CN111334170A - 一种uvled光油的配方 - Google Patents

一种uvled光油的配方 Download PDF

Info

Publication number
CN111334170A
CN111334170A CN202010373171.4A CN202010373171A CN111334170A CN 111334170 A CN111334170 A CN 111334170A CN 202010373171 A CN202010373171 A CN 202010373171A CN 111334170 A CN111334170 A CN 111334170A
Authority
CN
China
Prior art keywords
parts
acrylic
stirring
gloss oil
hexanediol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010373171.4A
Other languages
English (en)
Inventor
朱梦白
邓仔辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Yinlu New Material Co ltd
Original Assignee
Zhejiang Yinlu New Material Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Yinlu New Material Co ltd filed Critical Zhejiang Yinlu New Material Co ltd
Priority to CN202010373171.4A priority Critical patent/CN111334170A/zh
Publication of CN111334170A publication Critical patent/CN111334170A/zh
Pending legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10—Epoxy resins modified by unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/47—Levelling agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/48—Stabilisers against degradation by oxygen, light or heat
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epoxy Resins (AREA)

Abstract

本发明公开了一种UVLED光油的配方，包括以下组分：丙烯酸环氧树脂、丙烯酸聚酯树脂、丙烯酸单体、光敏剂、感光性树脂、消泡剂、流平剂、己二醇和光稳定剂，所述分量如下：丙烯酸环氧树脂20‑30份；丙烯酸聚酯树脂10‑20份；丙烯酸单体40‑50份；光敏剂10‑12份；感光性树脂10‑12份；消泡剂0.5‑1份；流平剂0.5‑1份；己二醇1‑2份；光稳定剂0.3‑0.5份，所述光油的工艺包括A：部分材料加热；B：剩余材料混合匀速搅拌；C：把A加入B后高速搅拌；D：检验、过滤和包装。本发明工艺合理，并且通过添加己二醇和光稳定剂从而使光油干燥速度快且使用寿命长。

Description

一种UVLED光油的配方
技术领域
本发明涉及UV光油技术领域，特别涉及一种UVLED光油的配方。
背景技术
UV光油是一种透明的涂料，也有人称之为UV清漆，其作用是喷涂或滚涂在基材表面之后，经过UV灯的照射，使其由液态转化为固态，进而达到表面硬化，实现其耐刮耐划的作用，且表面看起来光亮、美观、质感圆润。然而，传统的UV光油的干燥速度普遍较慢，且使用寿命较短。
发明内容
本发明的目的是提供一种UVLED光油的配方，具有干燥速度快和使用寿命长的优点。
本发明的上述技术目的是通过以下技术方案得以实现的：
一种UVLED光油的配方，包括以下组分：丙烯酸环氧树脂、丙烯酸聚酯树脂、丙烯酸单体、光敏剂、感光性树脂、消泡剂、流平剂、己二醇和光稳定剂，所述分量如下：丙烯酸环氧树脂20-30份；丙烯酸聚酯树脂10-20份；丙烯酸单体40-50份；光敏剂10-12份；感光性树脂10-12份；消泡剂0.5-1份；流平剂0.5-1份；己二醇1-2份；光稳定剂0.3-0.5份，所述光油的工艺包括A：部分材料加热；B：剩余材料混合匀速搅拌；C：把A加入B后高速搅拌；D：检验、过滤和包装。
作为优选，在A中先将一部分丙烯酸单体与光敏剂和光稳定剂在温度100℃以下混合加热，直至完全融化。
作为优选，在B中把剩下的部分丙烯酸单体与环氧树脂、聚酯树脂、感光性树脂、消泡剂和流平剂混合加入在反应釜中，反应釜搅拌速度600-900转/分钟，最终通过搅拌把材料都分散均匀。
作为优选，在C中先把A中完全融化的材料加入存放着剩余材料的反应釜中，接着再把己二醇加入至反应釜中，反应釜搅拌速度900-1200转/分钟，最终通过快速搅拌把所有材料都分散均匀。
作为优选，所述消泡剂为矿物油活聚醚改性有机硅。
作为优选，所述流平剂为聚醚改性有机硅烷。
作为优选，所述光稳定剂为UV3346。
本发明提供了一种UVLED光油的配方，包含丙烯酸环氧树脂、丙烯酸聚酯树脂、丙烯酸单体、光敏剂、感光性树脂、消泡剂、流平剂、己二醇和光稳定剂，消泡剂能降低水、溶液、悬浮液等的表面张力，并且防止了泡沫形成；流平剂能促使光油在干燥成膜过程中形成一个平整、光滑、均匀的涂膜，并且能减少刷涂时产生斑点和斑痕的可能性，增加覆盖性，使成膜均匀、自然；己二醇作为助剂时能加快光油的干燥速度，光稳定剂能屏蔽或吸收紫外线的能量，猝灭单线态氧及将氢过氧化物分解成非活性物质等功能，使光油在光的辐射下，能排除或减缓光化学反应可能性，阻止或延迟光老化的过程，从而达到延长光油使用寿命的目的。
附图说明
图1为实施例的流程图。
具体实施方式
以下所述仅是本发明的优选实施方式，保护范围并不仅局限于该实施例，凡属于本发明思路下的技术方案应当属于本发明的保护范围。同时应当指出，对于本技术领域的普通技术人员而言，在不脱离本发明原理前提下的若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。
一种UVLED光油的配方，包括以下组分：丙烯酸环氧树脂、丙烯酸聚酯树脂、丙烯酸单体、光敏剂、感光性树脂、消泡剂、流平剂、己二醇和光稳定剂，消泡剂为矿物油活聚醚改性有机硅，流平剂为聚醚改性有机硅烷，光稳定剂为UV3346，分量如下：丙烯酸环氧树脂20-30份；丙烯酸聚酯树脂10-20份；丙烯酸单体40-50份；光敏剂10-12份；感光性树脂10-12份；消泡剂0.5-1份；流平剂0.5-1份；己二醇1-2份；光稳定剂0.3-0.5份。
光油的工艺包括A：部分材料加热；先将一部分丙烯酸单体与光敏剂和光稳定剂在温度100℃以下混合加热，直至完全融化。
B：剩余材料混合匀速搅拌，把剩下的部分丙烯酸单体与环氧树脂、聚酯树脂、感光性树脂、消泡剂和流平剂混合加入在反应釜中，反应釜搅拌速度600-900转/分钟，最终通过搅拌把材料都分散均匀。
C：把A加入B后高速搅拌，先把A中完全融化的材料加入存放着剩余材料的反应釜中，接着再把己二醇加入至反应釜中，反应釜搅拌速度900-1200转/分钟，最终通过快速搅拌把所有材料都分散均匀。
D：检验、过滤和包装。
本发明提供了一种UVLED光油的配方，包含丙烯酸环氧树脂、丙烯酸聚酯树脂、丙烯酸单体、光敏剂、感光性树脂、消泡剂、流平剂、己二醇和光稳定剂，消泡剂能降低水、溶液、悬浮液等的表面张力，并且防止了泡沫形成；流平剂能促使光油在干燥成膜过程中形成一个平整、光滑、均匀的涂膜，并且能减少刷涂时产生斑点和斑痕的可能性，增加覆盖性，使成膜均匀、自然；己二醇作为助剂时能加快光油的干燥速度，光稳定剂能屏蔽或吸收紫外线的能量，猝灭单线态氧及将氢过氧化物分解成非活性物质等功能，使光油在光的辐射下，能排除或减缓光化学反应可能性，阻止或延迟光老化的过程，从而达到延长光油使用寿命的目的。

