CN115928434A - Production and preparation process of ice drilling permeable membrane - Google Patents
Production and preparation process of ice drilling permeable membrane Download PDFInfo
- Publication number
- CN115928434A CN115928434A CN202211435067.9A CN202211435067A CN115928434A CN 115928434 A CN115928434 A CN 115928434A CN 202211435067 A CN202211435067 A CN 202211435067A CN 115928434 A CN115928434 A CN 115928434A
- Authority
- CN
- China
- Prior art keywords
- parts
- permeable membrane
- fibers
- drilling
- ice
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 93
- 239000012528 membrane Substances 0.000 title claims abstract description 75
- 238000005553 drilling Methods 0.000 title claims abstract description 71
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 99
- 239000000835 fiber Substances 0.000 claims abstract description 84
- 239000000701 coagulant Substances 0.000 claims abstract description 51
- 238000000576 coating method Methods 0.000 claims abstract description 31
- 239000011248 coating agent Substances 0.000 claims abstract description 30
- 239000007788 liquid Substances 0.000 claims abstract description 30
- 229920001661 Chitosan Polymers 0.000 claims abstract description 29
- 239000002131 composite material Substances 0.000 claims abstract description 24
- 239000012153 distilled water Substances 0.000 claims abstract description 22
- 238000002156 mixing Methods 0.000 claims abstract description 20
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000661 sodium alginate Substances 0.000 claims abstract description 18
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 18
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 18
- 238000001035 drying Methods 0.000 claims abstract description 16
- -1 alkyl glycoside Chemical class 0.000 claims abstract description 15
- 229930182470 glycoside Natural products 0.000 claims abstract description 13
- 235000009051 Ambrosia paniculata var. peruviana Nutrition 0.000 claims abstract description 11
- 235000003097 Artemisia absinthium Nutrition 0.000 claims abstract description 11
- 240000001851 Artemisia dracunculus Species 0.000 claims abstract description 11
- 235000017731 Artemisia dracunculus ssp. dracunculus Nutrition 0.000 claims abstract description 11
- 235000003261 Artemisia vulgaris Nutrition 0.000 claims abstract description 11
- 239000001138 artemisia absinthium Substances 0.000 claims abstract description 11
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000009960 carding Methods 0.000 claims abstract description 9
- 230000002787 reinforcement Effects 0.000 claims abstract description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 54
- 229920002678 cellulose Polymers 0.000 claims description 48
- 239000001913 cellulose Substances 0.000 claims description 47
- 235000010980 cellulose Nutrition 0.000 claims description 45
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 42
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 27
- 239000000843 powder Substances 0.000 claims description 26
- 239000002994 raw material Substances 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 23
- 244000025254 Cannabis sativa Species 0.000 claims description 20
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 claims description 20
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 claims description 20
- 235000009120 camo Nutrition 0.000 claims description 20
- 235000005607 chanvre indien Nutrition 0.000 claims description 20
- 239000011487 hemp Substances 0.000 claims description 20
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 20
- 239000004626 polylactic acid Substances 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 19
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 claims description 15
- 229920002752 Konjac Polymers 0.000 claims description 14
- 239000002202 Polyethylene glycol Substances 0.000 claims description 14
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 14
- 239000000252 konjac Substances 0.000 claims description 14
- 229920001223 polyethylene glycol Polymers 0.000 claims description 14
- 229920001046 Nanocellulose Polymers 0.000 claims description 13
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 claims description 12
- 244000247812 Amorphophallus rivieri Species 0.000 claims description 12
- 235000001206 Amorphophallus rivieri Nutrition 0.000 claims description 12
- 229920002581 Glucomannan Polymers 0.000 claims description 12
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 12
- 229940046240 glucomannan Drugs 0.000 claims description 12
- 235000010485 konjac Nutrition 0.000 claims description 12
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 11
- 239000001110 calcium chloride Substances 0.000 claims description 11
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 11
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 9
- 238000002074 melt spinning Methods 0.000 claims description 8
- 239000010979 ruby Substances 0.000 claims description 8
- 229910001750 ruby Inorganic materials 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 7
- 244000261559 Smilax china Species 0.000 claims description 4
- 235000000485 Smilax china Nutrition 0.000 claims description 4
- 240000009022 Smilax rotundifolia Species 0.000 claims description 4
- 235000003205 Smilax rotundifolia Nutrition 0.000 claims description 4
- 230000001413 cellular effect Effects 0.000 claims description 2
- 235000019823 konjac gum Nutrition 0.000 claims description 2
- 230000001815 facial effect Effects 0.000 abstract description 28
- 238000010521 absorption reaction Methods 0.000 abstract description 19
- 238000009776 industrial production Methods 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 55
- 239000000047 product Substances 0.000 description 16
- 239000004744 fabric Substances 0.000 description 15
- 239000010408 film Substances 0.000 description 13
- 230000035699 permeability Effects 0.000 description 11
- 238000009987 spinning Methods 0.000 description 10
- 229910003460 diamond Inorganic materials 0.000 description 7
- 239000010432 diamond Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000009998 heat setting Methods 0.000 description 5
- 238000004804 winding Methods 0.000 description 5
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 4
- 240000000249 Morus alba Species 0.000 description 4
- 235000008708 Morus alba Nutrition 0.000 description 4
- 230000015271 coagulation Effects 0.000 description 4
- 238000005345 coagulation Methods 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- FCZCIXQGZOUIDN-UHFFFAOYSA-N ethyl 2-diethoxyphosphinothioyloxyacetate Chemical compound CCOC(=O)COP(=S)(OCC)OCC FCZCIXQGZOUIDN-UHFFFAOYSA-N 0.000 description 4
- 150000004676 glycans Chemical class 0.000 description 4
- 229920002674 hyaluronan Polymers 0.000 description 4
- 229960003160 hyaluronic acid Drugs 0.000 description 4
- 229920001282 polysaccharide Polymers 0.000 description 4
- 239000005017 polysaccharide Substances 0.000 description 4
- 229940111630 tea tree oil Drugs 0.000 description 4
- 239000010677 tea tree oil Substances 0.000 description 4
