CN111070933A - 一种雾面合成纸 - Google Patents

一种雾面合成纸 Download PDF

Info

Publication number
CN111070933A
CN111070933A CN201910371664.1A CN201910371664A CN111070933A CN 111070933 A CN111070933 A CN 111070933A CN 201910371664 A CN201910371664 A CN 201910371664A CN 111070933 A CN111070933 A CN 111070933A
Authority
CN
China
Prior art keywords
synthetic paper
matte
surface layer
printing surface
master batch
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201910371664.1A
Other languages
English (en)
Other versions
CN111070933B (zh
Inventor
廖德超
陈春来
吴文义
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nan Ya Plastics Corp
Original Assignee
Nan Ya Plastics Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nan Ya Plastics Corp filed Critical Nan Ya Plastics Corp
Publication of CN111070933A publication Critical patent/CN111070933A/zh
Application granted granted Critical
Publication of CN111070933B publication Critical patent/CN111070933B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001—Combinations of extrusion moulding with other shaping operations
    • B29C48/0018—Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07—Flat, e.g. panels
    • B29C48/08—Flat, e.g. panels flexible, e.g. films
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/21—Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/28—Storing of extruded material, e.g. by winding up or stacking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/49—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using two or more extruders to feed one die or nozzle
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/911—Cooling
    • B29C48/9135—Cooling of flat articles, e.g. using specially adapted supporting means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/10—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial
    • B29C55/12—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial
    • B29C55/14—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial successively
    • B29C55/143—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial successively firstly parallel to the direction of feed and then transversely thereto
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/10—Polymers of propylene
    • B29K2023/12—PP, i.e. polypropylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
    • B29K2105/0044—Stabilisers, e.g. against oxydation, light or heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2509/00—Use of inorganic materials not provided for in groups B29K2503/00 - B29K2507/00, as filler
    • B29K2509/02—Ceramics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037—Other properties
    • B29K2995/005—Oriented
    • B29K2995/0053—Oriented bi-axially
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/03—3 layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/05—5 or more layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/102—Oxide or hydroxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2274/00—Thermoplastic elastomer material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/408—Matt, dull surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/514—Oriented
    • B32B2307/518—Oriented bi-axially
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/732—Dimensional properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/75—Printability
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/16—Ethene-propene or ethene-propene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
    • C08K2003/2213—Oxides; Hydroxides of metals of rare earth metal of cerium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K2003/343—Peroxyhydrates, peroxyacids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/014—Stabilisers against oxidation, heat, light or ozone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005—Stabilisers against oxidation, heat, light, ozone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/04—Thermoplastic elastomer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2310/00—Masterbatches
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2848—Three or more layers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

本发明提供一种雾面合成纸，雾面合成纸为厚度25～300微米的多层叠层结构的双轴延伸聚丙烯合成纸，雾面合成纸包括作为最外层纸面层的一印刷表面层，印刷表面层的光泽度值，根据Tappi T480测量为15‑50％，且基于印刷表面层的总重量，其包含以下各成分，且各成分的总和100重量％：(1)聚丙烯0～66重量％；(2)聚乙烯0～30重量％；(3)二氧化钛母粒(30～60％)10～15重量％；(4)碳酸钙母粒(40～70％)10～15重量％；(5)抗氧化剂1～5重量％；(6)雾面粉母粒(10～70％)4～75重量％；(7)热塑性弹性体0～25重量％。

