CN111419774B - High-moisture-retention facial mask based on cellulose fibers and preparation method thereof - Google Patents
High-moisture-retention facial mask based on cellulose fibers and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a high-moisture-retention facial mask based on cellulose fibers and a preparation method thereof, wherein the moisture-retention facial mask comprises modified facial mask base cloth and facial mask base liquid, and the facial mask base liquid comprises the following raw materials: 8-10 parts of sodium hyaluronate, 8-12 parts of carbomer, 6-8 parts of antimicrobial peptide, 3-4 parts of N, N-dicyclohexylcarbodiimide, 10-15 parts of triethanolamine, 8-10 parts of glycerol, 3-5 parts of collagen, 4-7 parts of sodium methylparaben and 6-8 parts of a traditional Chinese medicine additive. The modified mask base cloth is prepared by processing mask base cloth, isopropanol, sodium hydroxide, tetramethylammonium hydroxide, propylene oxide and glucose oxidase. The moisture mask has the advantages that the process design is reasonable, the component proportion is proper, the prepared moisture mask has excellent effects of moisturizing and skin moistening, has an excellent antibacterial effect, can inhibit the growth of microorganisms on the surface of the skin, avoids the occurrence of acne and is good in practicability.
Description
Technical Field
The invention relates to the technical field of masks, in particular to a high-moisture mask based on cellulose fibers and a preparation method thereof.
Background
The moisturizing mask is a mask for moisturizing human skin, and is used for moisturizing and improving the skin state aiming at the adverse states of skin tightness, dryness, itching and the like. The moisture mask has various types, including a face mask, a cream milky mask, a mud mask, a jelly or jelly mask, a wash-free mask and a tear-off mask. The moisture mask comprises humectant, antiseptic, whitening component, plant extract component, soothing component, viscosity regulator, pH regulator, etc.
Nowadays, modern's rhythm of life is more and more fast, and pressure is also more and more big, sleeps not well to have become the phenomenon that modern often had, adds to add people and is in the air conditioning environment for a long time, and in the environment, the skin lack of water is serious, and skin is ageing very easily, also becomes the focus of our research gradually to the moisturizing problem of skin, and the moisturizing effect of current moisturizing facial mask can't satisfy our demand.
In order to solve the situation, a high-moisture mask based on cellulose fibers and a preparation method thereof are designed, which are one of the problems to be solved urgently.
Disclosure of Invention
The invention aims to provide a high-moisture mask based on cellulose fibers and a preparation method thereof, and aims to solve the problems in the prior art.
In order to achieve the purpose, the invention provides the following technical scheme:
the high-moisturizing facial mask based on the cellulose fibers comprises modified facial mask base cloth and facial mask base liquid, wherein the facial mask base liquid comprises the following raw materials: 8-10 parts of sodium hyaluronate, 8-12 parts of carbomer, 6-8 parts of antimicrobial peptide, 3-4 parts of N, N-dicyclohexylcarbodiimide, 10-15 parts of triethanolamine, 8-10 parts of glycerol, 3-5 parts of collagen, 4-7 parts of sodium methylparaben and 6-8 parts of a traditional Chinese medicine additive.
According to an optimized scheme, the modified mask base cloth is prepared by processing mask base cloth, isopropanol, sodium hydroxide, tetramethylammonium hydroxide, propylene oxide and glucose oxidase.
According to an optimized scheme, the mask base cloth comprises the following raw materials: 8-14 parts of chitosan fiber, 10-15 parts of viscose fiber, 6-8 parts of silk fiber and 10-14 parts of first fiber.
According to an optimized scheme, the traditional Chinese medicine additive comprises tremella, safflower and asparagus, wherein the mass ratio of the tremella to the safflower to the asparagus is 1: 1: (1-1.5).
According to an optimized scheme, the antibacterial peptide is prepared by treating pepper seed protein and pepsin.
According to an optimized scheme, the preparation method of the high-moisture mask based on the cellulose fibers comprises the following steps:
1) preparing materials;
2) preparing a mask base cloth:
a) dissolving sodium alginate in distilled water, stirring, standing, continuously stirring, filtering, and defoaming under vacuum to obtain spinning solution;
b) taking spinning solution, carrying out wet spinning, treating in calcium chloride coagulation bath, washing with water, and carrying out traction drying to obtain first fibers;
c) taking chitosan fibers, viscose fibers, silk fibers and first fibers, carding, lapping, and carrying out spunlace reinforcement to obtain a mask base fabric;
3) preparation of antibacterial peptide: taking pepper seed protein and pepsin, and carrying out enzymolysis to obtain the antibacterial peptide.
4) Preparation of the traditional Chinese medicine additive: taking tremella, safflower and asparagus, and preparing a traditional Chinese medicine additive;
5) dissolving N, N-dicyclohexylcarbodiimide in absolute ethyl alcohol, and stirring to obtain a solution A; mixing glycerol, collagen and sodium methyl hydroxybenzoate, stirring, heating to 40-45 deg.C, and stirring to obtain solution B;
6) placing the mask base cloth in a sodium hydroxide solution, standing at-15 ℃, adding isopropanol, stirring, adding tetramethylammonium hydroxide, continuing stirring, adding propylene oxide, stirring and refluxing for 5-6h at 45-50 ℃, adjusting the pH, adding glucose oxidase at 35-45 ℃, reacting for 2-4h, heating to inactivate enzyme, cooling to room temperature, washing with water, and drying in vacuum to obtain the modified mask base cloth;
7) taking modified mask base cloth, placing the modified mask base cloth in a hydrogen chloride solution, soaking, eluting with ethanol to neutrality, taking out, placing in a mixed solution of ethanol and sodium hydroxide, continuing to soak, adding sodium hyaluronate, carbomer and antibacterial peptide, stirring, adjusting pH, slowly adding the solution A at 60-70 ℃, reacting for 1-2.5h, adding the solution B and triethanolamine, continuing to stir, then adding a traditional Chinese medicine additive, stirring, and drying to obtain the moisturizing mask.
