JP7158394B2 - 洗浄剤組成物 - Google Patents
洗浄剤組成物 Download PDFInfo
- Publication number
- JP7158394B2 JP7158394B2 JP2019543607A JP2019543607A JP7158394B2 JP 7158394 B2 JP7158394 B2 JP 7158394B2 JP 2019543607 A JP2019543607 A JP 2019543607A JP 2019543607 A JP2019543607 A JP 2019543607A JP 7158394 B2 JP7158394 B2 JP 7158394B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- molecular weight
- dimethyldiallylammonium chloride
- foam
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 12
- 239000003599 detergent Substances 0.000 title description 15
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 22
- 239000000194 fatty acid Substances 0.000 claims description 22
- 229930195729 fatty acid Natural products 0.000 claims description 22
- 150000004665 fatty acids Chemical class 0.000 claims description 22
- 230000003472 neutralizing effect Effects 0.000 claims description 10
- 229920006322 acrylamide copolymer Polymers 0.000 claims description 9
- 239000000344 soap Substances 0.000 claims description 8
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical compound C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 claims description 7
- FJWSMXKFXFFEPV-UHFFFAOYSA-N prop-2-enamide;hydrochloride Chemical compound Cl.NC(=O)C=C FJWSMXKFXFFEPV-UHFFFAOYSA-N 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 239000006260 foam Substances 0.000 description 16
- -1 etc.) Chemical compound 0.000 description 10
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 6
- 239000012528 membrane Substances 0.000 description 6
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- 239000012459 cleaning agent Substances 0.000 description 5
- 238000006386 neutralization reaction Methods 0.000 description 5
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- 229920006317 cationic polymer Polymers 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
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- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
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- 239000004615 ingredient Substances 0.000 description 3
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- 239000000178 monomer Substances 0.000 description 3
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- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 2
- OXQGTIUCKGYOAA-UHFFFAOYSA-N 2-Ethylbutanoic acid Chemical compound CCC(CC)C(O)=O OXQGTIUCKGYOAA-UHFFFAOYSA-N 0.000 description 2