Description

一种雾面合成纸
技术领域
本发明涉及一种雾面合成纸，特别是涉及一种印刷表面具备高雾面低光泽特性且合适作为印刷用纸的双轴延伸聚丙烯合成纸。
背景技术
现有技术中的双轴延伸聚丙烯合成纸(以下简称合成纸)，为多层叠层结构的合成纸，而具三层叠层结构的合成纸10，如图1所示，由最外层纸面层(A1)、发泡中间层(C1)及最内层纸面层(E1)依序叠置构成，其制作工艺，如图2所示，是使用三台押出机(a1、c1及e1)，将各层叠层的配方组成汇流挤入同－T型模头而制成热融态的三层叠层制品。
具五层叠层结构的合成纸15，如图3所示，由最外层纸面层(A2)、上侧树脂层(B2)、发泡中间层(C2)、下侧树脂层(D2)及最内层纸面层(E2)依序叠置构成，其制作工艺，如图4所示，是使用五台押出机(a1、b1、c1、d1及e1)，将各层叠层的配方组成汇流挤入同－T型模头而制成热融态的五层叠层制品。
制成的呈热融态的三层或五层叠层制品，经过冷却成型装置20的快速冷却、纵向延伸装置30的倍率2.5～8纵向延伸、横向延伸装置40的倍率5～15横向延伸、电晕处理装置50的高周波处理提升表面张力后，再以卷取机60收取制得的具三层叠层结构的合成纸10或具五层叠层结构的合成纸15。
但是，双轴延伸聚丙烯合成纸的质量，经过近20年来的发展，仍存着合成纸的印刷表面光雾度不均的缺点，以致于尚未达到可以取代天然纸制品的目标。
发明内容
本发明所要解决的技术问题在于提供一种雾面合成纸，其特征在于，雾面合成纸为厚度25～300微米的多层叠层结构的双轴延伸聚丙烯合成纸，雾面合成纸包括作为最外层纸面层的一印刷表面层，印刷表面层的光泽度值，根据Tappi T480测量为15-50％，且基于印刷表面层的总重量，其包含以下各成分，且各成分的总和100重量％：(1)聚丙烯0～66重量％；(2)聚乙烯0～30重量％；(3)二氧化钛母粒(30～60％)10～15重量％；(4)碳酸钙母粒(40～70％)10～15重量％；(5)抗氧化剂1～5重量％；(6)雾面粉母粒(10～70％)4～75重量％；(7)热塑性弹性体0～25重量％。
本发明的雾面合成纸，借由配方所能达成的效果，可使本发明的雾面合成纸的印刷表面层形成微粗糙表面，表面雾度高光泽度低，甚至达到印刷表面无凹孔的要求。本发明的雾面合成纸，其打印性极佳，可以直接作为印刷用途外，也可作为涂布型产品的涂布素材使用。
所述雾面粉可以直接添加或以制成母粒(masterbatch，M.B)的形态添加到所述印刷表面层的配方组成中。本发明的雾面合成纸的印刷表面层，以母粒(M.B)的形态添加，可获得较佳的表面雾度高光泽度低的效果。
所述雾面粉可以选自有机型雾面粉或无机型雾面粉。所述有机型雾面粉的主要成分是蜡，可以选自合成蜡或硬脂酸的金属皂等。本发明的雾面合成纸，以添加无机型雾面粉，更能提升其印刷表面层(或其最外层纸面层)的纸面雾度。
所述无机型雾面粉制成母粒(M.B)形态时，包括主要成分二氧化硅(即白炭黑消光剂)、滑石粉及硫酸钡等其它成分；其中，所述二氧化硅可以选用表面经过改质的二氧化硅取代。
所述无机型雾面粉的二氧化硅的粒径，介于4～12μm；所述无机型雾面粉的滑石粉的粒径，介于2～8μm；所述无机型雾面粉的硫酸钡的粒径，介于0.6～2μm。
本发明的雾面合成纸，于其印刷表面层(或最外层纸面层)的配方中添加雾面粉后，雾面粉会促成本发明的雾面合成纸的印刷表面层(或最外层纸面层)的表面(或印刷表面)形成微粗糙表面。当入射光达到微粗糙表面时，光的反射方向会发生改变，藉此产生低光泽表面，达到雾面消光的目的。
所述热塑性弹性体具备低熔点的特性。配方中添加雾面粉及热塑性弹性体后，本发明的雾面合成纸，在制作呈热融态的多层迭层制品的工艺中，借助所述热塑性弹性体的低熔点特性，可以填平其印刷表面层(或最外层纸面层)在制作过程中产生的凹孔缺陷，从而使得本发明的雾面合成纸的印刷表面层形成表面雾度高光泽度低，且达到印刷表面无凹孔及雾度均匀的要求。
更进一步地，印刷表面层的组成，基于印刷表面层的总重量，包含以下各成分，且各成分的总和100重量％：(1)聚丙烯2～65重量％；(2)聚乙烯1～15重量％；(3)二氧化钛母粒(30～60％)10～15重量％；(4)碳酸钙母粒(40～70％)10～15重量％；(5)抗氧化剂1～5重量％；(6)雾面粉母粒(10～70％)8～55重量％；(7)热塑性弹性体5～20重量％。
更进一步地，雾面合成纸为具三层以上的叠层结构的合成纸。
更进一步地，雾面合成纸为具五层以上的叠层结构的合成纸。
更进一步地，雾面粉母粒(10～70％)的主要成分为二氧化硅，其它成分包含滑石粉及硫酸钡。
