CN110841619B - 一种碳模板法制备多孔氧化物的方法 - Google Patents
一种碳模板法制备多孔氧化物的方法 Download PDFInfo
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- CN110841619B CN110841619B CN201911183368.5A CN201911183368A CN110841619B CN 110841619 B CN110841619 B CN 110841619B CN 201911183368 A CN201911183368 A CN 201911183368A CN 110841619 B CN110841619 B CN 110841619B
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- 238000000034 method Methods 0.000 title claims abstract description 52
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- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 26
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- 239000007788 liquid Substances 0.000 claims description 13
- 235000005074 zinc chloride Nutrition 0.000 claims description 13
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- XNPMXMIWHVZGMJ-UHFFFAOYSA-N pyridine-2,6-dicarbonitrile Chemical compound N#CC1=CC=CC(C#N)=N1 XNPMXMIWHVZGMJ-UHFFFAOYSA-N 0.000 claims description 2
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- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
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- UJVRJBAUJYZFIX-UHFFFAOYSA-N nitric acid;oxozirconium Chemical compound [Zr]=O.O[N+]([O-])=O.O[N+]([O-])=O UJVRJBAUJYZFIX-UHFFFAOYSA-N 0.000 description 2
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- 239000000377 silicon dioxide Substances 0.000 description 2
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 2
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- IVORCBKUUYGUOL-UHFFFAOYSA-N 1-ethynyl-2,4-dimethoxybenzene Chemical compound COC1=CC=C(C#C)C(OC)=C1 IVORCBKUUYGUOL-UHFFFAOYSA-N 0.000 description 1
- RNAMYOYQYRYFQY-UHFFFAOYSA-N 2-(4,4-difluoropiperidin-1-yl)-6-methoxy-n-(1-propan-2-ylpiperidin-4-yl)-7-(3-pyrrolidin-1-ylpropoxy)quinazolin-4-amine Chemical compound N1=C(N2CCC(F)(F)CC2)N=C2C=C(OCCCN3CCCC3)C(OC)=CC2=C1NC1CCN(C(C)C)CC1 RNAMYOYQYRYFQY-UHFFFAOYSA-N 0.000 description 1
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- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
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- 125000002560 nitrile group Chemical group 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
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- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
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- 238000002336 sorption--desorption measurement Methods 0.000 description 1
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- 229910000348 titanium sulfate Inorganic materials 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- ZXAUZSQITFJWPS-UHFFFAOYSA-J zirconium(4+);disulfate Chemical compound [Zr+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZXAUZSQITFJWPS-UHFFFAOYSA-J 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
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Families Citing this family (5)
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CN112281185A (zh) * | 2020-09-29 | 2021-01-29 | 河北科技大学 | 多级孔共价有机框架化合物与金属复合析氢催化剂的制备方法及应用 |
CN112675840B (zh) * | 2021-01-11 | 2022-12-09 | 浙江工业大学上虞研究院有限公司 | 一种用于硝基苯胺的催化剂及其制备方法 |
CN112675838B (zh) * | 2021-01-11 | 2022-12-09 | 浙江工业大学上虞研究院有限公司 | 一种复合钯碳催化剂的制备方法 |
CN112675841B (zh) * | 2021-01-12 | 2022-12-09 | 浙江工业大学上虞研究院有限公司 | 一种复合钯催化剂的制备方法 |
CN112892512A (zh) * | 2021-01-20 | 2021-06-04 | 陕西瑞科新材料股份有限公司 | 一种多孔二氧化锆载体的制备方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1807246A (zh) * | 2005-04-13 | 2006-07-26 | 中国科学院大连化学物理研究所 | 一种有序中孔氧化铝的制备方法 |
CN101891157A (zh) * | 2009-05-18 | 2010-11-24 | 中国石油化工股份有限公司 | 介孔纳米金属复合氧化物的制备方法 |
KR101272200B1 (ko) * | 2012-05-23 | 2013-06-07 | 한국에너지기술연구원 | 다공성 탄소 주형틀을 이용한 용융함침 기반 고담지, 고분산 산화금속/탄소 나노촉매 담지체의 제조 방법 및 그 고담지, 고분산 산화금속/탄소 나노촉매 담지체 |
CN104163453A (zh) * | 2014-07-21 | 2014-11-26 | 复旦大学 | 一种高度有序纳米颗粒超晶格材料的制备方法 |
CN105017529A (zh) * | 2014-04-24 | 2015-11-04 | 中国科学院大连化学物理研究所 | 一种多级孔结构共价三嗪类骨架微孔聚合物的制备方法 |
CN105879862A (zh) * | 2016-04-22 | 2016-08-24 | 大连理工大学 | 一种蛋壳型贵金属催化剂的制备方法及其用于氧芴加氢开环制备邻苯基苯酚的方法 |
CN107539953A (zh) * | 2016-06-27 | 2018-01-05 | 中国科学院金属研究所 | 具备三维多孔单晶结构的金属氧化物纳米颗粒的制备方法 |
-
2019
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Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1807246A (zh) * | 2005-04-13 | 2006-07-26 | 中国科学院大连化学物理研究所 | 一种有序中孔氧化铝的制备方法 |
CN101891157A (zh) * | 2009-05-18 | 2010-11-24 | 中国石油化工股份有限公司 | 介孔纳米金属复合氧化物的制备方法 |
KR101272200B1 (ko) * | 2012-05-23 | 2013-06-07 | 한국에너지기술연구원 | 다공성 탄소 주형틀을 이용한 용융함침 기반 고담지, 고분산 산화금속/탄소 나노촉매 담지체의 제조 방법 및 그 고담지, 고분산 산화금속/탄소 나노촉매 담지체 |
CN105017529A (zh) * | 2014-04-24 | 2015-11-04 | 中国科学院大连化学物理研究所 | 一种多级孔结构共价三嗪类骨架微孔聚合物的制备方法 |
CN104163453A (zh) * | 2014-07-21 | 2014-11-26 | 复旦大学 | 一种高度有序纳米颗粒超晶格材料的制备方法 |
CN105879862A (zh) * | 2016-04-22 | 2016-08-24 | 大连理工大学 | 一种蛋壳型贵金属催化剂的制备方法及其用于氧芴加氢开环制备邻苯基苯酚的方法 |
CN107539953A (zh) * | 2016-06-27 | 2018-01-05 | 中国科学院金属研究所 | 具备三维多孔单晶结构的金属氧化物纳米颗粒的制备方法 |
Non-Patent Citations (1)
Title |
---|
Post-synthesis coating of alumina on the mesopore walls of SBA-15 by ammonia/water vapour induced internal hydrolysis and its consequences on pore structure and acidity;Kanakkampalayam K. Cheralathan et al.;《Microporous and Mesoporous Materials》;20080513;第116卷;第406-415页 * |
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