CN110904729B - 一种用于宣纸的表面施胶液及其制备方法和应用 - Google Patents

一种用于宣纸的表面施胶液及其制备方法和应用 Download PDF

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CN110904729B
CN110904729B CN201911181590.1A CN201911181590A CN110904729B CN 110904729 B CN110904729 B CN 110904729B CN 201911181590 A CN201911181590 A CN 201911181590A CN 110904729 B CN110904729 B CN 110904729B
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颜进华
杨焕磊
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Guangdong Kening Technology Co ltd
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Abstract

本发明公开了一种用于宣纸的表面施胶液及其制备方法和应用。该表面施胶液由以下原料制备而成：亲水性高分子、固色剂、抗水剂、消泡剂、氧化剂、水。本发明通过将亲水性高分子、氧化剂、水混合后于60～90℃水浴环境下搅拌10～60分钟；接着加入固色剂，混合均匀；再加入抗水剂；将得到的体系的温度调节至45～65℃，反应30～90min，自然冷却至室温后取出，加入消泡剂，得到宣纸表面施胶液。利用本发明提供的表面施胶液制备得到的宣纸，固色效果高，墨水色密度值高。

Description

一种用于宣纸的表面施胶液及其制备方法和应用
技术领域
本发明属于造纸化学品制备工艺领域，特别涉及一种用于宣纸的表面施胶液及其制备方法和应用。
背景技术
宣纸是文房四宝中的至宝，因其质地柔韧，纹理美观，并善于表现笔墨的浓淡润湿、变化无穷，用途广泛。第一，是用于印刷珍贵书籍、图册、拓碑帖、裱字画的最佳纸张。宣纸印刷品、裱托品光泽夺目，黑白分明，线条清晰，久藏不变色，不虫蛀。第二，是中国书画的理想用纸，能吸水，能吸墨，宜书宜画。根据加工不同分为生宣和熟宣，生宣就是不经过任何处理，保留了渗墨性和吸湿性。熟宣是经涂胶加工，防渗防洇。用于印刷图册及仿真艺术品的数码宣纸是一种熟宣，简单的涂胶并不能达到艺术品的逼真度，必须开发新的表面施胶液，专用于宣纸加工，保留生宣纸的纹理层次和外观，同时具有生宣不能实现的图像层次、清晰度和颜色效果。
发明内容
本发明的首要目的在于克服现有技术的缺点与不足，提供一种用于宣纸的表面施胶液。
本发明的另一目的在于提供上述用于宣纸的表面施胶液的制备方法。
本发明的再一目的在于提供上述用于宣纸的表面施胶液的应用。
本发明的目的通过下述技术方案实现：一种用于宣纸的表面施胶液，由下述按质量份计的原料制备而成：亲水性高分子10～30份、固色剂3～10份、抗水剂3～5份、消泡剂0.01份、氧化剂0.02～0.12份、水50～100份。
所述的亲水性高分子优选为聚乙烯醇、阳离子淀粉和羧甲基纤维素中的至少一种。
所述的亲水性高分子的用量优选为10～20质量份。
所述的固色剂优选为明矾、壳聚糖、聚合氯化铝、阳离子聚丙烯酰胺、聚乙烯亚胺、聚酰胺环氧氯丙烷树脂、聚二烯丙基二甲基氯化铵、聚胺类等阳离子性及具有吸附作用的物质。
所述的固色剂的用量优选为3质量份。
所述的抗水剂为降低纸张表面张力的物质，优选为松香乳液、AKD乳液和苯丙乳液(苯乙烯-丙烯酸酯乳液)中的至少一种。
所述的抗水剂的用量优选为3质量份。
所述的消泡剂为常用的有机硅消泡剂，包括但不限于佛山市南海大田化学有限公司的消泡剂AT-883。
所述的氧化剂优选为过硫酸铵。
所述的氧化剂的用量优选为0.02～0.08质量份。
所述的水优选为蒸馏水。
所述的用于宣纸的表面施胶液的制备方法，包括以下步骤：
(1)将10～30质量份亲水性高分子、0.02～0.12质量份氧化剂、50～100质量份水混合后于60～90℃水浴环境下搅拌10～60分钟；
(2)接着加入3～10质量份固色剂，混合均匀；再加入3～5质量份抗水剂；
(3)将步骤(2)得到的体系的温度调节至45～65℃，反应30～90min，自然冷却至室温后取出，加入0.01质量份消泡剂，得到宣纸表面施胶液。
步骤(1)中所述的水浴的时间优选为30分钟。
步骤(3)中所述的反应的时间优选为1h。
步骤(3)中所述的室温优选为5～40℃；更优选为15～30℃；最优选为24～28℃。
上述用于宣纸的表面施胶液在宣纸制备中的应用。将上述用于宣纸的表面施胶液进行宣纸表面施涂，能改善宣纸吸墨性质，提高图像质量。
上述用于宣纸的表面施胶液在宣纸制备中的应用，优选包括如下步骤：用水稀释所述的用于宣纸的表面施胶液，得到工作用施胶液；再将工作用施胶液涂布于宣纸表面。
所述的稀释的程度优选为将所述的用于宣纸的表面施胶液稀释至质量百分比10～20％；更优选为15％。