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 2
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 235000019482 Palm oil Nutrition 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 2
- 235000015278 beef Nutrition 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000008406 cosmetic ingredient Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 2
- XMHIUKTWLZUKEX-UHFFFAOYSA-N hexacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 239000000845 maltitol Substances 0.000 description 2
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 2
- 235000010449 maltitol Nutrition 0.000 description 2
- 229940035436 maltitol Drugs 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 239000002540 palm oil Substances 0.000 description 2
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- 230000002688 persistence Effects 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 235000003441 saturated fatty acids Nutrition 0.000 description 2
- 150000004671 saturated fatty acids Chemical class 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 2
- SZHOJFHSIKHZHA-UHFFFAOYSA-N tridecanoic acid Chemical compound CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 description 2
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 1
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 1
- KAKVFSYQVNHFBS-UHFFFAOYSA-N (5-hydroxycyclopenten-1-yl)-phenylmethanone Chemical compound OC1CCC=C1C(=O)C1=CC=CC=C1 KAKVFSYQVNHFBS-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
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Description
本発明は、多孔質膜を内蔵し、空気とともに内容物を泡状にして吐出するポンプフォーマー容器や狭小の流路を経て液化ガスとともに内容物を泡状に噴射するエアゾール容器に収容するための洗浄剤組成物であって、繰り返しの使用によっても多孔質膜や流路の目詰まりが生じることなく、泡の持続性、弾力性及び洗い落とし易さに優れる洗浄剤組成物に関する。
メーキャップ等を手軽に洗い落とすため、洗浄剤をポンプフォーマー容器あるいはエアゾール容器に収容し、泡状にして噴出する洗浄剤製品が知られている。
このような洗浄剤製品においては、噴出した泡を顔全体に塗り広げる必要があるため、泡に適度な弾力性や持続性を備えることが求められる。泡に適度な弾力性、持続性を付与するためには、洗浄剤にカチオンポリマーを配合することが効果的であるが、カチオンポリマーの分子量が大き過ぎると、多孔質膜や流路に目詰まりが生じ易くなり、洗浄剤を噴出できなくなるおそれがある。
また洗浄剤には、洗浄成分として、高級脂肪酸を中和処理することにより得られる石鹸が配合されるが、中和処理に用いる中和剤の種類によっては、カチオンポリマーを配合しても、十分な泡の弾力性が得られず、洗い流した後の使用感も満足できるものではなかった。
したがって、繰り返しの使用によってもポンプフォーマー容器等の目詰まりが生じることなく、泡の弾力性、持続性及び洗い流した後の使用感に優れる洗浄剤組成物を開発するためには、適正なカチオンポリマーと、高級脂肪酸を中和処理する中和剤について検討することが重要となる。
本発明は、ポンプフォーマー容器等に収容し、繰り返し使用しても目詰まりによる作動不良が生じることなく、泡の弾力性、持続性及び洗い流した後の使用感に優れる洗浄剤組成物を提供することを課題とする。
