CN106083308A - A kind of alkaline land improving is fertile and preparation method thereof - Google Patents
A kind of alkaline land improving is fertile and preparation method thereof Download PDFInfo
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- CN106083308A CN106083308A CN201610398210.XA CN201610398210A CN106083308A CN 106083308 A CN106083308 A CN 106083308A CN 201610398210 A CN201610398210 A CN 201610398210A CN 106083308 A CN106083308 A CN 106083308A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B17/00—Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
Abstract
The invention discloses a kind of alkaline land improving fertilizer and preparation method thereof, be to mix ardealite 5 20 parts, sodium ion adsorbent 35 parts and 5 10 parts of input batch mixers of Maifanitum to obtain A material;Acid conditioner 5 10 parts, solubility humic acids 15 40 parts and 20 35 parts of mix homogeneously of pyroligneous liquor, mixing and stirring in the A material that the B liquid obtained joins in batch mixer, after obtaining slurry C, put into farm manure 35 50 parts, 15 20 parts of mix homogeneously of straw stalk powder wherein, finally microbial bacterial agent 25 parts, the Tween 80 of 10 15 part 61 65% are put in above-mentioned feed liquid mix homogeneously and get final product.The present invention combines chemical method improvement soil salinity and alkalinity, utilizes microorganism to improve soil physical chemistry performance and the multiple alkaline land improving measure such as Soil structure, interpolation fertilizer improvement ASI systematic approach, good to the improved effect of alkaline land soil, long action time, it is achieved the benign cycle of alkaline land soil.
Description
Technical field
The invention belongs to alkaline land improving technical field, be specifically related to a kind of alkaline land improving fertilizer and preparation method thereof.
Background technology
Salt-soda soil due in soil salinity many, alkalescence is big, and the soil organism is destroyed and leaching loss, and trace element is in great shortage,
The most intuitively performance be soil compaction and Soil structure poor, after irrigation, grogs is easy to automatically disperse and formed skinning, and then
Stop moisture to penetrate into and reduce soil water storage capacity.Even if at this moment having put into substantial amounts of fertilizer can not be absorbed profit by crops
With, cause the negative effect of the low output of high investment.China's Saline area accounts for 1/4th of total area under cultivation, improves saline and alkaline
The soil physical chemistry present situation ploughed, the grain yield improving Saline, be the important content implementing country's relevant strategies.
At present, the Treatment process of saline-alkali soil mainly reduces salt, alkali composition, soil moved in improve the original cultivation, application of organic fertilizers by drip washing
Improving ASI systematic approach, soil can only be improved by these methods from single angle, and action time is limited, and soil is difficult to thorough
The end, improves.
Summary of the invention
For above technological deficiency, the technical problem to be solved is to provide a kind of alkaline land improving fertilizer and system thereof
Make method, this alkaline land improving fertilizer can comprehensive multiple amendement, good, during effect to the improved effect of alkaline land soil
Between long, it is achieved the benign cycle of alkaline land soil.
For solving above technological deficiency, the technical solution adopted in the present invention is:
A kind of alkaline land improving is fertile, including ardealite, sodium ion adsorbent, acid conditioner, solubility humic acids, pyroligneous
Liquid, microbial bacterial agent, farm manure, straw stalk powder and Maifanitum.
Wherein, the parts by weight of the fertile each composition of described alkaline land improving are respectively as follows: ardealite 5-20 part, sodium ion adsorbent
3-5 part, acid conditioner 5-10 part, solubility humic acids 15-40 part, pyroligneous liquor 20-35 part, microbial bacterial agent 2-5 part, farmers'
Fertile 35-50 part, straw stalk powder 15-20 part, tween 80 10-15 part and Maifanitum 5-10 part, wherein, the water content of described farm manure
For 5-10%.
Described ardealite is the side-product of sulfuric acid process phosphoric acid extraction production process, often produces 1 ton of phosphoric acid and produces 4.5-5.5 ton
Ardealite, a large amount of discharges of ardealite do not only take up substantial amounts of soil, due also to ardealite is through rainwater long period of soaking, it is right to cause
The severe contamination of soil, water system and air.Ardealite is mainly composed of calcium sulfate, and the addition of calcium ion can replace soil glue
The sodium of surface absorption, have adjusted the ratio between sodium ion and calcium ion in soil, reduces the activity of sodium ion, play fall
The effect of salt, simultaneously possibly together with nutrient necessary to the plant such as phosphorus, ferrum and a certain amount of free acid, both can be as fertilizer
It is used, it is possible to reduce the pH of saline-alkali soil as soil conditioner.
