CN112175172B - 一种用于废水的高效吸附有机多孔材料及其制备方法 - Google Patents

一种用于废水的高效吸附有机多孔材料及其制备方法 Download PDF

Info

Publication number
CN112175172B
CN112175172B CN202011037516.5A CN202011037516A CN112175172B CN 112175172 B CN112175172 B CN 112175172B CN 202011037516 A CN202011037516 A CN 202011037516A CN 112175172 B CN112175172 B CN 112175172B
Authority
CN
China
Prior art keywords
porous material
aromatic heterocyclic
wastewater
efficient
drying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202011037516.5A
Other languages
English (en)
Other versions
CN112175172A (zh
Inventor
徐业伟
常冠军
杨莉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sichuan Guanmusiyang New Material Technology Co ltd
Original Assignee
Sichuan Guanmusiyang New Material Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sichuan Guanmusiyang New Material Technology Co ltd filed Critical Sichuan Guanmusiyang New Material Technology Co ltd
Priority to CN202011037516.5A priority Critical patent/CN112175172B/zh
Publication of CN112175172A publication Critical patent/CN112175172A/zh
Application granted granted Critical
Publication of CN112175172B publication Critical patent/CN112175172B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/125—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one oxygen atom in the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/262—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/124—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one nitrogen atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/31—Monomer units or repeat units incorporating structural elements in the main chain incorporating aromatic structural elements in the main chain
    • C08G2261/312—Non-condensed aromatic systems, e.g. benzene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
    • C08G2261/3221—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more nitrogen atoms as the only heteroatom, e.g. pyrrole, pyridine or triazole
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/324—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
    • C08G2261/3241—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing one or more nitrogen atoms as the only heteroatom, e.g. carbazole
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/324—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
    • C08G2261/3242—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing one or more oxygen atoms as the only heteroatom, e.g. benzofuran
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/324—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
    • C08G2261/3243—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing one or more sulfur atoms as the only heteroatom, e.g. benzothiophene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/45—Friedel-Crafts-type

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Analytical Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

本发明公开了一种用于废水的高效吸附有机多孔材料及其制备方法。本发明的高效吸附有机多孔材料主要针对于废水中的金属离子、有机溶剂、碘、硝基爆炸物和二氧化碳等杂质进行吸附，该吸附材料是由芳香杂环化合物通过傅克酰基化交联而成，具有吸附容量大、吸附时间短、循环使用性能好的特点。本发明提供的制备高效吸附剂方法操作简单、无需高温、成本较低、成品率高，符合实际应用的要求，适于工业推广。

