CN111169111A - 一种高触感耐磨篮球皮革及其制作方法 - Google Patents

一种高触感耐磨篮球皮革及其制作方法 Download PDF

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CN111169111A
CN111169111A CN202010053453.6A CN202010053453A CN111169111A CN 111169111 A CN111169111 A CN 111169111A CN 202010053453 A CN202010053453 A CN 202010053453A CN 111169111 A CN111169111 A CN 111169111A
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parts
modified attapulgite
foaming
stirring
attapulgite
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CN111169111B (zh
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陈侯灿
陈公湖
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Zhangzhou Huafei Sports Goods Co ltd
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Abstract

本发明涉及一种高触感耐磨篮球皮革及其制作方法，该高触感耐磨篮球皮革包括基布、粘结层、发泡层以及表面层；所述表面层包括以下重量份数的组分：水性聚氨酯树脂80‑100份、二甲基甲酰胺100‑120份、聚丙烯酸钠10‑15份、水2‑5份、炭黑10‑15份、石英砂4‑6份、铁基合金粉末5‑10份、改性凹凸棒土5‑10份、N,N–二正丁基二硫氨基甲酸镍2‑5份、聚乙二醇10‑15份、双氧水1‑1.5份、亚硫酸氢钠0.5‑0.8份、发泡剂2‑4份、色粉12‑15份；该篮球皮革具有良好的耐候性能以及耐磨耐刮性能，且其质地柔软，由该篮球皮革制得的篮球弹性好且能及时吸收运动员手掌中的汗水，提高篮球皮革触感。

Description

一种高触感耐磨篮球皮革及其制作方法
技术领域
本发明涉及一种高触感耐磨篮球皮革及其制作方法。
背景技术
篮球是人们普遍的运动方式。目前有真皮和仿真皮，而市场广为应用的是聚氯乙烯(PVC)、聚氨基甲酸酯(PU)为原料的篮球革。传统的篮球革不仅耐候、耐磨性能欠佳，而且其吸湿排汗性能弱，传统的篮球革主要是在其表面压纹、造粒，从而提高篮球革的触感，然而在运动员出汗后，仅仅通过表面压纹、造粒得到的篮球革，其涩感、止滑性能降低，不利于运动员抓附篮球，进而影响运动员的发挥。
发明内容
本发明的目的在于提供一种具有良好耐候、耐磨、耐刮性能且能够及时吸收运动员手部汗液的高触感耐磨篮球皮革及其制作方法。
本发明的目的通过如下技术方案实现：一种高触感耐磨篮球皮革，它包括基布、粘结层、发泡层以及表面层；
其中，所述表面层包括以下重量份数的组分：水性聚氨酯树脂80-100份、二甲基甲酰胺100-120份、聚丙烯酸钠10-15份、水2-5份、炭黑10-15份、石英砂4-6份、铁基合金粉末5-10份、改性凹凸棒土5-10份、N,N–二正丁基二硫氨基甲酸镍2-5份、聚乙二醇10-15份、双氧水1-1.5份、亚硫酸氢钠0.5-0.8份、发泡剂2-4份、色粉12-15份；