Claims (7)

1.一种UVLED光油的配方，其特征在于，包括以下组分：丙烯酸环氧树脂、丙烯酸聚酯树脂、丙烯酸单体、光敏剂、感光性树脂、消泡剂、流平剂、己二醇和光稳定剂，所述分量如下：丙烯酸环氧树脂20-30份；丙烯酸聚酯树脂10-20份；丙烯酸单体40-50份；光敏剂10-12份；感光性树脂10-12份；消泡剂0.5-1份；流平剂0.5-1份；己二醇1-2份；光稳定剂0.3-0.5份，所述光油的工艺包括A：部分材料加热；B：剩余材料混合匀速搅拌；C：把A加入B后高速搅拌；D：检验、过滤和包装。
2.根据权利要求1所述的一种UVLED光油的配方，其特征在于，在A中先将一部分丙烯酸单体与光敏剂和光稳定剂在温度100℃以下混合加热，直至完全融化。
3.根据权利要求2所述的一种UVLED光油的配方，其特征在于，在B中把剩下的部分丙烯酸单体与环氧树脂、聚酯树脂、感光性树脂、消泡剂和流平剂混合加入在反应釜中，反应釜搅拌速度600-900转/分钟，最终通过搅拌把材料都分散均匀。
4.根据权利要求3所述的一种UVLED光油的配方，其特征在于，在C中先把A中完全融化的材料加入存放着剩余材料的反应釜中，接着再把己二醇加入至反应釜中，反应釜搅拌速度900-1200转/分钟，最终通过快速搅拌把所有材料都分散均匀。
5.根据权利要求4所述的一种UVLED光油的配方，其特征在于，所述消泡剂为矿物油活聚醚改性有机硅。
6.根据权利要求5所述的一种UVLED光油的配方，其特征在于，所述流平剂为聚醚改性有机硅烷。
7.根据权利要求6所述的一种UVLED光油的配方，其特征在于，所述光稳定剂为UV3346。
CN202010373171.4A 2020-05-06 2020-05-06 一种uvled光油的配方 Pending CN111334170A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010373171.4A CN111334170A (zh) 2020-05-06 2020-05-06 一种uvled光油的配方

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010373171.4A CN111334170A (zh) 2020-05-06 2020-05-06 一种uvled光油的配方

Publications (1)

Publication Number Publication Date
CN111334170A true CN111334170A (zh) 2020-06-26

