CN111139081A - Saline-alkali soil conditioner and preparation method thereof - Google Patents
Saline-alkali soil conditioner and preparation method thereof Download PDFInfo
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- CN111139081A CN111139081A CN201911387028.4A CN201911387028A CN111139081A CN 111139081 A CN111139081 A CN 111139081A CN 201911387028 A CN201911387028 A CN 201911387028A CN 111139081 A CN111139081 A CN 111139081A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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Abstract
The invention discloses a saline-alkali soil conditioner which comprises the following raw materials in parts by weight: 35-40 parts of attapulgite, 6-11 parts of humic acid, 4-7 parts of malic acid, 5-10 parts of manganese sulfate, 8-16 parts of azelaic acid, 1-3 parts of sodium alginate, 2-6 parts of ammonium sulfate and 1-3 parts of stearamide. The saline-alkali soil conditioner provided by the invention can adjust the pH value of soil, promote the formation of a soil aggregate structure, enhance the permeability of the soil and effectively reduce the pH value and the alkalization degree of the soil by carefully selecting a formula.
Description
Technical Field
The invention relates to the technical field of saline-alkali soil improvement, in particular to a saline-alkali soil conditioner and a preparation method thereof.
Background
Saline-alkali soil is a general term for various salinized soil and alkaline soil. Saline-alkali soil is one of the serious ecological environment problems faced by global agriculture nowadays, which causes serious influence on agricultural sustainable development, and how to properly solve the problem of soil salinization is a difficult task. Because the soil body contains a large amount of saline-alkali components and has poor physicochemical properties, the growth of plants is inhibited and even can not grow. Most of soluble salts in the saline-alkali soil are sodium salts, so that the soil is sticky and heavy, the soil colloid is dispersed and emulsified, the air permeability is poor, the soil swells and is muddy when meeting water, the water loss shrinkage is hard, the germination of crop seeds and the normal development of crops are seriously influenced, in addition, the excessive sodium ions in the soil are in alkaline reaction, plant tissues are directly damaged, the root systems of the crops are also easy to rot, the nutrient conversion is influenced, and phosphate fertilizers, trace elements and the like cannot be dissolved and lose efficacy. Therefore, the salinization of the soil has great harm to crops.
The saline-alkali soil improvement is based on the principle of local adjustment and comprehensive improvement, and the saline-alkali soil is actively cultivated and fertilized while salt discharge, salt isolation and salt prevention are carried out, so that the aim of efficiently utilizing the saline-alkali soil is achieved, and at present, the domestic saline-alkali soil control technology mainly comprises the following steps: water conservancy improvement technology, physical improvement technology, chemical improvement technology, biological improvement technology and the like. At present, the measures widely used at home and abroad for treating saline-alkali soil include water conservancy improvement measures (including irrigation, drainage, silt discharge, rice planting, seepage prevention and the like), agricultural improvement measures (including land leveling, improvement and cultivation, soil dressing, fertilization, seeding, crop rotation, intercropping and interplanting and the like), biological improvement measures (including planting salt-tolerant plants and pasture grass, green manure, afforestation and the like) and chemical improvement measures (including applying improvement substances such as gypsum, phosphogypsum, calcium sulfite and the like). Under the action of physical improvement technology, the volume weight of saline-alkali soil is reduced, the porosity and permeability of soil are increased, the water movement of soil is adjusted, and the soil fertility is improved. Chemical modification techniques work by applying chemically modified materials, which mainly include: gypsum, fly ash, citric acid, black alum, phosphogypsum and the like. After the modified material is applied, the physical and chemical properties of the soil are changed, and the acidity is increased. The chemical improvement is to apply some acidic salt substances to improve the property of saline-alkali soil, reduce the pH value of the soil, increase the cation replacement capacity of the soil, reduce the salt content of the soil, enhance the activity of microorganisms and enzymes in the soil and promote the growth of plant roots. Improving the physical property of soil, increasing the granular structure of soil, coordinating the water, fertilizer and gas heat of soil and increasing the fertility of soil. The saline-alkali soil is improved by biological measures in the traditional sense, namely the saline-alkali soil is improved by plants, the method is easy to implement, and the economic benefit is obvious. The biological measures can gradually change the physical characteristics of the soil, so that the soil structure is changed, the texture becomes loose, and the air permeability and water storage capacity are enhanced.
The saline-alkali soil improvement not only relates to effectively reducing the salt content and the pH value of soil, but also relates to the problems of improving the soil structure and reasonably increasing the soil nutrients. The traditional improvement method and the product can not achieve the effect of improving the soil structure while reducing the salt content and the pH value of the soil when improving the saline-alkali soil.