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- AJBZENLMTKDAEK-UHFFFAOYSA-N 3a,5a,5b,8,8,11a-hexamethyl-1-prop-1-en-2-yl-1,2,3,4,5,6,7,7a,9,10,11,11b,12,13,13a,13b-hexadecahydrocyclopenta[a]chrysene-4,9-diol Chemical compound CC12CCC(O)C(C)(C)C1CCC(C1(C)CC3O)(C)C2CCC1C1C3(C)CCC1C(=C)C AJBZENLMTKDAEK-UHFFFAOYSA-N 0.000 description 2
- 235000003880 Calendula Nutrition 0.000 description 2
- 240000001432 Calendula officinalis Species 0.000 description 2
- 241000167550 Centella Species 0.000 description 2
- 241000205578 Thalictrum Species 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229940002386 calendula officinalis extract Drugs 0.000 description 2
- 229940059958 centella asiatica extract Drugs 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 150000003384 small molecules Chemical class 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 229920006052 Chinlon® Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000009044 synergistic interaction Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
- Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
Landscapes
- Medicinal Preparation (AREA)
- Materials For Medical Uses (AREA)
Abstract
The application relates to the technical field of facial masks, and particularly discloses a production and preparation process of an ice drilling permeable membrane, which comprises the following steps: a production and preparation process of an ice drilling permeable membrane comprises the following steps: s1, carding the first fibers, the wormwood fibers, the silk fibers and the chitosan fibers, then lapping, and carrying out spunlace reinforcement to obtain a composite film; s2, adding sodium alginate, chitosan and alkyl glycoside into distilled water, and uniformly mixing to obtain a finishing liquid; then placing the composite film in finishing liquid, and taking out to obtain an initial product; s3, covering the initial product on a honeycomb grain mold containing a coagulant coating, solidifying and drying to obtain an ice drilling permeable membrane; the production and preparation process of the ice drilling permeable membrane is simple, the cost is low, the production and preparation method is suitable for industrial production, and the obtained ice drilling permeable membrane is good in moisture absorption and breathability, novel in appearance, degradable and environmentally-friendly and has the sustainable development significance.
Description
Technical Field
The application relates to the technical field of facial masks, in particular to a production and preparation process of an ice drilling permeable membrane.
Background
With the rapid development of social economy and the continuous improvement of living standard, the concept of people gradually changes, more and more attention is paid to the face appearance and image of people, people can adopt various cosmetics to improve the face skin of people, and the consumption of the facial mask is increased year by year. Currently, the consumption of mask base cloth used by the patch mask is increased year by year.
At present, raw materials used by mask base cloth on the market mainly comprise cotton fiber and polyester fiber, and also comprise byproducts generated in petroleum refining, namely polyethylene and polypropylene plastic particles, and chemical fiber prepared by melt spinning; the fibers are used as raw materials to form the mask base cloth through a spunlace technology, so most of the mask base cloth cannot be naturally degraded after being discarded, and the environment is polluted by novel white garbage. In addition, while the facial mask is desired to have remarkable effects, the facial mask is also desired to be improved in appearance, and the existing facial mask cannot meet the higher demand of people. Therefore, a production and preparation process of the ice drilling gel permeable membrane is urgently needed to solve the problems that the existing mask cloth is not easy to degrade and has a simple appearance, so that the ice drilling gel permeable membrane is green and environment-friendly, has a wide market prospect, and can meet higher demands of people.
Disclosure of Invention
In order to solve the problems that the existing mask cloth is not easy to degrade and has simple appearance, the application provides a production and preparation process of the ice drilling permeable membrane.
The application provides a production and preparation process of an ice drilling permeable membrane, which adopts the following technical scheme:
a production and preparation process of an ice drilling permeable membrane comprises the following steps:
s1, carding the first fibers, the wormwood fibers, the chitosan fibers and the silk fibers, then lapping, and carrying out spunlace reinforcement to obtain a composite membrane;
s2, adding sodium alginate, chitosan and alkyl glycoside into distilled water, and uniformly mixing to obtain a finishing liquid; then the composite film is immersed into the finishing liquid and taken out to obtain an initial product;
s3, covering the initial product on a honeycomb grain mold containing a coagulant coating, and solidifying to obtain an ice drilling permeable membrane;
the composite film comprises the following raw materials in parts by weight: 20-40 parts of first fibers, 10-20 parts of wormwood fibers, 11-15 parts of chitosan fibers and 1-5 parts of silk fibers.
By adopting the technical scheme, the production and preparation process of the ice drilling condensation permeable membrane mainly comprises three steps, firstly, mixing first fibers, wormwood fibers, silk fibers and chitosan fibers according to a certain mass ratio, then carding and spunlacing the mixture to form a high-transparency high-water-absorption composite membrane, then dispersing sodium alginate and chitosan in alkyl glycoside to form a finishing liquid, and treating the composite membrane to ensure that the surface of the composite membrane contains a large amount of sodium alginate and chitosan, so as to obtain an initial product; and finally, covering the primary product on a honeycomb grain mold containing a coagulant coating, and curing to form a honeycomb diamond surface on the surface of the primary product. The ice drilling permeable membrane has two different effects, one surface has high water absorption, high transparency and high air permeability, and the other surface is a honeycomb diamond surface, so that the appearance is novel and outstanding; and the ice drilling permeable membrane is green and environment-friendly, is degradable and has wide market prospect.
Preferably, the first fiber comprises the following raw materials in parts by weight: 30-40 parts of modified cellulose, 20-30 parts of polylactic acid and 16-20 parts of hemp stalk core superfine powder.
Preferably, the first fibers are prepared by the following method:
uniformly mixing the modified cellulose, the polylactic acid and the hemp stalk core superfine powder to obtain a premix; the premix is then passed through a melt spinning process to produce a first fiber.