所述发泡层包括以下重量份数的组分：水性聚氨酯树脂80-100份、二甲基甲酰胺80-90份、炭黑10-15份、重质碳酸钙30-40份、发泡剂5-8份、乳化剂S-80 3-5份。
较之现有技术而言，本发明的优点在于：本发明将改性凹凸棒土引入篮球皮革的表面层，不仅能够增加篮球皮革耐磨、耐刮、耐候性能，而且能够提高篮球皮革的吸水性能，使由该篮球皮革制成的篮球能够及时吸收运动员手掌中的汗水，提高篮球皮革触感。另外，该篮球皮革具有良好的耐候性能以及耐磨耐刮性能，且其质地柔软，由该篮球皮革制得的篮球弹性好。
具体实施方式
下面结合实施例对本发明内容进行详细说明：
一种高触感耐磨篮球皮革，它包括基布、粘结层、发泡层以及表面层；
其中，所述表面层包括以下重量份数的组分：水性聚氨酯树脂80-100份、二甲基甲酰胺100-120份、聚丙烯酸钠10-15份、水2-5份、炭黑10-15份、石英砂4-6份、铁基合金粉末5-10份、改性凹凸棒土5-10份、N,N–二正丁基二硫氨基甲酸镍2-5份、聚乙二醇10-15份、双氧水1-1.5份、亚硫酸氢钠0.5-0.8份、发泡剂2-4份、色粉12-15份；
所述发泡层包括以下重量份数的组分：水性聚氨酯树脂80-100份、二甲基甲酰胺80-90份、炭黑10-15份、重质碳酸钙30-40份、发泡剂5-8份、乳化剂S-80 3-5份。
所述基布为针织布或无纺布。
所述粘结层由粘结剂形成，所述粘结剂为水溶性酚醛树脂胶黏剂。
所述发泡剂为AC发泡剂、对甲苯磺酰肼中的一种或二者的混合物。
一种所述的高触感耐磨篮球皮革的制作方法，它包括以下步骤：
步骤(1)制备表面层浆料：
步骤a：制备改性凹凸棒土：步骤1)制备酸改性凹凸棒土：将凹凸棒土在750-800℃下焙烧4-5h后，放入10-15％盐酸溶液中浸泡3-4h，捞出，烘干至含水量2-3％，得酸改性凹凸棒土；步骤2)制备复配偶联剂：将重量比为1:2-4的硅烷偶联剂Kh560与马来酸酐进行混合，得复配偶联剂；步骤3)制备偶联剂改性凹凸棒土：在步骤1)所得的酸改性凹凸棒土中加入复配偶联剂，且复配偶联剂的添加量为酸改性凹凸棒土质量的4wt.％-6wt.％，再放入加热式捏合机，进行混合搅拌，搅拌速度为50r/min，搅拌的同时慢速升温，当温度升至80-90℃时，恒温搅拌2-3h，得偶联剂改性凹凸棒土；步骤4)在步骤3)所得的偶联剂改性凹凸棒土中加入硬脂酸，硬脂酸的添加量为酸改性凹凸棒土质量的1.0wt.％-1.2wt.％，利用加热式捏合机继续搅拌升温至95℃时，恒温搅拌1-2h后，进行排料；之后，对排出的物料进行烘干，烘干温度控制在50-60℃，待物料烘干至含水率小于0.5％时，将物料输送至盘式磨粉机，研磨成50-60目的粉末，即得所述改性凹凸棒土。
步骤b：将水性聚氨酯树脂、二甲基甲酰胺、聚丙烯酸钠、水、N,N–二正丁基二硫氨基甲酸镍、聚乙二醇、双氧水、亚硫酸氢钠、发泡剂(该发泡剂为表面层组分中的发泡剂)以及色粉混合后，再进行加热至熔融状态，其中，加热温度为220-230℃，加热时间为40-50min，之后倒入炭黑、石英砂、铁基合金粉末以及步骤a所得的改性凹凸棒土，在相同温度下，以40-50r/min的速度搅拌25-30min，得表面层浆料；
步骤(2)制备发泡层浆料：将水性聚氨酯树脂、二甲基甲酰胺、乳化剂S-80在210-220℃下加热30-40min，之后，加入发泡剂(该发泡剂为发泡层组分中的发泡剂)、炭黑、重质碳酸钙，以40-50r/min的速度搅拌30-40min，得发泡层浆料；