Disclosure of Invention
In order to solve the technical problem, the invention discloses a saline-alkali soil conditioner which comprises the following raw materials in parts by weight: 35-40 parts of attapulgite, 6-11 parts of humic acid, 4-7 parts of malic acid, 5-10 parts of manganese sulfate, 8-16 parts of azelaic acid, 1-3 parts of sodium alginate, 2-6 parts of ammonium sulfate and 1-3 parts of stearamide.
Preferably, the saline-alkali soil conditioner comprises the following preparation raw materials in parts by weight: 38 parts of attapulgite, 9 parts of humic acid, 6 parts of malic acid, 8 parts of manganese sulfate, 11 parts of azelaic acid, 2 parts of sodium alginate, 4 parts of ammonium sulfate and 2 parts of stearamide.
On the other hand, the invention provides a preparation method of the saline-alkali soil conditioner, which comprises the following steps:
(1) mixing the attapulgite and the manganese sulfate according to the formula dosage, stirring for 25-30 minutes at room temperature, and stirring to obtain a mixture A;
(2) mixing the rest raw materials in the formula, heating to 63-71 ℃, stirring for 2-3 hours, and cooling to room temperature to obtain a mixture B;
(3) and (2) heating the mixture A and the mixture B obtained in the step (1) to 45-55 ℃, stirring for 1-2 hours, and cooling to room temperature to obtain the saline-alkali soil conditioner.
Preferably, the stirring time of step (1) is 28 minutes.
Preferably, the heating temperature of the step (2) is 68 ℃ and the stirring time is 2.5 hours.
Preferably, the heating temperature of the step (3) is 50 ℃ and the stirring time is 1.5 minutes.
The invention has the beneficial effects that:
the saline-alkali soil conditioner provided by the invention can adjust the pH value of soil, promote the formation of a soil aggregate structure, enhance the permeability of the soil and effectively reduce the pH value and the alkalization degree of the soil by carefully selecting a formula.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. The experimental methods in the following examples, which are not specified under specific conditions, were generally conducted under conventional conditions. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.
Example 1 saline-alkali soil conditioner
The preparation raw materials comprise the following components in parts by weight: 35 parts of attapulgite, 6 parts of humic acid, 4 parts of malic acid, 5 parts of manganese sulfate, 8 parts of azelaic acid, 1 part of sodium alginate, 2 parts of ammonium sulfate and 1 part of stearamide.
The preparation method comprises the following steps:
(1) mixing the attapulgite and the manganese sulfate according to the formula amount, stirring for 25 minutes at room temperature, and stirring to obtain a mixture A;
(2) mixing the rest raw materials in the formula, heating to 63 ℃, stirring for 2 hours, and cooling to room temperature to obtain a mixture B;
(3) and (2) heating the mixture A and the mixture B obtained in the step (1) to 45 ℃, stirring for 1 hour, and cooling to room temperature to obtain the saline-alkali soil conditioner.
Example 2 saline-alkali soil conditioner
The preparation raw materials comprise the following components in parts by weight: 40 parts of attapulgite, 11 parts of humic acid, 7 parts of malic acid, 10 parts of manganese sulfate, 16 parts of azelaic acid, 3 parts of sodium alginate, 6 parts of ammonium sulfate and 3 parts of stearamide.
The preparation method comprises the following steps:
(1) mixing the attapulgite and the manganese sulfate according to the formula amount, stirring for 30 minutes at room temperature, and stirring to obtain a mixture A;
(2) mixing the rest raw materials in the formula, heating to 71 ℃, stirring for 3 hours, and cooling to room temperature to obtain a mixture B;
(3) and (2) heating the mixture A and the mixture B obtained in the step (1) to 55 ℃, stirring for 2 hours, and cooling to room temperature to obtain the saline-alkali soil conditioner.
Example 3 saline-alkali soil conditioner
The preparation raw materials comprise the following components in parts by weight: 38 parts of attapulgite, 9 parts of humic acid, 6 parts of malic acid, 8 parts of manganese sulfate, 11 parts of azelaic acid, 2 parts of sodium alginate, 4 parts of ammonium sulfate and 2 parts of stearamide.
The preparation method comprises the following steps:
(1) mixing attapulgite and manganese sulfate according to the formula amount, stirring for 28 minutes at room temperature, and stirring to obtain a mixture A;
(2) mixing the rest raw materials in the formula, heating to 68 ℃, stirring for 2.5 hours, and cooling to room temperature to obtain a mixture B;
(3) and (2) heating the mixture A and the mixture B obtained in the step (1) to 50 ℃, stirring for 1.5 hours, and cooling to room temperature to obtain the saline-alkali soil conditioner.