By adopting the technical scheme, the first fiber contains modified cellulose, polylactic acid and hemp stalk core superfine powder, and the modified cellulose has remarkable water absorption capacity and excellent degradability; the polylactic acid is a degradable profile membrane material, has good water absorption, can separate out partial free small molecules, and can inhibit bacteria while improving the absorption of nutrient components and enhancing the growth activity of facial skin after the small molecules are combined with lactic acid substances of the skin; the hemp stalk core superfine powder has a microporous structure, and has good moisture absorption, air permeability, antibacterial property, ultraviolet resistance and adsorbability; the surfaces of the modified cellulose, the polylactic acid and the hemp stalk core ultrafine powder contain active groups, and the modified cellulose, the polylactic acid and the hemp stalk core ultrafine powder interact with each other to realize synergistic interaction, so that the moisture absorption and the air permeability of the first fiber can be effectively improved, and the comprehensive performance of the prepared composite membrane is more excellent.
Preferably, the modified cellulose comprises the following raw materials in parts by weight: 30-50 parts of nano cellulose, 5-9 parts of tetrabutyl titanate, 20-30 parts of ethylene glycol, 1-3 parts of polyethylene glycol, 6-8 parts of tetrahydroxypropyl ethylenediamine and 8-12 parts of glycerol.
Preferably, the modified cellulose is prepared by the following method:
dissolving tetrabutyl titanate in ethylene glycol, adding polyethylene glycol, stirring at the speed of 600-1000r/min for 15-25min, and adjusting the pH to 3.7-4.2; adding nano cellulose, tetrahydroxypropyl ethylenediamine and glycerol, stirring at 2000-2500r/min for 20-60min, standing for 60-90min, filtering, drying at 40-80 deg.C for 8-10 hr, and grinding to obtain modified cellulose.
Through adopting above-mentioned technical scheme, this application uses tetrabutyl titanate as the titanium source, forms titanium dioxide on nanocellulose's surface for modified cellulose not only has excellent moisture absorption ventilation function, has whitening, clear effect moreover, can also improve first fibrous degradability simultaneously, and then has guaranteed that the ice drilling permeable membrane of this application returns natural feature of environmental protection after using.
Preferably, the finishing liquid comprises the following raw materials in parts by weight: 20-40 parts of sodium alginate, 10-20 parts of chitosan, 1-3 parts of alkyl glycoside and 100-200 parts of distilled water.
By adopting the technical scheme, the finishing liquid comprises sodium alginate, chitosan and alkyl glycoside, the sodium alginate is non-toxic and has good biocompatibility, can be gelatinized and has the characteristics of thermal stability and the like, and the chitosan has good film forming property and antibacterial property and obvious moisture absorption property; under the action of alkyl glycoside, sodium alginate and chitosan are uniformly dispersed, and are synergistic, so that a three-dimensional network structural hydraulic thin film with high moisture absorption, air permeability and strong antibacterial property can be formed on the surface of the composite film; in addition, the weight parts of the components are controlled within a certain range, so that the hydraulic thin film can better react with a coagulant, and the performance of the ice drilling permeable film is more excellent.
Preferably, the honeycomb grain mold with the coagulant coating is prepared by the following method: firstly, adding konjac glucomannan, calcium chloride, glutaraldehyde, citric acid, rubberlith powder and chinaroot greenbrier seed oil into distilled water, and uniformly mixing to form a coagulant solution; and then immersing the honeycomb grain mold into the coagulant solution, taking out the mold after 20-40min, and drying to obtain the honeycomb grain mold containing the coagulant coating.
Preferably, the coagulant solution comprises the following raw materials in parts by weight: 10-20 parts of konjac gum, 11-15 parts of calcium chloride, 1-3 parts of glutaraldehyde, 1-3 parts of citric acid, 5-10 parts of ruby powder, 1-3 parts of chinaroot greenbrier seed oil and 80-100 parts of distilled water.
By adopting the technical scheme, the honeycomb-shaped grain mold is soaked in the coagulant solution, so that a coating containing the coagulant is formed on the surface of the mold, and the coagulant solution comprises calcium ions, glutaraldehyde and ruby powder, so that the ice drilling permeable membrane has diamond-like luster; the meadowrue root oil not only can play a good dispersing role, but also is beneficial to demoulding of a coating; the konjac glucomannan can promote the coagulant to form a uniform coating on the surface of the honeycomb grain die, so that the primary product can be solidified in the die to form a honey-like grain diamond film; in addition, the weight parts of all components of the coagulant solution and all process parameters are controlled, so that the chitosan and the sodium alginate can be fully cured to form the ice drilling permeable membrane with more excellent performance.
The application also provides an ice drilling and condensation mask, which adopts the following technical scheme:
an ice drilling full-permeable mask comprises a mask cloth and a mask liquid; the mask cloth is prepared by the production and preparation process of the ice drilling permeable membrane;
the mask liquid comprises the following raw materials in parts by weight: 1-5 parts of hyaluronic acid, 2-4 parts of konjac glucomannan, 0.2-0.8 part of centella asiatica extract, 0.7-1.2 parts of calendula officinalis extract, 1-3 parts of tea tree oil, 1-2 parts of mulberry polysaccharide, 5-8 parts of glycerol and 20-40 parts of distilled water;
the ice drilling permeable mask is prepared by the following method:
and filling the mask liquid into a mask bag containing the mask cloth, drying, and sealing to obtain the ice diamond full-penetration mask.
By adopting the technical scheme, the ice drilling coagulation permeable facial mask comprises facial mask cloth and facial mask liquid which are prepared by the production and preparation process of the ice drilling coagulation permeable mask, the facial mask liquid contains raw materials such as hyaluronic acid, konjac glucomannan, centella asiatica extract, calendula officinalis extract, tea tree oil, mulberry polysaccharide and glycerol, and the components interact with each other and synergize, so that the ice drilling coagulation permeable facial mask can form a film on skin, active ingredients in the facial mask are fully absorbed by the skin, the effects of moisturizing can be achieved, the appearance is novel and outstanding, and the ice drilling coagulation permeable facial mask is green and environment-friendly.
