CN106221700A - A kind of salt-soda soil Helianthi special-purpose soil conditioner - Google Patents
A kind of salt-soda soil Helianthi special-purpose soil conditioner Download PDFInfo
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- CN106221700A CN106221700A CN201610587533.3A CN201610587533A CN106221700A CN 106221700 A CN106221700 A CN 106221700A CN 201610587533 A CN201610587533 A CN 201610587533A CN 106221700 A CN106221700 A CN 106221700A
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- soil
- helianthi
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- soil conditioner
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2101/00—Agricultural use
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2109/00—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation
Abstract
The present invention relates to soil improvement material technical field, in particular to a kind of salt-soda soil Helianthi special-purpose soil conditioner.Counting by weight, this conditioner is mainly made up of following component: mineral material, activator；Described mineral material includes zeolite, attapulgite, meerschaum；The Main Ingredients and Appearance of described activator is organic acid.
Description
Technical field
The present invention relates to soil improvement material technical field, in particular to a kind of salt-soda soil Helianthi special-purpose soil
Conditioner.
Background technology
Helianthi has stronger Saline alkali tolerance, also has concurrently and inhales salt performance, " pioneer crop " being referred to as on salt-soda soil, because of
And it is also the major economic crops of Hetao Irrigation District, cultivated area is big, with a long history.Hetao area Helianthi year sown area 23
About ten thousand hectares, accounting for the 30% of the total sown area of crops, 1/3rd of farmers' income are from Helianthi industry.The river bend fills
In existing arable land, district, 60% is middle low yield salt-soda soil, and Helianthi major part kind is on salt-soda soil, and soil salt content is high, nutrient
Low, physicochemical character is poor, perniciousness harm is big, Helianthi emergence rate is low, this be restriction Helianthi yield basic factor.
Prior art also discloses that several Helianthi special-purpose soil conditioner.At application number CN201110381701.0,
In technical scheme disclosed in the invention of Shen Qing Publication day 2013.06.05, its technology main composition is required for plant growth
A great number of elements N P and K, uses bentonite, zeolite powder, kieselguhr and humic acid powder, the method using chemicals on a small quantity
Increase Helianthi yield, another patent CN200910117236.2, apply for disclosed in the invention in publication date on August 12nd, 2009
In technical scheme, its technology main composition is desulfuration waste, furfural dregs, fertilizer, weathered coal, uses industry byproduct
The method improvement soil adding organic matter increases Helianthi yield.
But prior art still suffers from a lot of problem, or the macro-element nutrients mainly for supply crop, and only add
Add a small amount of in order to improve the content of soil, it is difficult to meet to administer the salinization of soil and supply the dual of trace element in crop and want
Asking, its impact nourishing and growing Helianthi is the most notable；Mineral and the organic form combined is used to carry out conditioned soil
Earth and then affect the growth of Helianthi, but it is contained while improving soil physico-chemical property not to account for mineral
Middle trace element also can be as nutrient utilization absorbed by crops.
In view of this, the special proposition present invention.
Summary of the invention
It is an object of the invention to provide a kind of salt-soda soil Helianthi special-purpose soil conditioner, to solve the problems referred to above.
In order to realize the above-mentioned purpose of the present invention, spy by the following technical solutions:
A kind of salt-soda soil Helianthi special-purpose soil conditioner, described soil conditioner is mainly by mineral material and activator
Make:
Described mineral material includes attapulgite, meerschaum, zeolite；
Described activator be mainly composed of organic acid.
Preferably, salt-soda soil as above Helianthi special-purpose soil conditioner, described attapulgite, meerschaum, zeolite
Mass ratio be (0.8～1.2): (0.4～0.6): (0.8～1.2)；
Zeolite also referred to as " zeolite ", be the general name of zeolite race mineral, including a series of aqueous calcium, sodium and barium, potassium
Aluminium silicate mineral.Because composition difference is divided into analcime, scolecite etc..Its water content has with the pressure of ambient temperature and steam
Closing, during heating, moisture can escape slowly, but not rupture life crystal structure, and form different size of aperture.It is typically light color,
Glassy lustre, hardness 3～5.5, proportion 2.0～2.4.Zeolite has aluminosilicate tetrahedron lattice-like mesh, wherein have can make from
The cation (such as sodium ion) of son exchange and unfixed hydrone；There is adsorption.
