CN111093608A - 清洗剂组合物 - Google Patents

清洗剂组合物 Download PDF

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CN111093608A
CN111093608A CN201880058428.8A CN201880058428A CN111093608A CN 111093608 A CN111093608 A CN 111093608A CN 201880058428 A CN201880058428 A CN 201880058428A CN 111093608 A CN111093608 A CN 111093608A
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acid
fatty acid
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平山奈津美
河野佐代子
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Shiseido Co Ltd
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Abstract

[课题]提供：收纳于泵起泡容器等中，并且即使重复使用也不会发生堵塞导致的工作不良，泡沫的弹性、持续性及冲洗后的使用感优异的清洗剂组合物。[解决手段]一种清洗剂组合物，其特征在于，含有：通过高级脂肪酸被N‑甲基牛磺酸钠中和而得到的皂、和包含二甲基二烯丙基氯化铵作为单体单元的分子量20万以下的聚合物。

Description

清洗剂组合物
技术领域
本发明涉及一种用于收纳于如下容器的清洗剂组合物：泵起泡容器，其内置多孔膜并将内容物与空气一同以泡沫状排出的泵起泡容器；气溶胶容器，其经过狭小的流路将内容物与液化气体一同以泡沫状喷射，所述清洗剂组合物即使经过重复的使用也不会发生多孔膜、流路的堵塞，泡沫的持续性、弹性及易洗净性优异。
背景技术
为了容易地将彩妆等洗净，已知有将清洗剂收纳于泵起泡容器或气溶胶容器、并将其以泡沫状喷出的清洗剂产品。
像这样的清洗剂产品中，有将喷出的泡沫在全脸涂开的必要，因此需要泡沫具备适度的弹性、持续性。为了赋予泡沫适度的弹性、持续性，于清洗剂中配合阳离子聚合物是有效的，但阳离子聚合物的分子量过大时，多孔膜、流路变得容易发生堵塞，从而有变得无法喷出清洗剂的担心。
另外，清洗剂中，作为清洗成分，配合有通过将高级脂肪酸进行中和处理而得到的皂，但根据中和处理使用的中和剂的种类，有时即使配合阳离子聚合物，也无法得到充分的泡沫的弹性，无法满足冲洗后的使用感。
因此，为了开发即使经过重复的使用也不会发生泵起泡容器等的堵塞，泡沫的弹性、持续性及冲洗后的使用感优异的清洗剂组合物，对适当的阳离子聚合物、和用以中和处理高级脂肪酸的中和剂的研究是重要的。
专利文献1：日本特开2017-88555号公报
发明内容
发明要解决的问题
本发明的课题在于提供：收纳于泵起泡容器等中，即使重复使用也不会发生堵塞导致的工作不良，并且泡沫的弹性、持续性及冲洗后的使用感优异的清洗剂组合物。
用于解决问题的方案
为了解决前述课题，本发明人等进行研究，结果发现：配合通过高级脂肪酸被N-甲基牛磺酸钠中和而得到的皂、和包含二甲基二烯丙基氯化铵作为单体单元的分子量20万以下的聚合物，由此，可以得到能够重复使用泵起泡容器等并且泡沫富有持续性、弹性、且冲洗后的使用感也优异的清洗剂，从而完成了本发明。
