CN110747634A - 一种纺织品防辐射剂及其制备方法 - Google Patents
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Abstract
本发明公开了一种织物防辐射剂及其制备方法，其中，一种纺织品防辐射剂，其包括，超细高岭土，氧化铁，硅泡树脂，亚次磷酸钠，硫酸镍，柔软剂，香精，水；其中，按质量份数计，所述超细高岭土为2‑3份，所述氧化铁为1‑2份，所述硅泡树脂为5‑10份，所述亚次磷酸钠为0.5份，所述硫酸镍为0.5份，所述柔软剂为1‑2份，所述香精为1‑2份，所述水为10‑20份；一种纺织品防辐射剂的制备方法，其包括，将硫酸镍、亚次磷酸钠加入水中，加热搅拌；加入超细高岭土，氧化铁，搅拌；加入硅泡树脂，搅拌；加入柔软剂、香精，搅拌，得防辐射剂。本发明操作简答方便，成本低，适合广泛应用。
Description
技术领域
本发明属于助剂技术领域，具体涉及一种纺织品防辐射剂及其制备方法。
背景技术
防辐射织物一直是人们日常生活所需要的，随着科技的的进步周围的辐射越来越多，对于防辐射织物的需求量也越来越多，目前的防辐射织物主要是通过防辐射纤维混纺、在织物表面镀一层稀有金属达到防辐射、在织物表面没涂抹一层防辐射树脂、通过改性使纤维达到防辐射。
本发明主要是通过在织物表面形成一层树脂软化膜，来达到防辐射的目的，通过少量的树脂与一些可以防辐射的金属离子相结合达到防辐射的目的，本发明操作简答方便，成本低，适合广泛应用。
发明内容
本部分的目的在于概述本发明的实施例的一些方面以及简要介绍一些较佳实施例。在本部分以及本申请的说明书摘要和发明名称中可能会做些简化或省略以避免使本部分、说明书摘要和发明名称的目的模糊，而这种简化或省略不能用于限制本发明的范围。
鉴于上述的技术缺陷，提出了本发明。
因此，作为本发明其中一个方面，本发明克服现有技术中存在的不足，提供一种纺织品防辐射剂及其制备方法。
为解决上述技术问题，本发明提供了如下技术方案：一种纺织品防辐射剂，其包括，超细高岭土，氧化铁，硅泡树脂，亚次磷酸钠，硫酸镍，柔软剂，香精，水；其中，按质量份数计，所述超细高岭土为2-3份，所述氧化铁为1-2份，所述硅泡树脂为5-10份，所述亚次磷酸钠为0.5份，所述硫酸镍为0.5份，所述柔软剂为1-2份，所述香精为1-2份，所述水为10-20份。
作为本发明所述的纺织品防辐射剂的优选方案，其中：所述柔软剂为柔软剂ES、柔软剂HQR、柔软剂KC中的一种或几种，所述香精为椰子油、β-环糊精、木瓜油、薰衣草精油中的一种或几种。
作为本发明所述的纺织品防辐射剂的优选方案，其中：所述柔软剂为柔软剂ES、柔软剂HQR、柔软剂KC中的一种或几种，所述香精为椰子油、β-环糊精、木瓜油、薰衣草精油中的一种或几种。
作为本发明其中一个方面，本发明克服现有技术中存在的不足，提供一种纺织品防辐射剂的制备方法，其包括，将硫酸镍、亚次磷酸钠加入水中，加热搅拌；加入超细高岭土，氧化铁，搅拌；加入硅泡树脂，搅拌；加入柔软剂、香精，搅拌，得防辐射剂。
作为本发明所述的纺织品防辐射剂的制备方法的优选方案，其中：所述超细高岭土为2-3份，所述氧化铁为1-2份，所述硅泡树脂为5-10份，所述亚次磷酸钠为0.5份，所述硫酸镍为0.5份，所述柔软剂为1-2份，所述香精为1-2份，所述水为10-20份。
作为本发明所述的纺织品防辐射剂的制备方法的优选方案，其中：所述柔软剂为柔软剂ES、柔软剂HQR、柔软剂KC中的一种或几种，所述香精为椰子油、β-环糊精、木瓜油、薰衣草精油中的一种或几种。
作为本发明所述的纺织品防辐射剂的制备方法的优选方案，其中：所述加热，其为加热至60～80℃，所述搅拌，其为200-1000转/分钟下搅拌5～40分钟。
作为本发明所述的纺织品防辐射剂的制备方法的优选方案，其中：所述将硫酸镍、亚次磷酸钠加入水中，加热搅拌，其为升高温度至60-80℃，500-1000转/分钟，搅拌20-30分钟；所述加入超细高岭土，氧化铁，搅拌，其为500-1000转/分钟，搅拌10分钟；所述加入硅泡树脂，搅拌，其为200-300转/分钟，搅拌10分钟；所述加入柔软剂、香精，搅拌，其为500-1000转/分钟，搅拌10-20分钟。
