CN110923510B - 一种高择优取向NiMnGa磁记忆合金丝的制备方法 - Google Patents
一种高择优取向NiMnGa磁记忆合金丝的制备方法 Download PDFInfo
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- CN110923510B CN110923510B CN201911300081.6A CN201911300081A CN110923510B CN 110923510 B CN110923510 B CN 110923510B CN 201911300081 A CN201911300081 A CN 201911300081A CN 110923510 B CN110923510 B CN 110923510B
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- memory alloy
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- 229910001285 shape-memory alloy Inorganic materials 0.000 title claims abstract description 91
- 230000005291 magnetic effect Effects 0.000 title claims abstract description 90
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 51
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 43
- 239000000956 alloy Substances 0.000 claims abstract description 43
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 230000006698 induction Effects 0.000 claims abstract description 25
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000005242 forging Methods 0.000 claims abstract description 21
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000003723 Smelting Methods 0.000 claims abstract description 16
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000011572 manganese Substances 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 12
- 238000009210 therapy by ultrasound Methods 0.000 claims abstract description 12
- 229910052786 argon Inorganic materials 0.000 claims abstract description 11
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims abstract description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000012153 distilled water Substances 0.000 claims abstract description 6
- 238000001035 drying Methods 0.000 claims abstract description 6
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 6
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 6
- 230000001681 protective effect Effects 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 8
- 229910052802 copper Inorganic materials 0.000 claims description 8
- 239000010949 copper Substances 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 238000005266 casting Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims 1
- 229910000734 martensite Inorganic materials 0.000 description 8
- 238000012360 testing method Methods 0.000 description 7
- 230000009466 transformation Effects 0.000 description 7
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 6
- 238000001228 spectrum Methods 0.000 description 6
- 230000007704 transition Effects 0.000 description 6
- 239000013078 crystal Substances 0.000 description 5
- 230000003446 memory effect Effects 0.000 description 5
- 238000011160 research Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- 238000001878 scanning electron micrograph Methods 0.000 description 4
- 238000013461 design Methods 0.000 description 3
- 238000010183 spectrum analysis Methods 0.000 description 3
- 230000006399 behavior Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910000807 Ga alloy Inorganic materials 0.000 description 1
- 229910003310 Ni-Al Inorganic materials 0.000 description 1
- 229910018102 Ni-Mn-Al Inorganic materials 0.000 description 1
- 229910018548 Ni—Mn—Al Inorganic materials 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 229910001566 austenite Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 1
- 230000005294 ferromagnetic effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000005476 size effect Effects 0.000 description 1
- 239000002520 smart material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21J—FORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
- B21J1/00—Preparing metal stock or similar ancillary operations prior, during or post forging, e.g. heating or cooling
- B21J1/06—Heating or cooling methods or arrangements specially adapted for performing forging or pressing operations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21J—FORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
