CN110691812B - 阻燃聚合物组合物 - Google Patents
阻燃聚合物组合物 Download PDFInfo
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- CN110691812B CN110691812B CN201880037882.5A CN201880037882A CN110691812B CN 110691812 B CN110691812 B CN 110691812B CN 201880037882 A CN201880037882 A CN 201880037882A CN 110691812 B CN110691812 B CN 110691812B
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- China
- Prior art keywords
- flame retardant
- polymer composition
- retardant polymer
- aspect ratio
- high aspect
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/042—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with carbon fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/10—Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/016—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/40—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/06—Organic materials
- C09K21/12—Organic materials containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K2003/343—Peroxyhydrates, peroxyacids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/004—Additives being defined by their length
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/006—Additives being defined by their surface area
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/016—Additives defined by their aspect ratio
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762482876P | 2017-04-07 | 2017-04-07 | |
| US62/482876 | 2017-04-07 | ||
| PCT/US2018/026362 WO2018187638A1 (en) | 2017-04-07 | 2018-04-06 | Flame-retardant polymer composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110691812A CN110691812A (zh) | 2020-01-14 |
| CN110691812B true CN110691812B (zh) | 2022-04-01 |
Family
ID=63712403
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201880037882.5A Active CN110691812B (zh) | 2017-04-07 | 2018-04-06 | 阻燃聚合物组合物 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US11661497B2 (enExample) |
| EP (1) | EP3606988A4 (enExample) |
| JP (1) | JP7111736B2 (enExample) |
| KR (1) | KR102559494B1 (enExample) |
| CN (1) | CN110691812B (enExample) |
| BR (1) | BR112019020703A8 (enExample) |
| WO (1) | WO2018187638A1 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12123110B2 (en) * | 2019-02-14 | 2024-10-22 | Denka Company Limited | Fiber for artificial hair, head accessory product, and resin composition for artificial hair |
| WO2020237157A1 (en) * | 2019-05-23 | 2020-11-26 | Imerys Usa, Inc. | Flame retardant polymer composition and methods of use |
| EP4328455A3 (en) | 2019-12-16 | 2024-05-01 | Basf Se | Industrial fan or blower comprising a flame-retardant polyamide composition |
| CN115551953A (zh) * | 2020-05-11 | 2022-12-30 | 伊梅斯切公司 | 滑石颗粒物 |
| KR102390212B1 (ko) * | 2020-05-19 | 2022-04-22 | 김현회 | 불연성이 우수하고 가스유해성이 없는 친환경 준불연성 시트 |
| WO2022011343A1 (en) * | 2020-07-10 | 2022-01-13 | Burgess Pigment Company | Kaolin-filled polymeric compositions |
| KR102590285B1 (ko) * | 2020-12-11 | 2023-10-17 | (주)엘엑스하우시스 | 난연 인테리어 필름 |
| EP4083144A1 (en) * | 2021-04-27 | 2022-11-02 | ImerTech SAS | Mica particulates |
| CN117321173A (zh) * | 2021-06-11 | 2023-12-29 | 英默里斯美国公司 | 阻燃聚合物组合物 |
| CN114031916B (zh) * | 2021-11-08 | 2023-07-07 | 金发科技股份有限公司 | 一种薄壁阻燃低收缩率的聚碳酸酯材料及其制备方法和应用 |
| KR102778070B1 (ko) * | 2022-06-22 | 2025-03-06 | 국립창원대학교 산학협력단 | 무기계 난연제를 포함하는 pvc용 난연 도료 코팅층 및 이의 형성 방법 |
| CN115490960B (zh) * | 2022-10-13 | 2023-12-01 | 江苏金发科技新材料有限公司 | 一种抗静电聚丙烯组合物及其制备方法和应用 |
| EP4585562A1 (en) * | 2024-01-15 | 2025-07-16 | ImerTech SAS | Synthetic acicular wollastonite |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5863974A (en) * | 1997-01-28 | 1999-01-26 | General Electric Company | Flame retardant polyamide composition |
| US6465555B1 (en) * | 1998-10-16 | 2002-10-15 | Idemitsu Petrochemical Co., Ltd. | Flame-retardant thermoplastic resin compositions and their injection moldings |
| CN1926192A (zh) * | 2004-01-07 | 2007-03-07 | 伊塔尔麦奇化学股份公司 | 用次磷酸铝阻燃剂处理过的聚酰胺组合物 |
| JP2011136443A (ja) * | 2009-12-28 | 2011-07-14 | Brother Industries Ltd | ラベルプリンタ装置 |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51117575A (en) * | 1975-04-09 | 1976-10-15 | Citizen Watch Co Ltd | Electronic circuit and its manufacturing method |
| GB2274337B (en) | 1993-01-18 | 1996-08-07 | Ecc Int Ltd | Aspect ratio measurement |
| JPH08259796A (ja) * | 1995-03-28 | 1996-10-08 | Mitsubishi Chem Corp | 難燃性熱可塑性樹脂組成物 |