Described sodium ion adsorbent is cationic-type polyacrylamide, has adsorption for sodium ion, can play salt reduction
Effect.Meanwhile, polyacrylamide has the strongest flocculation, it can between molecule adsorption bridging, make in soil
The molecule condensed into flocculates into the larger particles of Semen Pisi sativi grain size, increases permeability and the preservation capacity of water and fertility of soil.Meanwhile,
Polar group granule on polyacrylamide can also adsorb many ions, strengthens the nutrient preserving capability of soil.
Described acid conditioner includes maleic anhydride, citric acid, maleic acid, tartaric acid, pyrophosphoric acid, humic acid, grass
Acid, salicylic acid, its ratio of weight and number is 38:19:2:5:5:8:1:5:2, and its pH, between 5-5.5, can directly neutralize salt-soda soil
The alkaline matter of soil, reduces the pH of soil, makes salt affected soil be suitable for the plantation of crop or plant.
Described solubility humic acids is fulvic acid, biochemical fulvic acid, any one of nitro humic acid or its mixing.Natural
In humic acids, soluble component content is little, makes this type of fertilizer less on the impact of soil fertility or acts on less in a short time,
Fulvic acid, biochemical fulvic acid or nitro humic acid water soluble, have soil fertility and soil structure improved addictive, the work of enhancing
With.Wherein, the preparation method of nitro humic acid is:
It is that 1:0.2-0.4 is under agitation by brown coal powder or air slaking coal dust with the nitric acid of 35-45% concentration by coal acid ratio
Oxidation, the time is 40-60min, through extraction, distillation, i.e. obtains nitro humic acid after drying, and wherein, the fineness of coal dust is 40-60
Mesh.
Described pyroligneous liquor be mainly composed of auximone, gibberellins, cytokinin (planting), abscisic acid, ethylene,
Organic acid system (phosphoric acid, carbonic acid, silicic acid etc.) hundreds of, yttrium: 12 kinds of potassium, sodium, magnesium, ferrum, manganese, calcium, chromium, zinc etc.,
Possibly together with multivitamin, there is the effect promoting plant growing, saline-alkali soil can be applied to as plant growth substances, fertilizer
In improved, process.
Described microbial bacterial agent is multiple micro-by including photosynthetic bacteria, nitrogen-fixing bacteria, escherichia coli, dissolving phosphor and dissolving potassium bacterium
Biological a kind of sizing microbial inoculum that compound criteria becomes in same state, its weight proportion is: 1:1:1:2, pH value 4.8-5.5 it
Between.Microorganism produces substantial amounts of polysaccharide in reproductive process, and these glucides are the binding agents forming soil granular, and granule is tied
Structure makes loosing soil, cuts off soil capillary hole, increases non-capillary pore gap, improves the physical property of soil so that salt
Alkaline earth accelerates to drench salt action, it is suppressed that the accumulation of salt in the surface soil, and meanwhile, the fungus group organic acid that metabolism produces in soil accelerates in soil
The dissolving of insoluble salt, serves the effect of neutralization to surface soil alkalinity.
Described farm manure contains people and animals' fecaluria, and the contained plant nutrient of the edible part of people and animals is that crops are from soil
Absorb 1/the tens of part.And corn stalk, straw, soybean straws, Caulis et Folium Oryzae, Brassica campestris L, Semen arachidis hypogaeae straw stalk and leaves, Folium Pini
Leaf, weeds etc., containing substantial amounts of nutrient, pulverize, after any of which or its mixing, the dry straw stalk powder and farmers' obtained
Most of nutrient that crops absorb can be returned soil by fertile soil of returning, and alleviates the input of quick-acting chemical fertilizer, reduces cost
Also can reduce the further infringement that soil is caused by excessively fertilising simultaneously.
Described Maifanitum can be stabilized and increased, the physics function of balanced soil, and its contain ferrum, magnesium, calcium, potassium, phosphorus,
Middle trace element needed for the plant growing such as manganese, copper, has the use of facilitation growth, minimizing chemical fertilizer, soil conditioner
Effect.