- B21J5/00—Methods for forging, hammering, or pressing; Special equipment or accessories therefor
- B21J5/02—Die forging; Trimming by making use of special dies ; Punching during forging
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/023—Alloys based on nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C2202/00—Physical properties
- C22C2202/02—Magnetic
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Hard Magnetic Materials (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
Element(元素) | At%(原子百分比) | Wt%(重量百分比) |
Ni | 52.89 | 51 |
Mn | 24.11 | 22.96 |
Ga | 23 | 26.04 |
Element(元素) | At%(原子百分比) | Wt%(重量百分比 |
Ni | 52.63 | 51.25 |
Mn | 24.59 | 22.40 |
Ga | 22.79 | 26.35 |
Claims (3)
Priority Applications (1)
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CN201911300081.6A CN110923510B (zh) | 2019-12-16 | 2019-12-16 | 一种高择优取向NiMnGa磁记忆合金丝的制备方法 |
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CN201911300081.6A CN110923510B (zh) | 2019-12-16 | 2019-12-16 | 一种高择优取向NiMnGa磁记忆合金丝的制备方法 |
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CN110923510A CN110923510A (zh) | 2020-03-27 |
CN110923510B true CN110923510B (zh) | 2021-08-31 |
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Citations (14)
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JPS57149440A (en) * | 1981-03-11 | 1982-09-16 | Res Inst Electric Magnetic Alloys | Magnetic alloy for magnetic sound recording and reproducing head and prepartion thereof |
CN1105710A (zh) * | 1993-07-30 | 1995-07-26 | 财团法人电气材料研究所 | 耐磨的高磁导率合金及其制备方法 |
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CN101152822A (zh) * | 2006-09-28 | 2008-04-02 | 富士施乐株式会社 | 非晶质合金构件及其制造工艺、真伪判定装置和方法 |
CN101988166A (zh) * | 2010-11-18 | 2011-03-23 | 哈尔滨工程大学 | 具有抗菌功能的TiNiAg记忆合金及其制备方法 |
CN105132750A (zh) * | 2015-09-18 | 2015-12-09 | 北京科技大学 | 一种磁致扭转Ni-Mn-Ga合金丝 |
CN105316527A (zh) * | 2015-11-26 | 2016-02-10 | 北京科技大学 | 一种镍锰镓超弹性形状记忆合金丝及其制备方法 |
CN107130142A (zh) * | 2017-06-20 | 2017-09-05 | 大连大学 | 一种高温、高强度Ni‑Mn‑Ga‑Nb记忆合金的制备方法 |
CN107130141A (zh) * | 2017-06-20 | 2017-09-05 | 大连大学 | 一种高塑性、高强度Ni‑Mn‑Ga‑Hf记忆合金的制备方法 |
CN107299418A (zh) * | 2017-06-21 | 2017-10-27 | 北京科技大学 | 一种可用于纺织的Ni‑Mn‑Ga合金纤维及制备方法 |
CN107299252A (zh) * | 2017-06-20 | 2017-10-27 | 大连大学 | 一种高强度、高塑性Ni‑Mn‑Ga‑Nb记忆合金的制备方法 |
CN107345279A (zh) * | 2017-06-20 | 2017-11-14 | 大连大学 | 一种超塑性Ni‑Mn‑Ga‑Ta高温记忆合金的制备方法 |
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Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101705392A (zh) * | 2009-11-17 | 2010-05-12 | 大连大学 | 一种增韧铁磁性形状记忆合金及其制备方法 |
CN108060341B (zh) * | 2017-12-25 | 2019-09-27 | 大连大学 | 一种高韧性Ni50Mn25Ga25记忆合金及其制备方法 |
-
2019
- 2019-12-16 CN CN201911300081.6A patent/CN110923510B/zh active Active
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JPS57149440A (en) * | 1981-03-11 | 1982-09-16 | Res Inst Electric Magnetic Alloys | Magnetic alloy for magnetic sound recording and reproducing head and prepartion thereof |
CN1105710A (zh) * | 1993-07-30 | 1995-07-26 | 财团法人电气材料研究所 | 耐磨的高磁导率合金及其制备方法 |
CN1685067A (zh) * | 2002-05-17 | 2005-10-19 | 梅特格拉斯公司 | 铜-镍-硅二相淬火基层 |
CN101152822A (zh) * | 2006-09-28 | 2008-04-02 | 富士施乐株式会社 | 非晶质合金构件及其制造工艺、真伪判定装置和方法 |
CN101135018A (zh) * | 2007-10-10 | 2008-03-05 | 厦门大学 | 一种镍锰钴镓高温形状记忆合金及其制备方法 |
CN101988166A (zh) * | 2010-11-18 | 2011-03-23 | 哈尔滨工程大学 | 具有抗菌功能的TiNiAg记忆合金及其制备方法 |
CN105132750A (zh) * | 2015-09-18 | 2015-12-09 | 北京科技大学 | 一种磁致扭转Ni-Mn-Ga合金丝 |
CN105316527A (zh) * | 2015-11-26 | 2016-02-10 | 北京科技大学 | 一种镍锰镓超弹性形状记忆合金丝及其制备方法 |
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CN107130141A (zh) * | 2017-06-20 | 2017-09-05 | 大连大学 | 一种高塑性、高强度Ni‑Mn‑Ga‑Hf记忆合金的制备方法 |
CN107299252A (zh) * | 2017-06-20 | 2017-10-27 | 大连大学 | 一种高强度、高塑性Ni‑Mn‑Ga‑Nb记忆合金的制备方法 |
CN107345279A (zh) * | 2017-06-20 | 2017-11-14 | 大连大学 | 一种超塑性Ni‑Mn‑Ga‑Ta高温记忆合金的制备方法 |
CN107299418A (zh) * | 2017-06-21 | 2017-10-27 | 北京科技大学 | 一种可用于纺织的Ni‑Mn‑Ga合金纤维及制备方法 |
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