所述的工作用施胶液的表面施涂量优选为3g/m2。
本发明相对于现有技术，具有如下的优点及有益效果：
1、本发明提高了宣纸的固色效果，解决了宣纸的抗水差问题。
2、本发明施胶液能显著改善宣纸的墨水色密度值。
具体实施方式
下面结合实施例对本发明作进一步详细的描述，但本发明的实施方式不限于此。
实施例1
本发明的宣纸表面施胶液的制备方法，包括以下步骤：
(1)将10质量份聚乙烯醇(日本可乐丽PVA205)、0.04质量份过硫酸铵、50质量份水混合后在90℃水浴、搅拌下降解30分钟；
(2)向步骤(1)得到的体系中加入3质量份明矾；
(3)向步骤(2)得到的体系中加入3质量份AKD乳液(1860型)；
(4)将步骤(3)得到的体系的温度调节至45～65℃，反应1h，自然冷却至室温后取出，加入消泡剂，制得宣纸表面施胶液。
将上述制备获得的宣纸表面施胶液用水配制成15％质量浓度对生宣纸进行施涂，施涂量选择3g/m2。打印色密度采用X-Rite色密度计测量，对色块冲水1分钟后测量四色密度，冲水后四色密度高说明抗水性好，四色密度为C(蓝)、M(红)、Y(黄)、K(墨)。测得色密度值，及对比组的四色密度数据见表1。
实施例2
本发明的宣纸表面施胶液的制备方法，包括以下步骤：
(1)将20质量份聚乙烯醇(PVA205，日本可乐丽)、0.08质量份过硫酸铵、100质量份水混合后在水浴90℃、搅拌下降解30分钟；
(2)向步骤(1)得到的体系中加入3质量份聚酰胺环氧氯丙烷树脂(PAE3301，南海骏能造纸材料厂)；
(3)向步骤(2)得到的体系中加入3质量份松香乳液(SE780G松香乳液，佛山今佳新材料科技有限公司)；
(4)将步骤(3)得到的体系的温度调节至45～65℃，反应1h，自然冷却至室温后取出，加入消泡剂(消泡剂AT-883，佛山市南海大田化学有限公司)，制得宣纸表面施胶液。
将上述制备获得的宣纸表面施胶液用水配制成15％质量浓度进行施涂，施涂量选择3g/m2。打印色密度采用X-Rite色密度计测量，对色块冲水1分钟后测量四色密度，冲水后四色密度高说明抗水性好，四色密度为C(蓝)、M(红)、Y(黄)、K(墨)。测得色密度值，及对比组的四色密度数据见表1。
实施例3
本发明的宣纸表面施胶液的制备方法，包括以下步骤：
(1)将20质量份聚乙烯醇(PVA0588，四川维尼纶厂)、0.08质量份过硫酸铵、100质量份水混合后在水浴90℃、搅拌下降解30分钟；
(2)向步骤(1)得到的体系中加入由3质量份聚酰胺环氧氯丙烷树脂(PAE3301，南海骏能造纸材料厂)；
(3)向步骤(2)得到的体系中加入3质量份松香乳液(SE780G松香乳液，佛山今佳新材料科技有限公司)；
(4)将步骤(3)得到的体系的温度调节至45～65℃，反应1h，自然冷却至室温后取出，加入消泡剂(消泡剂AT-883，佛山市南海大田化学有限公司)，制得宣纸表面施胶液。
将上述制备获得的宣纸表面施胶液用水配制成15％质量浓度进行施涂，施涂量选择3g/m2。打印色密度采用X-Rite色密度计测量，对色块冲水1分钟后测量四色密度，冲水后四色密度高说明抗水性好，四色密度为C(蓝)、M(红)、Y(黄)、K(墨)。测得色密度值，及对比组的四色密度数据见表1。
实施例4
本发明的宣纸表面施胶液的制备方法，包括以下步骤：
(1)将10质量份羧甲基纤维素(QX10，赫克力士)、0.02质量份过硫酸铵、100质量份水混合后在水浴90℃、搅拌下降解30分钟；
(2)向步骤(1)得到的体系中加入由3质量份聚酰胺环氧氯丙烷树脂(PAE3301，南海骏能造纸材料厂)；
(3)向步骤(2)得到的体系中加入3质量份松香乳液(SE780G松香乳液，佛山今佳新材料科技有限公司)；
(4)将步骤(3)得到的体系的温度调节至45～65℃，反应1h，自然冷却至室温后取出，加入消泡剂(消泡剂AT-883，佛山市南海大田化学有限公司)，制得宣纸表面施胶液。
将上述制备获得的宣纸表面施胶液用水配制成15％质量浓度进行施涂，施涂量选择3g/m2。打印色密度采用X-Rite色密度计测量，对色块冲水1分钟后测量四色密度，冲水后四色密度高说明抗水性好，四色密度为C(蓝)、M(红)、Y(黄)、K(墨)。测得色密度值，及对比组的四色密度数据见表1。
对比现用的熟宣纸，冲水前后测定的四色(蓝、红、黄、墨)色密度值数据C(蓝)、M(红)、Y(黄)、K(墨)，如表1所示：
表1
色密度值 实施例1 实施例2 实施例3 实施例4 熟宣纸
C(蓝) 1.06 1.016 1.004 0.934 0.872
M(红) 1.074 1.046 1.038 1.062 1.048
Y(黄) 0.914 0.912 0.912 0.898 0.852
K(黑) 2.351 2.492 2.316 2.245 1.644
从表1中可看出，本发明宣纸施胶液施涂后均明显提高了成品的色密度，色彩图案清晰逼真，所检测的色密度值高，比不施胶的宣纸明显效果好。
上述实施例为本发明较佳的实施方式，但本发明的实施方式并不受上述实施例的限制，其他的任何未背离本发明的精神实质与原理下所作的改变、修饰、替代、组合、简化，均应为等效的置换方式，都包含在本发明的保护范围之内。