The preparation method that described alkaline land improving is fertile is:
(1) ardealite 5-20 part, sodium ion adsorbent 3-5 part and Maifanitum 5-10 part are put into batch mixer mixing, obtain A
Material;
(2) acid conditioner 5-10 part, solubility humic acids 15-40 part and pyroligneous liquor 20-35 part mix homogeneously, obtain B liquid;
(3) in A expects, add B liquid mixing and stirring in batch mixer, obtain slurry C;
(4), after adding farm manure 35-50 part, straw stalk powder 15-20 part mix homogeneously in slurry C, microbial bacterial agent is added
2-5 part, adds tween 80 10-15 part of 61-65% in batch mixer, and temperature is not higher than 40 DEG C, mix homogeneously and get final product.
Compared with prior art, the invention has the beneficial effects as follows:
The alkaline land improving fertilizer of the present invention uses the sodium ion of the calcium ion displacement soil colloid absorption in ardealite, by sun
Polyacrylamide adsorbs, and salt-soda soil is played the effect of salt reduction, alleviates the harm that crop root is produced by sodium ion, and
Produce water conservation fertilizer conservation effect, beneficially crop-planting;The pH of acid conditioner adjustable soil so that it is be suitable for plant growth;Micro-life
The acidic materials produced in thing microbial inoculum reproductive process and polysaccharide can improve the physicochemical property of soil, by solubility humic acids, pyroligneous
Liquid, farm manure, straw stalk powder provide the nutrient needed for growth and growth parahormone for crop, add Maifanitum and substitute tradition side
Quick-acting chemical fertilizer in method, supplement the middle trace element needed for plant growing, reduce and enter one because of use that quick-acting chemical fertilizer causes
Step infringement.The alkaline land improving fertilizer that the present invention provides combines chemical method improvement soil salinity and alkalinity, utilizes microorganism to improve soil
Earth physicochemical property and the multiple alkaline land improving measure such as Soil structure, interpolation fertilizer improvement ASI systematic approach, to salt-soda soil soil
The improved effect of earth is good, long action time, can be the arable land being suitable for plant growth by alkaline land improving, and the growth of crop is entered
One step improves the soil environment in salt-soda soil, it is achieved that the benign cycle of alkaline land soil.
Detailed description of the invention
Embodiment one
The alkaline land improving fertilizer of the present invention is made up by weight of following component: ardealite 5 parts, sodium ion adsorbent
3 parts, acid conditioner 5 parts, solubility humic acids 15 parts, pyroligneous liquor 20 parts, microbial bacterial agent 2 parts, farm manure 35 parts, straw stalk powder
15 parts, tween 80 10 parts and Maifanitum 5 parts, wherein, the water content of described farm manure is 5-10%.
Wherein, sodium ion adsorbent is cationic-type polyacrylamide.
Acid conditioner for including maleic anhydride, citric acid, maleic acid, tartaric acid, pyrophosphoric acid, humic acid, oxalic acid
The mix acid liquor that pH is 5 mixed with salicylic acid 38:19:2:5:5:8:1:5:2 by ratio of weight and the number of copies.
Solubility humic acids is fulvic acid.
Microbial bacterial agent is photosynthetic bacteria, escherichia coli, nitrogen-fixing bacteria, dissolving phosphor and dissolving potassium bacterium 1:1:1:2 by weight ratio mixing
The microbial bacterial agent that pH is 4.8, its.
Straw stalk powder use include corn stalk, straw, soybean straws, Caulis et Folium Oryzae, Brassica campestris L, Semen arachidis hypogaeae straw stalk and leaves, pine needle,
Pulverize, after the mixing such as weeds, the dry straw stalk powder obtained.
The preparation method that alkaline land improving is fertile:
(1) by ardealite 5 parts, cationic-type polyacrylamide 3 parts and 5 parts of input batch mixer mixings of Maifanitum, A material is obtained;
(2) acid conditioner 5 parts, solubility humic acids 15 parts and 20 parts of mix homogeneously of pyroligneous liquor, obtain B liquid;
(3) in A expects, add B liquid mixing and stirring in batch mixer, obtain slurry C;
(4), after adding farm manure 35 parts, 15 parts of mix homogeneously of straw stalk powder in slurry C, microbial bacterial agent 2 parts is added, will
The tween 80 of 10 parts of 61-65% adds in batch mixer, and temperature is not higher than 40 DEG C, mix homogeneously and get final product.