前記課題を解決するために本発明者らが検討を行った結果、高級脂肪酸をＮ－メチルタウリンナトリウムで中和することにより得られる石鹸と、分子量２０万以下の塩化ジメチルジアリルアンモニウム－アクリルアミド共重合体又は分子量２０万以下のアクリルアミド－アクリル酸－塩化ジメチルジアリルアンモニウム共重合体と、を配合することにより、ポンプフォーマー容器等による繰り返しの使用が可能となり、しかも泡の持続性、弾力性に富み、洗い流した後の使用感にも優れた洗浄剤を得ることができることを見出し、本発明を完成するに至った。
すなわち本発明は、高級脂肪酸をＮ－メチルタウリンナトリウムで中和することにより得られる石鹸と、分子量２０万以下の塩化ジメチルジアリルアンモニウム－アクリルアミド共重合体又は分子量２０万以下のアクリルアミド－アクリル酸－塩化ジメチルジアリルアンモニウム共重合体と、を含有することを特徴とする洗浄剤組成物である。
本発明の洗浄剤組成物によれば、ポンプフォーマー容器等による繰り返しの使用が可能であり、しかも泡の弾力性、持続性に富み、洗い流した後の使用感にも優れた洗浄剤を得ることができる。
本発明の洗浄剤組成物は、高級脂肪酸をＮ－メチルタウリンナトリウムで中和することにより得られる石鹸と、塩化ジメチルジアリルアンモニウムをモノマー単位として含む分子量２０万以下の重合体と、を含有することを特徴とする。
本発明に用いる高級脂肪酸は、炭素数５～２５程度の直鎖状又は分岐状の飽和又は不飽和の脂肪酸であり、例えば、カプロン酸、ヘプタン酸、カプリル酸、ペラルゴン酸、カプリン酸、ウンデカン酸、ラウリン酸、カプロレイン酸、ウンデシレン酸、ラウロレイン酸、２－エチルブタン酸、イソペンタン酸、２－エチルペンタン酸、２－エチルヘキサン酸、イソノナン酸、３，５，５－トリメチルヘキサン酸、トリデカン酸、テトラメチルノナン酸、ミリスチン酸、ペンタデカン酸、パルミチン酸、ステアリン酸、アラキン酸、ベヘン酸、リグノセリン酸、セロチン酸、ミリストレイン酸、パルミトレイン酸、オレイン酸、エライジン酸、ゴンドイン酸、エルカ酸、セラコレイン酸、リノール酸、リノエライジン酸、リノレン酸、アラキドン酸、２－ヘキシルデカン酸、イソステアリン酸、１２－ヒドロキシステアリン酸、ヤシ油脂肪酸、硬化ヤシ油脂肪酸、パーム油脂肪酸、硬化パーム油脂肪酸、パーム核油脂肪酸、硬化パーム核油脂肪酸、牛脂脂肪酸、硬化牛脂脂肪酸等が挙げられが、中でも、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸等の炭素数１２～１８の直鎖状飽和脂肪酸が好ましい。
高級脂肪酸を中和処理するための中和剤として、Ｎ－メチルタウリンナトリウムを用いる。中和率は１００～１５０％が好ましい。中和率が１００％より小さいと、低温下において高級脂肪酸の結晶が析出し、ポンプフォーマーの多孔質膜等で目詰まりを起こす危険性がある。一方、中和率が１５０％をこえると、時間の経過とともに洗浄剤が変色するなどの問題が生じる可能性がある。中和処理は、Ｎ－メチルタウリンナトリウムを反応容器に入れ、約６０℃に加熱し、混合脂肪酸を加えて中和し、石鹸を生成する。
本発明に用いる、塩化ジメチルジアリルアンモニウムをモノマー単位とする重合体としては、例えば、塩化ジメチルジアリルアンモニウム・アクリル酸共重合体、塩化ジメチルジアリルアンモニウム・アクリルアミド・アクリル酸共重合体、塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体等が挙げられる。
また、塩化ジメチルジアリルアンモニウムをモノマー単位とする重合体の分子量は２０万以下とする。分子量が２０万をこえると、ポンプフォーマーに内蔵される多孔質膜やエアゾール容器における狭小な流路において、許容外の流動抵抗となり、また、目詰まりによるポンプフォーマー容器等の作動不良を引き起こすおそれがある。このため、繰り返しによる泡の噴出を可能としながら、適度な弾力性を備えた泡を得るためには、重合体の分子量を２０万以下に調整する必要がある。尚、このような塩化ジメチルジアリルアンモニウム－アクリルアミド共重合体(分子量１２万)の市販品としては、日本ルーブリゾール社製商品「マーコート７４０」（化粧品の成分表示では、「ポリクオタニウム－７」に相当する。）等があり、アクリルアミド－アクリル酸－塩化ジメチルジアリルアンモニウム共重合体(分子量１５万)の市販品としては、日本ルーブリゾール社製商品「マーコート３９４０」（化粧品の成分表示では、「ポリクオタニウム－３９」に相当する。）等がある。
本発明の洗浄剤組成物には、上記必須成分に加えて、本発明の効果を損なわない範囲で化粧料や医薬品に通常配合される他の成分を１種又は２種以上配合することができる。下記にその具体例を挙げるが、これらに限定されるものではない。
保湿剤として、ポリエチレングリコール、グリセリン、プロピレングリコール、ジプロピレングリコール、ブチレングリコール、イソプレングリコール、ソルビトール、キシリトール、マルチトール、ムコ多糖、ヒアルロン酸、コンドロイチン硫酸、キトサン等を配合することができる。増粘剤として、メチルセルロース、エチルセルロース、アラビアガム、ポリビニルアルコール、モンモリロナイト、ラポナイト等を配合することができる。また溶剤としてエタノール等を配合することができる。
酸化防止剤として、ブチルヒドロキシトルエン、トコフェロール、フィチン酸等、抗菌防腐剤として、安息香酸、サリチル酸、ソルビン酸、パラオキシ安息香酸アルキルエステル（エチルパラベン、ブチルパラベン等）、ヘキサクロロフェン等を配合することができる。