Attapulgite refers to the attapulgite (attapulgite) a kind of clay mineral as key component.Attapulgite
For a kind of crystalloid hydrous magnesium aluminium silicate mineral, there is the layer chain structure feature of uniqueness, in its structure, there is crystal lattice,
Containing variable amount of Na+, Ca in side crystal2+、Fe3+、Al3+, crystal is needle-like, threadiness or fiber collection shape.Attapulgite has
There are the dispersion of uniqueness, good colloidal nature and the higher adsorption bleaching ability such as saline and alkaline high temperature resistant, anti-.Attapulgite applies soil
Can increase soil fertility after earth, increase crop yield, reduce water quantity for irrigating agricultural field.Have preferably mainly due to attapulgite
Cation replacement property, the feature such as adsorptivity, water-retaining property, cohesiveness, the materialization property of soil can be improved, improve the water of soil
Heat condition.Cation exchange capacity (CEC) is an important indicator of soil fertilizer fertilizer.Attapulgite has higher water absorption rate with preferable
Cohesiveness, these performances to coordinate soil liquid manure gas heat, increase soil fertility and there is good effect.Meanwhile, attapulgite
Soil, containing higher mineral nutrient element, can increase the fertility of soil, it is provided that trace element.Attapulgite can be with adsorptional earth
Harmful element in earth, alleviates the pollution of soil.Attapulgite can administer soil compaction, can allow crop yield, moreover it is possible to promotes product
Matter.Attapulgite ore deposit is nonmetal clay pit, selenium containing trace, phosphorus, iodine, boron etc., though these trace element are few, but to crop
Growth has the hugest effect, so attapulgite and the material mixing containing these a great number of elements of N P and K being used, effect
Fruit is best.
Meerschaum is the silicate clay mineral material that a kind of fibrous porous richness is magnesia, and specific surface area is big, and porosity is high,
There is high adsorption capacity and ion-exchange capacity, can be with the heavy metal generation ion exchange in soil, fixing soil
In heavy metal, reach the purpose of heavy metal pollution removing.It it is the preferred material as heavy metal-polluted soil stabilizer.
On the one hand in the present invention, the selection of the proportioning of certain minerals material is from its respective absorption property and intrinsic
Soil improves performance and considers, or the nutrient source of the carrier of microbial life activity and growth and breeding, is on the other hand then logical
Cross and after reacting with activator, make silicon contained in the mineral material of rational proportion, calcium, magnesium, aluminum, ferrum etc. be difficult to by crop
Absorb nutrient and middle trace element discharges and absorbs for plant growth.
Preferably, salt-soda soil as above Helianthi special-purpose soil conditioner, described attapulgite, meerschaum, zeolite
Particle diameter be 100～200 mesh.
Suitable mineral material is conducive to strengthening its adsorptivity, also can shorten the response time of itself and activator simultaneously.
Preferably, the described organic acid in activator be selected from the monocarboxylic acid such as formic acid, acetic acid or ethanedioic acid, succinic acid,
The dicarboxylic acids such as 1,3-propanedicarboxylic acid, it is possible to selected from sulfonic acid (-SO3H), the organic acid such as sulfinic acid (RSOOH), thionothiolic acid (RCOSH), optimum
Choosing selected from citric acid.
Preferably, salt-soda soil as above Helianthi special-purpose soil conditioner, described activator also includes amino second
Nitrile disulfate and chelated microelements；
It is further preferred that the mass ratio of described organic acid, amino acetonitrile bisulfate and chelated microelements is 1:
(0.01～0.03): (0.04～0.06)；
It is further preferred that described organic acid is citric acid；Described chelated microelements is zinc and the boron of Chelating state.
Citric acid and amino acetonitrile bisulfate can react with mineral material, discharge mineral nutrition therein unit
Plain and middle trace element.
The zinc of Chelating state and boron are fertile purchased from the rich trace element water-soluble of mole Chemical Group (Chinese) company limited mole of Germany.
More conducively plant absorbs for the zinc of Chelating state and boron, and water-soluble fertilizer is at the cereal crops in field, warps such as agricultural, forestry, flowers
Ji crop, fruit trees and vegetables, flowers tea place and Chinese crude drug are extensively applied.Existing soil does not typically the most lack a great number of elements, impact
The principal element of plant growth is to lack trace element, applies trace element and also can reduce a great number of elements fertilizer amount.
Preferably, salt-soda soil as above Helianthi special-purpose soil conditioner, described mineral material and described activation
The mass ratio of agent is 1:(0.01～0.03).