Family

ID=71179305

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010373171.4A Pending CN111334170A (zh) 2020-05-06 2020-05-06 一种uvled光油的配方

Country Status (1)

Country Link
CN (1) CN111334170A (zh)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101044193B1 (ko) * 2011-03-23 2011-06-28 정필문 Ｌｅｄ 평면조명장치용 패턴도광판 및 그 제조방법, 이를 이용한 ｌｅｄ 평면조명장치
WO2015105668A1 (en) * 2014-01-08 2015-07-16 Sun Chemical Corporation Energy curable inks with improved adhesion a method for formulating
CN105885524A (zh) * 2016-06-20 2016-08-24 上海飞凯光电材料股份有限公司 一种uv-led固化用油墨及其制备方法和应用
CN106280686A (zh) * 2015-05-26 2017-01-04 苏州市贝特利高分子材料股份有限公司 高遮盖黑色uv丝印油墨
CN108373786A (zh) * 2016-11-10 2018-08-07 广西真龙彩印包装有限公司 一种卷烟纸包装印刷品用防水雾、可烫金、uv-led固化上光油
CN108641470A (zh) * 2018-05-17 2018-10-12 清远慧谷新材料技术有限公司 一种uv-led固化移印油墨及其制备方法、应用
CN108912816A (zh) * 2018-09-20 2018-11-30 永修县利君科技有限公司 一种led固化的水转印油墨

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101044193B1 (ko) * 2011-03-23 2011-06-28 정필문 Ｌｅｄ 평면조명장치용 패턴도광판 및 그 제조방법, 이를 이용한 ｌｅｄ 평면조명장치
WO2015105668A1 (en) * 2014-01-08 2015-07-16 Sun Chemical Corporation Energy curable inks with improved adhesion a method for formulating
CN106280686A (zh) * 2015-05-26 2017-01-04 苏州市贝特利高分子材料股份有限公司 高遮盖黑色uv丝印油墨
CN105885524A (zh) * 2016-06-20 2016-08-24 上海飞凯光电材料股份有限公司 一种uv-led固化用油墨及其制备方法和应用
CN108373786A (zh) * 2016-11-10 2018-08-07 广西真龙彩印包装有限公司 一种卷烟纸包装印刷品用防水雾、可烫金、uv-led固化上光油
CN108641470A (zh) * 2018-05-17 2018-10-12 清远慧谷新材料技术有限公司 一种uv-led固化移印油墨及其制备方法、应用
CN108912816A (zh) * 2018-09-20 2018-11-30 永修县利君科技有限公司 一种led固化的水转印油墨

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
李肇强: "《现代涂料的生产及应用》", 31 March 2017, 上海科学技术文献出版社 *
李路海: "《印刷包装功能材料》", 31 January 2013, 中国轻工业出版社 *

Similar Documents

Publication Publication Date Title
US5349002A (en) Heat curable primerless silicone hardcoat compositions, and thermoplastic composites
KR20050118276A (ko) 고에너지 방사선에 의해 경화 가능한 아크릴옥시 작용성실리콘 조성물
KR930021750A (ko) 내마모성 자외선 경화성 경질 코팅 조성물
US5411807A (en) Heat curable primerless silicone hardcoat compositions
CN111334170A (zh) 一种uvled光油的配方
CN101967343A (zh) 一种光固化色漆
CA2457494A1 (en) An ultra-violet radiation curable ink composition and a process for its application on glass substrates
US4775597A (en) Ultraviolet light curable compositions for application to porous substrates based on unsaturated polyesters reacted with amino alcohols
Chang et al. Supported zinc oxide photocatalyst for decolorization and mineralization of orange G dye wastewater under UV365 irradiation
US5712321A (en) Dual-curing coating formulation and method
EP0906351A1 (en) Photopolymerizable polyester composition and process for the production thereof
CN110669375A (zh) 节能环保型led-uv固化油墨及其制备方法
CN106349890A (zh) 一种适用于手持led‑uv光源固化的木器底漆及制法
JP5100077B2 (ja) シリカ膜の製造方法
Arimitsu et al. UV-Curable organic-inorganic hybrids containing a base amplifier
CN114523528A (zh) 一种耐紫外线和超疏水的胶合木及其制备方法
CN108585108A (zh) 一种光催化处理含砷废水的装置
JP2003245606A (ja) 熱硬化塗膜形成方法
KR100417790B1 (ko) 광촉매용 피복조성물의 제조방법 및 그에 의해 제조된 광촉매용 피복조성물
JP2005298754A (ja) 活性エネルギー線硬化性コーティング用組成物および保護被膜形成方法
Dvorchak et al. UV Curing of Nail Gels by Light Emitting Diode (LED) and Fluorescent (FL) Light Sources
JP2007160524A (ja) 不飽和ポリエステル親水防汚成形体及びその処理方法
CN110157256A (zh) 基于石墨烯的光催化涂料及其制备方法
CN118146702A (zh) 新型uv延迟固化三防漆及其喷涂固化工艺
CN117487398A (zh) 一种阻焊油墨及背光mini-led的阻焊方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20200626