步骤(3)浆料刮涂：将步骤(1)所得的表面层浆料涂覆在离型纸上，100-120℃烘干60-80s，形成表面层；接着，在烘干的表面层上刮涂步骤(2)所得的发泡层浆料，100-120℃烘干60-80s，形成发泡层；之后，在发泡层上刮涂水溶性酚醛树脂胶黏剂作为粘结层，然后覆盖上基布，再在80-100℃下烘干，之后将离型纸剥离，即得所述高触感耐磨篮球皮革。
下面结合具体实施例对本发明作更细致的阐述：
实施例一：
一种高触感耐磨篮球皮革，它包括基布、粘结层、发泡层以及表面层；
其中，所述表面层包括以下组分：水性聚氨酯树脂80kg、二甲基甲酰胺100kg、聚丙烯酸钠15kg、水5kg、炭黑10kg、石英砂6kg、铁基合金粉末5kg、改性凹凸棒土10kg、N,N–二正丁基二硫氨基甲酸镍2kg、聚乙二醇15kg、双氧水1.5kg、亚硫酸氢钠0.8kg、发泡剂4kg、色粉12kg；
所述发泡层包括以下组分：水性聚氨酯树脂80kg、二甲基甲酰胺90kg、炭黑10kg、重质碳酸钙40kg、发泡剂5kg、乳化剂S-80 3kg。
所述基布为无纺布。
所述粘结层由粘结剂形成，所述粘结剂为水溶性酚醛树脂胶黏剂。
所述发泡剂为AC发泡剂。
一种所述的高触感耐磨篮球皮革的制作方法，它包括以下步骤：
步骤(1)制备表面层浆料：
步骤a：制备改性凹凸棒土：步骤1)制备酸改性凹凸棒土：将凹凸棒土在750℃下焙烧5h后，放入10％盐酸溶液中浸泡4h，捞出，烘干至含水量2％，得酸改性凹凸棒土；步骤2)制备复配偶联剂：将重量比为1:2的硅烷偶联剂Kh560与马来酸酐进行混合，得复配偶联剂；步骤3)制备偶联剂改性凹凸棒土：在步骤1)所得的酸改性凹凸棒土中加入复配偶联剂，且复配偶联剂的添加量为酸改性凹凸棒土质量的4wt.％，再放入加热式捏合机，进行混合搅拌，搅拌速度为50r/min，搅拌的同时慢速升温，当温度升至80℃时，恒温搅拌2h，得偶联剂改性凹凸棒土；步骤4)在步骤3)所得的偶联剂改性凹凸棒土中加入硬脂酸，硬脂酸的添加量为酸改性凹凸棒土质量的1.0wt.％，利用加热式捏合机继续搅拌升温至95℃时，恒温搅拌1h后，进行排料；之后，对排出的物料进行烘干，烘干温度控制在50℃，待物料烘干至含水率小于0.5％时，将物料输送至盘式磨粉机，研磨成60目的粉末，即得所述改性凹凸棒土。
步骤b：将水性聚氨酯树脂、二甲基甲酰胺、聚丙烯酸钠、水、N,N–二正丁基二硫氨基甲酸镍、聚乙二醇、双氧水、亚硫酸氢钠、发泡剂以及色粉混合后，再进行加热至熔融状态，其中，加热温度为220℃，加热时间为50min，之后倒入炭黑、石英砂、铁基合金粉末以及步骤a所得的改性凹凸棒土，在相同温度下，以40r/min的速度搅拌30min，得表面层浆料；
步骤(2)制备发泡层浆料：将水性聚氨酯树脂、二甲基甲酰胺、乳化剂S-80在210℃下加热40min，之后，加入发泡剂、炭黑、重质碳酸钙，以40r/min的速度搅拌40min，得发泡层浆料；
步骤(3)浆料刮涂：将步骤(1)所得的表面层浆料涂覆在离型纸上，100℃烘干80s，形成表面层；接着，在烘干的表面层上刮涂步骤(2)所得的发泡层浆料，100℃烘干80s，形成发泡层；之后，在发泡层上刮涂水溶性酚醛树脂胶黏剂作为粘结层，然后覆盖上基布，再在80℃下烘干，之后将离型纸剥离，即得所述高触感耐磨篮球皮革。
实施例二：
一种高触感耐磨篮球皮革，它包括基布、粘结层、发泡层以及表面层；
其中，所述表面层包括以下重量份数的组分：水性聚氨酯树脂100kg、二甲基甲酰胺120kg、聚丙烯酸钠10kg、水2kg、炭黑15kg、石英砂4kg、铁基合金粉末10kg、改性凹凸棒土5kg、N,N–二正丁基二硫氨基甲酸镍5kg、聚乙二醇10kg、双氧水1kg、亚硫酸氢钠0.5kg、发泡剂2kg、色粉15kg；
所述发泡层包括以下重量份数的组分：水性聚氨酯树脂100kg、二甲基甲酰胺80kg、炭黑15kg、重质碳酸钙30kg、发泡剂8kg、乳化剂S-80 5kg。