更进一步地，热塑性弹性体选自熔点在60℃以下的热塑性弹性体。
更进一步地，热塑性弹性体选自苯乙烯嵌段共聚物(TPE-S)、热塑性聚烯烃弹性体(TPO)和热塑性硫化橡胶(TPV)中的一种以上。
所述苯乙烯嵌段共聚物(TPE-S)可选自苯乙烯-丁二烯-苯乙烯弹性体(Styrene-Butadiene-Styrene；SBS)或苯乙烯-乙烯/丁烯-苯乙烯弹性体(Styrene-Ethylene-butylene-Styrene；SEBS)。
所述热塑性聚烯烃弹性体(TPO)可选自商业中的美国埃克森美孚化学公司(ExxonMobil Chemical)生产的商品名Vistamaxxt系列的丙烯基弹性体或商品名Exact系列的乙烯α-烯烃共聚物(Ethylene Alpha Olefin Copolymers)；或选自商业中的美国陶氏化学(Dow Chemical Company)生产的商品名INFUSE系列的烯烃嵌段共聚物(Olefin BlockCopolymers)或商品名AFFRINITY系列或ENGAGE系列的聚烯烃弹性体(PolyolefinElastomers)；或选自商业中的日本三井化学(Mitsui Chemicals,Inc.)生产的商品名TAFMER系列的聚烯烃弹性体(Polyolefin Elastomers)。
所述热塑性硫化橡胶(TPV)可选自商业中的美国埃克森美孚化学公司(ExxonMobil Chemical)生产的商品名Vistalon系列的PM/EPDM橡胶。
更进一步地，苯乙烯嵌段共聚物(TPE-S)选自苯乙烯-丁二烯-苯乙烯弹性体(SBS)或苯乙烯-乙烯/丁烯-苯乙烯弹性体(SEBS)。
更进一步地，热塑性聚烯烃弹性体(TPO)选自乙烯α-烯烃共聚物或聚烯烃弹性体。
更进一步地，热塑性硫化橡胶(TPV)为三元乙丙橡胶(EPDM)橡胶。
为使能更进一步了解本发明的特征及技术内容，请参阅以下有关本发明的详细说明与附图，然而所提供的附图仅用于提供参考与说明，并非用来对本发明加以限制。
附图说明
图1为具三层叠层结构的合成纸示意图。
图2为三层叠层结构的合成纸的制造流程图。
图3为五层叠层结构的合成纸示意图。
图4为具五层叠层结构的合成纸的制造流程图。
具体实施方式
以下是通过特定的具体实例。本发明的雾面合成纸，为厚度25～300μm的多层叠层结构的合成纸，可制成具三层或五层以上的叠层结构。举本发明的雾面合成纸为具三层或五层叠层结构的雾面合成纸为例，其叠层结构，与现有技术中如图1及图3所示的具三层或五层合成纸10或15的叠层结构相同，其制作工艺及制作流程也相同，且都以合成纸的最外层纸面层为印刷表面层。
本发明的雾面合成纸，其印刷表面层(或其最外层纸面层)的配方中，有添加雾面粉或同时添加雾面粉和热塑性弹性体，其印刷表面层(或其最外层纸面层)的光泽度值，根据Tappi T480测量为15-50％，优选为18-46％。
本发明的雾面合成纸，借此配方所能达成的效果，可使本发明的雾面合成纸的印刷表面层形成微粗糙表面，表面雾度高光泽度低，甚至达到印刷表面无凹孔的要求。本发明的雾面合成纸，其打印性极佳，可以直接作为印刷用途外，也可作为涂布型产品的涂布素材使用。
本发明的雾面合成纸，其印刷表面层(或其最外层纸面层)的配方组成，基于印刷表面层(或最外层纸面层)的总重量，包含以下各成分，且各成分的总和100重量％：
(1)聚丙烯0～66重量％；优选为2～65重量％；
(2)聚乙烯0～30重量％；优选为1～15重量％；
(3)二氧化钛母粒(masterbatch，M.B)(30～60％)10～15重量％；
(4)碳酸钙M.B(40～70％)10～15重量％；
(5)抗氧化剂1～5重量％；优选为1～2重量％；为商业上一般使用的抗氧化剂；
(6)雾面粉M.B(10～70％)4～75重量％；优选为8～55重量％；
(7)热塑性弹性体0～25重量％；优选为5～20重量％。
所述雾面粉可以直接添加或以制成母粒(masterbatch，M.B)的形态添加到所述印刷表面层的配方组成中。本发明的雾面合成纸的印刷表面层，以母粒(M.B)的形态添加，可获得较佳的表面雾度高光泽度低的效果。
所述雾面粉可以选自有机型雾面粉或无机型雾面粉。所述有机型雾面粉的主要成分是蜡，可以选自合成蜡或硬脂酸的金属皂等。本发明的雾面合成纸，以添加无机型雾面粉，更能提升其印刷表面层(或其最外层纸面层)的纸面雾度。
所述无机型雾面粉制成母粒(M.B)形态时，包括主要成分二氧化硅(即白炭黑消光剂)、滑石粉及硫酸钡等其它成分；其中，所述二氧化硅可以选用表面经过改质的二氧化硅取代。