The preparation method of salt-soda soil as above Helianthi special-purpose soil conditioner, comprises the following steps:
By mineral material and activator mixing reacting by heating, pelletize, obtain described salt-soda soil Helianthi special-purpose soil
Conditioner.
Preferably, the preparation method of salt-soda soil as above Helianthi special-purpose soil conditioner, described reacting by heating
Condition is: 150 DEG C～200 DEG C reaction 0.5h～5h.
Compared with prior art, the invention have the benefit that
1), to select natural mineral matter attapulgite, meerschaum and zeolite be main component, derive from nature return again from
So, there is special surface texture, there is good absorption and ion-exchange performance, the water conservation fertilizer conservation energy of soil can be improved
Power, it is possible to improve the adsorbance of salt ion, reduces salinity harm, and beneficially the formation of soil aggregate, imposes on degenerated soil,
Can improve soil base exchange capacity, this is conducive to the displacement drip washing of saline-alkali soil salt ion, is the environmental protection of a kind of function admirable
Type preparation for repairing.
2), the nutrient such as contained in mineral material silicon, calcium, magnesium, aluminum, ferrum be to be difficult to form absorbed by crops, this
Invention utilizes activator and mineral effect, activated mineral material, discharges mineral element therein supply plant growth and absorbs
Utilize, additionally, with the addition of zinc and the boron of the Chelating state of Chelating state always according to the growth characteristic of Helianthi.
3), the present invention while notable improvement alkaline land soil, improve Helianthi emergence rate, increase Helianthi yield,
Improve Helianthi quality, give full play to the effect of Helianthi salt-soda soil " pioneer crop ".
Detailed description of the invention
Below in conjunction with embodiment, embodiment of the present invention are described in detail, but those skilled in the art will
Understanding, the following example is merely to illustrate the present invention, and is not construed as limiting the scope of the present invention.In embodiment unreceipted specifically
Condition person, the condition advised according to normal condition or manufacturer is carried out.Agents useful for same or instrument unreceipted production firm person, be
Can be by the commercially available conventional products bought and obtain.
Embodiment 1
Present embodiments providing a kind of soil conditioner and preparation method thereof, this soil conditioner includes following component:
Mineral material, activator；
Described mineral material includes the attapulgite of 100～200 mesh, meerschaum, zeolite；Described attapulgite, Hai Pao
Stone, the mass ratio of zeolite are 0.8:0.6:0.8；
The composition of described activator be mass ratio be the citric acid of 1:0.01:0.06, amino acetonitrile bisulfate and chelating
The zinc of state and the mixture of boron；
This soil conditioner preparation method comprises the following steps:
Mineral material and activator are pressed the mass ratio mixing of 1:0.01, and 200 DEG C are reacted 0.5h in a kettle., obtain
Reactant；
By described reactant pelletize, obtain described soil conditioner.
Embodiment 2
Present embodiments providing a kind of soil conditioner and preparation method thereof, this soil conditioner includes following component:
Mineral material, activator；
Described mineral material includes the attapulgite of 100～200 mesh, meerschaum, zeolite；Described attapulgite, Hai Pao
Stone, the mass ratio of zeolite are 1.2:0.4:1.2；
The composition of described activator be mass ratio be the citric acid of 1:0.03:0.04, amino acetonitrile bisulfate and chelating
The zinc of state and the mixture of boron；
This soil conditioner preparation method comprises the following steps:
Mineral material and activator are pressed the mass ratio mixing of 1:0.03, and 150 DEG C are reacted 5h in a kettle., obtain anti-
Answer thing；
By described reactant pelletize, obtain described soil conditioner.
Embodiment 3
Present embodiments providing a kind of soil conditioner and preparation method thereof, this soil conditioner includes following component:
Mineral material, activator；
Described mineral material includes the attapulgite of 100～200 mesh, meerschaum, zeolite；Described attapulgite, Hai Pao
Stone, the mass ratio of zeolite are 1:0.5:1；
The composition of described activator be mass ratio be the citric acid of 1:0.02:0.05, amino acetonitrile bisulfate and chelating
The zinc of state and the mixture of boron；
This soil conditioner preparation method comprises the following steps:
Mineral material and activator are pressed the mass ratio mixing of 1:0.02, and 180 DEG C are reacted 3h in a kettle., obtain anti-
Answer thing；
By described reactant pelletize, obtain described soil conditioner.