The optimized scheme comprises the following steps:
1) preparing materials;
2) preparing a mask base cloth:
a) dissolving sodium alginate in distilled water, stirring for 10-20min, standing for 3-3.5 hr, stirring for 4-4.2 hr, filtering, and defoaming under vacuum to obtain spinning solution;
b) taking spinning solution, carrying out wet spinning, treating in calcium chloride coagulation bath for 30-40min, washing with water, and carrying out traction drying to obtain a first fiber;
c) taking chitosan fibers, viscose fibers, silk fibers and first fibers, carding, lapping, and carrying out spunlace reinforcement to obtain a mask base fabric;
3) preparation of antibacterial peptide: taking pepper seed protein and pepsin, and carrying out enzymolysis to obtain the antibacterial peptide.
4) Preparation of the traditional Chinese medicine additive: taking tremella, safflower and asparagus, and preparing a traditional Chinese medicine additive;
5) dissolving N, N-dicyclohexylcarbodiimide in absolute ethyl alcohol, and stirring for 5-10min to obtain a solution A; mixing glycerol, collagen and sodium methyl hydroxybenzoate, stirring for 8-12min, heating to 40-45 deg.C, and stirring for 10-20min to obtain solution B;
6) placing the mask base cloth in a sodium hydroxide solution, standing at-15 ℃ for 3-4h, adding isopropanol, stirring for 30-40min, adding tetramethylammonium hydroxide, continuing stirring for 1-1.5h, then adding propylene oxide, stirring and refluxing at 45-50 ℃ for 5-6h, adjusting the pH to 4-6, adding glucose oxidase at 35-45 ℃, reacting for 2-4h, heating to inactivate enzyme, cooling to room temperature, washing for 3-5 times, and drying in vacuum to obtain a modified mask base cloth;
7) placing the modified mask base cloth into a hydrogen chloride solution, soaking for 30-40min, eluting with ethanol to neutrality, taking out, placing into a mixed solution of ethanol and sodium hydroxide, continuing to soak for 1-1.5h, adding sodium hyaluronate, carbomer and antibacterial peptide, stirring for 10-12min, adjusting pH to 5-5.5, slowly adding the solution A at 60-70 ℃, reacting for 1-2.5h, adding the solution B and triethanolamine, continuing to stir for 20-30min, then adding a traditional Chinese medicine additive, stirring for 10-15min, and drying to obtain the moisturizing mask.
In the optimized scheme, in the step 4), the preparation method of the traditional Chinese medicine additive comprises the following steps: pulverizing Tremella, Carthami flos and radix asparagi, stirring for 10-15min, soaking in distilled water for 1-2 hr, decocting for 1-2 hr, and filtering to obtain Chinese medicinal additive.
In an optimized scheme, in the step 3), the preparation method of the antibacterial peptide comprises the following steps: dissolving pepper seed protein in distilled water, heating to 30-35 ℃ in water bath, adding pepsin, reacting for 3-3.5h, heating to 90 ℃ in water bath to inactivate enzyme, cooling, centrifuging for 10-15min at 8500r/min of 8000-.
In an optimized scheme, in the step 2), the vacuum defoaming time is 15-18 h.
Compared with the prior art, the invention has the beneficial effects that:
the invention discloses a high-moisture mask based on cellulose fibers and a preparation method thereof, wherein the mask comprises modified mask base cloth and mask base liquid, the facial mask base solution comprises sodium hyaluronate, carbomer, antibacterial peptide, traditional Chinese medicine additives and the like, wherein the antibacterial peptide is prepared by processing semen Zanthoxyli protein and pepsin, the semen Zanthoxyli protein is an active peptide with antibacterial, antioxidant and blood pressure lowering functions, and can be hydrolyzed by pepsin to obtain antibacterial peptide, the antibacterial peptide has certain inhibiting effect on Escherichia coli, Propionibacterium acnes and Pseudomonas aeruginosa, can improve antibacterial property of the moisture mask, the antibacterial peptide can not only ensure the shelf life of the moisture mask and avoid the moisture mask from being polluted by microorganisms, but also can be used on the face, also can carry out bacteriostasis and sterilization to the microorganism of the face, ensure the cleanness of the face and avoid the occurrence of the situations of pox, acne and the like.
The invention also adds traditional Chinese medicine additives which comprise tremella, safflower and asparagus, the tremella, safflower and asparagus are decocted to obtain the traditional Chinese medicine additives, wherein the asparagus contains various saponins, fructose and amino acid, and can activate skin cells and keep skin moist, smooth and elastic; the tremella contains various polysaccharides, fatty acids and phospholipids, can enhance the water retention function of the skin, activate collagen of a dermis layer, and can effectively delay skin aging; the safflower can enhance the functions of antioxidation and damage resistance of the skin, and the traditional Chinese medicine additive is obtained by compounding the safflower, the tremella and the asparagus, can effectively supplement the skin moisture, and has excellent moisturizing and moistening effects.