所述无机型雾面粉的二氧化硅的粒径，介于4～12μm；所述无机型雾面粉的滑石粉的粒径，介于2～8μm；所述无机型雾面粉的硫酸钡的粒径，介于0.6～2μm。
本发明的雾面合成纸，于其印刷表面层(或最外层纸面层)的配方中添加雾面粉后，雾面粉会促成本发明的雾面合成纸的印刷表面层(或最外层纸面层)的表面(或印刷表面)形成微粗糙表面。当入射光达到微粗糙表面时，光的反射方向会发生改变，借此产生低光泽表面，达到雾面消光的目的。
所述热塑性弹性体具备低熔点的特性。配方中添加雾面粉及热塑性弹性体后，本发明的雾面合成纸，在制作呈热融态的多层叠层制品的工艺中，借助所述热塑性弹性体的低熔点特性，可以填平其印刷表面层(或最外层纸面层)在制作过程中产生的凹孔缺陷，从而使得本发明的雾面合成纸的印刷表面层形成表面雾度高光泽度低，且达到印刷表面无凹孔及雾度均匀的要求。
所述热塑性弹性体(Thermoplastic Elastomer，TPE)优选为含有丙烯且熔点在60℃以下的热塑性弹性体，可以选自苯乙烯嵌段共聚物(Styrenic block copolymers，TPE-S)、热塑性聚烯烃弹性体(Thermoplastic Olefin Elastomer，TPO)或热塑性硫化橡胶(Thermoplastic Vulcanizates，TPV)中的一种以上。
所述苯乙烯嵌段共聚物(TPE-S)可选自苯乙烯-丁二烯-苯乙烯弹性体(Styrene-Butadiene-Styrene，SBS)或苯乙烯-乙烯/丁烯-苯乙烯弹性体(Styrene-Ethylene-butylene-Styrene，SEBS)。
所述热塑性聚烯烃弹性体(TPO)可选自商业中的美国埃克森美孚化学公司(ExxonMobil Chemical)生产的商品名Vistamaxxt系列的丙烯基弹性体或商品名Exact系列的乙烯α-烯烃共聚物(Ethylene Alpha Olefin Copolymers)；或选自商业中的美国陶氏化学(Dow Chemical Company)生产的商品名INFUSE系列的烯烃嵌段共聚物(Olefin BlockCopolymers)或商品名AFFRINITY系列或ENGAGE系列的聚烯烃弹性体(PolyolefinElastomers)；或选自商业中的日本三井化学(Mitsui Chemicals,Inc.)生产的商品名TAFMER系列的聚烯烃弹性体(Polyolefin Elastomers)。
所述热塑性硫化橡胶(TPV)可选自商业中的美国埃克森美孚化学公司(ExxonMobil Chemical)生产的商品名Vistalon系列的PM/EPDM橡胶。
以下列举实施例具体说明本发明的内容及可达成的功效，但本发明并不仅局限于此等实施例。实施例及比较例的各项物性评估，系实行下列方法加以进行：
1.光泽度(％)：
使用TappiT480标准在75°处测定。
2.粗糙度(μm)：
依据TAPPI T-555pm-94测试标准。
3.分散性：
采用人体视觉目视合成纸的印刷表面层(或最外层纸面层)是否出现凝集物。印刷表面层出现凝集物，代表其组成的分散性不佳，反之，则代表分散性佳。
4.膜面发泡性：
采用人体视觉目视合成纸的印刷表面层(或最外层纸面层)是否有发泡缺陷。
印刷表面层出现发泡，代表印刷表面层的膜面发泡性不佳，反之，则代表膜面发泡性佳。
5.贴轮性：
经过共押后呈热融态的叠层制品，当经过冷却成型装置进行快速冷却时，以目视观察是否会黏贴第一个冷却轮的轮面。
出现黏贴轮面时，代表印刷表面层的贴轮性不佳，反之，则代表贴轮性佳。
6.膜面凹孔：
采用人体视觉目视合成纸的印刷表面层(或最外层纸面层)是否有凹孔缺陷。
【实施例1】
参照表1的原料配方，调配合成纸的印刷表面层的原料，包括雾面粉M.B 8重量％、聚丙烯57重量％、二氧化钛M.B 15重量％、碳酸钙M.B 15重量％及抗氧化剂M.B 5重量％。
参照图2所示的制作工艺，经过三台押出机熔融共押制程后，经由冷却成型装置的快速冷却，在温度15～70℃下成型成三层叠层板片；此板片再经纵向延伸装置在温度155～150℃下进行4倍纵向延伸后，续经横向延伸装置在温度140～200℃下进行8倍横向延伸，之后，经过60kw功率高周波电晕处理提高表面张力，即制得80μm三层共挤压双向延伸合成纸成品。
所制得的合成纸的印刷表面层的物性，测试结果如表1所示。
【实施例2】
参照表1的原料配方，调配合成纸的印刷表面层的原料，包括雾面粉M.B 16重量％、聚丙烯49重量％、二氧化钛M.B 15重量％、碳酸钙M.B 15重量％及抗氧化剂M.B 5重量％。