即，本发明为一种清洗剂组合物，其特征在于，含有：通过高级脂肪酸被N-甲基牛磺酸钠中和而得到的皂、和包含二甲基二烯丙基氯化铵作为单体单元的分子量20万以下的聚合物。
发明的效果
根据本发明的清洗剂组合物，可以得到能够重复使用泵起泡容器等并且泡沫富有弹性、持续性、且冲洗后的使用感也优异的清洗剂。
具体实施方式
本发明的清洗剂组合物的特征在于，其含有：通过高级脂肪酸被N-甲基牛磺酸钠中和而得到的皂、和包含二甲基二烯丙基氯化铵作为单体单元的分子量20万以下的聚合物。
本发明使用的高级脂肪酸为碳数5～25左右的直链状或支链状的饱和或不饱和的脂肪酸，可举出例如己酸、庚酸、辛酸、壬酸、癸酸、十一烷酸、月桂酸、癸烯酸、十一烯酸、月桂烯酸、2-乙基丁酸、异戊酸、2-乙基戊酸、2-乙基己酸、异壬酸、3,5,5-三甲基己酸、十三烷酸、四甲基壬酸、肉豆蔻酸、十五烷酸、棕榈酸、硬脂酸、花生酸、山萮酸、二十四烷酸、二十六烷酸、肉豆蔻油酸、棕榈油酸、油酸、反油酸、花生油酸、芥酸、神经酸、亚油酸、亚麻酸、次亚麻油酸、花生四烯酸、2-己基癸酸、异硬脂酸、12-羟基硬脂酸、椰子油脂肪酸、氢化椰子油脂肪酸、棕榈油脂肪酸、氢化棕榈油脂肪酸、棕榈仁油脂肪酸、氢化棕榈仁油脂肪酸、牛脂脂肪酸、氢化牛脂脂肪酸等，其中优选月桂酸、肉豆蔻酸、棕榈酸、硬脂酸等碳数12～18的直链状饱和脂肪酸。
作为用于中和处理高级脂肪酸的中和剂，使用N-甲基牛磺酸钠。中和率优选为100～150％。中和率小于100％时，低温下的高级脂肪酸的结晶析出，有在泵起泡的多孔膜等发生堵塞的危险性。另一方面，中和率超过150％时，有可能发生清洗剂随时间而变色等问题。中和处理为将N-甲基牛磺酸钠放入反应容器，加热至约60℃，添加混合脂肪酸并中和，从而生成皂。
作为本发明使用的、以二甲基二烯丙基氯化铵为单体单元的聚合物，可举出例如二甲基二烯丙基氯化铵/丙烯酸共聚物、二甲基二烯丙基氯化铵/丙烯酰胺/丙烯酸共聚物、二甲基二烯丙基氯化铵/丙烯酰胺共聚物等。
另外，将以二甲基二烯丙基氯化铵为单体单元的聚合物的分子量设为20万以下。分子量超过20万时，在内置泵起泡的多孔膜、气溶胶容器中狭小的流路中，有变为容许外的流动阻力的担心，另外，有堵塞引起泵起泡容器等工作不良的担心。因此，为了使重复喷出泡沫成为可能，并且得到具备适度的弹性的泡沫，需要将聚合物的分子量调节至20万以下。需要说明的是，作为像这样的二甲基烯丙基氯化铵-丙烯酰胺共聚物(分子量12万)的市售品，有The Lubrizol Corporation制商品“Merquat 740”(相当于化妆品的成分表示中的“聚季铵盐-7”。)等，作为丙烯酰胺-丙烯酸-二甲基二烯丙基氯化铵共聚物(分子量15万)的市售品，有The Lubrizol Corporation制商品“Merquat 3940”(相当于化妆品的成分表示中的“聚季铵盐-39”。)等。
本发明的清洗剂组合物中，除了上述必须成分外，在不损害本发明的效果范围内还可以配合1种或2种以上化妆品、医药品中通常配合的其他成分。下述举出其具体例，但并不限定于这些。
作为保湿剂，可以配合聚乙二醇、甘油、丙二醇、一缩二丙二醇、丁二醇、异戊二烯二醇、山梨糖醇、木糖醇、麦芽糖醇、粘多糖、玻尿酸、硫酸软骨素、壳聚糖等。作为增稠剂，可以配合甲基纤维素、乙基纤维素、阿拉伯胶、聚乙烯醇、蒙脱土、皂石等。另外可以配合乙醇等作为溶剂。