When the mask base fabric is prepared, the first fiber (sodium alginate fiber) is prepared by utilizing a sodium alginate wet spinning method, then the sodium alginate fiber, the chitosan fiber, the viscose fiber and the silk fiber are carded, woven and laid, and the spunlace treatment is further carried out for reinforcement, so that the mask base fabric is obtained.
After the mask base cloth is prepared, the mask base cloth is modified, chitosan fibers in the mask base cloth are modified in a hydroxypropylation mode by utilizing components such as isopropanol, tetramethylammonium hydroxide and propylene oxide, so that a large number of hydrophilic groups such as hydroxyl groups and amino groups exist on the surface of the mask base cloth, the water absorption performance of the mask is further improved, meanwhile, viscose fibers in the mask base cloth are oxidized by utilizing Glucose Oxidase (GOD) to prepare carboxylated viscose fibers, finally, N-Dicyclohexylcarbodiimide (DCC) is used as a cross-linking agent to prepare the modified mask base cloth, and N, N-dicyclohexylcarbodiimide antibacterial peptide can be grafted to the surface of the mask base cloth subsequently, so that the antibacterial property and the moisture retention property of the mask base cloth are further improved, and the water replenishing effect of the mask on the skin is improved.
The skin care product is added with the sodium hyaluronate, the carbomer and the collagen, wherein the sodium hyaluronate has an excellent moisturizing effect on skin, can permeate into the epidermis layer of the skin and promote the supply of skin nutrition and the excretion of waste, thereby preventing skin aging and playing a role in maintaining beauty and keeping young; the substance can promote proliferation and differentiation of epidermal cells, scavenge oxygen free radicals, promote skin regeneration of injured parts, promote blood circulation, and has skin caring and wrinkle removing effects; collagen is a biological polymer substance, and can supplement nutrients required by each layer of skin, enhance collagen activity in skin, and has effects of moistening skin, delaying aging, caring skin, removing wrinkle, and nourishing hair.
The invention discloses a high-moisture-retention facial mask based on cellulose fibers and a preparation method thereof, the process design is reasonable, the component proportion is proper, the prepared moisture-retention facial mask has excellent effects of moisturizing and skin moistening, and the moisture-retention facial mask also has excellent antibacterial effect, can inhibit the growth of microorganisms on the surface of the skin, avoids the occurrence of acne, and has better practicability.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
s1: preparing the material
S2: preparing a mask base cloth:
dissolving sodium alginate in distilled water, stirring for 10min, standing for 3h, continuing stirring for 4h, filtering, and defoaming in vacuum for 15h to obtain a spinning solution; taking spinning solution, carrying out wet spinning, treating in calcium chloride coagulation bath for 30min, washing with water, and carrying out traction drying to obtain first fibers; taking chitosan fibers, viscose fibers, silk fibers and first fibers, carding, lapping, and carrying out spunlace reinforcement to obtain a mask base fabric;
s3: preparation of antibacterial peptide:
dissolving semen Zanthoxyli protein with distilled water, heating in water bath to 30 deg.C, adding pepsin, reacting for 3 hr, heating to 90 deg.C, inactivating enzyme in water bath, cooling, centrifuging at 8000r/min for 10min, collecting supernatant, adjusting pH to neutral, and vacuum freeze drying to obtain antibacterial peptide.
S4: preparation of the traditional Chinese medicine additive:
pulverizing Tremella, Carthami flos and radix asparagi, stirring for 10min, soaking in distilled water for 1 hr, decocting for 1 hr, and filtering to obtain Chinese medicinal additive.
S5: dissolving N, N-dicyclohexylcarbodiimide in absolute ethyl alcohol, and stirring for 5min to obtain a solution A; mixing glycerol, collagen and sodium methyl hydroxybenzoate, stirring for 8min, heating to 40 deg.C, and stirring for 10min to obtain solution B;
placing the mask base cloth in a sodium hydroxide solution, standing at-15 ℃ for 3h, adding isopropanol, stirring for 30min, adding tetramethylammonium hydroxide, continuing stirring for 1h, adding propylene oxide, stirring and refluxing at 45 ℃ for 5h, adjusting the pH to 4, adding glucose oxidase at 35 ℃, reacting for 2h, heating to inactivate enzyme, cooling to room temperature, washing for 3 times, and drying in vacuum to obtain a modified mask base cloth;
taking the modified mask base cloth, placing the modified mask base cloth in a hydrogen chloride solution, soaking for 30min, eluting with ethanol to neutrality, taking out, placing in a mixed solution of ethanol and sodium hydroxide, continuing to soak for 1h, adding sodium hyaluronate, carbomer and antibacterial peptide, stirring for 10min, adjusting the pH to 5, slowly adding the solution A at 60 ℃, reacting for 1h, adding the solution B and triethanolamine, continuing to stir for 20min, then adding the traditional Chinese medicine additive, stirring for 10min, and drying to obtain the moisturizing mask.
In this embodiment, the moisture mask includes a modified mask base cloth and a mask base solution, and the mask base solution includes the following raw materials: 8 parts of sodium hyaluronate, 8 parts of carbomer, 6 parts of antibacterial peptide, 3 parts of N, N-dicyclohexylcarbodiimide, 10 parts of triethanolamine, 8 parts of glycerol, 3 parts of collagen, 4 parts of sodium methylparaben and 6 parts of a traditional Chinese medicine additive.