同实施例1的制法加工，制得80μm三层共挤压双向延伸合成纸成品。
所制得的合成纸的印刷表面层的物性，测试结果如表1所示。
【实施例3】
参照表1的原料配方，调配合成纸的印刷表面层的原料，包括雾面粉M.B 4重量％、聚丙烯61重量％、二氧化钛M.B 15重量％、碳酸钙M.B 15重量％及抗氧化剂M.B 5重量％。
同实施例1的制法加工，制得80μm三层共挤压双向延伸合成纸成品。
所制得的合成纸的印刷表面层的物性，测试结果如表1所示。
【实施例4】
参照表1的原料配方，调配合成纸的印刷表面层的原料，包括雾面粉M.B 15重量％、聚丙烯50重量％、二氧化钛M.B 15重量％、碳酸钙M.B 15重量％及抗氧化剂M.B 5重量％。
同实施例1的制法加工，制得80μm三层共挤压双向延伸合成纸成品。
所制得的合成纸的印刷表面层的物性，测试结果如表1所示。
【实施例5】
参照表1的原料配方，调配合成纸的印刷表面层的原料，包括雾面粉M.B 40重量％、聚丙烯25重量％、二氧化钛M.B 15重量％、碳酸钙M.B 15重量％及抗氧化剂M.B 5重量％。
同实施例1的制法加工，制得厚度80μm三层共挤压双向延伸珠光合成纸成品。
所制得的合成纸的印刷表面层的物性，测试结果如表1所示。
【实施例6】
参照表1的原料配方，调配合成纸的印刷表面层的原料，包括雾面粉M.B 55重量％、聚丙烯10重量％、二氧化钛M.B 15重量％、碳酸钙M.B 15重量％及抗氧化剂M.B 5重量％。
同实施例1的制法加工，制得厚度80μm三层共挤压双向延伸珠光合成纸成品。
所制得的合成纸的印刷表面层的物性，测试结果如表1所示。
【实施例7】
参照表1的原料配方，调配合成纸的印刷表面层的原料，包括雾面粉M.B 55重量％、热塑性弹性体6重量％、聚丙烯4重量％、二氧化钛M.B 15重量％、碳酸钙M.B 15重量％及抗氧化剂M.B 5重量％。
同实施例1的制法加工，制得厚度80μm三层共挤压双向延伸珠光合成纸成品。
所制得的合成纸的印刷表面层的物性，测试结果如表1所示。从表1的结果，显示其贴轮性令人满意，且印刷表面层的(印刷)表面光泽度低雾度高，但仍有些许凹孔出现。
【实施例8】
参照表1的原料配方，调配合成纸的印刷表面层的原料，包括雾面粉M.B 55重量％、热塑性弹性体10重量％、二氧化钛M.B 15重量％、碳酸钙M.B 15重量％及抗氧化剂M.B 5重量％。
同实施例1的制法加工，制得厚度80μm三层共挤压双向延伸珠光合成纸成品。
所制得的合成纸的印刷表面层的物性，测试结果如表1所示。从表1的结果，显示其贴轮性令人满意，且印刷表面层的(印刷)表面不但光泽度低雾度高，且没有凹孔出现。
【比较例1】
参照表1的原料配方，调配合成纸的印刷表面层的原料，但不使用雾面粉及热塑性弹性体，包括聚丙烯65重量％、二氧化钛M.B 15重量％、碳酸钙M.B 15重量％及抗氧化剂M.B 5重量％。
同实施例1的制法加工，制得厚度80μm三层共挤压双向延伸珠光合成纸成品。
所制得的合成纸的印刷表面层的物性，测试结果如表1所示。从表1的结果，显示其贴轮性不佳，且印刷表面层的(印刷)表面不但光泽度偏高雾度低，且有许多凹孔出现。
【比较例2】
参照表1的原料配方，调配合成纸的印刷表面层的原料，但不使用雾面粉及热塑性弹性体，包括聚丙烯45重量％、聚乙烯20重量％、二氧化钛M.B 15重量％、碳酸钙M.B 15重量％及抗氧化剂M.B 5重量％。
同实施例1的制法加工，制得厚度80μm三层共挤压双向延伸珠光合成纸成品。
所制得的合成纸的印刷表面层的物性，测试结果如表1所示。从表1的结果，显示其物性较差，除了贴轮性不佳外，且印刷表面层的(印刷)表面不但光泽度偏高雾度低，且有许多凹孔出现。
【结果】
1.实施例1-6的印刷表面层的原料中，有添加及使用雾面粉，所制得的合成纸的印刷表面层，具备光泽度低雾度高的特性，打印性极佳，适合作为印刷的用途。
2.实施例7-8的印刷表面层的原料中，有添加及使用雾面粉及热塑性弹性体，所制得的合成纸的印刷表面层，其表面无凹孔缺陷且雾度均匀外，还具备光泽度低雾度高的特性，打印性极佳，适合作为印刷的用途。
3.比较例1及2的印刷表面层的原料中，未添加雾面粉或热塑性弹性体，所制得的合成纸的印刷表面层，不但表面出现许多凹孔缺陷，且其光泽度高雾度低，不合适作为印刷用纸。
表1：合成纸的印刷表面层的配方及物性。
Figure BDA0002050191630000101
以上所公开的内容仅为本发明的优选可行实施例，并非因此局限本发明的权利要求书的保护范围，所以凡是运用本发明说明书及附图内容所做的等效技术变化，均包含于本发明的权利要求书的保护范围内。