作为抗氧化剂，可以配合丁基羟基甲苯、生育酚、植酸等，作为抗菌防腐剂，可以配合苯甲酸、水杨酸、山梨酸、对羟基苯甲酸烷基酯(对羟基苯甲酸乙酯、对羟基苯甲酸丁酯等)、六氯酚等。
作为表面活性剂，可以配合聚乙二醇二异硬脂酸酯、聚乙二醇单异硬脂酸酯、聚氧乙烯甘油异硬脂酸酯、聚氧乙烯甘油三异硬脂酸酯、脱水山梨醇单月桂酸酯、脱水山梨醇单棕榈酸酯、脱水山梨醇倍半油酸酯、脱水山梨醇三油酸酯、聚氧乙烯脱水山梨醇单月桂酸酯、聚乙二醇单油酸酯、聚氧乙烯烷基醚、聚乙二醇二酯、月桂酰二乙醇酰胺、脂肪酸异丙醇酰胺、麦芽糖醇羟基脂肪族醚、烷基化多糖、烷基葡糖苷、糖酯、聚氧乙烯/甲基聚硅氧烷共聚物等非离子性表面活性剂、硬脂基三甲基氯化铵、苯扎氯铵、月桂基胺氧化物等阳离子性表面活性剂、棕榈酸钠、月桂酸钠、月桂基硫酸钠、月桂酸钾、聚氧乙烯烷基硫酸三乙醇胺、太古油、直链十二烷基苯硫酸盐、聚氧乙烯氢化蓖麻油马来酸、椰油脂肪酸精氨酸、酰基甲基牛磺酸盐等阴离子性表面活性剂、椰子油脂肪酸羟基丙基甜菜碱、月桂基甜菜碱等两性表面活性剂。
作为其他成分，可以适当配合色素、香料、稳定剂等。
本发明的清洗剂组合物作为被收纳于泵起泡容器等的毛发、皮肤的清洗剂，优选以洗面奶、沐浴液、洗手液、洗发水等方式被提供。
实施例
以下，根据实施例对本发明进行更详细地说明，但这些实施例并不限定本发明。需要说明的是，表中的数值若无特别记载则表示质量％。
通过下述表的各例记载的组成以通常方法制备清洗剂。制备的清洗剂收纳于具有多孔膜的泵起泡容器。泵起泡容器内置有泵机构，用手指按压与泵机构连接的盖子的上表面时，被收纳于容器内的清洗剂组合物与空气混合并通过多孔膜(200目和305目2片)，由此以泡沫状从容器排出口被排出。
从泵起泡容器排出的清洗剂由专业鉴定员对“排出时的泡沫的质感”、“泡沫的弹性”、“冲洗容易度”及“冲洗后的湿润感”等4个项目以8个阶段进行评价。需要说明的是，8个阶段中4～8判断为合格，1～3判断为不合格。
[表1]
Figure BDA0002404471160000061
表1示出关于清洗剂中所配合的阳离子聚合物的种类及量的研究结果。对于配合有0.01～3％分子量12万的聚季铵盐-7(二甲基二烯丙基氯化铵-丙烯酰胺共聚物)的实施例1～5、和配合有0.01～2％分子量15万的聚季铵盐-39(丙烯酰胺-丙烯酸-二甲基二烯丙基氯化铵共聚物)的实施例6～10而言，在全部的评价项目中均确认为良好的结果。需要说明的是，配合有分子量160万的聚季铵盐-7(二甲基二烯丙基氯化铵-丙烯酰胺共聚物)的比较例4由于变为容许外的流动阻力而发生泵起泡容器的工作不良，未能进行评价。
[表2]
Figure BDA0002404471160000071
表2示出关于用于中和高级脂肪酸的中和剂与阳离子聚合物的组合的研究结果。将氢氧化钾用作中和剂时，结果为泡沫的弹性不足，另外冲洗后的湿润感也差(比较例5、6)，但配合N-甲基牛磺酸钠作为中和剂，并配合分子量12万的聚季铵盐-7(二甲基二烯丙基氯化铵-丙烯酰胺共聚物)作为阳离子聚合物的实施例11中，在全部的项目中均得到良好的结果。

Claims (1)

1.一种清洗剂组合物，其特征在于，含有：通过高级脂肪酸被N-甲基牛磺酸钠中和而得到的皂、和包含二甲基二烯丙基氯化铵作为单体单元的分子量20万以下的聚合物。
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