所述基布为无纺布。
所述粘结层由粘结剂形成，所述粘结剂为水溶性酚醛树脂胶黏剂。
所述发泡剂为AC发泡剂。
一种所述的高触感耐磨篮球皮革的制作方法，它包括以下步骤：
步骤(1)制备表面层浆料：
步骤a：制备改性凹凸棒土：步骤1)制备酸改性凹凸棒土：将凹凸棒土在750℃下焙烧5h后，放入10％盐酸溶液中浸泡4h，捞出，烘干至含水量2％，得酸改性凹凸棒土；步骤2)制备复配偶联剂：将重量比为1:3的硅烷偶联剂Kh560与马来酸酐进行混合，得复配偶联剂；步骤3)制备偶联剂改性凹凸棒土：在步骤1)所得的酸改性凹凸棒土中加入复配偶联剂，且复配偶联剂的添加量为酸改性凹凸棒土质量的4wt.％，再放入加热式捏合机，进行混合搅拌，搅拌速度为50r/min，搅拌的同时慢速升温，当温度升至80℃时，恒温搅拌2h，得偶联剂改性凹凸棒土；步骤4)在步骤3)所得的偶联剂改性凹凸棒土中加入硬脂酸，硬脂酸的添加量为酸改性凹凸棒土质量的1.0wt.％，利用加热式捏合机继续搅拌升温至95℃时，恒温搅拌1h后，进行排料；之后，对排出的物料进行烘干，烘干温度控制在50℃，待物料烘干至含水率小于0.5％时，将物料输送至盘式磨粉机，研磨成60目的粉末，即得所述改性凹凸棒土。
步骤b：将水性聚氨酯树脂、二甲基甲酰胺、聚丙烯酸钠、水、N,N–二正丁基二硫氨基甲酸镍、聚乙二醇、双氧水、亚硫酸氢钠、发泡剂以及色粉混合后，再进行加热至熔融状态，其中，加热温度为220℃，加热时间为50min，之后倒入炭黑、石英砂、铁基合金粉末以及步骤a所得的改性凹凸棒土，在相同温度下，以40r/min的速度搅拌30min，得表面层浆料；
步骤(2)制备发泡层浆料：将水性聚氨酯树脂、二甲基甲酰胺、乳化剂S-80在210℃下加热40min，之后，加入发泡剂、炭黑、重质碳酸钙，以40r/min的速度搅拌40min，得发泡层浆料；
步骤(3)浆料刮涂：将步骤(1)所得的表面层浆料涂覆在离型纸上，100℃烘干80s，形成表面层；接着，在烘干的表面层上刮涂步骤(2)所得的发泡层浆料，100℃烘干80s，形成发泡层；之后，在发泡层上刮涂水溶性酚醛树脂胶黏剂作为粘结层，然后覆盖上基布，再在80℃下烘干，之后将离型纸剥离，即得所述高触感耐磨篮球皮革。
实施例三：
一种高触感耐磨篮球皮革，它包括基布、粘结层、发泡层以及表面层；
其中，所述表面层包括以下重量份数的组分：水性聚氨酯树脂90kg、二甲基甲酰胺110kg、聚丙烯酸钠12kg、水4kg、炭黑12kg、石英砂5kg、铁基合金粉末8kg、改性凹凸棒土8kg、N,N–二正丁基二硫氨基甲酸镍4kg、聚乙二醇12kg、双氧水1.3kg、亚硫酸氢钠0.6kg、发泡剂3kg、色粉13kg；
所述发泡层包括以下重量份数的组分：水性聚氨酯树脂90kg、二甲基甲酰胺85kg、炭黑12kg、重质碳酸钙35kg、发泡剂6kg、乳化剂S-80 4kg。
所述基布为无纺布。
所述粘结层由粘结剂形成，所述粘结剂为水溶性酚醛树脂胶黏剂。
所述发泡剂为AC发泡剂。
一种所述的高触感耐磨篮球皮革的制作方法，它包括以下步骤：
步骤(1)制备表面层浆料：
步骤a：制备改性凹凸棒土：步骤1)制备酸改性凹凸棒土：将凹凸棒土在750℃下焙烧5h后，放入10％盐酸溶液中浸泡4h，捞出，烘干至含水量2％，得酸改性凹凸棒土；步骤2)制备复配偶联剂：将重量比为1:2的硅烷偶联剂Kh560与马来酸酐进行混合，得复配偶联剂；步骤3)制备偶联剂改性凹凸棒土：在步骤1)所得的酸改性凹凸棒土中加入复配偶联剂，且复配偶联剂的添加量为酸改性凹凸棒土质量的4wt.％，再放入加热式捏合机，进行混合搅拌，搅拌速度为50r/min，搅拌的同时慢速升温，当温度升至80℃时，恒温搅拌2h，得偶联剂改性凹凸棒土；步骤4)在步骤3)所得的偶联剂改性凹凸棒土中加入硬脂酸，硬脂酸的添加量为酸改性凹凸棒土质量的1.0wt.％，利用加热式捏合机继续搅拌升温至95℃时，恒温搅拌1h后，进行排料；之后，对排出的物料进行烘干，烘干温度控制在50℃，待物料烘干至含水率小于0.5％时，将物料输送至盘式磨粉机，研磨成60目的粉末，即得所述改性凹凸棒土。