Preferably, the facial mask liquid is prepared by the following method:
adding hyaluronic acid, konjac glucomannan, centella extract, calendula extract, tea tree oil, mulberry polysaccharide and glycerol into distilled water, uniformly mixing at 50-70 ℃, and then homogenizing and emulsifying for 30-90min at the homogenizing speed of 1600-2000r/min to obtain the facial mask liquid.
By adopting the technical scheme, the preparation method of the facial mask liquid is simple, the preparation cost is low, the preparation method is suitable for industrial production, and the prepared ice drilling permeable facial mask has a wide market prospect.
In summary, the present application has the following beneficial effects:
1. the production and preparation process of the ice drilling permeable membrane has the advantages of simple preparation steps, low preparation cost, suitability for industrial production, no toxicity and harm of selected materials, environmental friendliness, degradability and positive significance in sustainable development.
2. The ice drilling gel permeable membrane prepared by the production and preparation process of the ice drilling gel permeable membrane has excellent moisture absorption and breathability performance, and is double-sided in different effects, one side of the membrane is high in water absorption, high in transparency and high in breathability, the other side of the membrane is a honeycomb-shaped diamond surface, the appearance is novel and prominent, the higher requirements of people on the facial mask can be met, and the membrane has wide application prospects.
Detailed Description
The present application will be described in further detail with reference to examples.
Preparation examples 1 to 5 provide modified celluloses and methods for their preparation.
Preparation example 1
The modified cellulose comprises the following raw materials: 30kg of nano-cellulose, 5kg of tetrabutyl titanate, 20kg of ethylene glycol, 1kg of polyethylene glycol, 6kg of tetrahydroxypropyl ethylenediamine and 8kg of glycerol.
The modified cellulose is prepared by the following method:
firstly, tetrabutyl titanate is dissolved in ethylene glycol, polyethylene glycol is added, stirring is carried out for 25min at the speed of 600r/min, and the pH value is adjusted to 3.7; adding nano-cellulose, tetrahydroxypropyl ethylenediamine and glycerol, stirring at 2000r/min for 60min, standing for 60min, filtering, drying at 40 deg.C for 10 hr, and grinding to obtain modified cellulose.
Preparation example 2
The modified cellulose comprises the following raw materials: 35kg of nanocellulose, 6kg of tetrabutyl titanate, 22kg of ethylene glycol, 1.5kg of polyethylene glycol, 6.5kg of tetrahydroxypropyl ethylenediamine and 9kg of glycerol.
The modified cellulose is prepared by the following method:
dissolving tetrabutyl titanate in ethylene glycol, adding polyethylene glycol, stirring at the speed of 700r/min for 22min, and adjusting the pH value to 3.9; adding nano cellulose, tetrahydroxypropyl ethylenediamine and glycerol, stirring at the rotation speed of 2200r/min for 50min, standing for 65min, filtering, drying at 50 deg.C for 9.5h, and grinding to obtain modified cellulose.
Preparation example 3
The modified cellulose comprises the following raw materials: 40kg of nanocellulose, 7kg of tetrabutyltitanate, 25kg of ethylene glycol, 2kg of polyethylene glycol, 7kg of tetrahydroxypropylethylenediamine and 10kg of glycerol.
The modified cellulose is prepared by the following method:
dissolving tetrabutyl titanate in ethylene glycol, adding polyethylene glycol, stirring at the speed of 800r/min for 20min, and adjusting the pH value to 4; adding nano cellulose, tetrahydroxypropyl ethylenediamine and glycerol, stirring at 2300r/min for 40min, standing for 75min, filtering, drying at 60 deg.C for 9h, and grinding to obtain modified cellulose.
Preparation example 4
The modified cellulose comprises the following raw materials: 45kg of nanocellulose, 8kg of tetrabutyl titanate, 28kg of ethylene glycol, 2.5kg of polyethylene glycol, 7.5kg of tetrahydroxypropyl ethylenediamine and 11kg of glycerol.
The modified cellulose is prepared by the following method:
dissolving tetrabutyl titanate in ethylene glycol, adding polyethylene glycol, stirring at 900r/min for 17min, and adjusting pH to 4.1; adding nano cellulose, tetrahydroxypropyl ethylenediamine and glycerol, stirring at 2400r/min for 30min, standing for 80min, filtering, drying at 70 deg.C for 8.5h, and grinding to obtain modified cellulose.
Preparation example 5
The modified cellulose comprises the following raw materials: 50kg of nanocellulose, 9kg of tetrabutyl titanate, 30kg of ethylene glycol, 3kg of polyethylene glycol, 8kg of tetrahydroxypropyl ethylenediamine and 12kg of glycerol.
The modified cellulose is prepared by the following method:
dissolving tetrabutyl titanate in ethylene glycol, adding polyethylene glycol, stirring at the speed of 1000r/min for 15min, and adjusting the pH value to 4.2; adding nano cellulose, tetrahydroxypropyl ethylenediamine and glycerol, stirring at 2500r/min for 20min, standing for 90min, filtering, drying at 80 deg.C for 8h, and grinding to obtain modified cellulose.
Preparations 6-10 and comparative preparations 1-4 provide first fibers and methods of making the same.
Preparation example 6
A first fiber comprising the following raw materials: 30kg of modified cellulose (preparation example 1), 20kg of polylactic acid and 16kg of hemp stalk core superfine powder.
A first fiber made by the process of:
uniformly mixing the modified cellulose, the polylactic acid and the hemp stalk core superfine powder to obtain a premix; then, preparing the first fiber from the premix through a melt spinning process;
wherein the spinning temperature is 210 ℃, the spinning speed is 3100m/min, the total drafting multiplying power is 2 times, the heat setting temperature is 120 ℃, and the winding speed is 1000m/min.
Preparation example 7
A first fiber comprising the following raw materials: 32kg of modified cellulose (preparation example 2), 22kg of polylactic acid and 17kg of hemp stalk core micropowder.