The mask base cloth comprises the following raw materials: 8 parts of chitosan fiber, 10 parts of viscose fiber, 6 parts of silk fiber and 10 parts of first fiber by weight; the traditional Chinese medicine additive comprises white fungus, safflower and asparagus, wherein the mass ratio of the white fungus to the safflower to the asparagus is 1: 1: 1.
example 2:
s1: preparing the material
S2: preparing a mask base cloth:
dissolving sodium alginate in distilled water, stirring for 15min, standing for 3.2h, continuing stirring for 4.1h, filtering, and defoaming in vacuum for 17h to obtain a spinning solution; taking spinning solution, carrying out wet spinning, treating in calcium chloride coagulation bath for 35min, washing with water, and carrying out traction drying to obtain first fibers; taking chitosan fibers, viscose fibers, silk fibers and first fibers, carding, lapping, and carrying out spunlace reinforcement to obtain a mask base fabric;
s3: preparation of antibacterial peptide:
dissolving semen Zanthoxyli protein in distilled water, heating to 32 deg.C in water bath, adding pepsin, reacting for 3.2 hr, heating to 90 deg.C in water bath to inactivate enzyme, cooling, centrifuging at 8200r/min for 13min, collecting supernatant, adjusting pH to neutral, and vacuum freeze drying to obtain antibacterial peptide.
S4: preparation of the traditional Chinese medicine additive:
pulverizing Tremella, Carthami flos and radix asparagi, stirring for 14min, soaking in distilled water for 1.5 hr, decocting for 1.5 hr, and filtering to obtain Chinese medicinal additive.
S5: dissolving N, N-dicyclohexylcarbodiimide in absolute ethyl alcohol, and stirring for 8min to obtain a solution A; mixing glycerol, collagen and sodium methyl hydroxybenzoate, stirring for 10min, heating to 42 deg.C, and stirring for 15min to obtain solution B;
placing the mask base cloth in a sodium hydroxide solution, standing at-15 ℃, keeping standing for 3.5h, adding isopropanol, stirring for 35min, adding tetramethylammonium hydroxide, continuing to stir for 1.2h, then adding propylene oxide, stirring and refluxing for 5.5h at 48 ℃, adjusting the pH to 5, adding glucose oxidase at 40 ℃, reacting for 3h, heating to inactivate enzyme, cooling to room temperature, washing for 4 times, and drying in vacuum to obtain a modified mask base cloth;
taking the modified mask base cloth, placing the modified mask base cloth in a hydrogen chloride solution, soaking for 35min, eluting with ethanol to neutrality, taking out, placing in a mixed solution of ethanol and sodium hydroxide, continuing to soak for 1.2h, adding sodium hyaluronate, carbomer and antibacterial peptide, stirring for 11min, adjusting the pH value to 5, slowly adding the solution A at 65 ℃, reacting for 1.5h, adding the solution B and triethanolamine, continuing to stir for 25min, then adding a traditional Chinese medicine additive, stirring for 12min, and drying to obtain the moisturizing mask.
In this embodiment, the moisture mask includes a modified mask base cloth and a mask base solution, and the mask base solution includes the following raw materials: by weight, 9 parts of sodium hyaluronate, 10 parts of carbomer, 7 parts of antimicrobial peptide, 3.5 parts of N, N-dicyclohexylcarbodiimide, 13 parts of triethanolamine, 9 parts of glycerol, 4 parts of collagen, 6 parts of sodium methylparaben and 7 parts of a traditional Chinese medicine additive.
The mask base cloth comprises the following raw materials: by weight, 12 parts of chitosan fiber, 13 parts of viscose fiber, 7 parts of silk fiber and 13 parts of first fiber; the traditional Chinese medicine additive comprises white fungus, safflower and asparagus, wherein the mass ratio of the white fungus to the safflower to the asparagus is 1: 1: 1.2.
example 3:
s1: preparing the material
S2: preparing a mask base cloth:
dissolving sodium alginate in distilled water, stirring for 20min, standing for 3.5h, continuing stirring for 4.2h, filtering, and defoaming in vacuum for 18h to obtain a spinning solution; taking spinning solution, carrying out wet spinning, treating in calcium chloride coagulation bath for 40min, washing with water, and carrying out traction drying to obtain first fibers; taking chitosan fibers, viscose fibers, silk fibers and first fibers, carding, lapping, and carrying out spunlace reinforcement to obtain a mask base fabric;
s3: preparation of antibacterial peptide:
dissolving semen Zanthoxyli protein in distilled water, heating to 35 deg.C in water bath, adding pepsin, reacting for 3.5 hr, heating to 90 deg.C in water bath to inactivate enzyme, cooling, centrifuging at 8500r/min for 15min, collecting supernatant, adjusting pH to neutral, and vacuum freeze drying to obtain antibacterial peptide.
S4: preparation of the traditional Chinese medicine additive:
pulverizing Tremella, Carthami flos and radix asparagi, stirring for 15min, soaking in distilled water for 2 hr, decocting for 2 hr, and filtering to obtain Chinese medicinal additive.