本发明的有益效果：
本发明的防辐射剂采用的原料，基本无毒，无腐蚀性，且在织物表面形成一层超细膜，此膜耐水洗，耐摩擦性能均良好补充相应验证性数据，此防辐射剂广泛适用于各种织物，如针织物、机织物、无纺布等。
具体实施方式
为使本发明的上述目的、特征和优点能够更加明显易懂，下面结合具体实施例对本发明的具体实施方式做详细的说明。
在下面的描述中阐述了很多具体细节以便于充分理解本发明，但是本发明还可以采用其他不同于在此描述的其它方式来实施，本领域技术人员可以在不违背本发明内涵的情况下做类似推广，因此本发明不受下面公开的具体实施例的限制。
其次，此处所称的“一个实施例”或“实施例”是指可包含于本发明至少一个实现方式中的特定特征、结构或特性。在本说明书中不同地方出现的“在一个实施例中”并非均指同一个实施例，也不是单独的或选择性的与其他实施例互相排斥的实施例。
实施例1：
按重量份数，步骤1，在反应釜中加入硫酸镍0.5份，亚次磷酸钠0.5份，水10-20份，升高温度至60-80℃，500-1000转/分钟，搅拌20-30分钟，待硫酸镍，亚次磷酸钠溶解；
步骤2，待温度降至室温时加入超细高岭土2-3份，氧化铁1-2份，500-1000转/分钟，搅拌10分钟；
步骤3，加入硅泡树脂5-10份200-300转/分钟，搅拌10分钟；
步骤4，加入柔软剂1-2份，香精1-2份，500-1000转/分钟，搅拌10-20分钟。放料封装，制得成品。
实施例2：
按重量份数，步骤1，在反应釜中加入硫酸镍0.5份，亚次磷酸钠0.5份，水10份，升高温度至60-80℃，500-1000转/分钟，搅拌20-30分钟，待硫酸镍，亚次磷酸钠溶解；
步骤2，待温度降至室温时加入超细高岭土2份，氧化铁1份，500-1000转/分钟，搅拌10分钟；
步骤3，加入硅泡树脂5份200-300转/分钟，搅拌10分钟；
步骤4，加入柔软剂1份，香精1份，500-1000转/分钟，搅拌10-20分钟。放料封装，制得成品。
实施例3：
按重量份数，步骤1，在反应釜中加入硫酸镍0.5份，亚次磷酸钠0.5份，水15份，升高温度至60-80℃，500-1000转/分钟，搅拌20-30分钟，待硫酸镍，亚次磷酸钠溶解，；
步骤2，待温度降至室温时加入超细高岭土3份，氧化铁2份，500-1000转/分钟，搅拌10分钟；
步骤3，加入硅泡树脂7份200-300转/分钟，搅拌10分钟；
步骤4，加入柔软剂2份，香精2份，500-1000转/分钟，搅拌10-20分钟。放料封装，制得成品。
实施例4：
步骤1，在反应釜中加入硫酸镍0.5份，亚次磷酸钠0.5份，水20份，升高温度至60-80℃，500-1000转/分钟，搅拌20-30分钟，待硫酸镍，亚次磷酸钠溶解；
步骤2，待温度降至室温时加入超细高岭土3份，氧化铁2份，500-1000转/分钟，搅拌10分钟；
步骤3，加入硅泡树脂10份200-300转/分钟，搅拌10分钟；
步骤4，加入柔软剂2份，香精2份，500-1000转/分钟，搅拌10-20分钟。放料封装，制得成品。
对照例1：
按重量份数，步骤1，在反应釜中加入硫酸镍0.5份，亚次磷酸钠0.5份，水10份，升高温度至60-80℃，500-1000转/分钟，搅拌20-30分钟，待硫酸镍，亚次磷酸钠溶解；
步骤2，待温度到室温加入硅泡树脂5份200-300转/分钟，搅拌10分钟；
步骤3，加入柔软剂1份，香精1份，500-1000转/分钟，搅拌10-20分钟。放料封装，制得成品。
对照例2：
按重量份数，步骤1，在反应釜中加入硫酸镍0.5份，亚次磷酸钠0.5份，水20份，升高温度至60-80℃，500-1000转/分钟，搅拌20-30分钟，待硫酸镍，亚次磷酸钠溶解；
步骤2，待温度降至室温时加入超细高岭土3份，氧化铁2份，500-1000转/分钟，搅拌10分钟；
步骤3，加入柔软剂2份，香精2份，500-1000转/分钟，搅拌10-20分钟。放料封装，制得成品。
对照例3：
按重量份数，步骤1，在反应釜中加入硫酸镍0.5份，亚次磷酸钠0.5份，水10-20份，升高温度至60-80℃，500-1000转/分钟，搅拌20-30分钟，待硫酸镍，亚次磷酸钠溶解；