Claims (10)

1.一种雾面合成纸，其特征在于，所述雾面合成纸为厚度25～300微米的多层叠层结构的双轴延伸聚丙烯合成纸，所述雾面合成纸包括作为最外层纸面层的一印刷表面层，所述印刷表面层的光泽度值，根据Tappi T480测量为15-50％，且基于所述印刷表面层的总重量，其包含以下各成分，且各成分的总和100重量％：
(1)聚丙烯0～66重量％；
(2)聚乙烯0～30重量％；
(3)二氧化钛母粒(30～60％)10～15重量％；
(4)碳酸钙母粒(40～70％)10～15重量％；
(5)抗氧化剂1～5重量％；
(6)雾面粉母粒(10～70％)4～75重量％；以及
(7)热塑性弹性体0～25重量％。
2.根据权利要求1所述的雾面合成纸，其特征在于，所述印刷表面层的组成，基于所述印刷表面层的总重量，包含以下各成分，且各成分的总和100重量％：
(1)聚丙烯2～65重量％；
(2)聚乙烯1～15重量％；
(3)二氧化钛母粒(30～60％)10～15重量％；
(4)碳酸钙母粒(40～70％)10～15重量％；
(5)抗氧化剂1～5重量％；
(6)雾面粉母粒(10～70％)8～55重量％；以及
(7)热塑性弹性体5～20重量％。
3.根据权利要求1或2所述的雾面合成纸，其特征在于，所述雾面合成纸为具三层以上的叠层结构的合成纸。
4.根据权利要求1或2所述的雾面合成纸，其特征在于，所述雾面合成纸为具五层以上的叠层结构的合成纸。
5.根据权利要求1或2所述的雾面合成纸，其特征在于，所述雾面粉母粒(10～70％)的主要成分为二氧化硅，其它成分包含滑石粉及硫酸钡。
6.根据权利要求1或2所述的雾面合成纸，其特征在于，所述热塑性弹性体选自熔点在60℃以下的热塑性弹性体。
7.根据权利要求6所述的雾面合成纸，其特征在于，所述热塑性弹性体选自苯乙烯嵌段共聚物、热塑性聚烯烃弹性体和热塑性硫化橡胶中的一种以上。
8.根据权利要求7所述的雾面合成纸，其特征在于，所述苯乙烯嵌段共聚物选自苯乙烯-丁二烯-苯乙烯弹性体或苯乙烯-乙烯/丁烯-苯乙烯弹性体。
9.根据权利要求7所述的雾面合成纸，其特征在于，所述热塑性聚烯烃弹性体选自乙烯α-烯烃共聚物或聚烯烃弹性体。
10.根据权利要求7所述的雾面合成纸，其特征在于，所述热塑性硫化橡胶为三元乙丙橡胶。
CN201910371664.1A 2018-10-19 2019-05-06 一种雾面合成纸 Active CN111070933B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TW107136853 2018-10-19
TW107136853A TWI677435B (zh) 2018-10-19 2018-10-19 一種霧面合成紙