界面活性剤として、ジイソステアリン酸ポリエチレングリコール、モノイソステアリン酸ポリエチレングリコール、イソステアリン酸ポリオキシエチレングリセリル、トリイソステアリン酸ポリオキシエチレングリセリル、モノラウリン酸ソルビタン、モノパルミチン酸ソルビタン、セスキオレイン酸ソルビタン、トリオレイン酸ソルビタン、モノラウリン酸ポリオキシエチレンソルビタン、ポリエチレングリコールモノオレエート、ポリオキシエチレンアルキルエーテル、ポリグリコールジエステル、ラウロイルジエタノールアマイド、脂肪酸イソプロパノールアマイド、マルチトールヒドロキシ脂肪族エーテル、アルキル化多糖、アルキルグルコシド、シュガーエステル、ポリオキシエチレン・メチルポリシロキサン共重合体等の非イオン性界面活性剤、ステアリルトリメチルアンモニウムクロライド、塩化ベンザルコニウム、ラウリルアミンオキサイド等のカチオン性界面活性剤、パルミチン酸ナトリウム、ラウリン酸ナトリウム、ラウリル硫酸ナトリウム、ラウリン酸カリウム、ポリオキシエチレンアルキル硫酸トリエタノールアミン、ロート油、リニアドデシルベンゼン硫酸塩、ポリオキシエチレン硬化ヒマシ油マレイン酸、ヤシ脂肪酸アルギニン、アシルメチルタウリン塩等のアニオン性界面活性剤、ヤシ油脂肪酸ヒドロキシプロピルベタイン、ラウリルベタイン等の両性界面活性剤を配合することができる。
その他成分として、色素、香料、安定剤等を適宜配合することができる。
本発明の洗浄剤組成物は、ポンプフォーマー容器等に収容された毛髪や皮膚の洗浄剤として、洗顔料、ボディソープ、ハンドソープ、シャンプーなどの形態で好適に提供される。
以下、実施例に沿って本発明をさらに詳細に説明するが、これらの実施例は本発明を限定するものではない。なお、表中の数値は、特に記載のない限り質量％を示す。
下記表の各例に記載する組成で洗浄剤を常法により調整した。調製した洗浄剤は、多孔質膜を有するポンプフォーマー容器に収容した。ポンプフォーマー容器にはポンプ機構が内蔵されており、ポンプ機構に連結するキャップの上面を指で押圧すると、容器内に収容された洗浄剤組成物は空気と混合され、多孔質膜（２００メッシュと３０５メッシュの２枚）を通過することにより、容器吐出口から泡状に吐出される。
ポンプフォーマー容器から吐出した洗浄剤は、専門パネルにより、「吐出時の泡のキメ細かさ」、「泡の弾力性」、「洗い流しやすさ」及び「洗い流した後のしっとり感」の４項目について８段階で評価を行った。尚、８段階中４～８は合格、１～３は不合格と判断する。
表１は、洗浄剤に配合するカチオンポリマーの種類及び量について検討した結果を示す。分子量１２万のポリクオタニウム－７(塩化ジメチルジアリルアンモニウム－アクリルアミド共重合体)を０．０１～３％配合した実施例１～５と、分子量１５万のポリクオタニウム－３９(アクリルアミド－アクリル酸－塩化ジメチルジアリルアンモニウム共重合体)を０．０１～２％配合した実施例６～１０については、すべての評価項目において良好な結果を確認することができた。尚、分子量１６０万のポリクオタニウム－７(塩化ジメチルジアリルアンモニウム－アクリルアミド共重合体)を配合した比較例４は、許容外の流動抵抗となりポンプフォーマー容器の作動不良が生じたため、評価を行うことは不可能であった。
表２は、高級脂肪酸を中和するための中和剤とカチオンポリマーとの組み合わせを検討した結果を示す。中和剤として水酸化カリウムを用いた場合には、泡の弾力性が不足し、また洗い流した後のしっとり感についても劣る結果であったが(比較例５，６)、中和剤としてＮ－メチルタウリンナトリウムを配合し、カチオンポリマーとして分子量１２万のポリクオタニウム－７(塩化ジメチルジアリルアンモニウム－アクリルアミド共重合体)を配合した実施例11では、すべての項目で良好な結果を得ることができた。
Claims (1)
- 高級脂肪酸をＮ－メチルタウリンナトリウムで中和することにより得られる石鹸と、分子量２０万以下の塩化ジメチルジアリルアンモニウム－アクリルアミド共重合体又は分子量２０万以下のアクリルアミド－アクリル酸－塩化ジメチルジアリルアンモニウム共重合体と、を含有することを特徴とする洗浄剤組成物。
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| JP2017178605 | 2017-09-19 | ||
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| PCT/JP2018/034108 WO2019059111A1 (ja) | 2017-09-19 | 2018-09-14 | 洗浄剤組成物 |
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| WO2019059111A1 (ja) | 2019-03-28 |
| US20210000716A1 (en) | 2021-01-07 |
| CN111093608B (zh) | 2023-05-30 |
| TW201920643A (zh) | 2019-06-01 |
| JPWO2019059111A1 (ja) | 2020-11-05 |
| CN111093608A (zh) | 2020-05-01 |
| US11684556B2 (en) | 2023-06-27 |
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