Description

一种用于废水的高效吸附有机多孔材料及其制备方法
技术领域
本发明属于高分子材料技术领域，具体涉及一种用于废水的高效吸附有机多孔材料及其傅克酰基化制备方法。
背景技术
由于泄漏和排放造成的水污染以及被广泛关注的二氧化碳问题严重威胁着地球上所有生物的安全。多孔有机聚合物作为一类新型的吸附材料，具有高的比表面积和永久的孔结构。同时，由于其在合成多样性、孔径可控性和孔表面改性等方面的优势，被尝试用于金属离子、有机溶剂、碘、硝基爆炸物和二氧化碳等的高效吸附。相较于传统制备多孔有机聚合物的方法，傅克酰基化反应是一类新型、高效聚合反应的统称，具备快速高效、反应条件温和、原料廉价易得、提纯简便、产物区域选择性和立体选择性好等突出优势。
如何选择原料进行傅克酰基化反应，通过交联制备得到对金属离子、有机溶剂、碘、硝基爆炸物和二氧化碳等具有高效吸附作用的有机多孔材料，成为亟待解决的技术问题。
发明内容
本发明的目的就是为了解决上述技术问题，提供一种高效吸附有机多孔材料及其制备方法。本发明获得的吸附剂对金属离子、有机溶剂、碘、硝基爆炸物和二氧化碳等具有高效吸附作用。
本发明的目的之一是提供一种高效吸附有机多孔材料，其中，所述多孔材料包括含有苯并噻吩、苯并呋喃、苯并咪唑、吲哚或咔唑基团的芳香杂环多孔聚合物，其是通过芳香杂环化合物经傅克酰基化交联而成；其中，所述的芳香杂环化合物中至少含有以下一种基团：
具体的，本发明所述的高效吸附有机多孔材料的结构式包括以下中的任一种：
本发明的目的之二是提供上述高效吸附有机多孔材料的制备方法，其包括以下步骤：
(1)于氮气氛围下，将芳香杂环化合物、二甲氧基甲烷和无水三氯化铁添加至溶剂中；
(2)控制反应温度，进行傅克酰基化反应数小时；
(3)对步骤(2)所得物进行过滤，并用大量蒸馏水冲洗过滤后的产物，重复以上操作，直至洗至滤液无色；
(4)对过滤后所得固态产物进行干燥，得到所述高效吸附有机多孔材料。
进一步的是，步骤(1)中所述溶剂为沸点在80℃以上能溶解芳香杂环化合物的有机溶剂，其用量以将芳香杂环化合物完全溶解即可。
进一步的是，步骤(1)中所述的二甲氧基甲烷和无水三氯化铁的质量比为1:1；所述芳香杂环化合物和二甲氧基甲烷的质量比在1:2以上。
进一步的是，步骤(2)中所述的制备工艺条件为：控制温度条件80-120℃，反应时间18-36小时。
进一步的是，步骤(4)中所述的干燥工艺为真空干燥、超临界干燥或冷冻干燥。
本发明由芳香杂环化合物通过傅克酰基化反应交联制备对金属离子、有机溶剂、碘、硝基爆炸物和二氧化碳等具有高效吸附作用的有机多孔材料，该吸附剂具有吸附容量大、吸附时间短、循环使用性能好的特点。本发明的傅克酰基化制备方法操作简单、无需高温、成本较低、成品率高，符合实际应用的要求，适于工业推广。
与现有技术相比，本发明的有益效果如下：
(1)本发明提供的吸附有机多孔材料具备吸附容量大、吸附时间短、循环使用性能好的优点；
(2)本发明提供的高效吸附剂的制备方法操作简单、无需高温、成本较低、成品率高，符合实际应用的要求，适于工业推广。
具体实施方式
下面通过实施例对本发明进行具体描述，有必要在此指出的是以下实施例只是用于对本发明进行进一步的说明，不能理解为对本发明保护范围的限制，该领域的技术熟练人员根据上述发明内容所做出的一些非本质的改进和调整，仍属于本发明的保护范围。
实施例1
于氮气保护下，将摩尔比为1:3:3的苯并呋喃、甲氧基甲烷和三氯化铁加入无水1,2-二氯乙烷中，加热至80℃，持续反应18h。反应结束后，过滤收集固体产物，用大量去离子水反复洗涤固体，直至滤液无色，干燥得高效吸附剂-Ⅰ，其化学反应式如下：
高效吸附剂-Ⅰ可用于金属离子、有机溶剂、碘、硝基爆炸物和二氧化碳等的吸附，并表现出良好的循环吸附性能，重复5次后吸附能力无明显变化。
实施例2