Experimental example
The soil conditioner that the checking present invention the provides improved effect to Hetao area saline-alkali soil.
One, test material and method
Test site: test and carry out in Baya ur, NeiMengGu city in October, 2015 in May, 2015.
Test material:
N P and K NPK, soil conditioner (attapulgite, meerschaum, zeolite, anti-saline and alkaline microbial inoculum, activator)；
Sunflower seeds (kind 590).
EXPERIMENTAL DESIGN:
Testing ground area one mu, arranges five process, respectively altogether:
Process one: routine executes azophoska (NPK group)；
Processing two: NPK+ and use attapulgite, meerschaum, zeolite, three's proportioning is with embodiment 4 (BN1 group)；
Process three: NPK+ embodiment 3 (BN2 group)；
Process four: NPK+ embodiment 2 (BN3 group)；
Process five: NPK+ embodiment 1 (BN4 group).
Two, test procedure:
Test sets five process altogether, and 0.07 hectare is averagely divided into five communities, and each community is executed by EXPERIMENTAL DESIGN
Fertilizer, azophoska NPK disposably applies as base manure, 60～80 kilograms every mu.Process two, three, four, five to exist respectively
Seedling stage and flower bud phase carry out conditioner and impose, and impose 30 kilograms seedling stage every mu, and the flower bud phase every mu imposes 20 kilograms.
During test results, every community singles singly receive, and carry out Helianthi 100-grain weight and yield detection, carry out after the results of every community
The data monitorings such as P in soil H, organic matter, electrical conductivity, total salt.
Three, result of the test and analysis
The test data respectively processed by relative analysis, is carried out the group (BN2 group) of each group with optimum embodiment of the present invention
Contrast, result shows:
The impact on Helianthi economic characters of 3.1 conditioners
By the analysis to Helianthi economic characters, testing result shows: use the process crop setting percentage of BN2 than NPK,
BN1 process has been respectively increased 20%, 13%, and plant height has been respectively increased 8.3%, 6.4%, and strain stem has been respectively increased 39%, 30%,
Dish stem has been respectively increased 23%, 17%.
The impact on Helianthi economic characters of table 1 conditioner
The impact on Helianthi yield of 3.2 conditioners
The test data respectively processed by relative analysis, result shows: BN2 process crop 100-grain weight than NPK, BN1 at
Reason has been respectively increased 17.39%, 13.86%；The Helianthi yield that BN2 processes is respectively increased than NPK, BN1 process
15.85%, 10.04%.
The impact on Helianthi yield of table 2 conditioner
| Process | 100-grain weight (g) | Improve | Yield (kg/ mu) | Volume increase |
| NPK | 16.1 | 17.39% | 265 | 15.85% |
| BN1 | 16.6 | 13.86% | 279 | 10.04% |
| BN2 | 18.9 | 307 | ||
| BN3 | 18.4 | 305 | ||
| BN4 | 18.5 | 304 |
The impact on soil physico-chemical property of 3.3 conditioners
After Helianthi results, detecting soil four indices, detection data show: the soil ph ratio that BN2 processes
NPK, BN1 process and reduce 11.1%, 6.34% respectively；The soil conductivity that BN2 processes processes than NPK, BN1 and reduces respectively
14.7%, 9.81%；The soil total salt that BN2 processes processes than NPK, BN1 and reduces 15.6%, 8.84% respectively；BN2 processes
The soil organism processes than NPK, BN1 and adds 3.7%, 2.5% respectively.
The impact on soil physico-chemical property of table 3 conditioner
Four, conclusion
Imposing soil conditioner product on the basis of conventional fertilizer application all can make Helianthi economic characters and yield be improved,
Wherein attapulgite, meerschaum, zeolite, anti-saline and alkaline microbial inoculum and the symphyogenetic effect of activator are best, and Helianthi can be made to increase production
15.85%, this process has substantially change to the four indices of saline-alkali soil, plays reduction soil alkaline, the effect of improvement soil.
Although illustrate and describing the present invention with specific embodiment, but it will be appreciated that without departing substantially from the present invention's
May be made that in the case of spirit and scope many other change and amendment.It is, therefore, intended that in the following claims
Including all such changes and modifications belonged in the scope of the invention.
Claims (9)
1. a salt-soda soil Helianthi special-purpose soil conditioner, it is characterised in that described soil conditioner is mainly by mineral material
Material and activator are made:
Described mineral material includes attapulgite, meerschaum, zeolite；
Described activator be mainly composed of organic acid.