Claims (7)

1.一种用于宣纸的表面施胶液，其特征在于由下述按质量份计的原料制备而成：亲水性高分子10～30份、固色剂3～10份、抗水剂3～5份、消泡剂0.01份、氧化剂0.02～0.12份、水50～100份；
所述的亲水性高分子为聚乙烯醇、阳离子淀粉和羧甲基纤维素中的至少一种；
所述的固色剂为明矾、壳聚糖、聚合氯化铝、聚酰胺环氧氯丙烷树脂和聚二烯丙基二甲基氯化铵中的至少一种；
所述的抗水剂为松香乳液、AKD乳液和苯丙乳液中的至少一种。
2.根据权利要求1所述的用于宣纸的表面施胶液，其特征在于：
所述的亲水性高分子的用量为10～20质量份；
所述的固色剂的用量为3质量份；
所述的抗水剂的用量为3质量份；
所述的氧化剂的用量为0.02～0.08质量份。
3.根据权利要求1或2所述的用于宣纸的表面施胶液，其特征在于：
所述的消泡剂为消泡剂AT-883；
所述的氧化剂为过硫酸铵。
4.权利要求1～3任一项所述的用于宣纸的表面施胶液的制备方法，其特征在于包括以下步骤：
(1)将10～30质量份亲水性高分子、0.02～0.12质量份氧化剂、50～100质量份水混合后于60～90℃水浴环境下搅拌10～60分钟；
(2)接着加入3～10质量份固色剂，混合均匀；再加入3～5质量份抗水剂；
(3)将步骤(2)得到的体系的温度调节至45～65℃，反应30～90min，自然冷却至室温后取出，加入0.01质量份消泡剂，得到宣纸表面施胶液。
5.根据权利要求4所述的用于宣纸的表面施胶液的制备方法，其特征在于：
步骤(1)中所述的水浴的时间为30分钟；
步骤(3)中所述的反应的时间为1h；
步骤(3)中所述的室温为5～40℃。
6.权利要求1～3任一项所述的用于宣纸的表面施胶液在宣纸制备中的应用。
7.根据权利要求6所述用于宣纸的表面施胶液在宣纸制备中的应用，其特征在于包括如下步骤：用水稀释权利要求1～3任一项所述的用于宣纸的表面施胶液，得到工作用施胶液；再将工作用施胶液涂布于宣纸表面。
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