A first fiber made by the process of:
uniformly mixing the modified cellulose, the polylactic acid and the hemp stalk core superfine powder to obtain a premix; then, preparing the premix into a first fiber through a melt spinning process;
wherein the spinning temperature is 220 ℃, the spinning speed is 3200m/min, the total drafting multiplying power is 2.5 times, the heat setting temperature is 130 ℃, and the winding speed is 1500m/min.
Preparation example 8
A first fiber comprising the following raw materials: 35kg of modified cellulose (preparation example 3), 25kg of polylactic acid and 18kg of hemp stalk core micropowder.
A first fiber made by the process of:
uniformly mixing the modified cellulose, the polylactic acid and the hemp stalk core superfine powder to obtain a premix; then, preparing the premix into a first fiber through a melt spinning process;
wherein the spinning temperature is 230 ℃, the spinning speed is 3300m/min, the total drafting magnification is 3 times, the heat setting temperature is 140 ℃, and the winding speed is 3000m/min.
Preparation example 9
A first fiber comprising the following raw materials: 38kg of modified cellulose (preparation example 4), 27kg of polylactic acid and 19kg of hemp stalk core micropowder.
A first fiber made by the process of:
uniformly mixing the modified cellulose, the polylactic acid and the hemp stalk core superfine powder to obtain a premix; then, preparing the first fiber from the premix through a melt spinning process;
wherein the spinning temperature is 240 ℃, the spinning speed is 3400m/min, the total drafting ratio is 3.5 times, the heat setting temperature is 150 ℃, and the winding speed is 300m/min.
Preparation example 10
A first fiber comprising the following raw materials: 40kg of modified cellulose (preparation example 5), 30kg of polylactic acid and 20kg of hemp stalk core superfine powder.
A first fiber made by the process of:
uniformly mixing the modified cellulose, the polylactic acid and the hemp stalk core superfine powder to obtain a premix; then, preparing the first fiber from the premix through a melt spinning process;
wherein the spinning temperature is 250 ℃, the spinning speed is 3500m/min, the total drafting ratio is 4 times, the heat setting temperature is 160 ℃, and the winding speed is 4000m/min.
Comparative preparation example 1
Comparative preparation 1, like preparation 6, differs only in that: the modified cellulose is replaced by nano-cellulose.
Comparative preparation example 2
Comparative preparation 2, like preparation 6, differs only in that: modified cellulose was not added.
Comparative preparation example 3
Comparative preparation 3, like preparation 6, differs only in that: the hemp stalk core superfine powder is not added.
Comparative preparation example 4
Comparative preparation 4, like preparation 6, differs only in that: polylactic acid was not added.
Preparations 11-15 and comparative preparations 5-7 provide methods of making honeycomb vein molds with coagulant coatings.
Preparation example 11
Firstly, adding 10kg of konjac glucomannan, 11kg of calcium chloride, 8kg of glutaraldehyde, 1kg of citric acid, 5kg of ruby powder and 1kg of white pond flower seed oil into 80-kg of distilled water, and uniformly mixing to form a coagulant solution; and then immersing the honeycomb grain mold into the coagulant solution, taking out the mold after 20min, and drying to obtain the honeycomb grain mold containing the coagulant coating.
Preparation example 12
Firstly, adding 12kg of konjac glucomannan, 12kg of calcium chloride, 8.5kg of glutaraldehyde, 1.5kg of citric acid, 7kg of ruby powder and 1.5kg of white pond flower seed oil into 85kg of distilled water, and uniformly mixing to form a coagulant solution; and then soaking the honeycomb-shaped grain mold into the coagulant solution, taking out the mold after 25min, and drying to obtain the honeycomb-shaped grain mold containing the coagulant coating.
Preparation example 13
Firstly, adding 15kg of konjac glucomannan, 13kg of calcium chloride, 9kg of glutaraldehyde, 2kg of citric acid, 8kg of ruby powder and 2kg of white pond flower seed oil into 90kg of distilled water, and uniformly mixing to form a coagulant solution; and then soaking the honeycomb-shaped grain mold into the coagulant solution, taking out the mold after 30min, and drying to obtain the honeycomb-shaped grain mold containing the coagulant coating.
Preparation example 14
Firstly, adding 17kg of konjac glucomannan, 14kg of calcium chloride, 9.5kg of glutaraldehyde, 2.5kg of citric acid, 9kg of ruby powder and 2.5kg of white pond flower seed oil into 95kg of distilled water, and uniformly mixing to form a coagulant solution; and then immersing the honeycomb grain mold into the coagulant solution, taking out the mold after 35min, and drying to obtain the honeycomb grain mold containing the coagulant coating.
Preparation example 15
Adding 20kg of konjac glucomannan, 15kg of calcium chloride, 10kg of glutaraldehyde, 3kg of citric acid, 10kg of ruby powder and 3kg of white chinlon oil into 100kg of distilled water, and uniformly mixing to form a coagulant solution; and then immersing the honeycomb grain mold into the coagulant solution, taking out the mold after 40min, and drying to obtain the honeycomb grain mold containing the coagulant coating.
Comparative preparation example 5
Comparative preparation 5, identical to preparation 11, except that: no calcium chloride was added.
Comparative preparation example 6
Comparative preparation 6, identical to preparation 11, differs only in that: glutaraldehyde was not added.
Comparative preparation example 7
Comparative preparation 7, identical to preparation 11, differs only in that: no meadowrue seed oil was added.
Examples 1-5 provide a process for the production of an ice drilling permeable membrane.
Example 1
A production and preparation process of an ice drilling permeable membrane comprises the following steps:
s1, carding 20kg of first fibers, 10kg of wormwood fibers, 11kg of chitosan fibers and 1kg of silk fibers, then lapping, and carrying out spunlace reinforcement to obtain a composite film;
wherein the first fiber was prepared from preparation example 6;
s2, adding 20kg of sodium alginate, 10kg of chitosan and 1kg of alkyl glycoside into 100kg of distilled water, and stirring at the rotating speed of 600r/min for 30min to obtain finishing liquid; then placing the composite membrane in finishing liquid, treating for 20min, and taking out to obtain an initial product;
s3, covering the initial product on a honeycomb grain mold containing a coagulant coating, and curing for 1h at 60 ℃ to obtain an ice drilling permeable membrane; wherein, the honeycomb grain die with the coagulant coating is prepared by preparation example 11.