Comparative example 1 saline-alkali soil conditioner
The preparation raw material examples are basically the same as example 3, and the difference from example 3 is that: the raw materials do not contain azelaic acid.
The preparation method is the same as example 3.
Comparative example 2 saline-alkali soil conditioner
The preparation raw materials are basically the same as those in example 3, and the difference from example 3 is that: the starting material contained no stearamide.
The preparation method is basically the same as that of example 3.
Experimental example 1
And (3) field test design: selecting saline-alkali soil, and totally 6 cells (20 m)2Cell), respectively50Kg of soil conditioner per acre of examples 1-3 and comparative examples 1-2 were applied, with other levels of management being consistent. The original samples of soil (original group) were taken and the total porosity, soil pH in the field of the blank control, examples 1-3 and comparative examples 1-2, and the total porosity, soil pH in the soil samples of examples 1-3 and comparative examples 1-2, respectively, were determined after half a year as shown in the following table:
note: all data are mean ± sd of 4 replicates.
As can be seen from the above table, the plant community constructed by the method for constructing a plant community for saline-alkali soil improvement provided in embodiments 1 to 3 of the present invention can improve the total porosity and water content of saline-alkali soil, and can reduce pH, which is better than that in comparative examples 1 to 2.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein. In addition, the technical solutions between the various embodiments can be combined with each other, but must be based on the realization of those skilled in the art; where combinations of features are mutually inconsistent or impractical, such combinations should not be considered as being absent and not within the scope of the claimed invention.
Claims (6)
1. A saline-alkali soil conditioner is characterized in that: the preparation raw materials comprise the following components in parts by weight: 35-40 parts of attapulgite, 6-11 parts of humic acid, 4-7 parts of malic acid, 5-10 parts of manganese sulfate, 8-16 parts of azelaic acid, 1-3 parts of sodium alginate, 2-6 parts of ammonium sulfate and 1-3 parts of stearamide.
2. The saline-alkali soil conditioner according to claim 1, wherein: the preparation raw materials comprise the following components in parts by weight: 38 parts of attapulgite, 9 parts of humic acid, 6 parts of malic acid, 8 parts of manganese sulfate, 11 parts of azelaic acid, 2 parts of sodium alginate, 4 parts of ammonium sulfate and 2 parts of stearamide.
3. The method for preparing a soil conditioner for saline-alkali soil as claimed in claim 1 or 2, comprising the steps of:
(1) mixing the attapulgite and the manganese sulfate according to the formula dosage, stirring for 25-30 minutes at room temperature, and stirring to obtain a mixture A;
(2) mixing the rest raw materials in the formula, heating to 63-71 ℃, stirring for 2-3 hours, and cooling to room temperature to obtain a mixture B;
(3) and (2) heating the mixture A and the mixture B obtained in the step (1) to 45-55 ℃, stirring for 1-2 hours, and cooling to room temperature to obtain the saline-alkali soil conditioner.
4. The method for preparing a soil conditioner for saline-alkali soil according to claim 3, characterized in that: the stirring time in the step (1) is 28 minutes.
5. The method for preparing a soil conditioner for saline-alkali soil according to claim 3, characterized in that: the heating temperature of the step (2) is 68 ℃, and the stirring time is 2.5 hours.
6. The method for preparing a soil conditioner for saline-alkali soil according to claim 3, characterized in that: the heating temperature of the step (3) is 50 ℃, and the stirring time is 1.5 minutes.
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Cited By (2)
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---|---|---|---|---|
CN112794775A (en) * | 2021-01-19 | 2021-05-14 | 上海工程技术大学 | Microcapsule soil conditioner and preparation method thereof |
CN114015450A (en) * | 2021-11-01 | 2022-02-08 | 白银丰宝农化科技有限公司 | Attapulgite-based saline-alkali soil conditioner and preparation method thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112794775A (en) * | 2021-01-19 | 2021-05-14 | 上海工程技术大学 | Microcapsule soil conditioner and preparation method thereof |
CN112794775B (en) * | 2021-01-19 | 2022-10-14 | 上海工程技术大学 | Microcapsule soil conditioner and preparation method thereof |
CN114015450A (en) * | 2021-11-01 | 2022-02-08 | 白银丰宝农化科技有限公司 | Attapulgite-based saline-alkali soil conditioner and preparation method thereof |
CN114015450B (en) * | 2021-11-01 | 2022-11-04 | 白银丰宝农化科技有限公司 | Attapulgite-based saline-alkali soil conditioner and preparation method thereof |
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Application publication date: 20200512 |