步骤b：将水性聚氨酯树脂、二甲基甲酰胺、聚丙烯酸钠、水、N,N–二正丁基二硫氨基甲酸镍、聚乙二醇、双氧水、亚硫酸氢钠、发泡剂以及色粉混合后，再进行加热至熔融状态，其中，加热温度为220℃，加热时间为50min，之后倒入炭黑、石英砂、铁基合金粉末以及步骤a所得的改性凹凸棒土，在相同温度下，以40r/min的速度搅拌30min，得表面层浆料；
步骤(2)制备发泡层浆料：将水性聚氨酯树脂、二甲基甲酰胺、乳化剂S-80在210℃下加热40min，之后，加入发泡剂、炭黑、重质碳酸钙，以40r/min的速度搅拌40min，得发泡层浆料；
步骤(3)浆料刮涂：将步骤(1)所得的表面层浆料涂覆在离型纸上，100℃烘干80s，形成表面层；接着，在烘干的表面层上刮涂步骤(2)所得的发泡层浆料，100℃烘干80s，形成发泡层；之后，在发泡层上刮涂水溶性酚醛树脂胶黏剂作为粘结层，然后覆盖上基布，再在80℃下烘干，之后将离型纸剥离，即得所述高触感耐磨篮球皮革。
实施例四：
一种高触感耐磨篮球皮革，它包括基布、粘结层、发泡层以及表面层；
其中，所述表面层包括以下重量份数的组分：水性聚氨酯树脂90kg、二甲基甲酰胺110kg、聚丙烯酸钠12kg、水4kg、炭黑12kg、石英砂5kg、铁基合金粉末8kg、改性凹凸棒土8kg、N,N–二正丁基二硫氨基甲酸镍4kg、聚乙二醇12kg、双氧水1.3kg、亚硫酸氢钠0.6kg、发泡剂3kg、色粉13kg；
所述发泡层包括以下重量份数的组分：水性聚氨酯树脂90kg、二甲基甲酰胺85kg、炭黑12kg、重质碳酸钙35kg、发泡剂6kg、乳化剂S-80 4kg。
所述基布为无纺布。
所述粘结层由粘结剂形成，所述粘结剂为水溶性酚醛树脂胶黏剂。
所述发泡剂为AC发泡剂。
一种所述的高触感耐磨篮球皮革的制作方法，它包括以下步骤：
步骤(1)制备表面层浆料：
步骤a：制备改性凹凸棒土：步骤1)制备酸改性凹凸棒土：将凹凸棒土在780℃下焙烧4.5h后，放入15％盐酸溶液中浸泡3.5h，捞出，烘干至含水量2.5％，得酸改性凹凸棒土；步骤2)制备复配偶联剂：将重量比为1:3的硅烷偶联剂Kh560与马来酸酐进行混合，得复配偶联剂；步骤3)制备偶联剂改性凹凸棒土：在步骤1)所得的酸改性凹凸棒土中加入复配偶联剂，且复配偶联剂的添加量为酸改性凹凸棒土质量的5wt.％，再放入加热式捏合机，进行混合搅拌，搅拌速度为50r/min，搅拌的同时慢速升温，当温度升至85℃时，恒温搅拌2.5h，得偶联剂改性凹凸棒土；步骤4)在步骤3)所得的偶联剂改性凹凸棒土中加入硬脂酸，硬脂酸的添加量为酸改性凹凸棒土质量的1.1wt.％，利用加热式捏合机继续搅拌升温至95℃时，恒温搅拌1.5h后，进行排料；之后，对排出的物料进行烘干，烘干温度控制在55℃，待物料烘干至含水率小于0.5％时，将物料输送至盘式磨粉机，研磨成60目的粉末，即得所述改性凹凸棒土。
步骤b：将水性聚氨酯树脂、二甲基甲酰胺、聚丙烯酸钠、水、N,N–二正丁基二硫氨基甲酸镍、聚乙二醇、双氧水、亚硫酸氢钠、发泡剂以及色粉混合后，再进行加热至熔融状态，其中，加热温度为225℃，加热时间为45min，之后倒入炭黑、石英砂、铁基合金粉末以及步骤a所得的改性凹凸棒土，在相同温度下，以45r/min的速度搅拌28min，得表面层浆料；
