CN110804229A - 一种裂解炭黑的改性方法及其应用 - Google Patents
一种裂解炭黑的改性方法及其应用 Download PDFInfo
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- CN110804229A CN110804229A CN201911127967.5A CN201911127967A CN110804229A CN 110804229 A CN110804229 A CN 110804229A CN 201911127967 A CN201911127967 A CN 201911127967A CN 110804229 A CN110804229 A CN 110804229A
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- rubber
- carbon black
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- aging treatment
- organic solvents
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- 239000006229 carbon black Substances 0.000 title claims abstract description 100
- 238000000197 pyrolysis Methods 0.000 title claims abstract description 20
- 238000002715 modification method Methods 0.000 title description 4
- 229920001971 elastomer Polymers 0.000 claims abstract description 105
- 239000005060 rubber Substances 0.000 claims abstract description 105
- 239000003960 organic solvent Substances 0.000 claims abstract description 42
- 238000000034 method Methods 0.000 claims abstract description 32
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 52
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 28
- 230000032683 aging Effects 0.000 claims description 18
- 244000043261 Hevea brasiliensis Species 0.000 claims description 16
- 229920003052 natural elastomer Polymers 0.000 claims description 16
- 229920001194 natural rubber Polymers 0.000 claims description 16
- 238000005336 cracking Methods 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000002699 waste material Substances 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 11
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 9
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- 229930195733 hydrocarbon Natural products 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 6
- 239000010920 waste tyre Substances 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 5
- 229920003023 plastic Polymers 0.000 claims description 5
- SYBYTAAJFKOIEJ-UHFFFAOYSA-N 3-Methylbutan-2-one Chemical compound CC(C)C(C)=O SYBYTAAJFKOIEJ-UHFFFAOYSA-N 0.000 claims description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 3
- 229920000181 Ethylene propylene rubber Polymers 0.000 claims description 3
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims description 3
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 claims description 3
- 229920000459 Nitrile rubber Polymers 0.000 claims description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000005062 Polybutadiene Substances 0.000 claims description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 3
- 241000872198 Serjania polyphylla Species 0.000 claims description 3
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 3
- -1 alicyclic hydrocarbon Chemical class 0.000 claims description 3
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
- 229920005549 butyl rubber Polymers 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 229920003049 isoprene rubber Polymers 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 3
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 3
- 229920002857 polybutadiene Polymers 0.000 claims description 3
- 239000005077 polysulfide Substances 0.000 claims description 3
- 229920001021 polysulfide Polymers 0.000 claims description 3
- 150000008117 polysulfides Polymers 0.000 claims description 3
- UBXSCAIGDWEAQP-UHFFFAOYSA-N propan-2-one propyl acetate Chemical compound CC(C)=O.CCCOC(C)=O UBXSCAIGDWEAQP-UHFFFAOYSA-N 0.000 claims description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 3
- 150000003457 sulfones Chemical class 0.000 claims description 3
- 229920003051 synthetic elastomer Polymers 0.000 claims description 3
- 239000005061 synthetic rubber Substances 0.000 claims description 3
- 239000008096 xylene Substances 0.000 claims description 3
- 230000003014 reinforcing effect Effects 0.000 abstract description 8
- 239000012535 impurity Substances 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 5
- 238000000605 extraction Methods 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 39
- 239000002904 solvent Substances 0.000 description 11
- 238000001723 curing Methods 0.000 description 8
- 238000003756 stirring Methods 0.000 description 6
- 239000011269 tar Substances 0.000 description 6