S5: dissolving N, N-dicyclohexylcarbodiimide in absolute ethyl alcohol, and stirring for 10min to obtain a solution A; mixing glycerol, collagen and sodium methyl hydroxybenzoate, stirring for 12min, heating to 45 deg.C, and stirring for 20min to obtain solution B;
placing the mask base cloth in a sodium hydroxide solution, standing at-15 ℃ for 4h, adding isopropanol, stirring for 40min, adding tetramethylammonium hydroxide, continuing stirring for 1.5h, then adding propylene oxide, stirring and refluxing at 50 ℃ for 6h, adjusting the pH to 6, adding glucose oxidase at 45 ℃, reacting for 4h, heating to inactivate enzyme, cooling to room temperature, washing for 5 times, and drying in vacuum to obtain a modified mask base cloth;
taking the modified mask base cloth, placing the modified mask base cloth in a hydrogen chloride solution, soaking for 40min, eluting with ethanol to neutrality, taking out, placing in a mixed solution of ethanol and sodium hydroxide, continuing to soak for 1.5h, adding sodium hyaluronate, carbomer and antibacterial peptide, stirring for 12min, adjusting the pH to 5.5, slowly adding the solution A at 70 ℃, reacting for 2.5h, adding the solution B and triethanolamine, continuing to stir for 30min, then adding a traditional Chinese medicine additive, stirring for 15min, and drying to obtain the moisturizing mask.
In this embodiment, the moisture mask includes a modified mask base cloth and a mask base solution, and the mask base solution includes the following raw materials: by weight, 10 parts of sodium hyaluronate, 12 parts of carbomer, 8 parts of antibacterial peptide, 4 parts of N, N-dicyclohexylcarbodiimide, 15 parts of triethanolamine, 10 parts of glycerol, 5 parts of collagen, 7 parts of sodium methylparaben and 8 parts of a traditional Chinese medicine additive.
The mask base cloth comprises the following raw materials: by weight, 14 parts of chitosan fiber, 15 parts of viscose fiber, 8 parts of silk fiber and 14 parts of first fiber; the traditional Chinese medicine additive comprises white fungus, safflower and asparagus, wherein the mass ratio of the white fungus to the safflower to the asparagus is 1: 1: 1.5.
comparative example 1:
s1: preparing the material
S2: preparing a mask base cloth:
dissolving sodium alginate in distilled water, stirring for 15min, standing for 3.2h, continuing stirring for 4.1h, filtering, and defoaming in vacuum for 17h to obtain a spinning solution; taking spinning solution, carrying out wet spinning, treating in calcium chloride coagulation bath for 35min, washing with water, and carrying out traction drying to obtain first fibers; taking chitosan fibers, viscose fibers, silk fibers and first fibers, carding, lapping, and carrying out spunlace reinforcement to obtain a mask base fabric;
s3: preparation of antibacterial peptide:
dissolving semen Zanthoxyli protein in distilled water, heating to 32 deg.C in water bath, adding pepsin, reacting for 3.2 hr, heating to 90 deg.C in water bath to inactivate enzyme, cooling, centrifuging at 8200r/min for 13min, collecting supernatant, adjusting pH to neutral, and vacuum freeze drying to obtain antibacterial peptide.
S4: dissolving N, N-dicyclohexylcarbodiimide in absolute ethyl alcohol, and stirring for 8min to obtain a solution A; mixing glycerol, collagen and sodium methyl hydroxybenzoate, stirring for 10min, heating to 42 deg.C, and stirring for 15min to obtain solution B;
placing the mask base cloth in a sodium hydroxide solution, standing at-15 ℃, keeping standing for 3.5h, adding isopropanol, stirring for 35min, adding tetramethylammonium hydroxide, continuing to stir for 1.2h, then adding propylene oxide, stirring and refluxing for 5.5h at 48 ℃, adjusting the pH to 5, adding glucose oxidase at 40 ℃, reacting for 3h, heating to inactivate enzyme, cooling to room temperature, washing for 4 times, and drying in vacuum to obtain a modified mask base cloth;
taking the modified mask base cloth, placing the modified mask base cloth in a hydrogen chloride solution, soaking for 35min, eluting with ethanol to neutrality, taking out, placing in a mixed solution of ethanol and sodium hydroxide, continuing to soak for 1.2h, adding sodium hyaluronate, carbomer and antimicrobial peptide, stirring for 11min, adjusting the pH value to 5, slowly adding the solution A at 65 ℃, reacting for 1.5h, adding the solution B and triethanolamine, continuing to stir for 25min, and drying to obtain the moisturizing mask.
In this embodiment, the moisture mask includes a modified mask base cloth and a mask base solution, and the mask base solution includes the following raw materials: by weight, 9 parts of sodium hyaluronate, 10 parts of carbomer, 7 parts of antimicrobial peptide, 3.5 parts of N, N-dicyclohexylcarbodiimide, 13 parts of triethanolamine, 9 parts of glycerol, 4 parts of collagen and 6 parts of sodium methylparaben.
The mask base cloth comprises the following raw materials: by weight, 12 parts of chitosan fiber, 13 parts of viscose fiber, 7 parts of silk fiber and 13 parts of first fiber.