步骤(2)制备发泡层浆料：将水性聚氨酯树脂、二甲基甲酰胺、乳化剂S-80在215℃下加热35min，之后，加入发泡剂、炭黑、重质碳酸钙，以45r/min的速度搅拌35min，得发泡层浆料；
步骤(3)浆料刮涂：将步骤(1)所得的表面层浆料涂覆在离型纸上，110℃烘干70s，形成表面层；接着，在烘干的表面层上刮涂步骤(2)所得的发泡层浆料，110℃烘干70s，形成发泡层；之后，在发泡层上刮涂水溶性酚醛树脂胶黏剂作为粘结层，然后覆盖上基布，再在90℃下烘干，之后将离型纸剥离，即得所述高触感耐磨篮球皮革。
实施例五：
一种高触感耐磨篮球皮革，它包括基布、粘结层、发泡层以及表面层；
其中，所述表面层包括以下重量份数的组分：水性聚氨酯树脂90kg、二甲基甲酰胺110kg、聚丙烯酸钠10kg、水4kg、炭黑12kg、石英砂5kg、铁基合金粉末8kg、改性凹凸棒土10kg、N,N–二正丁基二硫氨基甲酸镍4kg、聚乙二醇12kg、双氧水1.3kg、亚硫酸氢钠0.6kg、发泡剂3kg、色粉13kg；
所述发泡层包括以下重量份数的组分：水性聚氨酯树脂90kg、二甲基甲酰胺85kg、炭黑12kg、重质碳酸钙35kg、发泡剂6kg、乳化剂S-80 4kg。
所述基布为针织布。
所述粘结层由粘结剂形成，所述粘结剂为水溶性酚醛树脂胶黏剂。
所述发泡剂为对甲苯磺酰肼。
一种所述的高触感耐磨篮球皮革的制作方法，它包括以下步骤：
步骤(1)制备表面层浆料：
步骤a：制备改性凹凸棒土：步骤1)制备酸改性凹凸棒土：将凹凸棒土在800℃下焙烧4h后，放入15％盐酸溶液中浸泡3h，捞出，烘干至含水量3％，得酸改性凹凸棒土；步骤2)制备复配偶联剂：将重量比为1:4的硅烷偶联剂Kh560与马来酸酐进行混合，得复配偶联剂；步骤3)制备偶联剂改性凹凸棒土：在步骤1)所得的酸改性凹凸棒土中加入复配偶联剂，且复配偶联剂的添加量为酸改性凹凸棒土质量的6wt.％，再放入加热式捏合机，进行混合搅拌，搅拌速度为50r/min，搅拌的同时慢速升温，当温度升至90℃时，恒温搅拌3h，得偶联剂改性凹凸棒土；步骤4)在步骤3)所得的偶联剂改性凹凸棒土中加入硬脂酸，硬脂酸的添加量为酸改性凹凸棒土质量的1.2wt.％，利用加热式捏合机继续搅拌升温至95℃时，恒温搅拌2h后，进行排料；之后，对排出的物料进行烘干，烘干温度控制在60℃，待物料烘干至含水率小于0.5％时，将物料输送至盘式磨粉机，研磨成50目的粉末，即得所述改性凹凸棒土。
步骤b：将水性聚氨酯树脂、二甲基甲酰胺、聚丙烯酸钠、水、N,N–二正丁基二硫氨基甲酸镍、聚乙二醇、双氧水、亚硫酸氢钠、发泡剂以及色粉混合后，再进行加热至熔融状态，其中，加热温度为230℃，加热时间为40min，之后倒入炭黑、石英砂、铁基合金粉末以及步骤a所得的改性凹凸棒土，在相同温度下，以50r/min的速度搅拌25min，得表面层浆料；
步骤(2)制备发泡层浆料：将水性聚氨酯树脂、二甲基甲酰胺、乳化剂S-80在220℃下加热30min，之后，加入发泡剂、炭黑、重质碳酸钙，以50r/min的速度搅拌30min，得发泡层浆料；
步骤(3)浆料刮涂：将步骤(1)所得的表面层浆料涂覆在离型纸上，120℃烘干60s，形成表面层；接着，在烘干的表面层上刮涂步骤(2)所得的发泡层浆料，120℃烘干60s，形成发泡层；之后，在发泡层上刮涂水溶性酚醛树脂胶黏剂作为粘结层，然后覆盖上基布，再在100℃下烘干，之后将离型纸剥离，即得所述高触感耐磨篮球皮革。
实施例六：性能测试
将传统的篮球皮革与实施例一至实施例五所得的篮球皮革进行耐磨性能测试，耐磨性能测试结果如表1所示。
