CN110923629A - 汽车标牌镀氮化钛工艺 - Google Patents

汽车标牌镀氮化钛工艺 Download PDF

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CN110923629A
CN110923629A CN201911241009.0A CN201911241009A CN110923629A CN 110923629 A CN110923629 A CN 110923629A CN 201911241009 A CN201911241009 A CN 201911241009A CN 110923629 A CN110923629 A CN 110923629A
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titanium nitride
plastic substrate
carrying
plating
washed
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韩锡
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NINGBO XINXING AUTO PARTS Co Ltd
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NINGBO XINXING AUTO PARTS Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/221—Ion beam deposition
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/0021—Reactive sputtering or evaporation
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/02—Pretreatment of the material to be coated
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0641—Nitrides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/58—After-treatment
    • C23C14/5806—Thermal treatment

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

本发明公开了一种汽车标牌镀氮化钛工艺，包括以下步骤：(1)对塑料基板进行表面处理；(2)对塑料基板表面进行电镀高光或哑光处理；(3)对塑料基板表面进行超声波清洗，清洗完后进行烘干处理；(4)将塑料基板放入真空镀膜机，对塑料基板表面进行高能钛离子轰击，工作偏压为1000‑1100伏；(5)将工作偏压调低至300‑350V，使钛离子轰击变成沉积过程，并通入氮气，使塑料基板表面沉积一层氮化钛。该工艺较为环保，可以在塑料基板上镀上一层氮化钛薄膜，氮化钛呈金黄色，且氮化钛薄膜硬度高，使得产品更加耐刮。

Description

汽车标牌镀氮化钛工艺
技术领域
本发明涉及汽车标牌金色非仿金镀膜技术领域，具体讲是一种汽车标牌镀氮化钛工艺。
背景技术
目前，金色汽车标牌以金属制品镀钛，或用塑料镀真金和仿金来达到金色标牌的目的，存在着成本高、金属标牌质量重的缺点，而且镀仿金用到氰化物，对环境影响极大，用无氰电镀则达不到仿金效果。
发明内容
鉴于上述现有技术的缺陷，本发明的目的在于：提供一种汽车标牌镀氮化钛工艺。
为解决上述问题，本发明的技术解决方案是：汽车标牌镀氮化钛工艺，包括以下步骤：
(1)对塑料基板进行表面处理；
(2)对塑料基板表面进行电镀高光或哑光处理；
(3)对塑料基板表面进行超声波清洗，清洗完后进行烘干处理；
(4)将塑料基板放入真空镀膜机，对塑料基板表面进行高能钛离子轰击，工作偏压为1000-1100伏；
(5)将工作偏压调低至300-350V，使钛离子轰击变成沉积过程，并通入氮气，使塑料基板表面沉积一层氮化钛。
进一步地，它还包括步骤(6)将镀好氮化钛基板进行老化处理。
进一步地，老化处理是指：将镀好氮化钛基板在空气中进行烘烤处理。
进一步地，步骤(1)中，先将塑料基板除油，除油后进行水洗，水洗后放入前处理液中同时进行粗化、敏化、活化，然后水洗后烘干。
进一步地，所述前处理液由铬酸、硫酸、湿润剂、硫酸化氧化铝、乙酸、氯化钯、乳化剂和水组成。
本发明的有益效果是：该工艺较为环保，可以在塑料基板上镀上一层氮化钛薄膜，氮化钛呈金黄色，且氮化钛薄膜硬度高，使得产品更加耐刮。
具体实施方式
为比较直观、完整地理解本发明的技术方案，现进行非限制性的特征说明如下：
实施例一：汽车标牌镀氮化钛工艺，包括以下步骤：
(1)对塑料基板进行表面处理；
(2)对塑料基板表面进行电镀高光或哑光处理；
(3)对塑料基板表面进行超声波清洗，清洗完后进行烘干处理；
(4)将塑料基板放入真空镀膜机，对塑料基板表面进行高能钛离子轰击，工作偏压为1000伏；
(5)将工作偏压调低至300V，使钛离子轰击变成沉积过程，并通入氮气，使塑料基板表面沉积一层氮化钛；
(6)将镀好氮化钛基板进行老化处理。
老化处理是指：将镀好氮化钛基板在空气中进行烘烤处理。氮化钛制成后，因为沉积过程中薄膜材料分子从气相到固相的冷却非常迅速，其性质会逐渐发生变化，存在着各种缺陷，采用烘烤退火处理后，使薄膜具有再结晶过程和再反应过程，烘烤后薄膜牢固度和抗潮能力大大提高。
步骤(1)中，先将塑料基板除油，除油后进行水洗，水洗后放入前处理液中同时进行粗化、敏化、活化，然后水洗后烘干。
前处理液由以下质量比的原料组成：铬酸12％、硫酸12％、湿润剂1％、硫酸化氧化铝15％、乙酸7.9％、氯化钯0.1％、乳化剂2％、水50％。制备时称取适量的原料，将原料混合后在温度为30摄氏度的环境下均匀搅拌40分钟。
铬酸12％、硫酸12％、湿润剂1％组成粗化剂，起到粗化塑料表面的作用，硫酸化氧化铝用于溶解氯化钯，氯化钯被吸附或渗透到塑料基板表面，乙酸不但可消除塑料的残余应力，提高镀层的结合力，还可防止粗化剂的水解，乳化剂可以降低塑料表面张力，提高塑料表面的亲水性。

