CN111235893A - 一种有机硅整理剂及其制备方法 - Google Patents

一种有机硅整理剂及其制备方法 Download PDF

Info

Publication number
CN111235893A
CN111235893A CN201910674831.XA CN201910674831A CN111235893A CN 111235893 A CN111235893 A CN 111235893A CN 201910674831 A CN201910674831 A CN 201910674831A CN 111235893 A CN111235893 A CN 111235893A
Authority
CN
China
Prior art keywords
component
finishing agent
stirring
percent
emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910674831.XA
Other languages
English (en)
Inventor
罗祖存
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Decai New Material Technology Co Ltd
Original Assignee
Zhejiang Decai New Material Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Decai New Material Technology Co Ltd filed Critical Zhejiang Decai New Material Technology Co Ltd
Priority to CN201910674831.XA priority Critical patent/CN111235893A/zh
Publication of CN111235893A publication Critical patent/CN111235893A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D06M2101/08—Esters or ethers of cellulose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
    • D06M2101/28—Acrylonitrile; Methacrylonitrile
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/38—Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

本发明公开了一种有机硅整理剂及其制备方法，有机硅整理剂的原料及其质量百分比为：A组分10%，B组分20%，C组分30%，D组分15%，吸湿排汗整理剂25%，包括如下步骤：（1）A组分的稀释；（2）B组分的稀释；（3）C组分的稀释；（4）吸湿排汗整理剂的稀释；（5）将D组分加入搅拌缸中，搅拌3‑5min，在搅拌状态下，进行3‑5次加水，加水量为每次1‑2kg，使其充分乳化，再将步骤（1）、（2）和（3）稀释的A组分乳液、B组分乳液和C组分乳液加入搅拌缸中，继续搅拌10‑20min，使其充分乳化，再加入步骤（4）稀释的吸湿排汗整理剂乳液，继续搅拌20‑30min，使其完全均匀，加滤网过滤放料，得有机硅整理剂成品；（6）称重，待检测合格后，入库摆放整齐。