表1耐磨性能测试结果
Figure BDA0002372008240000101
将传统的篮球皮革与实施例一至实施例五所得的篮球皮革进行吸水性能测试，吸水性能测试结果如表2所示，测试方法为：用1uL的针管滴1uL的水至各实施例所得的篮球皮革以及传统篮球皮革上，而后静置，记录水迹变干所用的时间。
表2耐磨性能测试结果
Figure BDA0002372008240000102
需要说明的是，以上所述仅是本发明的优选实施例，对于本技术领域的普通技术人员，在不脱离本发明构思的前提下，还可以作出若干改变、改进和润饰，这些改变、改进和润饰也应视为本发明的保护范围。

Claims (6)

1.一种高触感耐磨篮球皮革，其特征在于：它包括基布、粘结层、发泡层以及表面层；
其中，所述表面层包括以下重量份数的组分：水性聚氨酯树脂80-100份、二甲基甲酰胺100-120份、聚丙烯酸钠10-15份、水2-5份、炭黑10-15份、石英砂4-6份、铁基合金粉末5-10份、改性凹凸棒土5-10份、N,N–二正丁基二硫氨基甲酸镍2-5份、聚乙二醇10-15份、双氧水1-1.5份、亚硫酸氢钠0.5-0.8份、发泡剂2-4份、色粉12-15份；
所述发泡层包括以下重量份数的组分：水性聚氨酯树脂80-100份、二甲基甲酰胺80-90份、炭黑10-15份、重质碳酸钙30-40份、发泡剂5-8份、乳化剂S-80 3-5份。
2.根据权利要求1所述的高触感耐磨篮球皮革，其特征在于：所述基布为针织布或无纺布。
3.根据权利要求1所述的高触感耐磨篮球皮革，其特征在于：所述粘结层由粘结剂形成，所述粘结剂为水溶性酚醛树脂胶黏剂。
4.根据权利要求1所述的高触感耐磨篮球皮革，其特征在于：所述发泡剂为AC发泡剂、对甲苯磺酰肼中的一种或二者的混合物。
5.一种如权利要求1所述的高触感耐磨篮球皮革的制作方法，其特征在于：它包括以下步骤：
步骤(1)制备表面层浆料：
步骤a：制备改性凹凸棒土；
步骤b：将水性聚氨酯树脂、二甲基甲酰胺、聚丙烯酸钠、水、N,N–二正丁基二硫氨基甲酸镍、聚乙二醇、双氧水、亚硫酸氢钠、发泡剂以及色粉混合后，再进行加热至熔融状态，其中，加热温度为220-230℃，加热时间为40-50min，之后倒入炭黑、石英砂、铁基合金粉末以及步骤a所得的改性凹凸棒土，在相同温度下，以40-50r/min的速度搅拌25-30min，得表面层浆料；
步骤(2)制备发泡层浆料：将水性聚氨酯树脂、二甲基甲酰胺、乳化剂S-80在210-220℃下加热30-40min，之后，加入发泡剂、炭黑、重质碳酸钙，以40-50r/min的速度搅拌30-40min，得发泡层浆料；
步骤(3)浆料刮涂：将步骤(1)所得的表面层浆料涂覆在离型纸上，100-120℃烘干60-80s，形成表面层；接着，在烘干的表面层上刮涂步骤(2)所得的发泡层浆料，100-120℃烘干60-80s，形成发泡层；之后，在发泡层上刮涂水溶性酚醛树脂胶黏剂作为粘结层，然后覆盖上基布，再在80-100℃下烘干，之后将离型纸剥离，即得所述高触感耐磨篮球皮革。
6.根据权利要求5所述的高触感耐磨篮球皮革的制作方法，其特征在于：步骤(1)中步骤a的具体操作方法为：
步骤1)制备酸改性凹凸棒土：将凹凸棒土在750-800℃下焙烧4-5h后，放入10-15％盐酸溶液中浸泡3-4h，捞出，烘干至含水量2-3％，得酸改性凹凸棒土；
步骤2)制备复配偶联剂：将重量比为1:2-4的硅烷偶联剂Kh560与马来酸酐进行混合，得复配偶联剂；
步骤3)制备偶联剂改性凹凸棒土：在步骤1)所得的酸改性凹凸棒土中加入复配偶联剂，且复配偶联剂的添加量为酸改性凹凸棒土质量的4wt.％-6wt.％，再放入加热式捏合机，进行混合搅拌，搅拌速度为50r/min，搅拌的同时慢速升温，当温度升至80-90℃时，恒温搅拌2-3h，得偶联剂改性凹凸棒土；