Result of the test:
The alkaline land improving fertilizer of the present invention is applied in the salt-soda soil, littoral area that original Suaeda salsa grows, its original pH
Value > 8.5, basicity 5-10%, salinity < 0.5%, soil moisture content is 10-11%, and a Nian Hou test experience district soil is each
Item index, finds that the alkaline land soil of planting area can effectively be improved by this alkaline land improving fertilizer, hence it is evident that reduce soil salt content, fall
Low soil alkalinity, reduces sodium ions content.Wherein, pH value is reduced to 7.64 by 8.71, and soil salt content is improved to 0.23%, soil
Earth basicity is reduced to 1.6%, and sodium ions content reduces 33.67%, and soil moisture content improves to 23%, soil physico-chemical property
The most substantially there is improvement.
Embodiment two
The alkaline land improving fertilizer of the present invention is made up by weight of following component: ardealite 20 parts, cationic poly
Acrylamide 5 parts, maleic anhydride, citric acid, maleic acid, tartaric acid, pyrophosphoric acid, humic acid, oxalic acid, salicylic acid is by weight
The pH that portion rate 38:19:2:5:5:8:1:5:2 mixes be 5.5 mix acid liquor 10 parts, biochemical fulvic acid 40 parts, pyroligneous
The pH that liquid 35 parts, photosynthetic bacteria, nitrogen-fixing bacteria, escherichia coli, dissolving phosphor and dissolving potassium bacterium 1:1:1:2 by weight ratio mix is 5.5
Microbial bacterial agent 5 parts, water content be the farm manure 50 parts of 5-10%, corn stalk, straw, soybean straws, Caulis et Folium Oryzae, Brassica campestris L,
20 parts of straw stalk powder after Semen arachidis hypogaeae straw stalk and leaves, pine needle, weeds co-grinding, tween 80 15 parts and Maifanitum 10 parts.
Its preparation method is identical with embodiment one.
Result of the test:
The alkaline land improving fertilizer of the present invention is applied in the salt-soda soil, littoral area that original Suaeda salsa grows, its original pH
Value > 8.5, basicity 5-10%, salinity < 0.5%, soil moisture content is 10-11%, and a Nian Hou test experience district soil is each
Item index, finds that the alkaline land soil of planting area can effectively be improved by this alkaline land improving fertilizer, hence it is evident that reduce soil salt content, fall
Low soil alkalinity, reduces sodium ions content.Wherein, pH value is reduced to 7.24 by 8.53, and soil salt content is improved to 0.19%, soil
Earth basicity is reduced to 1.2%, and sodium ions content reduces 50.56%, and soil moisture content improves to 27%, soil physico-chemical property
The most substantially there is improvement.
Embodiment three
The alkaline land improving fertilizer of the present invention is made up by weight of following component: ardealite 15 parts, cationic poly
Acrylamide 4 parts, maleic anhydride, citric acid, maleic acid, tartaric acid, pyrophosphoric acid, humic acid, oxalic acid, salicylic acid is by weight
The pH that portion rate 38:19:2:5:5:8:1:5:2 mixes be 5.2 mix acid liquor 8 parts, nitro humic acid 30 parts, pyroligneous
The pH that liquid 30 parts, photosynthetic bacteria, nitrogen-fixing bacteria, escherichia coli, dissolving phosphor and dissolving potassium bacterium 1:1:1:2 by weight ratio mix is 5.2
Microbial bacterial agent 4 parts, water content be the farm manure 45 parts of 5-10%, corn stalk, straw, soybean straws, Caulis et Folium Oryzae, Brassica campestris L,
18 parts of straw stalk powder after Semen arachidis hypogaeae straw stalk and leaves, pine needle, weeds co-grinding, tween 80 12 parts and Maifanitum 8 parts.
Wherein, the preparation method of nitro humic acid is:
It is that 1:0.2-0.4 is under agitation by brown coal powder or air slaking coal dust with the nitric acid of 35-45% concentration by coal acid ratio
Oxidation, the time is 40-60min, through extraction, distillation, i.e. obtains nitro humic acid after drying, and wherein, the fineness of coal dust is 40-60
Mesh.
The preparation method that alkaline land improving is fertile is identical with embodiment one.
Result of the test:
The alkaline land improving fertilizer of the present invention is applied in the salt-soda soil, littoral area that original Suaeda salsa grows, its original pH
Value > 8.5, basicity 5-10%, salinity < 0.5%, soil moisture content is 10-11%, and a Nian Hou test experience district soil is each
Item index, finds that the alkaline land soil of planting area can effectively be improved by this alkaline land improving fertilizer, hence it is evident that reduce soil salt content, fall
Low soil alkalinity, reduces sodium ions content.Wherein, pH value is reduced to 7.87 by 8.69, and soil salt content is improved to 0.26%, soil
Earth basicity is reduced to 1.5%, and sodium ions content reduces 45.31%, and soil moisture content improves to 25%, soil physico-chemical property
The most substantially there is improvement.