| FR2761692B1 (fr) | 1997-04-04 | 2000-08-11 | Talc De Luzenac | Procede pour obtenir une poudre minerale de lamellarite elevee et applications notamment pour le renforcement de matieres plastiques |
| KR100236656B1 (ko) * | 1997-08-30 | 2000-01-15 | 성재갑 | 외관이 양호한 비할로겐계 난연 폴리아미드 수지 조성물 |
| JP3616792B2 (ja) * | 1998-10-16 | 2005-02-02 | 出光興産株式会社 | 難燃性熱可塑性樹脂組成物および射出成形品 |
| EP1283245B1 (en) * | 2000-05-19 | 2005-11-09 | Kaneka Corporation | Polyester resin composition and process for the preparation thereof |
| JP4467142B2 (ja) * | 2000-05-22 | 2010-05-26 | 株式会社カネカ | 難燃性ポリエステル樹脂組成物 |
| JP2005521767A (ja) * | 2002-03-28 | 2005-07-21 | イメリーズ ミネラルズ リミテッド | 粒状粘土鉱物を含む難燃性ポリマー組成物 |
| AU2002952373A0 (en) * | 2002-10-31 | 2002-11-14 | Commonwealth Scientific And Industrial Research Organisation | Fire resistant material |
| DE10251294B4 (de) * | 2002-11-04 | 2007-05-16 | Ems Chemie Ag | Polyamidformmasse und deren Verwendung |
| GB0229810D0 (en) * | 2002-12-20 | 2003-01-29 | Vantico Ag | Flame retardant polymer compositions |
| JP2005220240A (ja) | 2004-02-06 | 2005-08-18 | Mitsubishi Engineering Plastics Corp | 難燃性ポリアミド樹脂組成物 |
| JPWO2007034905A1 (ja) * | 2005-09-22 | 2009-03-26 | 富士通株式会社 | 植物系樹脂含有組成物及びそれを用いた植物系樹脂含有成形体 |
| BRPI0718527A2 (pt) * | 2006-11-09 | 2013-11-19 | Valspar Sourcing Inc | Composição em pó, método, e, artigo tridimensional |
| FR2941460B1 (fr) * | 2009-01-28 | 2011-02-18 | Arkema France | Composition de polyamide ignifugee et renforcee |
| US9790367B2 (en) * | 2013-01-11 | 2017-10-17 | Sabic Global Technologies B.V. | Polycarbonate compositions for reduced splay in combination with sustained or improved impact resistance |
| US9828503B2 (en) * | 2013-04-15 | 2017-11-28 | Basf Se | Glow wire resistant polyamides |
| WO2015051060A1 (en) * | 2013-10-02 | 2015-04-09 | Ticona Llc | Fiber-reinforced polymer composites with flame-resistant properties |
| US20160272779A1 (en) * | 2013-11-06 | 2016-09-22 | Solvay Specialty Polymers Usa, Llc | Flame retardant led for indoor lighting |
| EP3483221B1 (en) * | 2014-09-01 | 2020-07-01 | Imertech Sas | Talc particulate and uses thereof |
| WO2016157098A1 (en) * | 2015-03-31 | 2016-10-06 | Sabic Global Technologies B.V. | Flame retardant composition, methods of manufacture thereof and articles comprising the same |
| CN108884315A (zh) * | 2016-02-22 | 2018-11-23 | 巴斯夫欧洲公司 | 黑色聚酰胺组合物及其制备和用途 |
| EP3281973A1 (en) * | 2016-08-11 | 2018-02-14 | Borealis AG | Polypropylene composition with flame retardant activity |
| KR101913912B1 (ko) * | 2016-10-14 | 2018-10-31 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
| JP6767496B2 (ja) * | 2016-10-19 | 2020-10-14 | 旭化成株式会社 | ポリアミド樹脂組成物 |
| DE102017214048A1 (de) * | 2017-08-11 | 2019-02-14 | Clariant Plastics & Coatings Ltd | Flammhemmende Polyamidzusammensetzungen mit hoher Glühdrahtentzündungstemperatur und deren Verwendung |
-
2018
- 2018-04-06 WO PCT/US2018/026362 patent/WO2018187638A1/en not_active Ceased
- 2018-04-06 US US16/603,353 patent/US11661497B2/en active Active
- 2018-04-06 KR KR1020197032513A patent/KR102559494B1/ko active Active
- 2018-04-06 BR BR112019020703A patent/BR112019020703A8/pt not_active Application Discontinuation
- 2018-04-06 EP EP18781186.4A patent/EP3606988A4/en active Pending
- 2018-04-06 CN CN201880037882.5A patent/CN110691812B/zh active Active
- 2018-04-06 JP JP2019554968A patent/JP7111736B2/ja active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5863974A (en) * | 1997-01-28 | 1999-01-26 | General Electric Company | Flame retardant polyamide composition |
| US6465555B1 (en) * | 1998-10-16 | 2002-10-15 | Idemitsu Petrochemical Co., Ltd. | Flame-retardant thermoplastic resin compositions and their injection moldings |
| CN1926192A (zh) * | 2004-01-07 | 2007-03-07 | 伊塔尔麦奇化学股份公司 | 用次磷酸铝阻燃剂处理过的聚酰胺组合物 |
| JP2011136443A (ja) * | 2009-12-28 | 2011-07-14 | Brother Industries Ltd | ラベルプリンタ装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20210087363A1 (en) | 2021-03-25 |
| JP2020513053A (ja) | 2020-04-30 |
| CN110691812A (zh) | 2020-01-14 |
| KR20190132488A (ko) | 2019-11-27 |
| JP7111736B2 (ja) | 2022-08-02 |
| BR112019020703A2 (pt) | 2020-05-12 |
| EP3606988A1 (en) | 2020-02-12 |
| BR112019020703A8 (pt) | 2023-02-28 |
| WO2018187638A1 (en) | 2018-10-11 |
| US11661497B2 (en) | 2023-05-30 |
| EP3606988A4 (en) | 2020-11-25 |
| KR102559494B1 (ko) | 2023-07-25 |
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