氮气保护下，将摩尔比为1:2:2的二苯并噻吩、甲氧基甲烷和三氯化铁加入二甲基甲酰胺中，加热至100℃，持续反应24h。反应结束后，过滤收集固体产物，用大量去离子水反复洗涤固体，直至滤液无色，干燥得高效吸附剂-Ⅱ，其化学反应式如下：
高效吸附剂-Ⅱ可用于金属离子、有机溶剂、碘、硝基爆炸物和二氧化碳等的吸附，并表现出良好的循环吸附性能，重复5次后吸附能力无明显变化。
实施例3
氮气保护下，将摩尔比为1:10:10的4,4'-双(2-苯并咪唑基)二苯甲酮、甲氧基甲烷和三氯化铁加入无水1,2-二氯乙烷中，加热至120℃，持续反应36h。反应结束后，过滤收集固体产物，用大量去离子水反复洗涤固体，直至滤液无色，干燥得高效吸附剂-Ⅲ，其化学反应式如下：
高效吸附剂-Ⅲ可用于金属离子、有机溶剂、碘、硝基爆炸物和二氧化碳等的吸附，并表现出良好的循环吸附性能，重复5次后吸附能力无明显变化。
实施例4
氮气保护下，将摩尔比为1:6:6的2,4,6-三咔唑-1,3,5-三嗪、甲氧基甲烷和三氯化铁加入无水1,2-二氯乙烷中，加热至80℃，持续反应18h。反应结束后，过滤收集固体产物，用大量去离子水反复洗涤固体，直至滤液无色，干燥得高效吸附剂-Ⅳ，其化学反应式如下：
高效吸附剂-Ⅳ可用于金属离子、有机溶剂、碘、硝基爆炸物和二氧化碳等的吸附，并表现出良好的循环吸附性能，重复5次后吸附能力无明显变化。
实施例5
氮气保护下，将摩尔比为1:3:3的吲哚、甲氧基甲烷和三氯化铁加入无水1,2-二氯乙烷中，加热至80℃，持续反应18h。反应结束后，过滤收集固体产物，用大量去离子水反复洗涤固体，直至滤液无色，干燥得高效吸附剂-Ⅴ，其化学反应式如下：
高效吸附剂-Ⅴ可用于金属离子、有机溶剂、碘、硝基爆炸物和二氧化碳等的吸附，并表现出良好的循环吸附性能，重复5次后吸附能力无明显变化。
实施例6
氮气保护下，将摩尔比为1:2:2的咔唑、甲氧基甲烷和三氯化铁加入二甲基甲酰胺中，加热至100℃，持续反应24h。反应结束后，过滤收集固体产物，用大量去离子水反复洗涤固体，直至滤液无色，干燥得高效吸附剂-Ⅵ，其化学反应式如下：
高效吸附剂-Ⅵ可用于金属离子、有机溶剂、碘、硝基爆炸物和二氧化碳等的吸附，并表现出良好的循环吸附性能，重复5次后吸附能力无明显变化。
实施例7
氮气保护下，将摩尔比为1:8:8的三吲哚化合物、甲氧基甲烷和三氯化铁加入无水1,2-二氯乙烷中，加热至80℃，持续反应18h。反应结束后，过滤收集固体产物，用大量去离子水反复洗涤固体，直至滤液无色，干燥得高效吸附剂-Ⅶ，其化学反应式如下：
高效吸附剂-Ⅶ可用于金属离子、有机溶剂、碘、硝基爆炸物和二氧化碳等的吸附，并表现出良好的循环吸附性能，重复5次后吸附能力无明显变化。
实施例8
氮气保护下，将摩尔比为1:10:10的三苯并咪唑化合物、甲氧基甲烷和三氯化铁加入二甲基甲酰胺中，加热至120℃，持续反应36h。反应结束后，过滤收集固体产物，用大量去离子水反复洗涤固体，直至滤液无色，干燥得高效吸附剂-Ⅷ，其化学反应式如下：
高效吸附剂-Ⅷ可用于金属离子、有机溶剂、碘、硝基爆炸物和二氧化碳等的吸附，并表现出良好的循环吸附性能，重复5次后吸附能力无明显变化。
实施例9
氮气保护下，将摩尔比为1:3:3的氨基吲哚、甲氧基甲烷和三氯化铁加入无水1,2-二氯乙烷中，加热至80℃，持续反应18h。反应结束后，过滤收集固体产物，用大量去离子水反复洗涤固体，直至滤液无色，干燥得高效吸附剂-Ⅸ，其化学反应式如下：
高效吸附剂-Ⅸ可用于金属离子、有机溶剂、碘、硝基爆炸物和二氧化碳等的吸附，并表现出良好的循环吸附性能，重复5次后吸附能力无明显变化。
实施例10
氮气保护下，将摩尔比为1:10:10的三苯并咪唑化合物、甲氧基甲烷和三氯化铁加入二甲基甲酰胺中，加热至120℃，持续反应30h。反应结束后，过滤收集固体产物，用大量去离子水反复洗涤固体，直至滤液无色，干燥得高效吸附剂-X，其化学反应式如下：
高效吸附剂-X可用于金属离子、有机溶剂、碘、硝基爆炸物和二氧化碳等的吸附，并表现出良好的循环吸附性能，重复5次后吸附能力无明显变化。