Example 2
A production and preparation process of an ice drilling permeable membrane comprises the following steps:
s1, carding 25kg of first fibers, 12kg of wormwood fibers, 12kg of chitosan fibers and 2kg of silk fibers, then lapping, and carrying out spunlace reinforcement to obtain a composite membrane;
wherein the first fiber was prepared from preparation example 7;
s2, adding 25kg of sodium alginate, 12kg of chitosan and 1.5kg of alkyl glycoside into 120kg of distilled water, and stirring at the rotating speed of 650r/min for 25min to obtain finishing liquid; then placing the composite membrane in finishing liquid, treating for 25min, and taking out to obtain an initial product;
s3, covering the initial product on a honeycomb grain mold containing a coagulant coating, and curing at 55 ℃ for 1.2h to obtain an ice drilling permeable membrane;
wherein, the honeycomb grain mold containing the coagulant coating is prepared by preparation example 12.
Example 3
A production and preparation process of an ice drilling permeable membrane comprises the following steps:
s1, carding 30kg of first fibers, 15kg of wormwood fibers, 13kg of chitosan fibers and 3kg of silk fibers, then lapping, and carrying out spunlace reinforcement to obtain a composite film;
wherein the first fiber was prepared from preparation example 8;
s2, adding 30kg of sodium alginate, 15kg of chitosan and 2kg of alkyl glycoside into 150kg of distilled water, and stirring at the rotating speed of 700r/min for 20min to obtain finishing liquid; then placing the composite membrane in finishing liquid, treating for 30min, and taking out to obtain an initial product;
s3, covering the initial product on a honeycomb grain mold containing a coagulant coating, and curing at 50 ℃ for 1.5 hours to obtain an ice drilling permeable membrane;
wherein, the honeycomb grain mold having the coagulant coating was prepared by preparation example 13.
Example 4
A production and preparation process of an ice drilling permeable membrane comprises the following steps:
s1, carding 35kg of first fibers, 18kg of wormwood fibers, 14kg of chitosan fibers and 4kg of silk fibers, then lapping, and carrying out spunlace reinforcement to obtain a composite membrane;
wherein the first fiber was prepared from preparation example 9;
s2, adding 36kg of sodium alginate, 17kg of chitosan and 2.5kg of alkyl glycoside into 180kg of distilled water, and stirring at the rotating speed of 750r/min for 15min to obtain a finishing liquid; then placing the composite membrane in finishing liquid, treating for 35min, and taking out to obtain an initial product;
s3, covering the initial product on a honeycomb grain mold containing a coagulant coating, and curing for 1.8 hours at 45 ℃ to obtain an ice drilling permeable membrane;
wherein, the honeycomb grain mold containing the coagulant coating is prepared by preparation example 14.
Example 5
A production and preparation process of an ice drilling permeable membrane comprises the following steps:
s1, carding 40kg of first fibers, 20kg of wormwood fibers, 15kg of chitosan fibers and 5kg of silk fibers, then lapping, and carrying out spunlace reinforcement to obtain a composite film;
wherein the first fiber was prepared by preparation example 10;
s2, adding 40kg of sodium alginate, 20kg of chitosan and 3kg of alkyl glycoside into 200kg of distilled water, and stirring at the rotating speed of 800r/min for 10min to obtain finishing liquid; then placing the composite membrane in finishing liquid, treating for 40min, and taking out to obtain an initial product;
s3, covering the initial product on a honeycomb grain mold containing a coagulant coating, and curing for 2 hours at 40 ℃ to obtain an ice drilling permeable membrane; wherein, the honeycomb grain mold containing the coagulant coating is prepared by preparation example 15.
Example 6 provides a facial mask solution.
Example 6
Firstly, 1kg of hyaluronic acid, 2kg of konjac glucomannan, 0.2kg of centella extract, 0.7kg of calendula extract, 1.5kg of tea tree oil, 1kg of mulberry polysaccharide and 5kg of glycerol are added into 20kg of distilled water, and after uniform mixing at 50 ℃, homogenization emulsification is carried out for 90min at the homogenization speed of 1600r/min, thus obtaining the mask liquid.
To verify the performance of an ice drilling permeable membrane provided by the present application, the applicant has set up comparative examples 1-10, in which: comparative example 1
Comparative example 1, like example 1, differs only in that: the first fiber was prepared from comparative preparation example 1.
Comparative example 2
Comparative example 2, like example 1, differs only in that: the first fiber was prepared from comparative preparation example 2.
Comparative example 3
Comparative example 3, like example 1, differs only in that: the first fiber was prepared from comparative preparation example 3.
Comparative example 4
Comparative example 4, like example 1, differs only in that: the first fiber was prepared from comparative preparation example 4.
Comparative example 5
Comparative example 5, like example 1, differs only in that: no first fibers were added.
Comparative example 6
Comparative example 6, like example 1, differs only in that: sodium alginate was not added.
Comparative example 7
Comparative example 7, like example 1, differs only in that: no chitosan was added.
Comparative example 8
Comparative example 8, like example 1, differs only in that: a honeycomb grain mold having a coagulant coating was prepared from comparative preparation example 5.
Comparative example 9
Comparative example 9, like example 1, differs only in that: a honeycomb grain mold having a coagulant coating was prepared from comparative preparation example 6.
Comparative example 10
Comparative example 10, like example 1, differs only in that: a honeycomb grain die having a coagulant coating was prepared from comparative preparation example 7.
In which the properties of the ice drilling through-films prepared in examples 1 to 5 of the present application and comparative examples 1 to 10 were measured, respectively, to obtain the following result parameters, which are specifically shown in table 1.
Water absorption performance: and (4) testing the water absorption performance of the ice drilling condensation permeable membrane by referring to QB/T2872-2017 facial mask.