Claims (5)

1.汽车标牌镀氮化钛工艺，其特征在于包括以下步骤：
(1)对塑料基板进行表面处理；
(2)对塑料基板表面进行电镀高光或哑光处理；
(3)对塑料基板表面进行超声波清洗，清洗完后进行烘干处理；
(4)将塑料基板放入真空镀膜机，对塑料基板表面进行高能钛离子轰击，工作偏压为1000-1100伏；
(5)将工作偏压调低至300-350V，使钛离子轰击变成沉积过程，并通入氮气，使塑料基板表面沉积一层氮化钛。
2.根据权利要求1所述的汽车标牌镀氮化钛工艺，其特征在于：它还包括步骤(6)将镀好氮化钛基板进行老化处理。
3.根据权利要求2所述的汽车标牌镀氮化钛工艺，其特征在于：老化处理是指：将镀好氮化钛基板在空气中进行烘烤处理。
4.根据权利要求1所述的汽车标牌镀氮化钛工艺，其特征在于：步骤(1)中，先将塑料基板除油，除油后进行水洗，水洗后放入前处理液中同时进行粗化、敏化、活化，然后水洗后烘干。
5.根据权利要求4所述的汽车标牌镀氮化钛工艺，其特征在于：所述前处理液由铬酸、硫酸、湿润剂、硫酸化氧化铝、乙酸、氯化钯、乳化剂和水组成。
CN201911241009.0A 2019-12-06 2019-12-06 汽车标牌镀氮化钛工艺 Pending CN110923629A (zh)

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1109921A (zh) * 1995-03-22 1995-10-11 樊联哲 金刚石单晶镀超硬薄膜技术
JP2004308340A (ja) * 2003-04-10 2004-11-04 Horikawa Inc プラスチック製の取っ手とその製造方法
WO2005102734A2 (en) * 2004-04-22 2005-11-03 Hph Limited Method of manufacturing a sign displaying sign indicia
CN101629279A (zh) * 2009-08-13 2010-01-20 杭州博纳特光电科技有限公司 一种在塑料材料表面磁控溅射制备化合物薄膜的方法
CN102383158A (zh) * 2010-08-31 2012-03-21 尹卫欣 一种塑料表面电镀铜的方法
CN102409320A (zh) * 2011-11-29 2012-04-11 沈阳工业大学 一种abs塑料表面电镀前处理的方法
CN104513960A (zh) * 2013-09-29 2015-04-15 无锡慧明电子科技有限公司 一种磁控溅射制备彩色氮化钛膜的方法
CN105112970A (zh) * 2015-09-22 2015-12-02 太仓市金鹿电镀有限公司 一种汽车标牌塑料电镀工艺
CN107444289A (zh) * 2016-06-01 2017-12-08 丰田合成株式会社 车辆用装饰件

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1109921A (zh) * 1995-03-22 1995-10-11 樊联哲 金刚石单晶镀超硬薄膜技术
JP2004308340A (ja) * 2003-04-10 2004-11-04 Horikawa Inc プラスチック製の取っ手とその製造方法
WO2005102734A2 (en) * 2004-04-22 2005-11-03 Hph Limited Method of manufacturing a sign displaying sign indicia
CN101629279A (zh) * 2009-08-13 2010-01-20 杭州博纳特光电科技有限公司 一种在塑料材料表面磁控溅射制备化合物薄膜的方法
CN102383158A (zh) * 2010-08-31 2012-03-21 尹卫欣 一种塑料表面电镀铜的方法
CN102409320A (zh) * 2011-11-29 2012-04-11 沈阳工业大学 一种abs塑料表面电镀前处理的方法
CN104513960A (zh) * 2013-09-29 2015-04-15 无锡慧明电子科技有限公司 一种磁控溅射制备彩色氮化钛膜的方法
CN105112970A (zh) * 2015-09-22 2015-12-02 太仓市金鹿电镀有限公司 一种汽车标牌塑料电镀工艺
CN107444289A (zh) * 2016-06-01 2017-12-08 丰田合成株式会社 车辆用装饰件

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
丁耀华等: "17-4PH钢表面Ti/TiN多层复合薄膜的研究", 《上海电气技术》 *
严一心等: "《薄膜技术》", 31 October 1994, 兵器工业出版社 *
刘艳辉等: "塑料基体上真空离子镀TiN膜的微观组织特征", 《PLATING AND FINISHING》 *
商成杰等: "《新型染整助剂手册》", 31 October 2002, 中国纺织出版社 *
梁明昌等: "《注塑成型实用技术》", 31 January 2010, 辽宁科学技术出版社 *
谢保忠等: "《铭牌设计制作与粘接》", 29 February 1984, 四川科学技术出版社 *
钱志屏: "《塑料制品设计与制造》", 31 May 1993, 同济大学出版社 *

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Application publication date: 20200327