Claims (6)

1.一种用于废水的高效吸附有机多孔材料的制备方法，其特征在于，所述多孔材料是通过芳香杂环化合物经傅克酰基化交联而成；其中，所述芳香杂环化合物为4,4'-双(2-苯并咪唑基)二苯甲酮或三苯并咪唑化合物，其具体的结构式为：
所述多孔材料是用于高效吸附废水中的金属离子、有机溶剂、碘、硝基爆炸物和二氧化碳；
所述多孔材料的制备方法包括以下步骤：
(1)于氮气氛围下，将芳香杂环化合物、二甲氧基甲烷和无水三氯化铁按照摩尔比1：10：10添加至溶剂中；
(2)控制反应温度为120℃，进行傅克酰基化反应36小时；
(3)对步骤(2)所得物进行过滤，并用蒸馏水冲洗过滤后的产物，重复以上操作，直至洗至滤液无色；
(4)对过滤后所得固态产物进行干燥，得到所述高效吸附有机多孔材料。
2.根据权利要求1所述的制备方法，其特征在于，所述多孔材料的结构式为：
3.根据权利要求1所述的制备方法，其特征在于，步骤(1)中所述溶剂为沸点在80℃以上能溶解芳香杂环化合物的有机溶剂，其用量以将芳香杂环化合物完全溶解即可。
4.根据权利要求1所述的制备方法，其特征在于，步骤(4)中所述的干燥工艺为真空干燥、超临界干燥或冷冻干燥。
5.由权利要求1-4任一项所述方法制备得到的多孔材料。
6.由权利要求1-4任一项所述方法制备得到的多孔材料在高效吸附废水中的金属离子、有机溶剂、碘、硝基爆炸物和二氧化碳中的应用。
CN202011037516.5A 2020-09-28 2020-09-28 一种用于废水的高效吸附有机多孔材料及其制备方法 Active CN112175172B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011037516.5A CN112175172B (zh) 2020-09-28 2020-09-28 一种用于废水的高效吸附有机多孔材料及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011037516.5A CN112175172B (zh) 2020-09-28 2020-09-28 一种用于废水的高效吸附有机多孔材料及其制备方法

Publications (2)

Publication Number Publication Date
CN112175172A CN112175172A (zh) 2021-01-05
CN112175172B true CN112175172B (zh) 2023-08-04

Family

ID=73944372

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011037516.5A Active CN112175172B (zh) 2020-09-28 2020-09-28 一种用于废水的高效吸附有机多孔材料及其制备方法

Country Status (1)

Country Link
CN (1) CN112175172B (zh)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115028811B (zh) * 2022-06-23 2023-08-22 西南科技大学 一种大孔径三吲哚烷基多孔化合物及其制备方法与应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102093539A (zh) * 2010-11-24 2011-06-15 华中科技大学 一种多孔聚合物材料及其制备方法
KR20120021899A (ko) * 2010-08-20 2012-03-09 한국화학연구원 다공성 유무기 혼성체, 그의 제조 방법, 그를 포함하는 흡착제 및 그의 응용
CN108940361A (zh) * 2018-08-02 2018-12-07 吉林大学 一种手性离子型多孔有机聚合物材料及其制备方法与应用
CN111266088A (zh) * 2020-01-13 2020-06-12 武汉工程大学 一种用于处理含酚废水的高效多孔吸附剂及其制备方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4401665B2 (ja) * 2003-03-20 2010-01-20 株式会社半導体エネルギー研究所 電界発光素子