Description

一种有机硅整理剂及其制备方法
技术领域
本发明涉及纺织添加剂领域，特别涉及一种有机硅整理剂及其制备方法。
背景技术
随着经济的增长，人们对纺织品舒适性要求也不断提升，不仅手感方面需要优异的滑爽冰凉、细腻、回弹、蓬松、柔软感；舒适性方面需要透气、吸湿排汗、环保。基于上述需求，本发明提供一种对毛绒、棉、麻、涤纶、涤棉等各种纤维混纺织物有优越的柔软、爽滑、蓬松之手感，整理后的织物丰满、滑爽的有机硅整理剂。
发明内容
本发明要解决的技术问题是提供一种有优越的柔软、爽滑、蓬松之手感，整理后的织物丰满、滑爽的有机硅整理剂。
为了解决上述技术问题，本发明通过以下技术方案实现：
一种有机硅整理剂，所述有机硅整理剂的原料及其质量百分比为：
A组分 10-20%
B组分 15-25%
C组分 20-30%
D组分 5-15%
吸湿排汗整理剂 25-35%
所述A组分的原料及其质量百分比为：
硅氧烷40-45%
氨基 12-15%
聚醚 40-45%
所述B组分的原料及其质量百分比为：
硅氧烷46-50%
氨基 8-10%
聚醚 40-45%
所述C组分的原料及其质量百分比为：
硅氧烷聚合物 10-40%
异丙醇 5-20%
脂肪醇聚氧乙烯醚 1-6%
水 30-50%
所述D组分的原料及其质量百分比为：
氨含量为0.6%的氨基硅油 30-35%
氨含量为0.3%的氨基硅油 30-35%
非离子乳化剂 30-35%
溶剂 4-8%。
作为优选，上述所述有机硅整理剂的原料及其质量百分比为：A组分15%，B组分20%；C组分25%；D组分10%，吸湿排汗整理剂30%。
一种有机硅整理剂的制备方法，包括如下步骤：
（1）A组分的稀释：把A组分加入反应釜内，再加入A组分1-4%的冰醋，搅拌均匀后，然后一边搅拌一边慢慢加入自来水，稀释形成一定浓度的乳液，加滤网过滤放料，备用；
（2）B组分的稀释：稀释步骤同步骤（1）；
（3）C组分的稀释：稀释步骤同步骤（1）；
（4）吸湿排汗整理剂的稀释：将吸湿排汗整理剂原料逐渐加入水中，水的温度为90-95℃，边加料边搅拌，使其膨胀，慢慢融化，融化后将稀释环境温度降至80-85℃，保温145-150min，再冷却至40-50℃，稀释形成一定浓度的乳液，加滤网过滤放料，备用；
（5）将D组分加入搅拌缸中，搅拌3-5min，在搅拌状态下，进行3-5次加水，加水量为每次1-2kg，使其充分乳化，再将步骤（1）、（2）和（3）稀释的A组分乳液、B组分乳液和C组分乳液加入搅拌缸中，继续搅拌10-20min，使其充分乳化，再加入步骤（4）稀释的吸湿排汗整理剂乳液，继续搅拌20-30min，使其完全均匀，加滤网过滤放料，得有机硅整理剂成品；
（6）称重，待检测合格后，入库摆放整齐。
作为优选，上述步骤（4）中所述的吸湿排汗整理剂为水溶性聚酯。
本发明的有益效果是：
（1）本发明的有机硅整理剂不含APEO、NPEO，符合GB环保标准，绿色环保，具备优秀的耐水洗性和良好的使用安全性，能与阳离子/非离子表面活性剂相容，高效、环保、节能降耗，用于毛绒、棉、涤纶及其混纺织物的手感整理，整理后的织物丰满、滑爽，可使毛绒、棉、麻、涤纶、涤棉等各种纤维混纺织物有优越的柔软、爽滑、蓬松之手感；
（2）本发明中选用的A组分原料，克服了普通氨基硅油稳定性差，不可复染的缺点，是普通氨基硅油的更新换代产品，用于各种毛绒织物后整理，可加强织物的蓬松手感；
（3）本发明中选用的B组分原料，用于化纤的后整理，特别用于带绒毛的化纤布，柔软性、滑爽性、蓬松性俱佳；对于涤、涤棉、人棉混纺织物，也可获得非常优异的手感；
（4）本发明中选用的C组分原料，主要用于锦棉，涤棉混纺织物柔软和蓬松整理，也可适用于全涤织物，棉织物等手感整理，能给予织物蓬松丰满手感，与一般的氨基改性有机硅柔软剂相比，其拥有崭新的改性有机硅化学结构，再配合双重改性功能团，它能赋予织物更加出色的柔软蓬松性和滑弹手感；同时在人造纤维上（如涤纶、尼龙、腈纶、人造棉、毛等）均有很好的柔软和蓬松效果；
（5）本发明中选用的吸湿排汗整理剂，其为非离子高分子聚合物，本产品适用于涤纶、涤棉混纺、锦纶、醋酸纤维及氨纶等织物的后整理工艺，可使织物具有优异的蓬松性和柔软手感，减少织物的擦伤、折痕，赋予织物良好的吸湿排汗及抗静电和易去污性。
具体实施方式
下面对本发明的具体实施方式作进一步说明。在此需要说明的是，对于这些实施方式的说明用于帮助理解本发明，但并不构成对本发明的限定。此外，下面所描述的本发明各个实施方式中所涉及的技术特征只要彼此之间未构成冲突就可以相互组合。
实施例1
一种有机硅整理剂及其制备方法，有机硅整理剂的原料及其质量百分比为：A组分10%，B组分20%，C组分30%，D组分15%，吸湿排汗整理剂25%，包括如下步骤：
（1）A组分的稀释：把A组分加入反应釜内，再加入A组分1%的冰醋，搅拌均匀后，然后一边搅拌一边慢慢加入自来水，稀释形成一定浓度的乳液，加滤网过滤放料，备用；
（2）B组分的稀释：稀释步骤同步骤（1）；
（3）C组分的稀释：稀释步骤同步骤（1）；
（4）吸湿排汗整理剂的稀释：将吸湿排汗整理剂原料逐渐加入水中，水的温度为90-95℃，边加料边搅拌，使其膨胀，慢慢融化，融化后将稀释环境温度降至80-85℃，保温145-150min，再冷却至40-50℃，稀释形成一定浓度的乳液，加滤网过滤放料，备用；