步骤2，待温度降至室温时加入超细高岭土2-3份，500-1000转/分钟，搅拌10分钟；
步骤3，加入硅泡树脂5-10份200-300转/分钟，搅拌10分钟；
步骤4，加入柔软剂1-2份，香精1-2份，500-1000转/分钟，搅拌10-20分钟。放料封装，制得成品。
防辐射测试：
取5块相同的棉织物，将实施例1、2、3和对照例1、2的防辐射剂涂抹在织物上，待自然风干，然后水洗晾干，可以得到5块具有防辐射性能的织物。测试结果如下。随后测试找出防辐射效果的好坏。通过织物能够吸收多少电磁波来测定其等级，如电磁波(50Hz～25.6GHz)吸收效能为3.5～14.8dB，理论上防辐射效率在95％以上。以此类推。
从上表中可以看出，对照例1没有加超细高岭土，氧化铁，防辐射效果大大降低；对照例2没有加硅泡树脂，其离子吸附在织物表面极少，防辐射效果几乎没有；对照例3添加超细高岭土，氧化铁，硅泡树脂添加这三种物质，但防辐射效果有所下降，本发明制备的防辐射剂应用于混纺，涤纶、锦纶都可达到上述效果，制备防辐射织物的透气率均在80％以上。
应说明的是，以上实施例仅用以说明本发明的技术方案而非限制，尽管参照较佳实施例对本发明进行了详细说明，本领域的普通技术人员应当理解，可以对本发明的技术方案进行修改或者等同替换，而不脱离本发明技术方案的精神和范围，其均应涵盖在本发明的权利要求范围当中。
Claims (10)
1.一种纺织品防辐射剂，其特征在于：包括，
超细高岭土，氧化铁，硅泡树脂，亚次磷酸钠，硫酸镍，柔软剂，香精，水；
其中，按质量份数计，所述超细高岭土为2-3份，所述氧化铁为1-2份，所述硅泡树脂为5-10份，所述亚次磷酸钠为0.5份，所述硫酸镍为0.5份，所述柔软剂为1-2份，所述香精为1-2份，所述水为10-20份。
2.如权利要求1所述的纺织品防辐射剂，其特征在于：所述柔软剂为柔软剂ES、柔软剂HQR、柔软剂KC中的一种或几种，所述香精为椰子油、β-环糊精、木瓜油、薰衣草精油中的一种或几种。
3.如权利要求1所述的纺织品防辐射剂，其特征在于：所述柔软剂为柔软剂ES、柔软剂HQR中的一种或几种，所述香精为椰子油、β-环糊精、薰衣草精油中的一种或几种。
4.一种纺织品防辐射剂的制备方法，其特征在于：包括，
将硫酸镍、亚次磷酸钠加入水中，加热搅拌；
加入超细高岭土，氧化铁，搅拌；
加入硅泡树脂，搅拌；
加入柔软剂、香精，搅拌，得防辐射剂。
5.如权利要求4所述的纺织品防辐射剂的制备方法，其特征在于：所述超细高岭土为2-3份，所述氧化铁为1-2份，所述硅泡树脂为5-10份，所述亚次磷酸钠为0.5份，所述硫酸镍为0.5份，所述柔软剂为1-2份，所述香精为1-2份，所述水为10-20份。
6.如权利要求4所述的纺织品防辐射剂的制备方法，其特征在于：所述超细高岭土为3份，所述氧化铁为2份，所述硅泡树脂为10份，所述亚次磷酸钠为0.5份，所述硫酸镍为0.5份，所述柔软剂为1份，所述香精为1份，所述水为20份。
7.如权利要求5或6所述的纺织品防辐射剂的制备方法，其特征在于：所述柔软剂为柔软剂ES、柔软剂HQR、柔软剂KC中的一种或几种，所述香精为椰子油、β-环糊精、木瓜油、薰衣草精油中的一种或几种。
8.如权利要求5或6所述的纺织品防辐射剂的制备方法，其特征在于：所述柔软剂为柔软剂ES、柔软剂HQR中的一种或几种，所述香精为椰子油、β- 环糊精、薰衣草精油中的一种或几种。
9.如权利要求4所述的纺织品防辐射剂的制备方法，其特征在于：所述加热，其为加热至60～80℃，所述搅拌，其为200～1000转/分钟下搅拌5～40分钟。
10.如权利要求4所述的纺织品防辐射剂的制备方法，其特征在于：所述将硫酸镍、亚次磷酸钠加入水中，加热搅拌，其为升高温度至60-80℃，500～1000转/分钟，搅拌20～30分钟；所述加入超细高岭土，氧化铁，搅拌，其为500～1000转/分钟，搅拌10分钟；所述加入硅泡树脂，搅拌，其为200～300转/分钟，搅拌10分钟；所述加入柔软剂、香精，搅拌，其为500～1000转/分钟，搅拌10～20分钟。
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