Comparative example 2:
s1: preparing the material
S2: preparing a mask base cloth:
dissolving sodium alginate in distilled water, stirring for 15min, standing for 3.2h, continuing stirring for 4.1h, filtering, and defoaming in vacuum for 17h to obtain a spinning solution; taking spinning solution, carrying out wet spinning, treating in calcium chloride coagulation bath for 35min, washing with water, and carrying out traction drying to obtain first fibers; taking chitosan fibers, viscose fibers, silk fibers and first fibers, carding, lapping, and carrying out spunlace reinforcement to obtain a mask base fabric;
s3: dissolving N, N-dicyclohexylcarbodiimide in absolute ethyl alcohol, and stirring for 8min to obtain a solution A; mixing glycerol, collagen and sodium methyl hydroxybenzoate, stirring for 10min, heating to 42 deg.C, and stirring for 15min to obtain solution B;
placing the mask base cloth in a sodium hydroxide solution, standing at-15 ℃, keeping standing for 3.5h, adding isopropanol, stirring for 35min, adding tetramethylammonium hydroxide, continuing to stir for 1.2h, then adding propylene oxide, stirring and refluxing for 5.5h at 48 ℃, adjusting the pH to 5, adding glucose oxidase at 40 ℃, reacting for 3h, heating to inactivate enzyme, cooling to room temperature, washing for 4 times, and drying in vacuum to obtain a modified mask base cloth;
and (2) placing the modified mask base cloth into a hydrogen chloride solution, soaking for 35min, eluting with ethanol to neutrality, taking out, placing into a mixed solution of ethanol and sodium hydroxide, continuing to soak for 1.2h, adding sodium hyaluronate and carbomer, stirring for 11min, then adding solution B and triethanolamine, continuing to stir for 25min, and drying to obtain the moisturizing mask.
In this embodiment, the moisture mask includes a modified mask base cloth and a mask base solution, and the mask base solution includes the following raw materials: by weight, 9 parts of sodium hyaluronate, 10 parts of carbomer, 13 parts of triethanolamine, 9 parts of glycerol, 4 parts of collagen and 6 parts of sodium methylparaben.
The mask base cloth comprises the following raw materials: by weight, 12 parts of chitosan fiber, 13 parts of viscose fiber, 7 parts of silk fiber and 13 parts of first fiber.
Experiment:
1. and (3) safety testing:
50 healthy female volunteers of 20-30 years old without allergic history were selected and divided into 5 groups of 10 persons each, and the mask samples prepared in examples 1-3 and comparative examples 1-2 were tested, respectively. All subjects had signed an informed consent.
In the test, the left forearm of the subject was used as the test site, the mask sample was applied 1 time a day, gently massaged with a finger until complete absorption, and the skin reaction after 24 hours was observed using the right forearm itself as a blank control.
As a result: after detection, the product has good smell and stability, all subjects have no abnormal phenomena such as erythema and the like, and the result is still free of any reaction after continuous observation for 3-4 days, which indicates that the moisturizing mask prepared by the technical scheme is safe.
2. Moisture retention test:
60 healthy female volunteers without allergic history of 20-30 years old were selected and divided into 6 groups of 10 persons, and the mask samples prepared in examples 1-3, the mask samples prepared in comparative examples 1-2, and a commercially available conventional mask were tested, respectively, and all subjects had signed informed consent.
During testing, the inner area of the left forearm of a subject is used as a tested part, the tested part is cleaned by clean water before testing and is stabilized for 30min before testing, the testing temperature is 20-25 ℃, the relative humidity is 50-60%, after the inner sides of the left forearm and the right forearm are respectively coated with a mask sample for 15min, the mask is taken down, the moisture percentage content of each part in 0, 60 and 120min is measured by an intelligent moisture tester, and the test is repeated for 5 times every time to obtain the average value.
The specific data are shown in the following table:
as a result: examples 1 to 3 are masks prepared according to the technical scheme of the present application, and no traditional Chinese medicine additive is added in comparative example 1, and no antibacterial peptide and no traditional Chinese medicine additive are added in comparative example 2.
As can be seen from the above table, the mask samples prepared in the present application have excellent moisturizing and moistening effects, while the moisturizing effects of the masks prepared in comparative examples 1 and 2 are significantly inferior to the solutions disclosed in the present application, and meanwhile, the moisturizing effects of the mask samples prepared in comparative examples 1 and 2 are also significantly superior to those of conventional masks purchased in the market.
3. And (3) testing the antibacterial performance:
taking the mask samples prepared in the examples 1-3, the comparative example 1 and the comparative example 2, and respectively carrying out bacteriostasis tests by using escherichia coli, propionibacterium acnes and pseudomonas aeruginosa, wherein the specific test method comprises the following steps:
and (4) taking a facial mask sample, and carrying out a bacteriostatic test after degerming. Inoculating test bacteria in LB liquid culture medium, culturing at 37 deg.C for 24 hr, collecting the filtered and sterilized facial mask sample, adding LB culture medium and bacterial suspension (bacterial suspension concentration is 10)3CFU/mL), mixing, incubating for 1h at 37 ℃ and 150r/min in a shaking table, placing on a solid medium plate, culturing overnight at 37 ℃, calculating the number of colonies, and calculating the bacteriostasis rate.
The specific data are as follows:
| item | Example 1 | Example 2 | Example 3 | Comparative example 1 | Comparative example 2 |
| Bacteriostasis rate (Escherichia coli) | 99.2％ | 99.2％ | 99.1％ | 99％ | 65％ |
| Bacteriostasis rate (Propionibacterium acnes) | 98.3％ | 98.1％ | 98.4％ | 97.8％ | 68％ |
| Bacteriostasis rate (Pseudomonas aeruginosa) | 98.1％ | 98.2％ | 98.2％ | 97.7％ | 67.3％ |
As a result: examples 1 to 3 are masks prepared according to the technical scheme of the present application, and no traditional Chinese medicine additive is added in comparative example 1, and no antibacterial peptide and no traditional Chinese medicine additive are added in comparative example 2.