步骤4)在步骤3)所得的偶联剂改性凹凸棒土中加入硬脂酸，硬脂酸的添加量为酸改性凹凸棒土质量的1.0wt.％-1.2wt.％，利用加热式捏合机继续搅拌升温至95℃时，恒温搅拌1-2h后，进行排料；之后，对排出的物料进行烘干，烘干温度控制在50-60℃，待物料烘干至含水率小于0.5％时，将物料输送至盘式磨粉机，研磨成50-60目的粉末，即得所述改性凹凸棒土。
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111621989A (zh) * 2020-06-05 2020-09-04 漳州华飞体育用品有限公司 一种抑菌耐磨球类皮革及其制作方法
WO2022089555A1 (zh) * 2020-10-30 2022-05-05 康健 一种水果提取物皮革及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101565588A (zh) * 2009-06-01 2009-10-28 四川大学 一种有机凹凸棒土-水性聚氨酯纳米复合皮革涂饰剂及其制备方法
CN102995449A (zh) * 2012-10-23 2013-03-27 合肥市安山涂层织物有限公司 聚氯乙烯合成革及其制造方法
CN102995450A (zh) * 2012-10-23 2013-03-27 合肥市安山涂层织物有限公司 箱包用耐用聚氯乙烯合成革及其制造方法
CN102995451A (zh) * 2012-10-23 2013-03-27 合肥市安山涂层织物有限公司 耐曲折的聚氯乙烯合成革及其制造方法
CN108797148A (zh) * 2018-05-22 2018-11-13 佛山市高明区生产力促进中心 一种具有耐磨抗刮性的pu革及其制作方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101565588A (zh) * 2009-06-01 2009-10-28 四川大学 一种有机凹凸棒土-水性聚氨酯纳米复合皮革涂饰剂及其制备方法
CN102995449A (zh) * 2012-10-23 2013-03-27 合肥市安山涂层织物有限公司 聚氯乙烯合成革及其制造方法
CN102995450A (zh) * 2012-10-23 2013-03-27 合肥市安山涂层织物有限公司 箱包用耐用聚氯乙烯合成革及其制造方法
CN102995451A (zh) * 2012-10-23 2013-03-27 合肥市安山涂层织物有限公司 耐曲折的聚氯乙烯合成革及其制造方法
CN108797148A (zh) * 2018-05-22 2018-11-13 佛山市高明区生产力促进中心 一种具有耐磨抗刮性的pu革及其制作方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111621989A (zh) * 2020-06-05 2020-09-04 漳州华飞体育用品有限公司 一种抑菌耐磨球类皮革及其制作方法
CN111621989B (zh) * 2020-06-05 2023-07-11 漳州华飞体育用品有限公司 一种抑菌耐磨球类皮革及其制作方法
WO2022089555A1 (zh) * 2020-10-30 2022-05-05 康健 一种水果提取物皮革及其制备方法

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