（5）将D组分加入搅拌缸中，搅拌3-5min，在搅拌状态下，进行5次加水，加水量为每次1kg，使其充分乳化，再将步骤（1）、（2）和（3）稀释的A组分乳液、B组分乳液和C组分乳液加入搅拌缸中，继续搅拌15min，使其充分乳化，再加入步骤（4）稀释的吸湿排汗整理剂乳液，继续搅拌20min，使其完全均匀，加滤网过滤放料，得有机硅整理剂成品；
（6）称重，待检测合格后，入库摆放整齐。
其中，A组分的原料及其质量百分比为：硅氧烷40-45%，氨基12-15%，聚醚40-45%，B组分的原料及其质量百分比为：硅氧烷46-50%，氨基8-10%，聚醚40-45%，C组分的原料及其质量百分比为：硅氧烷聚合物10-40%，异丙醇5-20%，脂肪醇聚氧乙烯醚1-6%，水30-50%，D组分的原料及其质量百分比为：氨含量为0.6%的氨基硅油30-35%，氨含量为0.3%的氨基硅油30-35%，非离子乳化剂30-35%，溶剂4-8%。
实施例2
一种有机硅整理剂及其制备方法，有机硅整理剂的原料及其质量百分比为：A组分15%，B组分20%，C组分25%，D组分105%，吸湿排汗整理剂30%，包括如下步骤：
（1）A组分的稀释：把A组分加入反应釜内，再加入A组分2%的冰醋，搅拌均匀后，然后一边搅拌一边慢慢加入自来水，稀释形成一定浓度的乳液，加滤网过滤放料，备用；
（2）B组分的稀释：稀释步骤同步骤（1）；
（3）C组分的稀释：稀释步骤同步骤（1）；
（4）吸湿排汗整理剂的稀释：将吸湿排汗整理剂原料逐渐加入水中，水的温度为90-95℃，边加料边搅拌，使其膨胀，慢慢融化，融化后将稀释环境温度降至80-85℃，保温145-150min，再冷却至40-50℃，稀释形成一定浓度的乳液，加滤网过滤放料，备用；
（5）将D组分加入搅拌缸中，搅拌3-5min，在搅拌状态下，进行3次加水，加水量为每次2kg，使其充分乳化，再将步骤（1）、（2）和（3）稀释的A组分乳液、B组分乳液和C组分乳液加入搅拌缸中，继续搅拌20min，使其充分乳化，再加入步骤（4）稀释的吸湿排汗整理剂乳液，继续搅拌25min，使其完全均匀，加滤网过滤放料，得有机硅整理剂成品；
（6）称重，待检测合格后，入库摆放整齐。
其中A组分，B组分，C组分和D组分的原料及其质量百分比同实施例1。
实施例3
一种有机硅整理剂及其制备方法，有机硅整理剂的原料及其质量百分比为：A组分20%，B组分25%，C组分20%，D组分5%，吸湿排汗整理剂30%，包括如下步骤：
（1）A组分的稀释：把A组分加入反应釜内，再加入A组分3%的冰醋，搅拌均匀后，然后一边搅拌一边慢慢加入自来水，稀释形成一定浓度的乳液，加滤网过滤放料，备用；
（2）B组分的稀释：稀释步骤同步骤（1）；
（3）C组分的稀释：稀释步骤同步骤（1）；
（4）吸湿排汗整理剂的稀释：将吸湿排汗整理剂原料逐渐加入水中，水的温度为90-95℃，边加料边搅拌，使其膨胀，慢慢融化，融化后将稀释环境温度降至80-85℃，保温145-150min，再冷却至40-50℃，稀释形成一定浓度的乳液，加滤网过滤放料，备用；
（5）将D组分加入搅拌缸中，搅拌3-5min，在搅拌状态下，进行4次加水，加水量为每次1.5kg，使其充分乳化，再将步骤（1）、（2）和（3）稀释的A组分乳液、B组分乳液和C组分乳液加入搅拌缸中，继续搅拌10min，使其充分乳化，再加入步骤（4）稀释的吸湿排汗整理剂乳液，继续搅拌30min，使其完全均匀，加滤网过滤放料，得有机硅整理剂成品；
（6）称重，待检测合格后，入库摆放整齐。
其中A组分，B组分，C组分和D组分的原料及其质量百分比同实施例1。
实施例4
一种有机硅整理剂及其制备方法，有机硅整理剂的原料及其质量百分比为：A组分18%，B组分15%，C组分22%，D组分10%，吸湿排汗整理剂35%，包括如下步骤：
（1）A组分的稀释：把A组分加入反应釜内，再加入A组分4%的冰醋，搅拌均匀后，然后一边搅拌一边慢慢加入自来水，稀释形成一定浓度的乳液，加滤网过滤放料，备用；
（2）B组分的稀释：稀释步骤同步骤（1）；
（3）C组分的稀释：稀释步骤同步骤（1）；
（4）吸湿排汗整理剂的稀释：将吸湿排汗整理剂原料逐渐加入水中，水的温度为90-95℃，边加料边搅拌，使其膨胀，慢慢融化，融化后将稀释环境温度降至80-85℃，保温145-150min，再冷却至40-50℃，稀释形成一定浓度的乳液，加滤网过滤放料，备用；
（5）将D组分加入搅拌缸中，搅拌3-5min，在搅拌状态下，进行3次加水，加水量为每次2kg，使其充分乳化，再将步骤（1）、（2）和（3）稀释的A组分乳液、B组分乳液和C组分乳液加入搅拌缸中，继续搅拌15min，使其充分乳化，再加入步骤（4）稀释的吸湿排汗整理剂乳液，继续搅拌22min，使其完全均匀，加滤网过滤放料，得有机硅整理剂成品；
（6）称重，待检测合格后，入库摆放整齐。
其中A组分，B组分，C组分和D组分的原料及其质量百分比同实施例1。
作为优选，上述实施例1-4中，步骤（4）中的吸湿排汗整理剂为水溶性聚酯。
以上对本发明的实施方式作了详细说明，但本发明不限于所描述的实施方式。对于本领域的技术人员而言，在不脱离本发明原理和精神的情况下，对这些实施方式进行多种变化、修改、替换和变型，仍落入本发明的保护范围内。