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20120021899A (ko) * 2010-08-20 2012-03-09 한국화학연구원 다공성 유무기 혼성체, 그의 제조 방법, 그를 포함하는 흡착제 및 그의 응용
CN102093539A (zh) * 2010-11-24 2011-06-15 华中科技大学 一种多孔聚合物材料及其制备方法
CN108940361A (zh) * 2018-08-02 2018-12-07 吉林大学 一种手性离子型多孔有机聚合物材料及其制备方法与应用
CN111266088A (zh) * 2020-01-13 2020-06-12 武汉工程大学 一种用于处理含酚废水的高效多孔吸附剂及其制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
基于溶剂原位傅克偶联反应合成杯芳烃有机多孔网络(CalixPOF)及其染料吸附特性;邓文秀;张朝亮;刘习奎;;功能高分子学报(第01期);46-52 *

Also Published As

Publication number Publication date
CN112175172A (zh) 2021-01-05

Similar Documents

Publication Publication Date Title
CN109517211B (zh) 一种氨基类多孔聚合物及其制备方法与应用
CN112175172B (zh) 一种用于废水的高效吸附有机多孔材料及其制备方法
Wang et al. Porous organic frameworks with mesopores and [Ru (bpy) 3] 2+ ligand built-in as a highly efficient visible-light heterogeneous photocatalyst
CN110787663B (zh) 用于气体分离的高渗透率聚合物复合膜及其制备方法
CN107629222B (zh) 一种超交联聚苯胺的制备方法
CN113698579A (zh) 卟啉型共轭微孔聚合物及其合成方法和应用
CN113351186A (zh) 一种碘吸附剂的制备方法及所得产品和应用
CN110938184A (zh) 一种基于有机醛和三聚氰胺的希夫碱型生物基多孔材料及其制备方法
CN113831512B (zh) 一种多氮共轭微孔聚合物及其制备方法与应用
CN101648839A (zh) 一种溴甲基联苯化合物的绿色合成方法
CN110694598B (zh) 一种β-环糊精聚合物多孔吸附树脂及其制备方法
CN112500545A (zh) 一种片层状二维多孔共价有机骨架材料的制备方法
CN111484602B (zh) 基于1,3,6,8-四(对甲酰基苯基)芘的共轭微孔聚合物及其制备方法
CN112851944B (zh) 三嗪功能化倍半硅氧烷基杂化多孔聚合物、其制备方法及应用
CN111644160A (zh) 一种超疏水微孔聚合物吸附材料的绿色制备方法
CN113413900B (zh) 基于聚氮化碳的共聚物及其制备方法和应用
CN114349890A (zh) 一种超高交联树脂及其制备方法与应用
CN111039879B (zh) 一种含砜基三唑类化合物/聚合物及其制备方法和应用
CN109942570B (zh) 一种基于吩噻嗪的共轭微孔聚合物、制备方法和高效催化应用
CN112547027A (zh) 一种掺杂高岭土的共轭微孔聚合物复合材料的制备方法
CN109384909B (zh) 可纺丝的偶氮苯聚合物储能材料及其制备方法
CN117105990B (zh) 一种催化制备聚噻吩用催化剂及p3ht材料
CN115028811B (zh) 一种大孔径三吲哚烷基多孔化合物及其制备方法与应用
CN117106162B (zh) 一种基于三唑三嗪基共轭微孔聚合物及其应用
CN113600026B (zh) 一种基于聚乙烯醇抗污染交联型阴离子交换膜的制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant