CN112012024A - 一种再生锦纶针织面料 - Google Patents

一种再生锦纶针织面料 Download PDF

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CN112012024A
CN112012024A CN202010893419.XA CN202010893419A CN112012024A CN 112012024 A CN112012024 A CN 112012024A CN 202010893419 A CN202010893419 A CN 202010893419A CN 112012024 A CN112012024 A CN 112012024A
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regenerated nylon
regenerated
agent
speed
cotton
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姚馨馨
冯培生
过志良
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Wuxi Hanuo Textile Technology Co ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/0032—Determining dye recipes and dyeing parameters; Colour matching or monitoring
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653—Nitrogen-free carboxylic acids or their salts
    • D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82—Textiles which contain different kinds of fibres
    • D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8219—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and amide groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
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    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
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    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/38—Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

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  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
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Abstract

本发明提供了一种再生锦纶针织面料，其制得的再生锦纶针织面料绿色环保、可回收循环利用的同时，吸湿性优于再生涤纶面料，且更易染色，弹性佳，具有棉的柔肤和再生锦纶的爽滑触感。其包括20%‑40％质量分数的再生锦纶、50%‑60%质量分数的精梳棉纱和10%‑20％质量分数的氨纶；再生锦纶通过每米80‑200个空气交络与氨纶进行复合，或以每米200‑1500捻的方式与氨纶进行复合制得再生锦纶包覆丝，将所述再生锦纶包覆丝与所述精梳棉纱一隔一穿纱，采用罗纹或双罗纹组织进行编织得到毛坯，所述毛坯经过前处理、预定型、双浴染色、后整理工序得到再生锦纶针织面料。

Description

一种再生锦纶针织面料
技术领域
本发明涉及锦纶面料技术领域，具体为一种再生锦纶针织面料。
背景技术
随着社会发展的需要，作为工程塑料的尼龙材料在人类的生产生活中的应用越来越广泛，如家用器具、汽车、服装、运动器材、渔具等领域，从而产生了大量的废旧尼龙制品，对生态环境造成巨大压力。在纺织行业，涤纶再生纤维的使用以及获得普遍的认可，再生尼龙及再生锦纶纤维面料也是势在必行，是今后发展的趋势。这既节省了石油资源，大大节约了能耗，达到了生态与经济二个系统的良性循环。
发明内容
针对现在一般采用再生涤纶制作面料的问题，本发明提供了一种再生锦纶针织面料，其制得的再生锦纶针织面料绿色环保、可回收循环利用的同时，吸湿性优于再生涤纶面料，且更易染色，弹性佳，具有棉的柔肤和再生锦纶的爽滑触感。
其技术方案是这样的：一种再生锦纶针织面料，其特征在于：其包括20%-40％质量分数的再生锦纶、50%-60%质量分数的精梳棉纱和10%-20％质量分数的氨纶；所述再生锦纶通过每米80-200个空气交络与氨纶进行复合，或以每米200-1500捻的方式与氨纶进行复合制得再生锦纶包覆丝，将所述再生锦纶包覆丝与所述精梳棉纱一隔一穿纱，采用罗纹或双罗纹组织进行编织得到毛坯，所述毛坯经过前处理、预定型、双浴染色、后整理工序得到再生锦纶针织面料，所述再生锦纶针织面料的克重为200-400g/m2；所述前处理的步骤为：加入水和去油剂，浴比为1：15-1：20，以1.5-2℃/min的速度升温至70-80℃并保温15-20min，再对其进行水洗完成前处理；毛坯前处理后经定型机定型，定型温度为180-190℃；所述双浴染色的步骤为：将毛坯置入染缸中，加入水、双氧水、液体烧碱，以2-3℃/min的速度升温至95-98℃并保温18-22min，对胚布进行前处理去除棉纱中的杂质，降温到38-42℃保温8-12min，加入染色助剂和棉染料并使浴比为1：15-1：25，染色助剂包括元明粉、冰醋酸、匀染剂、释酸剂，以2-3℃/min的速度升温至118-122℃，保温10-20min，完成对棉的染色，洗去浮色后降温排水，输入PH值为6-7的清水后以3-4℃/min的速度升温至38-42℃，加入锦纶染料，元明粉、冰醋酸、匀染剂、释酸剂，然后再以2-3℃/min的速度升温至95-98℃，保温10-20min，最后使用固色剂固色，通过排水、皂洗完成染色；后整理定型时定型温度为110℃-130℃，定型速度为25-35m/min。
其进一步特征在于：
所述染色助剂包括2-3g/L的元明粉，0.4-0.6g/L的冰醋酸，1.6-1.9g/L的匀染剂和0.7-0.9g/L的释酸剂；
后整理采用亲水性柔软剂、抗静电剂、硅油。
本发明的有益效果为：用再生锦纶代替再生涤纶，制得的再生锦纶针织面料绿色环保、可回收循环利用的同时，吸湿性优于再生涤纶面料，且更易染色，弹性佳，具有棉的柔肤和再生锦纶的爽滑触感；用再生锦纶包覆丝代替氨纶面料，将氨纶包覆在再生锦纶中，不仅具有氨纶的良好弹性，同时会大大提高氨纶的耐久性，改善氨纶易老化的问题；在染色过程中控制升温速率及时间、降温速率及时间、保温速率及时间，严格控制各阶段温度，保证了染色的稳定性、面料的色牢度。
具体实施方式
实施例1：一种再生锦纶针织面料，其包括30％质量分数的再生锦纶、55%质量分数的精梳棉纱和15％质量分数的氨纶；所述再生锦纶通过每米200个空气交络与氨纶进行复合，或以每米850捻的方式与氨纶进行复合制得再生锦纶包覆丝，将所述再生锦纶包覆丝与所述精梳棉纱一隔一穿纱，采用罗纹或双罗纹组织进行编织得到毛坯，所述毛坯经过前处理、预定型、双浴染色、后整理工序得到再生锦纶针织面料，所述再生锦纶针织面料的克重为200g/m2；所述前处理的步骤为：加入水和去油剂，浴比为1：20，以1.8℃/min的速度升温至70℃并保温20min，再对其进行水洗完成前处理；毛坯前处理后经定型机定型，定型温度为185℃；所述双浴染色的步骤为：将毛坯置入染缸中，加入水、双氧水、液体烧碱，以2℃/min的速度升温至98℃并保温20min，对胚布进行前处理去除棉纱中的棉籽壳等杂质，降温到40℃保温10min，加入染色助剂和棉染料并使浴比为1：19，染色助剂包括2g/L的元明粉，0.5g/L的冰醋酸，1.8g/L的匀染剂和0.9g/L的释酸剂，以2℃/min的速度升温至120℃，保温15min，完成对棉的染色，洗去浮色后降温排水，输入pH值为6的清水后以4℃/min的速度升温至40℃，加入锦纶染料，2g/L的元明粉，0.5g/L的冰醋酸，1.8g/L的匀染剂和0.9g/L的释酸剂，然后再以2℃/min的速度升温至98℃，保温15min，最后使用固色剂固色，通过排水、皂洗完成染色；后整理定型时定型温度为120℃，定型速度为27m/min，后整理采用亲水性柔软剂、抗静电剂、硅油，使面料更为柔软同时能够抗静电。
实施例2：一种再生锦纶针织面料，其包括20%质量分数的再生锦纶、60%质量分数的精梳棉纱和20％质量分数的氨纶；所述再生锦纶通过每米110个空气交络与氨纶进行复合，或以每米200捻的方式与氨纶进行复合制得再生锦纶包覆丝，将所述再生锦纶包覆丝与所述精梳棉纱一隔一穿纱，采用罗纹或双罗纹组织进行编织得到毛坯，所述毛坯经过前处理、预定型、双浴染色、后整理工序得到再生锦纶针织面料，所述再生锦纶针织面料的克重为300g/m2；所述前处理的步骤为：加入水和去油剂，浴比为1：15，以1.5℃/min的速度升温至75℃并保温15min，再对其进行水洗完成前处理；毛坯前处理后经定型机定型，定型温度为180℃；所述双浴染色的步骤为：将毛坯置入染缸中，加入水、双氧水、液体烧碱，以3℃/min的速度升温至95℃并保温18min，对胚布进行前处理去除棉纱中的棉籽壳等杂质，降温到38℃保温12min，加入染色助剂和棉染料并使浴比为1：25，染色助剂包括2.5g/L的元明粉，0.6g/L的冰醋酸，1.6g/L的匀染剂和0.8g/L的释酸剂，以2.5℃/min的速度升温至122℃，保温10min，完成对棉的染色，洗去浮色后降温排水，输入PH值为7的清水后以3℃/min的速度升温至38℃，加入锦纶染料，2.5g/L的元明粉，0.6g/L的冰醋酸，1.6g/L的匀染剂和0.8g/L的释酸剂，然后再以3℃/min的速度升温至95℃，保温10min，最后使用固色剂固色，通过排水、皂洗完成染色；后整理定型时定型温度为130℃，定型速度为25m/min，后整理采用亲水性柔软剂、抗静电剂、硅油，使面料更为柔软同时能够抗静电。
实施例3：一种再生锦纶针织面料，其包括40％质量分数的再生锦纶、50%质量分数的精梳棉纱和10%质量分数的氨纶；所述再生锦纶通过每米80个空气交络与氨纶进行复合，或以每米1500捻的方式与氨纶进行复合制得再生锦纶包覆丝，将所述再生锦纶包覆丝与所述精梳棉纱一隔一穿纱，采用罗纹或双罗纹组织进行编织得到毛坯，所述毛坯经过前处理、预定型、双浴染色、后整理工序得到再生锦纶针织面料，所述再生锦纶针织面料的克重为400g/m2；所述前处理的步骤为：加入水和去油剂，浴比为1：17，以2℃/min的速度升温至80℃并保温17min，再对其进行水洗完成前处理；毛坯前处理后经定型机定型，定型温度为190℃；所述双浴染色的步骤为：将毛坯置入染缸中，加入水、双氧水、液体烧碱，以2.5℃/min的速度升温至96℃并保温22min，对胚布进行前处理去除棉纱中的棉籽壳等杂质，降温到42℃保温8min，加入染色助剂和棉染料并使浴比为1：15，染色助剂包括3g/L的元明粉，0.4g/L的冰醋酸，1.9g/L的匀染剂和0.7g/L的释酸剂，以3℃/min的速度升温至118℃，保温20min，完成对棉的染色，洗去浮色后降温排水，输入pH值为7的清水后以3.5℃/min的速度升温至42℃，加入锦纶染料，3g/L的元明粉，0.4g/L的冰醋酸，1.9g/L的匀染剂和0.7g/L的释酸剂，然后再以2.5℃/min的速度升温至97℃，保温20min，最后使用固色剂固色，通过排水、皂洗完成染色；后整理定型时定型温度为110℃，定型速度为25m/min，后整理采用亲水性柔软剂、抗静电剂、硅油，使面料更为柔软同时能够抗静电。
分别从实施例1、实施例2和实施例3制得的面料上裁取2.5cm*3cm的试样，并取3根长20cm宽2.5cm的棉添付白布，将试样置于棉添付白布下，在与其重叠1.5cm处两端各缝一条线，然后调配非离子界面活性剂溶液：将0.5g非离子界面活性剂溶解到1000ml的蒸馏水中，将试样的一端浸在试验溶液中2cm深, 在常温下根据各公司的基准方法放置2小时，移走溶液,让试样在原状态下自然晾干，用JIS沾色灰卡对试样进行评级，三个试样的色牢度均在4级以上。
以上，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉该技术的人在本发明所揭露的技术范围内，可轻易想到的变化或替换，都应涵盖在本发明的保护范围之内。因此，本发明的保护范围应该以权利要求的保护范围为准。