The foregoing is only embodiments of the invention, not thereby limit the scope of the claims of the present invention, every utilize this
Amendment that bright description is made, equivalent, improvement etc., or directly or indirectly apply to other relevant technical fields,
The most in like manner it is included in the scope of patent protection of the present invention.
Claims (10)
1. an alkaline land improving fertilizer, it is characterised in that: include that ardealite, sodium ion adsorbent, acid conditioner, solubility are rotten
Phytic acid, pyroligneous liquor, microbial bacterial agent, farm manure, straw stalk powder and Maifanitum.
Alkaline land improving the most according to claim 1 is fertile, it is characterised in that include the raw material of following weight: phosphorus stone
Cream 5-20 part, sodium ion adsorbent 3-5 part, acid conditioner 5-10 part, solubility humic acids 15-40 part, pyroligneous liquor 20-35
Part, microbial bacterial agent 2-5 part, farm manure 35-50 part, straw stalk powder 15-20 part, tween 80 10-15 part and Maifanitum 5-10 part,
Wherein, the water content of described farm manure is 5-10%.
Alkaline land improving the most according to claim 2 is fertile, it is characterised in that: described sodium ion adsorbent is cationic poly
Acrylamide.
Alkaline land improving the most according to claim 3 is fertile, it is characterised in that: described acid conditioner includes maleic anhydride,
Citric acid, maleic acid, tartaric acid, pyrophosphoric acid, humic acid, oxalic acid and salicylic acid.
Alkaline land improving the most according to claim 4 is fertile, it is characterised in that: described maleic anhydride, citric acid, maleic two
Acid, tartaric acid, pyrophosphoric acid, humic acid, oxalic acid, salicylic ratio of weight and number is 38:19:2:5:5:8:1:5:2, and its pH is at 5-
Between 5.5.
Alkaline land improving the most according to claim 5 is fertile, it is characterised in that: described solubility humic acids is fulvic acid, life
Change fulvic acid, any one of nitro humic acid or its mixing.
Alkaline land improving the most according to claim 6 is fertile, it is characterised in that: described microbial bacterial agent is photosynthetic bacteria, big
Enterobacteria, nitrogen-fixing bacteria, the microbial bacterial agent of dissolving phosphor and dissolving potassium bacterium 1:1:1:2 by weight ratio mixing, its pH is between 4.8-5.5.
Alkaline land improving the most according to claim 7 is fertile, it is characterised in that: described straw stalk powder use include corn stalk,
Pulverize after straw, soybean straws, Caulis et Folium Oryzae, Brassica campestris L, Semen arachidis hypogaeae straw stalk and any one of leaves, pine needle, weeds etc. or its mixing
The dry straw stalk powder obtained.
9. according to the manufacture method that a kind of alkaline land improving described in any one of claim 1-8 is fertile, it is characterised in that: use with
Lower step is made:
(1) ardealite 5-20 part, sodium ion adsorbent 3-5 part and Maifanitum 5-10 part are put into batch mixer mixing, obtain A material;
(2) acid conditioner 5-10 part, solubility humic acids 15-40 part and pyroligneous liquor 20-35 part mix homogeneously, obtain B liquid;
(3) in A expects, add B liquid mixing and stirring in batch mixer, obtain slurry C;
(4), after adding farm manure 35-50 part, straw stalk powder 15-20 part mix homogeneously in slurry C, microbial bacterial agent 2-5 is added
Part, the tween 80 of 10-15 part 61-65% is added in batch mixer, temperature is not higher than 40 DEG C, mix homogeneously and get final product.
The manufacture method that alkaline land improving the most according to claim 9 is fertile, it is characterised in that: described nitro humic acid
Preparation method is: be that 1:0.2-0.4 is under agitation by brown coal powder or weathered coal with the nitric acid of 35-45% concentration by coal acid ratio
Powder aoxidizes, and the time is 40-60min, through extraction, distillation, i.e. obtains nitro humic acid after drying, and wherein, the fineness of coal dust is 40-60
Mesh.
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CN106831239A (en) * | 2017-02-13 | 2017-06-13 | 北京市波普克生态科技有限公司 | Saline alkali soil conditioner, preparation method and applications |
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