Air permeability: the air permeability of the ice-drilling condensation permeable membrane is tested by referring to GB/T5453-1997 determination of air permeability of textile fabrics.
Sensory indexes are as follows: the facial mask solution prepared in the example 6 is used as a facial mask solution, the ice drilling permeable films prepared in the examples 1-5 and the comparative examples 1-10 of the application are used as facial mask cloth to prepare the ice drilling permeable facial mask, and the sensory index of the ice drilling permeable facial mask is tested according to QB/T2872-2017 facial mask.
Table 1:
as can be seen from the data shown in table 1 above: the comprehensive quality of the ice drilling permeable membrane prepared in the embodiment 1-5 is far better than that of the ice drilling permeable membrane prepared in the comparative example 1-10 and a commercially available facial mask, the ice drilling permeable membrane prepared in the embodiment 1-5 has obvious water absorption and air permeability, the appearance of the ice drilling permeable membrane is unique and outstanding, one surface is a smooth and regular cellular diamond surface, the other surface is a high-transparency surface, and the ice drilling permeable membrane is green and environment-friendly and has wide market prospect.
From example 1 and comparative example 1, it can be seen that: the raw material of the first fiber in example 1 includes the modified cellulose obtained in preparation example 1, and the ice drilling permeable membrane obtained in example 1 has excellent water absorption performance and good air permeability compared with comparative example 1, and the comfort and efficacy of the mask can be improved by using the ice drilling permeable membrane obtained in example 1 as the mask cloth.
From example 1 and comparative examples 2 to 4, it can be seen that: the raw materials of the first fiber in example 1 include modified cellulose, hemp stalk core micropowder, and polylactic acid, and the ice drilling permeable membrane prepared in example 1 has more excellent overall properties than those of comparative examples 2 to 4.
From example 1 and comparative example 5, it can be seen that: the composite membrane of example 1, in which the first fibers were added, had higher water absorption capacity and air permeability than those of comparative example 5, and was a material for a mask cloth having excellent overall properties.
As is clear from example 1 and comparative examples 6 and 7, the finishing liquid in example 1 contains sodium alginate and chitosan, and the ice drilling permeable film prepared in example 1 has better water absorption and air permeability, and has smooth and regular appearance, and can bring different visual feelings to people compared with comparative examples 6 and 7.
From example 1 and comparison 8-10, the honeycomb grain mold containing the coagulant coating of example 1 is prepared from preparation 11, wherein the coagulant solution comprises calcium chloride, glutaraldehyde and white-pool flower seed oil, compared with comparison 8-10, the ice drilling permeable membrane prepared from example 1 is used as a mask cloth, one surface of the ice drilling permeable membrane is a smooth and regular honeycomb diamond surface, the other surface is a high-transparency surface, and the two surfaces are different in effect, so that higher requirements of people can be met.
The present embodiment is only for explaining the present application, and it is not limited to the present application, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present application.
Claims (8)
1. The production and preparation process of the ice drilling permeable membrane is characterized by comprising the following steps of:
s1, carding the first fibers, the wormwood fibers, the silk fibers and the chitosan fibers, then lapping, and carrying out spunlace reinforcement to obtain a composite film;
s2, adding sodium alginate, chitosan and alkyl glycoside into distilled water, and uniformly mixing to obtain a finishing liquid; then placing the composite membrane in finishing liquid, and taking out to obtain an initial product;
s3, covering the initial product on a honeycomb grain mold containing a coagulant coating, and solidifying to obtain an ice drilling permeable membrane;
the composite film comprises the following raw materials in parts by weight: 20-40 parts of first fibers, 10-20 parts of wormwood fibers, 11-15 parts of chitosan fibers and 1-5 parts of silk fibers.
2. The production and preparation process of the ice drilling permeable membrane according to claim 1, wherein the first fiber comprises the following raw materials in parts by weight: 30-40 parts of modified cellulose, 20-30 parts of polylactic acid and 16-20 parts of hemp stalk core superfine powder.
3. The process for producing an ice-drilling permeable membrane according to claim 2, wherein the first fibers are produced by:
uniformly mixing the modified cellulose, the polylactic acid and the hemp stalk core superfine powder to obtain a premix; the premix is then passed through a melt spinning process to produce a first fiber.
4. The production and preparation process of the ice drilling permeable membrane according to claim 2, wherein the modified cellulose comprises the following raw materials in parts by weight: 30-50 parts of nano cellulose, 5-9 parts of tetrabutyl titanate, 20-30 parts of ethylene glycol, 1-3 parts of polyethylene glycol, 6-8 parts of tetrahydroxypropyl ethylenediamine and 8-12 parts of glycerol.
5. The process for producing an ice-drilling permeable membrane according to claim 4, wherein the modified cellulose is produced by the following method:
dissolving tetrabutyl titanate in ethylene glycol, adding polyethylene glycol, stirring at the speed of 600-1000r/min for 15-25min, and adjusting the pH to 3.7-4.2; adding nano cellulose, tetrahydroxypropyl ethylenediamine and glycerol, stirring at 2000-2500r/min for 20-60min, standing for 60-90min, filtering, drying at 40-80 deg.C for 8-10h, and grinding to obtain modified cellulose.
6. The production and preparation process of the ice drilling permeable membrane according to claim 1, wherein the finishing liquid comprises the following raw materials in parts by weight: 20-40 parts of sodium alginate, 10-20 parts of chitosan, 1-3 parts of alkyl glycoside and 100-200 parts of distilled water.
7. The process for preparing the ice-drilling permeable membrane according to claim 1, wherein the cellular texture mold containing the coagulant coating is prepared by the following steps:
firstly, adding konjac glucomannan, calcium chloride, glutaraldehyde, citric acid, rubberlith powder and chinaroot greenbrier seed oil into distilled water, and uniformly mixing to form a coagulant solution; and then immersing the honeycomb grain mold into the coagulant solution, taking out the mold after 20-40min, and drying to obtain the honeycomb grain mold containing the coagulant coating.