Publications (2)

Publication Number Publication Date
CN111070933A true CN111070933A (zh) 2020-04-28
CN111070933B CN111070933B (zh) 2022-04-19

Family

ID=69188871

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910371664.1A Active CN111070933B (zh) 2018-10-19 2019-05-06 一种雾面合成纸

Country Status (4)

Country Link
US (1) US10774206B2 (zh)
JP (1) JP6995816B2 (zh)
CN (1) CN111070933B (zh)
TW (1) TWI677435B (zh)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI804905B (zh) * 2021-06-30 2023-06-11 南亞塑膠工業股份有限公司 抗菌防黴聚酯疊層結構

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030035944A1 (en) * 2001-07-25 2003-02-20 Blackwell Christopher J. Synthetic paper skins, paper and labels containing the same and methods of making the same
CN1488498A (zh) * 2003-09-01 2004-04-14 南亚塑胶工业股份有限公司 五层共挤压双轴延伸聚丙烯珠光合成纸及其制造方法
JP2005125708A (ja) * 2003-10-27 2005-05-19 Nan Ya Plast Corp 五層共押出二軸延伸ポリプロピレンパール光沢合成紙及びその製造法
CN101073960A (zh) * 2006-05-18 2007-11-21 汕头市新协包装材料厂 一种丝光喷墨打印纸及其制作方法
US20080206505A1 (en) * 2006-06-20 2008-08-28 Blackwell Christopher J Multilayered Polymeric Film for Hot Melt Adhesive Labeling and Label Stock and Label Thereof
CN101633261A (zh) * 2008-07-21 2010-01-27 泉州利昌塑胶有限公司 双向拉伸聚乙烯合成纸
CN102378841A (zh) * 2009-04-01 2012-03-14 阿约威津斯优质纸有限公司 高级哑光印刷纸及其制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2755265B2 (ja) * 1989-07-28 1998-05-20 日本製紙株式会社 積層シート及びその製造方法
JP3874537B2 (ja) * 1998-06-04 2007-01-31 株式会社ユポ・コーポレーション 多層樹脂延伸フィルム
KR20010043687A (ko) * 1998-05-20 2001-05-25 다나베 마사히코 열가소성 수지 연신필름
JP2002096435A (ja) * 2000-09-21 2002-04-02 Bando Chem Ind Ltd 木口用化粧シート