- 238000001704 evaporation Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 238000005406 washing Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 238000011112 process operation Methods 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000010130 dispersion processing Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000018984 mastication Effects 0.000 description 2
- 238000010077 mastication Methods 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 238000003878 thermal aging Methods 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002641 tar oil Substances 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L19/00—Compositions of rubbers not provided for in groups C08L7/00 - C08L17/00
- C08L19/003—Precrosslinked rubber; Scrap rubber; Used vulcanised rubber
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/44—Carbon
- C09C1/48—Carbon black
- C09C1/56—Treatment of carbon black ; Purification
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
Description
Claims (10)
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CN201911127967.5A CN110804229B (zh) | 2019-11-18 | 2019-11-18 | 一种裂解炭黑的改性方法及其应用 |
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CN110804229A true CN110804229A (zh) | 2020-02-18 |
CN110804229B CN110804229B (zh) | 2022-05-20 |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111500092A (zh) * | 2020-04-15 | 2020-08-07 | 安徽省克林泰迩再生资源科技有限公司 | 一种废旧轮胎裂解炭黑的改性处理方法 |
CN111808448A (zh) * | 2020-05-07 | 2020-10-23 | 安徽省克林泰迩再生资源科技有限公司 | 一种在裂解炭黑表面负载金属氧化物的制备方法 |
CN113150578A (zh) * | 2021-04-23 | 2021-07-23 | 双星集团有限责任公司 | 一种新型改性裂解炭黑及其制备方法 |
CN113563743A (zh) * | 2021-07-09 | 2021-10-29 | 中国化学工业桂林工程有限公司 | 一种裂解炭黑的催化再生方法 |
CN113667328A (zh) * | 2021-07-09 | 2021-11-19 | 中国化学工业桂林工程有限公司 | 一种再生炭黑及其制备方法和应用 |
CN114736539A (zh) * | 2022-05-12 | 2022-07-12 | 安徽浩悦生态科技有限责任公司 | 一种报废旧轮胎炭黑深处理工艺及其造粒方法 |
CN115229201A (zh) * | 2022-09-23 | 2022-10-25 | 西安稀有金属材料研究院有限公司 | 一种高分散纳米钨粉的制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130281581A1 (en) * | 2012-02-24 | 2013-10-24 | Ripp Resource Recovery Corporation | Pyrolytic carbon black and polymer composites manufactured therefrom |
CN104371123A (zh) * | 2014-11-03 | 2015-02-25 | 怡维怡橡胶研究院有限公司 | 一种连续式制备的橡胶母炼胶在卡车胎胎面胶中的应用 |
CN105838116A (zh) * | 2016-04-01 | 2016-08-10 | 上海交通大学 | 一种浅度裂解炭黑的制备方法 |
JP2017014314A (ja) * | 2015-06-26 | 2017-01-19 | 昭和電工株式会社 | エラストマー組成物の製造方法、エラストマー組成物、マスターバッチ及びエラストマー混合物 |
-
2019
- 2019-11-18 CN CN201911127967.5A patent/CN110804229B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130281581A1 (en) * | 2012-02-24 | 2013-10-24 | Ripp Resource Recovery Corporation | Pyrolytic carbon black and polymer composites manufactured therefrom |
US20150045497A1 (en) * | 2012-02-24 | 2015-02-12 | Kenn HARPER | Pyrolytic Carbon Black and Polymer Composites Manufactured Therefrom |
CN104371123A (zh) * | 2014-11-03 | 2015-02-25 | 怡维怡橡胶研究院有限公司 | 一种连续式制备的橡胶母炼胶在卡车胎胎面胶中的应用 |
JP2017014314A (ja) * | 2015-06-26 | 2017-01-19 | 昭和電工株式会社 | エラストマー組成物の製造方法、エラストマー組成物、マスターバッチ及びエラストマー混合物 |
CN105838116A (zh) * | 2016-04-01 | 2016-08-10 | 上海交通大学 | 一种浅度裂解炭黑的制备方法 |
Non-Patent Citations (1)
Title |
---|
刘英俊等: "不同溶剂处理废轮胎热解炭黑在丁苯橡胶中的应用", 《橡胶工业》 * |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111500092A (zh) * | 2020-04-15 | 2020-08-07 | 安徽省克林泰迩再生资源科技有限公司 | 一种废旧轮胎裂解炭黑的改性处理方法 |
CN111808448A (zh) * | 2020-05-07 | 2020-10-23 | 安徽省克林泰迩再生资源科技有限公司 | 一种在裂解炭黑表面负载金属氧化物的制备方法 |
CN113150578A (zh) * | 2021-04-23 | 2021-07-23 | 双星集团有限责任公司 | 一种新型改性裂解炭黑及其制备方法 |
CN113150578B (zh) * | 2021-04-23 | 2022-04-15 | 双星集团有限责任公司 | 一种新型改性裂解炭黑及其制备方法 |
CN113563743A (zh) * | 2021-07-09 | 2021-10-29 | 中国化学工业桂林工程有限公司 | 一种裂解炭黑的催化再生方法 |
CN113667328A (zh) * | 2021-07-09 | 2021-11-19 | 中国化学工业桂林工程有限公司 | 一种再生炭黑及其制备方法和应用 |
CN113563743B (zh) * | 2021-07-09 | 2022-04-22 | 中国化学工业桂林工程有限公司 | 一种裂解炭黑的催化再生方法 |
CN114736539A (zh) * | 2022-05-12 | 2022-07-12 | 安徽浩悦生态科技有限责任公司 | 一种报废旧轮胎炭黑深处理工艺及其造粒方法 |
CN115229201A (zh) * | 2022-09-23 | 2022-10-25 | 西安稀有金属材料研究院有限公司 | 一种高分散纳米钨粉的制备方法 |
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Effective date of registration: 20240523 Address after: No. 12, 15th Road, Tianjin Ziya Circular Economy Industrial Park, Jinghai District, Tianjin, 301600 Patentee after: Tianjin green renewable resources utilization Co.,Ltd. Country or region after: China Patentee after: Zhuhai Gree green renewable resources Co.,Ltd. Address before: 519000 room 105-67609, No.6 Baohua Road, Hengqin New District, Zhuhai City, Guangdong Province (centralized office area) Patentee before: Zhuhai Gree green renewable resources Co.,Ltd. Country or region before: China |