Salt-soda soil the most according to claim 1 Helianthi special-purpose soil conditioner, it is characterised in that described attapulgite,
Meerschaum, the mass ratio of zeolite are (0.8～1.2): (0.4～0.6): (0.8～1.2).
Salt-soda soil the most according to claim 2 Helianthi special-purpose soil conditioner, it is characterised in that described attapulgite,
Meerschaum, the particle diameter of zeolite are 100～200 mesh.
Salt-soda soil the most according to claim 1 Helianthi special-purpose soil conditioner, it is characterised in that in described activator also
Including amino acetonitrile bisulfate and chelated microelements.
Salt-soda soil the most according to claim 4 Helianthi special-purpose soil conditioner, it is characterised in that described organic acid, ammonia
The mass ratio of base acetonitrile disulfate and chelated microelements is 1:(0.01～0.03): (0.04～0.06).
Salt-soda soil the most according to claim 5 Helianthi special-purpose soil conditioner, it is characterised in that described organic acid is lemon
Lemon acid；Described chelated microelements is zinc and the boron of Chelating state.
7. according to the salt-soda soil Helianthi special-purpose soil conditioner described in any one of claim 1～6, it is characterised in that described
Mineral material is 1:(0.01～0.03 with the mass ratio of described activator).
8. the preparation method of the salt-soda soil Helianthi special-purpose soil conditioner described in any one of claim 1～7, its feature exists
In, comprise the following steps:
By mineral material and activator mixing reacting by heating, pelletize, obtain the Helianthi special-purpose soil conditioning of described salt-soda soil
Agent.
The preparation method of salt-soda soil the most according to claim 8 Helianthi special-purpose soil conditioner, it is characterised in that described
The condition of reacting by heating is: 150 DEG C～200 DEG C reaction 0.5h～5h.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106916592A (en) * | 2017-03-14 | 2017-07-04 | 夏璐 | A kind of soil conditioner for planting tobacco and preparation method thereof |
| CN109082279A (en) * | 2018-11-09 | 2018-12-25 | 刘景岳 | A kind of high-effective saline-alkali soil conditioner and preparation method thereof |
| CN111040773A (en) * | 2019-12-19 | 2020-04-21 | 安徽瀑飞通讯科技有限公司 | Soil conditioner for improving saline-alkali soil and preparation method and application thereof |
| CN111139081A (en) * | 2019-12-29 | 2020-05-12 | 山东胜伟盐碱地科技有限公司 | Saline-alkali soil conditioner and preparation method thereof |
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| CN102531960A (en) * | 2012-01-13 | 2012-07-04 | 太仓市茜泾化工有限公司 | Method for preparing aminoacetonitrile sulfate |
| CN103343010A (en) * | 2013-06-03 | 2013-10-09 | 南阳永富达矿产品有限公司 | Novel soil amendment |
| CN104263376A (en) * | 2014-09-22 | 2015-01-07 | 安徽大泽生物肥料科技有限公司 | Compound water-retaining agent for soil as well as preparation method and application of compound water-retaining agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102531960A (en) * | 2012-01-13 | 2012-07-04 | 太仓市茜泾化工有限公司 | Method for preparing aminoacetonitrile sulfate |
| CN103343010A (en) * | 2013-06-03 | 2013-10-09 | 南阳永富达矿产品有限公司 | Novel soil amendment |
| CN104263376A (en) * | 2014-09-22 | 2015-01-07 | 安徽大泽生物肥料科技有限公司 | Compound water-retaining agent for soil as well as preparation method and application of compound water-retaining agent |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106916592A (en) * | 2017-03-14 | 2017-07-04 | 夏璐 | A kind of soil conditioner for planting tobacco and preparation method thereof |
| CN109082279A (en) * | 2018-11-09 | 2018-12-25 | 刘景岳 | A kind of high-effective saline-alkali soil conditioner and preparation method thereof |
| CN111040773A (en) * | 2019-12-19 | 2020-04-21 | 安徽瀑飞通讯科技有限公司 | Soil conditioner for improving saline-alkali soil and preparation method and application thereof |
| CN111139081A (en) * | 2019-12-29 | 2020-05-12 | 山东胜伟盐碱地科技有限公司 | Saline-alkali soil conditioner and preparation method thereof |
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