8. The production and preparation process of the ice drilling permeable membrane according to claim 7, wherein the coagulant solution comprises the following raw materials in parts by weight: 10-20 parts of konjac gum, 11-15 parts of calcium chloride, 8-10 parts of glutaraldehyde, 1-3 parts of citric acid, 5-10 parts of ruby powder, 1-3 parts of chinaroot greenbrier seed oil and 80-100 parts of distilled water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211435067.9A CN115928434B (en) | 2022-11-16 | 2022-11-16 | Production and preparation process of ice drill coagulation membrane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211435067.9A CN115928434B (en) | 2022-11-16 | 2022-11-16 | Production and preparation process of ice drill coagulation membrane |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115928434A true CN115928434A (en) | 2023-04-07 |
| CN115928434B CN115928434B (en) | 2024-08-27 |
Family
ID=86696979
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202211435067.9A Active CN115928434B (en) | 2022-11-16 | 2022-11-16 | Production and preparation process of ice drill coagulation membrane |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115928434B (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0457672A1 (en) * | 1990-05-16 | 1991-11-21 | Shin-Etsu Chemical Co., Ltd. | Toiletry preparation |
| CN108166157A (en) * | 2017-12-25 | 2018-06-15 | 合肥洁诺无纺布制品有限公司 | Antibacterial spunlace non-woven cloth beauty mask base fabric of a kind of moisture absorption and preparation method thereof |
| CN108547058A (en) * | 2018-04-18 | 2018-09-18 | 魏科峰 | A kind of bamboo charcoal Biofibre facial mask base fabric of high water lock anti-drip and high water lock moisture saver mask |
| CN108785130A (en) * | 2018-07-06 | 2018-11-13 | 佛山皖阳生物科技有限公司 | A kind of preparation method of mounted facial mask special face pack base fabric |
| CN111419774A (en) * | 2020-06-01 | 2020-07-17 | 苏州逸纪杰电子科技有限公司 | High-moisture-retention facial mask based on cellulose fibers and preparation method thereof |
| CN115198444A (en) * | 2022-07-04 | 2022-10-18 | 宜兴申联机械制造有限公司 | Preparation method of high-breathability 3D three-dimensional spunlace net for mask base cloth |
-
2022
- 2022-11-16 CN CN202211435067.9A patent/CN115928434B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0457672A1 (en) * | 1990-05-16 | 1991-11-21 | Shin-Etsu Chemical Co., Ltd. | Toiletry preparation |
| CN108166157A (en) * | 2017-12-25 | 2018-06-15 | 合肥洁诺无纺布制品有限公司 | Antibacterial spunlace non-woven cloth beauty mask base fabric of a kind of moisture absorption and preparation method thereof |
| CN108547058A (en) * | 2018-04-18 | 2018-09-18 | 魏科峰 | A kind of bamboo charcoal Biofibre facial mask base fabric of high water lock anti-drip and high water lock moisture saver mask |
| CN108785130A (en) * | 2018-07-06 | 2018-11-13 | 佛山皖阳生物科技有限公司 | A kind of preparation method of mounted facial mask special face pack base fabric |
| CN111419774A (en) * | 2020-06-01 | 2020-07-17 | 苏州逸纪杰电子科技有限公司 | High-moisture-retention facial mask based on cellulose fibers and preparation method thereof |
| CN115198444A (en) * | 2022-07-04 | 2022-10-18 | 宜兴申联机械制造有限公司 | Preparation method of high-breathability 3D three-dimensional spunlace net for mask base cloth |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115928434B (en) | 2024-08-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101922064B (en) | Bacterial cellulose and natural polysaccharide blend fiber and preparation method thereof | |
| CN112176525B (en) | One-way water guide mask base material and preparation method thereof | |
| CN106948180A (en) | The preparation method of woven fabric first layer leather | |
| CN105463605A (en) | Method for preparing antibacterial viscose fibers by comprehensively utilizing water lilies | |
| CN108721679B (en) | Anti-inflammatory and antibacterial medical dressing | |
| CN115928434B (en) | Production and preparation process of ice drill coagulation membrane | |
| CN101570935B (en) | Modification method for preparing highly-hydrophilic real silk fiber spunlace non-woven material | |
| CN111235901A (en) | Processing method of super-simulation leather mildew-proof antibacterial superfine fiber synthetic leather | |
| CN102220647B (en) | Manufacturing method of bamboo pulp high-dissolved functional fiber and spinneret plate used therein | |
| CN108505215B (en) | Degradable hot air non-woven fabric and preparation method thereof | |
| CN111139593A (en) | Preparation method of high-toughness mask fabric | |
| CN111593477A (en) | Mask base cloth, preparation method thereof and mask containing mask base cloth | |
| CN115161792B (en) | Washable light thermal aerogel regenerated cellulose fiber and preparation method thereof | |
| CN103088495A (en) | Method for producing refined hemp cotton blended vortex spinning finished product | |
| CN1190531C (en) | Manufacturing method for bamboo cellulose fibre by solvent method | |
| CN105595705A (en) | Ecological cotton comforter batt and preparation method thereof | |
| CN115198444A (en) | Preparation method of high-breathability 3D three-dimensional spunlace net for mask base cloth | |
| CN107641849A (en) | A kind of preparation method of elastic force bubble satin antibacterial polyurethane fiber | |
| CN113774659A (en) | Preparation method of centella asiatica fiber | |
| CN113174697A (en) | Tough environment-friendly type carex meyeriana non-woven fabric with good heat preservation performance and preparation method thereof | |
| CN106521697A (en) | Carboxyethyl chitosan and polyvinyl alcohol composite fiber and preparation method and application thereof | |
| CN111394830A (en) | Seaweed fiber containing Tremella polysaccharide and its preparation method | |
| CN105780486A (en) | Waterborne polyurethane coating agent containing superfine down feather fiber-bacterial cellulose microsphere | |
| CN105560071A (en) | Seaweed mask and production method thereof | |
| CN104963020A (en) | Down feather complex fiber with good breathability |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |