CN111534884A - 一种阻燃纤维针织面料的加工方法 - Google Patents
一种阻燃纤维针织面料的加工方法 Download PDFInfo
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 142
- 239000003063 flame retardant Substances 0.000 title claims abstract description 142
- 239000000835 fiber Substances 0.000 title claims abstract description 108
- 239000004744 fabric Substances 0.000 title claims abstract description 71
- 238000003672 processing method Methods 0.000 title claims abstract description 20
- 238000001035 drying Methods 0.000 claims abstract description 41
- 238000002156 mixing Methods 0.000 claims abstract description 33
- 229920002972 Acrylic fiber Polymers 0.000 claims abstract description 20
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 20
- 239000000853 adhesive Substances 0.000 claims abstract description 20
- 230000001070 adhesive effect Effects 0.000 claims abstract description 20
- 239000004917 carbon fiber Substances 0.000 claims abstract description 20
- 239000003365 glass fiber Substances 0.000 claims abstract description 20
- 239000007788 liquid Substances 0.000 claims abstract description 18
- 229920000728 polyester Polymers 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 11
- 238000004806 packaging method and process Methods 0.000 claims abstract description 11
- 238000002360 preparation method Methods 0.000 claims abstract description 9
- 239000002270 dispersing agent Substances 0.000 claims description 21
- 239000004014 plasticizer Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 10
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 claims description 10
- 238000001125 extrusion Methods 0.000 claims description 10
- 238000009940 knitting Methods 0.000 claims description 10
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 10
- -1 polyethylene Polymers 0.000 claims description 10
- 238000009987 spinning Methods 0.000 claims description 10
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 5
- TXQVDVNAKHFQPP-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CO)(CO)CO TXQVDVNAKHFQPP-UHFFFAOYSA-N 0.000 claims description 5
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 5
- 238000004061 bleaching Methods 0.000 claims description 5
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 5
- 235000013539 calcium stearate Nutrition 0.000 claims description 5
- 239000008116 calcium stearate Substances 0.000 claims description 5
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical group [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 5
- 239000000347 magnesium hydroxide Substances 0.000 claims description 5
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 5
- 235000019359 magnesium stearate Nutrition 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 229920000573 polyethylene Polymers 0.000 claims description 5
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 238000004513 sizing Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- 230000002087 whitening effect Effects 0.000 claims description 5
- 230000000694 effects Effects 0.000 abstract description 13
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract description 3
- 238000000034 method Methods 0.000 description 6
- 239000004753 textile Substances 0.000 description 6
- 238000011161 development Methods 0.000 description 3
- 230000001133 acceleration Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
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- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
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Abstract
本发明公开了一种阻燃纤维针织面料的加工方法,包括以下步骤,取料、阻燃纤维的制备a、阻燃纤维的制备b、面料的初制备、阻燃整理液的制备、浸轧、烘干包装。该阻燃纤维针织面料的加工方法,通过先通过阻燃剂和具有阻燃效果的碳纤维、玻璃纤维、胶粘纤维及腈纶进行混合制备阻燃纤维,然后再由阻燃纤维针织成面料,并重新在阻燃剂制备的阻燃整理液中浸轧烘干,从而实现对针织面料的双重阻燃效果,进一步的提高了该面料的阻燃性能,使其适应大部分的使用环境;另外碳纤维、腈纶和胶粘纤维的组合,还提高了面料的强度效果,使其在制备服装时,强度更高,性价比更大,同时玻璃纤维和聚酯纤维的使用,还提高了面料的柔软效果。
Description
技术领域
本发明属于阻燃纤维针织面料技术领域,具体涉及一种阻燃纤维针织面料的加工方法。
背景技术
随着经济的发展和国家法制的健全,阻燃纺织品的推广应用必将引起全社会的重视。国外对阻燃织物的开发及研究较多,一些工业发达国家早在20世纪70年代中期就制定了纺织品的阻燃法规,而且近年来要求越来越高,规定越来越细。近年来,我国对阻燃纺织品的研究开发逐渐增多,并已取得了相当大的进展。随着城市现代化建设的加快,旅游、交通运输业的发展,以及外销纺织品需求的增加,阻燃纺织品存在着巨大的潜在市场。
目前阻燃纤维制备纺织面料的方法大多为共聚法、共混法、纤维后处理三种方法进行制备,但是这三种方法大多是单独使用,其制备的面料阻燃效果一般,对于一些要求较高的环境使用时,其会造成使用的不适,同时现有的阻燃面料,其大多只具有单一的功能,应对不同环境的使用,其还会造成其他方面的不便,影响使用感官效果,因此需要开发具有多功能的阻燃纤维针织面料。
发明内容
本发明的目的在于提供一种阻燃纤维针织面料的加工方法,以解决上述背景技术中提出的问题。
为实现上述目的,本发明提供如下技术方案:
一种阻燃纤维针织面料的加工方法,所述加工方法包括以下步骤:
S1:取料,按照配方中重量份称取碳纤维、腈纶、胶粘纤维、玻璃纤维、聚酯纤维、阻燃剂、增塑剂和分散剂;
S2:阻燃纤维的制备a,将S1中各重量份的碳纤维、腈纶、胶粘纤维、玻璃纤维和聚酯纤维混合的一起,并送入混料机内进行混合搅拌,混合完成后送入双螺杆挤出机内,并依次加入阻燃剂、增塑剂和分散剂,进行双螺杆挤出;
S3:阻燃纤维的制备b,将S2中挤出后的混合物料送入纺丝设备内,进行纺丝并纱,得到阻燃纤维;
S4:面料的初制备,将S3得到的阻燃纤维在混纺设备内,进行混纺针织,针织完成后经氧漂增白、脱水、烘干定型,得到半成品的阻燃纤维针织面料;
S5:阻燃整理液的制备,按重量份的阻燃剂和水加入到搅拌机内搅拌,制得阻燃液;
S6:浸轧,将S4得到的半成品的阻燃纤维针织面料送入S5制备的阻燃液中进行浸轧;
S7:烘干包装,将S6浸轧后的阻燃纤维针织面料放入到烘干箱中烘干,烘干完成后将得到成品阻燃纤维针织面料,并进行包装整理。
优选的,S1中,配方中碳纤维、腈纶、胶粘纤维、玻璃纤维、聚酯纤维、阻燃剂、增塑剂和分散剂所占的重量份依次为:5-10份、20-30份、15-25份、5-10份、30-50份、10-20份、6-10份、3-8份。
优选的,S1中,阻燃剂为氢氧化镁、氢氧化铝、聚磷酸和二氧化硅,且所占的重量份的比例依次为3-5:1:3.5-6:4-8。
优选的,S1中,增塑剂为为DEHP、邻苯二甲酸二丁酯和邻苯二甲酸二乙酯中的任一种,分散剂为低分子量聚乙烯蜡、无规聚丙烯、硬脂酸镁、硬脂酸钙和季戊四醇硬脂酸酯中的任一种或几种组合。
优选的,S2中,混料机内混料的温度控制在160-200℃,混料时间2-3小时,且双螺杆挤出机的挤出温度控制在145-165℃。
优选的,S2和S5中阻燃剂所占总份数的重量比为1:2-3。
优选的,S7中,在烘干箱内的烘干温度控制在65-85℃,烘干时间控制在3-5分钟。
本发明的技术效果和优点:该阻燃纤维针织面料的加工方法,通过先通过阻燃剂和具有阻燃效果的碳纤维、玻璃纤维、胶粘纤维及腈纶进行混合制备阻燃纤维,然后再由阻燃纤维针织成面料,并重新在阻燃剂制备的阻燃整理液中浸轧烘干,从而实现对针织面料的双重阻燃效果,进一步的提高了该面料的阻燃性能,使其适应大部分的使用环境;另外碳纤维、腈纶和胶粘纤维的组合,还提高了面料的强度效果,使其在制备服装时,强度更高,性价比更大,同时玻璃纤维和聚酯纤维的使用,还提高了面料的柔软效果,使面料在清洗时更加方便,提高清洗的效率,更容易被洗净,能够满足多种使用需求。
具体实施方式
下面将结合本发明的内容,对本发明中的技术方案进行清楚、完整地描述,显然,所描述的内容仅仅是本发明一部分内容,而不是全部的内容。基于本发明中的内容,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他内容,都属于本发明保护的范围。
实施例1
本发明提供了一种阻燃纤维针织面料的加工方法,所述加工方法包括以下步骤:
S1:取料,按照配方中重量份称取碳纤维、腈纶、胶粘纤维、玻璃纤维、聚酯纤维、阻燃剂、增塑剂和分散剂;
S2:阻燃纤维的制备a,将S1中各重量份的碳纤维、腈纶、胶粘纤维、玻璃纤维和聚酯纤维混合的一起,并送入混料机内进行混合搅拌,混合完成后送入双螺杆挤出机内,并依次加入阻燃剂、增塑剂和分散剂,进行双螺杆挤出;
S3:阻燃纤维的制备b,将S2中挤出后的混合物料送入纺丝设备内,进行纺丝并纱,得到阻燃纤维;