As can be seen from the above table, the mask samples prepared in the present application have excellent antibacterial effects, while the antibacterial effects of the masks prepared in comparative examples 1 and 2 are significantly inferior to the solutions disclosed in the present application, and meanwhile, the antibacterial effect of the mask sample prepared in comparative example 2 is significantly superior to that of the mask prepared in comparative example 1.
And (4) conclusion: the invention discloses a high-moisture-retention facial mask based on cellulose fibers and a preparation method thereof, the process design is reasonable, the component proportion is proper, the prepared moisture-retention facial mask has excellent effects of moisturizing and skin moistening, and the moisture-retention facial mask also has excellent antibacterial effect, can inhibit the growth of microorganisms on the surface of the skin, avoids the occurrence of acne, and has better practicability.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Claims (7)
1. A high moisture mask based on cellulose fiber is characterized in that: the moisturizing mask comprises modified mask base cloth and mask base liquid, wherein the mask base liquid comprises the following raw materials: 8-10 parts of sodium hyaluronate, 8-12 parts of carbomer, 6-8 parts of antibacterial peptide, 3-4 parts of N, N-dicyclohexylcarbodiimide, 10-15 parts of triethanolamine, 8-10 parts of glycerol, 3-5 parts of collagen, 4-7 parts of sodium methylparaben and 6-8 parts of a traditional Chinese medicine additive by weight;
the preparation method comprises the following specific steps:
1) preparing materials;
2) preparing a mask base cloth:
a) dissolving sodium alginate in distilled water, stirring, standing, continuously stirring, filtering, and defoaming under vacuum to obtain spinning solution;
b) taking spinning solution, carrying out wet spinning, treating in calcium chloride coagulation bath, washing with water, and carrying out traction drying to obtain first fibers;
c) taking chitosan fibers, viscose fibers, silk fibers and first fibers, carding, lapping, and carrying out spunlace reinforcement to obtain a mask base fabric;
3) preparation of antibacterial peptide: taking pepper seed protein and pepsin, and carrying out enzymolysis to obtain antibacterial peptide;
4) preparation of the traditional Chinese medicine additive: taking tremella, safflower and asparagus, and preparing a traditional Chinese medicine additive;
5) dissolving N, N-dicyclohexylcarbodiimide in absolute ethyl alcohol, and stirring to obtain a solution A; mixing glycerol, collagen and sodium methyl hydroxybenzoate, stirring, heating to 40-45 deg.C, and stirring to obtain solution B;
6) placing the mask base cloth in a sodium hydroxide solution, standing at-15 ℃, adding isopropanol, stirring, adding tetramethylammonium hydroxide, continuing stirring, adding propylene oxide, stirring and refluxing for 5-6h at 45-50 ℃, adjusting the pH, adding glucose oxidase at 35-45 ℃, reacting for 2-4h, heating to inactivate enzyme, cooling to room temperature, washing with water, and drying in vacuum to obtain the modified mask base cloth;
7) taking modified mask base cloth, placing the modified mask base cloth in a hydrogen chloride solution, soaking, eluting with ethanol to neutrality, taking out, placing in a mixed solution of ethanol and sodium hydroxide, continuing to soak, adding sodium hyaluronate, carbomer and antibacterial peptide, stirring, adjusting pH, slowly adding the solution A at 60-70 ℃, reacting for 1-2.5h, adding the solution B and triethanolamine, continuing to stir, then adding a traditional Chinese medicine additive, stirring, and drying to obtain the moisturizing mask.
2. A cellulose fiber-based high moisturizing mask as claimed in claim 1, wherein: the mask base cloth comprises the following raw materials: 8-14 parts of chitosan fiber, 10-15 parts of viscose fiber, 6-8 parts of silk fiber and 10-14 parts of first fiber.
3. A cellulose fiber-based high moisturizing mask as claimed in claim 1, wherein: the traditional Chinese medicine additive comprises white fungus, safflower and asparagus, wherein the mass ratio of the white fungus to the safflower to the asparagus is 1: 1: (1-1.5).
4. A cellulose fiber-based high moisturizing mask as claimed in claim 1, wherein: the method comprises the following steps:
1) preparing materials;
2) preparing a mask base cloth:
a) dissolving sodium alginate in distilled water, stirring for 10-20min, standing for 3-3.5 hr, stirring for 4-4.2 hr, filtering, and defoaming under vacuum to obtain spinning solution;
b) taking spinning solution, carrying out wet spinning, treating in calcium chloride coagulation bath for 30-40min, washing with water, and carrying out traction drying to obtain a first fiber;
c) taking chitosan fibers, viscose fibers, silk fibers and first fibers, carding, lapping, and carrying out spunlace reinforcement to obtain a mask base fabric;
3) preparation of antibacterial peptide: taking pepper seed protein and pepsin, and carrying out enzymolysis to obtain antibacterial peptide;
4) preparation of the traditional Chinese medicine additive: taking tremella, safflower and asparagus, and preparing a traditional Chinese medicine additive;
5) dissolving N, N-dicyclohexylcarbodiimide in absolute ethyl alcohol, and stirring for 5-10min to obtain a solution A; mixing glycerol, collagen and sodium methyl hydroxybenzoate, stirring for 8-12min, heating to 40-45 deg.C, and stirring for 10-20min to obtain solution B;
6) placing the mask base cloth in a sodium hydroxide solution, standing at-15 ℃ for 3-4h, adding isopropanol, stirring for 30-40min, adding tetramethylammonium hydroxide, continuing stirring for 1-1.5h, then adding propylene oxide, stirring and refluxing at 45-50 ℃ for 5-6h, adjusting the pH to 4-6, adding glucose oxidase at 35-45 ℃, reacting for 2-4h, heating to inactivate enzyme, cooling to room temperature, washing for 3-5 times, and drying in vacuum to obtain a modified mask base cloth;
7) placing the modified mask base cloth into a hydrogen chloride solution, soaking for 30-40min, eluting with ethanol to neutrality, taking out, placing into a mixed solution of ethanol and sodium hydroxide, continuing to soak for 1-1.5h, adding sodium hyaluronate, carbomer and antibacterial peptide, stirring for 10-12min, adjusting pH to 5-5.5, slowly adding the solution A at 60-70 ℃, reacting for 1-2.5h, adding the solution B and triethanolamine, continuing to stir for 20-30min, then adding a traditional Chinese medicine additive, stirring for 10-15min, and drying to obtain the moisturizing mask.