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030035944A1 (en) * 2001-07-25 2003-02-20 Blackwell Christopher J. Synthetic paper skins, paper and labels containing the same and methods of making the same
CN1488498A (zh) * 2003-09-01 2004-04-14 南亚塑胶工业股份有限公司 五层共挤压双轴延伸聚丙烯珠光合成纸及其制造方法
JP2005125708A (ja) * 2003-10-27 2005-05-19 Nan Ya Plast Corp 五層共押出二軸延伸ポリプロピレンパール光沢合成紙及びその製造法
CN101073960A (zh) * 2006-05-18 2007-11-21 汕头市新协包装材料厂 一种丝光喷墨打印纸及其制作方法
US20080206505A1 (en) * 2006-06-20 2008-08-28 Blackwell Christopher J Multilayered Polymeric Film for Hot Melt Adhesive Labeling and Label Stock and Label Thereof
CN101633261A (zh) * 2008-07-21 2010-01-27 泉州利昌塑胶有限公司 双向拉伸聚乙烯合成纸
CN102378841A (zh) * 2009-04-01 2012-03-14 阿约威津斯优质纸有限公司 高级哑光印刷纸及其制备方法

Also Published As

Publication number Publication date
JP2020066238A (ja) 2020-04-30
US10774206B2 (en) 2020-09-15
JP6995816B2 (ja) 2022-01-17
US20200123363A1 (en) 2020-04-23
TW202015918A (zh) 2020-05-01
CN111070933B (zh) 2022-04-19
TWI677435B (zh) 2019-11-21

Similar Documents

Publication Publication Date Title
AU771216B2 (en) Breathable multilayer films with breakable skin layers
CN104476889B (zh) 一种pe薄膜及其制备方法
JP2023017015A (ja) 二軸配向ポリプロピレンフィルム
DE69903644T2 (de) Etiketten mit weicher berührungseigenschaft
WO2017170244A1 (ja) 二軸配向ポリプロピレンフィルム
JP7548346B2 (ja) 二軸配向ポリプロピレン系フィルムの製造方法
JP7205462B2 (ja) 二軸配向ポリプロピレンフィルム
CN108463347A (zh) 具有良好密封性能的双取向的空化线性低密度膜
EP0616885A1 (de) Matte, biaxial gereckte Polypropylenfolie Verfahren zu ihrer Herstellung
EP0703071B1 (en) Composite plastics film or sheet
JPH0664120A (ja) 艶消し効果を有する二軸延伸ポリプロピレンフイルムおよびその製造方法
US9669607B2 (en) Biaxially oriented polypropylene film with low moisture vapor transmission rate
CN107082931A (zh) 一种cpp薄膜用消光母料及其制备方法
EP3197677B2 (en) Polyolefin-based elastic film structures, laminates and methods thereof
CN111070933B (zh) 一种雾面合成纸
KR102034326B1 (ko) 개선된 기계적 특성 및 밀봉 특성을 갖는 폴리프로필렌-기재 필름 및 그의 제조 방법
CN113799462B (zh) 一种微发泡聚乙烯仿纸薄膜及其制备方法
TWM583375U (zh) 防霧貼合膜
JP2020151907A (ja) 二軸延伸多層フィルム
US11708483B2 (en) Heat sealable films
CN109591310B (zh) 一种超薄超镜面的聚丙烯镀铝基材薄膜制备方法
CN114311898A (zh) 一种冷裱复合膜用聚丙烯薄膜及其制备方法和冷裱复合膜
JP5132518B2 (ja) 熱成形用防汚性シート、防汚性成形体およびその製造方法
KR0174164B1 (ko) 내열성및가공성이우수한압출라미네이션용수지조성물
JPS5989340A (ja) 高密度ポリエチレンシ−ト

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant