) | 硬挺度（cm） |
| 实施例1 | 274 | 3.86 |
| 实施例2 | 281 | 3.51 |
| 实施例3 | 285 | 3.25 |
对比例1
所述的柔软剂为一种环氧改性甜菜碱柔软剂，其制备方法如下：
在高压搅拌釜中,通入氮气,加入10kg油基甜菜碱,2kg质量百分比浓度为6%的氯铂酸的异丙醇溶液，再加入100kg的200#溶剂油，6kg2,4,6,8-四甲基环四硅氧烷, 0.5kgN-烯丙基-N'-乙基脲，控温55℃，搅拌反应2h，减压蒸馏除去200#溶剂油，得到环氧改性甜菜碱柔软剂。
其它技术方案与实施例1相同。
对比例2
所述的柔软剂为一种环氧改性甜菜碱柔软剂，其制备方法如下：
在高压搅拌釜中,通入氮气,加入10kg油基甜菜碱,3.1kg3,4-环氧-1-丁烯,2kg质量百分比浓度为6%的氯铂酸的异丙醇溶液，再加入100kg的200#溶剂油，6kg2,4,6,8-四甲基环四硅氧烷,控温55℃，搅拌反应2h，减压蒸馏除去200#溶剂油，得到环氧改性甜菜碱柔软剂。
其它技术方案与实施例1相同。
对比例3
一种具有防皱功能的强触感羊毛面料的制备方法，其具体方案为：
将75kg羊毛纤维，15kg莱卡纤维，5kg大豆蛋白纤维和14kg聚氨酯纤维混纺后得到羊毛混纺纱线，然后将得到的纱线进行第一次浸扎，轧液率为68%，完成后在80℃烘2min，然后进行第二次浸扎，轧液率为70%，完成后在80℃烘1min，然后在110℃烘干3min，完成后再安装到织机上，由织机制成面料即可；其特征在于所述的第一次浸扎液中含有质量kg数为3.4%的亚硫酸氢钠；所述的第二次浸扎液中含有0.3%的防皱剂。
所述的防皱剂按照质量百分比含量，包括23%的二羟甲基二羟基乙烯脲，4.6%的海藻糖，5%的三羟甲基三聚氰胺，12%的二氯异氰尿酸钠，2%的褐藻胶和1%的甘氨酸的原料；将其加入到1.5倍的乙醇中，搅拌混合均匀后控温60℃，反应1h后蒸干溶剂后得到。
所述的第一次浸扎时间为30s。
所述的第二次浸扎时间为1min。
所述的第一次浸扎液中还含有0.3%的硅油精。
所述的第二次浸扎液中还含有0.1%的十八烷基异氰酸酯。
以上对比例制备的织物的回复角和硬挺度，其结果统计结果如下：
| 编号 | 回复角(°) | 硬挺度（cm） |
| 对比例1 | 264 | 4.15 |
| 对比例2 | 269 | 4.38 |
| 对比例3 | 256 | 6.87 |
Claims (7)
1.一种具有防皱功能的强触感羊毛面料的制备方法，其具体方案为：
按照质量份数，将75-90份的羊毛纤维，15-32份的莱卡纤维，5-12份的大豆蛋白纤维和14-26份的聚氨酯纤维混纺后得到羊毛混纺纱线，然后将得到的纱线进行第一次浸扎，轧液率为68%-75%，完成后在80-90℃烘2-6min，然后进行第二次浸扎，轧液率为70%-85%，完成后在80-90℃烘1-3min，然后在110-130℃烘干3-6min，完成后再安装到织机上，由织机制成面料即可；其特征在于所述的第一次浸扎液中含有质量份数为3.4%-6.8%的亚硫酸氢钠和1.2%-3.4%的柔软剂；所述的第二次浸扎液中含有0.3%-0.8%的防皱剂。
2.根据权利要求1所述的一种具有防皱功能的强触感羊毛面料的制备方法，其特征在于：所述的防皱剂按照质量份，包括23%-31%的二羟甲基二羟基乙烯脲，4.6%-8.2%的海藻糖，5%-14%的三羟甲基三聚氰胺，12%-18%的二氯异氰尿酸钠，2%-6%的褐藻胶和1%-5%的甘氨酸的原料；将其加9i入到1.5-4倍的乙醇中，搅拌混合均匀后控温60-80℃，反应1-5h后蒸干溶剂后得到。
3.根据权利要求1所述的一种具有防皱功能的强触感羊毛面料的制备方法，其特征在于：所述的柔软剂为一种环氧改性甜菜碱柔软剂，其制备方法如下：
按质量份，在高压搅拌釜中,通入氮气,加入10-15份油基甜菜碱, 3.1-4.7份3,4-环氧-1-丁烯,2-5份质量百分比浓度为6-12%的氯铂酸的异丙醇溶液，再加入100-150份的200#溶剂油，6-12份2,4,6,8-四甲基环四硅氧烷, 0.5-2.1份N-烯丙基-N'-乙基脲，控温55-65℃，搅拌反应2-5h，减压蒸馏除去200#溶剂油，得到环氧改性甜菜碱柔软剂。
4.根据权利要求1所述的一种具有防皱功能的强触感羊毛面料的制备方法，其特征在于：所述的第一次浸扎时间为30-60s。
5.根据权利要求1所述的一种具有防皱功能的强触感羊毛面料的制备方法，其特征在于：所述的第二次浸扎时间为1-5min。
6.根据权利要求1所述的一种具有防皱功能的强触感羊毛面料的制备方法，其特征在于：所述的第一次浸扎液中还含有0.3%-0.6%的硅油精。
7.根据权利要求1所述的一种具有防皱功能的强触感羊毛面料的制备方法，其特征在于：所述的第二次浸扎液中还含有0.1%-0.5%的十八烷基异氰酸酯。
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| US3521997A (en) * | 1966-04-15 | 1970-07-28 | Iws Nominee Co Ltd | Continuous process for treating wool with chlorocyanurate |
| WO1996015309A2 (en) * | 1994-11-10 | 1996-05-23 | The Procter & Gamble Company | Wrinkle reducing composition |
| WO2012040131A2 (en) * | 2010-09-20 | 2012-03-29 | The Procter & Gamble Company | Fabric care formulations and methods |
| CN107287905A (zh) * | 2017-06-26 | 2017-10-24 | 苏州威尔德工贸有限公司 | 一种蚕丝织物抗皱抗菌整理方法 |
| CN110016749A (zh) * | 2019-04-30 | 2019-07-16 | 相里海霞 | 一种具有抗皱功能的羊毛制面料 |
-
2020
- 2020-10-11 CN CN202011080786.4A patent/CN112176726B/zh active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3521997A (en) * | 1966-04-15 | 1970-07-28 | Iws Nominee Co Ltd | Continuous process for treating wool with chlorocyanurate |
| WO1996015309A2 (en) * | 1994-11-10 | 1996-05-23 | The Procter & Gamble Company | Wrinkle reducing composition |
| WO2012040131A2 (en) * | 2010-09-20 | 2012-03-29 | The Procter & Gamble Company | Fabric care formulations and methods |
| CN107287905A (zh) * | 2017-06-26 | 2017-10-24 | 苏州威尔德工贸有限公司 | 一种蚕丝织物抗皱抗菌整理方法 |
| CN110016749A (zh) * | 2019-04-30 | 2019-07-16 | 相里海霞 | 一种具有抗皱功能的羊毛制面料 |
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