5. The cellulose fiber-based high moisturizing mask as claimed in claim 4, wherein: in the step 4), the preparation method of the traditional Chinese medicine additive comprises the following steps: pulverizing Tremella, Carthami flos and radix asparagi, stirring for 10-15min, soaking in distilled water for 1-2 hr, decocting for 1-2 hr, and filtering to obtain Chinese medicinal additive.
6. The cellulose fiber-based high moisturizing mask as claimed in claim 4, wherein: in the step 3), the preparation method of the antibacterial peptide comprises the following steps: dissolving pepper seed protein in distilled water, heating to 30-35 ℃ in water bath, adding pepsin, reacting for 3-3.5h, heating to 90 ℃ in water bath to inactivate enzyme, cooling, centrifuging for 10-15min at 8500r/min of 8000-.
7. The cellulose fiber-based high moisturizing mask as claimed in claim 4, wherein: in the step 2), the vacuum defoaming time is 15-18 h.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011135716.4A CN112294661B (en) | 2020-06-01 | 2020-06-01 | High-moisture mask based on cellulose fibers |
| CN202011135710.7A CN112190517A (en) | 2020-06-01 | 2020-06-01 | High-moisture-retention facial mask based on cellulose fibers |
| CN202010484633.XA CN111419774B (en) | 2020-06-01 | 2020-06-01 | High-moisture-retention facial mask based on cellulose fibers and preparation method thereof |
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| CN202010484633.XA CN111419774B (en) | 2020-06-01 | 2020-06-01 | High-moisture-retention facial mask based on cellulose fibers and preparation method thereof |
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| CN202011135716.4A Division CN112294661B (en) | 2020-06-01 | 2020-06-01 | High-moisture mask based on cellulose fibers |
| CN202011135710.7A Division CN112190517A (en) | 2020-06-01 | 2020-06-01 | High-moisture-retention facial mask based on cellulose fibers |
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| CN111419774B true CN111419774B (en) | 2021-06-29 |
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| CN202011135710.7A Withdrawn CN112190517A (en) | 2020-06-01 | 2020-06-01 | High-moisture-retention facial mask based on cellulose fibers |
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| CN111939099A (en) * | 2020-09-04 | 2020-11-17 | 陈广文 | Acne-removing moisturizing mask and preparation method thereof |
| CN112076094B (en) * | 2020-09-22 | 2023-09-26 | 广州梵之容化妆品有限公司 | Moisturizing mask and preparation method thereof |
| CN112494343A (en) * | 2020-12-29 | 2021-03-16 | 泉州市伊兰佳丰化妆品科技有限公司 | Preparation method of deep nourishing facial mask |
| CN112981576A (en) * | 2021-02-23 | 2021-06-18 | 刘磊 | Skin-care moisture-retention fabric and preparation method thereof |
| CN113397991A (en) * | 2021-07-16 | 2021-09-17 | 蓝科医美科学技术(吉林)有限公司 | Whitening, moisturizing and water-locking solid essence mask and preparation method thereof |
| CN115300415B (en) * | 2022-09-15 | 2023-06-09 | 深圳前海港影生物科技有限公司 | Preparation method of carboxymethyl cellulose fiber mask |
| CN115928434A (en) * | 2022-11-16 | 2023-04-07 | 画美实业(上海)有限公司 | Production and preparation process of ice drilling permeable membrane |
| CN116856089B (en) * | 2023-08-11 | 2023-12-26 | 广州宝恒纺织科技有限公司 | Antibacterial viscose composite yarn and preparation method thereof |
| CN117100621B (en) * | 2023-10-24 | 2024-01-09 | 山东一飞环保材料科技有限公司 | Antibacterial nanofiber dry mask and preparation method thereof |
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| EP1242572A2 (en) * | 1999-12-22 | 2002-09-25 | Unilever N.V. | Method of delivering a benefit agent |
| CN108403446B (en) * | 2018-04-18 | 2021-08-31 | 魏科峰 | Bamboo charcoal viscose fiber mask base cloth and high-water-locking moisturizing mask |
| CN108685812A (en) * | 2018-07-12 | 2018-10-23 | 高昕文 | A kind of washable facial mask and preparation method thereof |
| CN108703919B (en) * | 2018-08-25 | 2021-04-27 | 素妆生物科技(上海)有限公司 | Preparation method of biological cellulose facial mask capable of keeping water for long time |
| CN109010139A (en) * | 2018-10-10 | 2018-12-18 | 广州仙施生物科技有限公司 | A kind of replenishing water and preserving moisture facial mask and preparation method thereof |
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| CN111419774A (en) | 2020-07-17 |
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