Claims (4)

1.一种有机硅整理剂，其特征在于：所述有机硅整理剂的原料及其质量百分比为：
A组分 10-20%
B组分 15-25%
C组分 20-30%
D组分 5-15%
吸湿排汗整理剂 25-35%
所述A组分的原料及其质量百分比为：
硅氧烷40-45%
氨基 12-15%
聚醚 40-45%
所述B组分的原料及其质量百分比为：
硅氧烷46-50%
氨基 8-10%
聚醚 40-45%
所述C组分的原料及其质量百分比为：
硅氧烷聚合物 10-40%
异丙醇 5-20%
脂肪醇聚氧乙烯醚 1-6%
水 30-50%
所述D组分的原料及其质量百分比为：
氨含量为0.6%的氨基硅油 30-35%
氨含量为0.3%的氨基硅油 30-35%
非离子乳化剂 30-35%
溶剂 4-8%。
2.根据权利要求1所述的一种有机硅整理剂，其特征在于：所述有机硅整理剂的原料及其质量百分比为：A组分15%，B组分20%；C组分25%；D组分10%，吸湿排汗整理剂30%。
3.根据权利要求1-2任一项所述的一种有机硅整理剂的制备方法，其特征在于：包括如下步骤：
A组分的稀释：把A组分加入反应釜内，再加入A组分1-4%的冰醋，搅拌均匀后，然后一边搅拌一边慢慢加入自来水，稀释形成一定浓度的乳液，加滤网过滤放料，备用；
B组分的稀释：稀释步骤同步骤（1）；
C组分的稀释：稀释步骤同步骤（1）；
吸湿排汗整理剂的稀释：将吸湿排汗整理剂原料逐渐加入水中，水的温度为90-95℃，边加料边搅拌，使其膨胀，慢慢融化，融化后将稀释环境温度降至80-85℃，保温145-150min，再冷却至40-50℃，稀释形成一定浓度的乳液,加滤网过滤放料，备用；
将D组分加入搅拌缸中，搅拌3-5min，在搅拌状态下，进行3-5次加水，加水量为每次1-2kg，使其充分乳化，再将步骤（1）、（2）和（3）稀释的A组分乳液、B组分乳液和C组分乳液加入搅拌缸中，继续搅拌10-20min，使其充分乳化，再加入步骤（4）稀释的吸湿排汗整理剂乳液，继续搅拌20-30min，使其完全均匀，加滤网过滤放料，得有机硅整理剂成品；
称重，待检测合格后，入库摆放整齐。
4.根据权利要求3所述的一种有机硅整理剂的制备方法，其特征在于：步骤（4）中所述的吸湿排汗整理剂为水溶性聚酯。
CN201910674831.XA 2019-07-25 2019-07-25 一种有机硅整理剂及其制备方法 Pending CN111235893A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910674831.XA CN111235893A (zh) 2019-07-25 2019-07-25 一种有机硅整理剂及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910674831.XA CN111235893A (zh) 2019-07-25 2019-07-25 一种有机硅整理剂及其制备方法