S4:面料的初制备,将S3得到的阻燃纤维在混纺设备内,进行混纺针织,针织完成后经氧漂增白、脱水、烘干定型,得到半成品的阻燃纤维针织面料;
S5:阻燃整理液的制备,按重量份的阻燃剂和水加入到搅拌机内搅拌,制得阻燃液;
S6:浸轧,将S4得到的半成品的阻燃纤维针织面料送入S5制备的阻燃液中进行浸轧;
S7:烘干包装,将S6浸轧后的阻燃纤维针织面料放入到烘干箱中烘干,烘干完成后将得到成品阻燃纤维针织面料,并进行包装整理。
具体的,S1中,配方中碳纤维、腈纶、胶粘纤维、玻璃纤维、聚酯纤维、阻燃剂、增塑剂和分散剂所占的重量份依次为:5份、20份、15份、5份、30份、10份、6份和3份。
具体的,S1中,阻燃剂为氢氧化镁、氢氧化铝、聚磷酸和二氧化硅,且所占的重量份的比例依次为3:1:3.5:4。
具体的,S1中,增塑剂为为DEHP、邻苯二甲酸二丁酯和邻苯二甲酸二乙酯中的任一种,分散剂为低分子量聚乙烯蜡、无规聚丙烯、硬脂酸镁、硬脂酸钙和季戊四醇硬脂酸酯中的任一种或几种组合。
具体的,S2中,混料机内混料的温度控制在160℃,混料时间2小时,且双螺杆挤出机的挤出温度控制在145℃。
具体的,S2和S5中阻燃剂所占总份数的重量比为1:2。
具体的,S7中,在烘干箱内的烘干温度控制在65℃,烘干时间控制在3分钟。
实施例2
一种阻燃纤维针织面料的加工方法,所述加工方法包括以下步骤:
S1:取料,按照配方中重量份称取碳纤维、腈纶、胶粘纤维、玻璃纤维、聚酯纤维、阻燃剂、增塑剂和分散剂;
S2:阻燃纤维的制备a,将S1中各重量份的碳纤维、腈纶、胶粘纤维、玻璃纤维和聚酯纤维混合的一起,并送入混料机内进行混合搅拌,混合完成后送入双螺杆挤出机内,并依次加入阻燃剂、增塑剂和分散剂,进行双螺杆挤出;
S3:阻燃纤维的制备b,将S2中挤出后的混合物料送入纺丝设备内,进行纺丝并纱,得到阻燃纤维;
S4:面料的初制备,将S3得到的阻燃纤维在混纺设备内,进行混纺针织,针织完成后经氧漂增白、脱水、烘干定型,得到半成品的阻燃纤维针织面料;
S5:阻燃整理液的制备,按重量份的阻燃剂和水加入到搅拌机内搅拌,制得阻燃液;
S6:浸轧,将S4得到的半成品的阻燃纤维针织面料送入S5制备的阻燃液中进行浸轧;
S7:烘干包装,将S6浸轧后的阻燃纤维针织面料放入到烘干箱中烘干,烘干完成后将得到成品阻燃纤维针织面料,并进行包装整理。
具体的,S1中,配方中碳纤维、腈纶、胶粘纤维、玻璃纤维、聚酯纤维、阻燃剂、增塑剂和分散剂所占的重量份依次为:8份、25份、20份、7份、40份、15份、8份和5份。
具体的,S1中,阻燃剂为氢氧化镁、氢氧化铝、聚磷酸和二氧化硅,且所占的重量份的比例依次为4:1:5:6。
具体的,S1中,增塑剂为为DEHP、邻苯二甲酸二丁酯和邻苯二甲酸二乙酯中的任一种,分散剂为低分子量聚乙烯蜡、无规聚丙烯、硬脂酸镁、硬脂酸钙和季戊四醇硬脂酸酯中的任一种或几种组合。
具体的,S2中,混料机内混料的温度控制在180℃,混料时间2.5小时,且双螺杆挤出机的挤出温度控制在150℃。
具体的,S2和S5中阻燃剂所占总份数的重量比为1:2.5。
具体的,S7中,在烘干箱内的烘干温度控制在75℃,烘干时间控制在4分钟。
实施例3
一种阻燃纤维针织面料的加工方法,所述加工方法包括以下步骤:
S1:取料,按照配方中重量份称取碳纤维、腈纶、胶粘纤维、玻璃纤维、聚酯纤维、阻燃剂、增塑剂和分散剂;
S2:阻燃纤维的制备a,将S1中各重量份的碳纤维、腈纶、胶粘纤维、玻璃纤维和聚酯纤维混合的一起,并送入混料机内进行混合搅拌,混合完成后送入双螺杆挤出机内,并依次加入阻燃剂、增塑剂和分散剂,进行双螺杆挤出;
S3:阻燃纤维的制备b,将S2中挤出后的混合物料送入纺丝设备内,进行纺丝并纱,得到阻燃纤维;
S4:面料的初制备,将S3得到的阻燃纤维在混纺设备内,进行混纺针织,针织完成后经氧漂增白、脱水、烘干定型,得到半成品的阻燃纤维针织面料;
S5:阻燃整理液的制备,按重量份的阻燃剂和水加入到搅拌机内搅拌,制得阻燃液;
S6:浸轧,将S4得到的半成品的阻燃纤维针织面料送入S5制备的阻燃液中进行浸轧;
S7:烘干包装,将S6浸轧后的阻燃纤维针织面料放入到烘干箱中烘干,烘干完成后将得到成品阻燃纤维针织面料,并进行包装整理。
具体的,S1中,配方中碳纤维、腈纶、胶粘纤维、玻璃纤维、聚酯纤维、阻燃剂、增塑剂和分散剂所占的重量份依次为:10份、30份、25份、10份、50份、20份、10份和8份。
具体的,S1中,阻燃剂为氢氧化镁、氢氧化铝、聚磷酸和二氧化硅,且所占的重量份的比例依次为5:1:6:8。
具体的,S1中,增塑剂为为DEHP、邻苯二甲酸二丁酯和邻苯二甲酸二乙酯中的任一种,分散剂为低分子量聚乙烯蜡、无规聚丙烯、硬脂酸镁、硬脂酸钙和季戊四醇硬脂酸酯中的任一种或几种组合。
具体的,S2中,混料机内混料的温度控制在200℃,混料时间3小时,且双螺杆挤出机的挤出温度控制在165℃。
具体的,S2和S5中阻燃剂所占总份数的重量比为1:3。
具体的,S7中,在烘干箱内的烘干温度控制在85℃,烘干时间控制在5分钟。
具体的,该阻燃纤维针织面料的加工方法,当配方中碳纤维、腈纶、胶粘纤维、玻璃纤维、聚酯纤维、阻燃剂、增塑剂和分散剂所占的重量份依次为:8份、25份、20份、7份、40份、15份、8份和5份时,实施例2中S2和S5中阻燃剂所占总份数的重量比为1:2.5时,其制备的阻燃纤维针织面料阻燃效果更好,更明显,能够在有双重阻燃的效果,既提高其阻燃的效果,同时还能够提高保证制备阻燃纤维面料的柔软、透气、轻薄,并具有一定的抗菌效果,能够更适应针织面料在生产中的使用。
最后应说明的是:以上所述仅为本发明的优选实施例而已,并不用于限制本发明,尽管参照前述实施例对本发明进行了详细的说明,对于本领域的技术人员来说,其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。
Claims (7)
1.一种阻燃纤维针织面料的加工方法,其特征在于:所述加工方法包括以下步骤:
S1:取料,按照配方中重量份称取碳纤维、腈纶、胶粘纤维、玻璃纤维、聚酯纤维、阻燃剂、增塑剂和分散剂;
S2:阻燃纤维的制备a,将S1中各重量份的碳纤维、腈纶、胶粘纤维、玻璃纤维和聚酯纤维混合的一起,并送入混料机内进行混合搅拌,混合完成后送入双螺杆挤出机内,并依次加入阻燃剂、增塑剂和分散剂,进行双螺杆挤出;
S3:阻燃纤维的制备b,将S2中挤出后的混合物料送入纺丝设备内,进行纺丝并纱,得到阻燃纤维;
S4:面料的初制备,将S3得到的阻燃纤维在混纺设备内,进行混纺针织,针织完成后经氧漂增白、脱水、烘干定型,得到半成品的阻燃纤维针织面料;
S5:阻燃整理液的制备,按重量份的阻燃剂和水加入到搅拌机内搅拌,制得阻燃液;
S6:浸轧,将S4得到的半成品的阻燃纤维针织面料送入S5制备的阻燃液中进行浸轧;
S7:烘干包装,将S6浸轧后的阻燃纤维针织面料放入到烘干箱中烘干,烘干完成后将得到成品阻燃纤维针织面料,并进行包装整理。
2.根据权利要求1所述的一种阻燃纤维针织面料的加工方法,其特征在于:S1中,配方中碳纤维、腈纶、胶粘纤维、玻璃纤维、聚酯纤维、阻燃剂、增塑剂和分散剂所占的重量份依次为:5-10份、20-30份、15-25份、5-10份、30-50份、10-20份、6-10份、3-8份。
3.根据权利要求1所述的一种阻燃纤维针织面料的加工方法,其特征在于:S1中,阻燃剂为氢氧化镁、氢氧化铝、聚磷酸和二氧化硅,且所占的重量份的比例依次为3-5:1:3.5-6:4-8。
4.根据权利要求1所述的一种阻燃纤维针织面料的加工方法,其特征在于:S1中,增塑剂为为DEHP、邻苯二甲酸二丁酯和邻苯二甲酸二乙酯中的任一种,分散剂为低分子量聚乙烯蜡、无规聚丙烯、硬脂酸镁、硬脂酸钙和季戊四醇硬脂酸酯中的任一种或几种组合。
5.根据权利要求1所述的一种阻燃纤维针织面料的加工方法,其特征在于:S2中,混料机内混料的温度控制在160-200℃,混料时间2-3小时,且双螺杆挤出机的挤出温度控制在145-165℃。
6.根据权利要求1所述的一种阻燃纤维针织面料的加工方法,其特征在于:S2和S5中阻燃剂所占总份数的重量比为1:2-3。
7.根据权利要求1所述的一种阻燃纤维针织面料的加工方法,其特征在于:S7中,在烘干箱内的烘干温度控制在65-85℃,烘干时间控制在3-5分钟。
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CN113174687A (zh) * | 2021-04-20 | 2021-07-27 | 石狮雍仓织造有限公司 | 一种多层阻燃透气针织面料及其制备方法 |
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CN113174687A (zh) * | 2021-04-20 | 2021-07-27 | 石狮雍仓织造有限公司 | 一种多层阻燃透气针织面料及其制备方法 |
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