Claims (3)

1.一种再生锦纶针织面料，其特征在于：其包括20%-40％质量分数的再生锦纶、50%-60%质量分数的精梳棉纱和10%-20％质量分数的氨纶；所述再生锦纶通过每米80-200个空气交络与氨纶进行复合，或以每米200-1500捻的方式与氨纶进行复合制得再生锦纶包覆丝，将所述再生锦纶包覆丝与所述精梳棉纱一隔一穿纱，采用罗纹或双罗纹组织进行编织得到毛坯，所述毛坯经过前处理、预定型、双浴染色、后整理工序得到再生锦纶针织面料，所述再生锦纶针织面料的克重为200-400g/m2；所述前处理的步骤为：加入水和去油剂，浴比为1：15-1：20，以1.5-2℃/min的速度升温至70-80℃并保温15-20min，再对其进行水洗完成前处理；毛坯前处理后经定型机定型，定型温度为180-190℃；所述双浴染色的步骤为：将毛坯置入染缸中，加入水、双氧水、液体烧碱，以2-3℃/min的速度升温至95-98℃并保温18-22min，对胚布进行前处理去除棉纱中的杂质，降温到38-42℃保温8-12min，加入染色助剂和棉染料并使浴比为1：15-1：25，染色助剂包括元明粉、冰醋酸、匀染剂、释酸剂，以2-3℃/min的速度升温至118-122℃，保温10-20min，完成对棉的染色，洗去浮色后降温排水，输入PH值为6-7的清水后以3-4℃/min的速度升温至38-42℃，加入锦纶染料，元明粉、冰醋酸、匀染剂、释酸剂，然后再以2-3℃/min的速度升温至95-98℃，保温10-20min，最后使用固色剂固色，通过排水、皂洗完成染色；后整理定型时定型温度为110℃-130℃，定型速度为25-35m/min。
2.根据权利要求1所述的一种再生锦纶针织面料，其特征在于：所述染色助剂包括2-3g/L的元明粉，0.4-0.6g/L的冰醋酸，1.6-1.9g/L的匀染剂和0.7-0.9g/L的释酸剂。
3.根据权利要求1所述的一种再生锦纶针织面料，其特征在于：后整理采用亲水性柔软剂、抗静电剂、硅油。
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