Publications (1)

Publication Number Publication Date
CN111235893A true CN111235893A (zh) 2020-06-05

Family

ID=70873998

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910674831.XA Pending CN111235893A (zh) 2019-07-25 2019-07-25 一种有机硅整理剂及其制备方法

Country Status (1)

Country Link
CN (1) CN111235893A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114108322A (zh) * 2021-11-30 2022-03-01 深圳天鼎新材料有限公司 一种肉感滑弹织物整理剂及其制备方法与应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101497744A (zh) * 2008-07-29 2009-08-05 浙江传化股份有限公司 氨基硅油乳液及其制备方法
CN102031698A (zh) * 2010-11-19 2011-04-27 浙江华晟化学制品有限公司 一种改性自交联有机硅抗皱微乳液免烫整理剂的制备方法
CN102653589A (zh) * 2011-03-02 2012-09-05 上海诺科生物科技有限公司 利用废旧聚酯合成的水溶性或水分散性聚酯及其在纺织加工中的应用
CN103726338A (zh) * 2013-12-17 2014-04-16 薛成强 一种不黄变起毛剂的制造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101497744A (zh) * 2008-07-29 2009-08-05 浙江传化股份有限公司 氨基硅油乳液及其制备方法
CN102031698A (zh) * 2010-11-19 2011-04-27 浙江华晟化学制品有限公司 一种改性自交联有机硅抗皱微乳液免烫整理剂的制备方法
CN102653589A (zh) * 2011-03-02 2012-09-05 上海诺科生物科技有限公司 利用废旧聚酯合成的水溶性或水分散性聚酯及其在纺织加工中的应用
CN103726338A (zh) * 2013-12-17 2014-04-16 薛成强 一种不黄变起毛剂的制造方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114108322A (zh) * 2021-11-30 2022-03-01 深圳天鼎新材料有限公司 一种肉感滑弹织物整理剂及其制备方法与应用
CN114108322B (zh) * 2021-11-30 2024-01-30 深圳天鼎新材料有限公司 一种肉感滑弹织物整理剂及其制备方法与应用

Similar Documents

Publication Publication Date Title
CN107012685B (zh) 一种超软滑抗起毛亲肤cvc汗布生产工艺
CN101603223A (zh) 羊绒和水溶性纤维混纺纱、制备方法及其针织产品
CN102877293A (zh) 适用多种织物的柔软剂
CN111945433B (zh) 一种含腈纶布料后整理用柔软剂及其制备方法
CN105155260A (zh) 一种固体柔软剂及其制备方法
CN115354490B (zh) 一种纤维混纺吸湿抑菌面料的制备方法
CN110699799B (zh) 一种高弹涤纶纱及其制备方法
CN116461160A (zh) 一种耐磨透气的校服面料制备方法
CN111235893A (zh) 一种有机硅整理剂及其制备方法
CN111155223B (zh) 一种高强阻燃面料的制备方法
CN110791965A (zh) 一种面料柔软剂及其制备方法
CN112323213A (zh) 一种竹纤维与羊毛的面料
CN107700037A (zh) 一种亚麻人棉交织面料及其染整方法
CN111235890A (zh) 一种起毛剂及其制备方法
CN106676899A (zh) 一种提高锦/氨针织织物吸湿排汗性能的方法
CN113122991A (zh) 一种吸湿速干织物的制备方法
CN112680971A (zh) 一种性能优异面料及在服装领域的应用
CN110552194A (zh) 一种阻燃性好的抗菌性布料的制备工艺
CN110172832A (zh) 一种多功能面料复合工艺
CN112127153A (zh) 一种抗菌防臭纺织品及其制备方法
KR20020042287A (ko) 셀룰로오스계 의류의 수축 및 주름방지용 처리제 조성물
CN104372478A (zh) 一种新型混纺羊毛及其丝光处理工艺
CN110670238B (zh) 一种抗褶皱高弹麻棉复合纤维及制备方法
CN117306263B (zh) 一种远红外负离子抗菌多功能健康被及其制备方法
CN204356472U (zh) 一种新型混纺羊毛

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20200605

RJ01 Rejection of invention patent application after publication