CN110655865A - Aqueous antistatic suede handfeel artistic coating - Google Patents

Aqueous antistatic suede handfeel artistic coating Download PDF

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Publication number
CN110655865A
CN110655865A CN201910850864.5A CN201910850864A CN110655865A CN 110655865 A CN110655865 A CN 110655865A CN 201910850864 A CN201910850864 A CN 201910850864A CN 110655865 A CN110655865 A CN 110655865A
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China
Prior art keywords
suede
artistic
handfeel
agent
antistatic
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Pending
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CN201910850864.5A
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Chinese (zh)
Inventor
陈俊
徐昌平
陈志达
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Crocodile Painting (shanghai) Co Ltd
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Crocodile Painting (shanghai) Co Ltd
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Priority to CN201910850864.5A priority Critical patent/CN110655865A/en
Publication of CN110655865A publication Critical patent/CN110655865A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18Spheres

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention provides a water-based antistatic suede handfeel artistic paint which is characterized by comprising the following raw materials of water, cellulose, an anti-settling agent, a dispersing agent, an antifreezing agent, PU microspheres, an emulsion, an antistatic auxiliary agent, an antifoaming agent, a leveling agent, a film-forming auxiliary agent, a bactericide, a mildew preventive and photocatalyst powder. The invention provides a water-based antistatic suede handfeel artistic paint and a preparation method thereof, wherein the water-based suede handfeel artistic paint has composite color and elastic velvet handfeel on a wall surface through simple spraying, has the function of decorating the wall surface as if the water-based suede handfeel artistic paint is pasted on the wall surface, and also has the functions of aldehyde purification, sterilization, odor removal, static resistance, dust prevention and the like. The wall surface using the invention has the composite color and the elastic velvet hand feeling, is as thin as a velvet cloth pasted wall, has the functions of decorating the wall surface, and also has the functions of formaldehyde purification, sterilization, odor removal, static resistance, dust prevention and the like.

Description

Aqueous antistatic suede handfeel artistic coating
Technical Field
The invention relates to a water-based artistic decorative coating, in particular to a water-based antistatic suede handfeel artistic coating and a preparation method thereof, belonging to the technical field of coatings.
Background
At present, China advocates environmental protection and energy conservation vigorously, creates innovation greatly, promotes building coating enterprises to change and upgrade continuously, seeks more environment-friendly and novel coating products to meet the continuous pursuit of people on environment and wall decoration, each background wall is a unique artwork, and a large amount of novel decorative materials continuously rush from abroad to impact the domestic coating market.
At present, our country has higher and higher requirements on environment-friendly innovative coatings, and the coatings are developed towards the water-based and environment-friendly directions for the first time, and the variety and structure of the coatings are developed towards the reduction of VOC content and towards environment-friendly products: the second approach is to develop functionality. Thirdly, the method develops to a high-performance and high-grade level: and fourthly, the preparation technology of the coating is improved, and the preparation technology mainly comprises the production and selection of high-quality fillers, the matching application of various auxiliaries and the preparation of color paste, so that the quality and the level of the architectural coating are improved, and the development trend of the green environment-friendly coating industry is reached.
Disclosure of Invention
The technical problem to be solved by the invention is as follows: the coating in the prior art has the technical problems of poor weather resistance, large surface color difference and unevenness.
In order to solve the problems, the invention is realized by the following technical scheme:
the water-based antistatic suede handfeel artistic coating is characterized by comprising the following raw materials in percentage by weight:
Figure BDA0002196880070000011
Figure BDA0002196880070000021
preferably, the dispersant is a polyacrylate.
More preferably, the dispersant is a sodium, potassium or ammonium salt of polyacrylic acids.
Preferably, the antifoaming agent is a mineral oil type antifoaming agent.
Preferably, the coalescent is an alcohol ester twelve.
Preferably, the PU beads are model Dec0 axle PU beads manufactured by ningbodi ltd.
Preferably, the anti-settling agent is model KW inorganic bentonite produced by Shanghai grid International trade company Limited.
Preferably, the cellulose is hydroxyethyl cellulose.
Preferably, the leveling agent is an american roman hart RM2020 leveling agent.
Preferably, the antistatic auxiliary agent is a model JL-E12 produced by polyester antistatic technology.
Preferably, the emulsion is any one of DP 233 emulsion, acrylic emulsion, styrene-acrylic emulsion and silicone-acrylic emulsion, which are manufactured by Shanghai Dupli chemical technology Co.
Preferably, the photocatalyst powder is at least one of nano titanium dioxide and nano zinc dioxide.
Preferably, other auxiliaries are also included: at least one of a bactericide, a preservative and a mildewcide.
The invention provides a water-based antistatic suede handfeel artistic paint and a preparation method thereof, wherein the water-based suede handfeel artistic paint has composite color and elastic velvet handfeel on a wall surface through simple spraying, has the function of decorating the wall surface as if the water-based suede handfeel artistic paint is pasted on the wall surface, and also has the functions of aldehyde purification, sterilization, odor removal, static resistance, dust prevention and the like.
The invention is used as a top coat, and the wall surface which is processed by the bottom surface or the middle coat is sprayed for 1 to 3 times by rolling, and natural drying is adopted. The wall surface using the invention has the composite color and the elastic velvet hand feeling, is as thin as a velvet cloth pasted wall, has the functions of decorating the wall surface, and also has the functions of formaldehyde purification, sterilization, odor removal, static resistance, dust prevention and the like.
Detailed Description
In order to make the invention more comprehensible, preferred embodiments are described in detail below.
The production process of the water-based antistatic suede-like artistic coating provided by the embodiments 1 and 2 comprises the following steps:
(1) sequentially adding water, a bactericide, cellulose, an anti-settling agent and a dispersing agent into production equipment, controlling the rotating speed to be 1000-;
(2) sequentially adding photocatalyst powder and PU micro-beads, controlling the rotating speed to be 1500 rpm, and dispersing for 25 minutes;
(3) sequentially adding an antifreezing agent and a film-forming assistant, controlling the rotating speed to be 800 revolutions per minute, and dispersing for 10 minutes;
(4) adding the emulsion, controlling the rotating speed to 600 revolutions per minute, and dispersing for 10 minutes;
(5) adding an antistatic auxiliary agent, a defoaming agent, a mildew preventive, a leveling agent and a mildew preventive, controlling the rotating speed to 800 revolutions per minute, and dispersing for 10 minutes;
(6) filtering and packaging to obtain the water-based suede handfeel artistic coating.
Example 1
A water-based antistatic suede handfeel artistic coating comprises the following raw materials in percentage by weight:
Figure BDA0002196880070000031
the dispersing agent is sodium polyacrylate and P30 produced by high-purity-content assistant
The defoaming agent is mineral oil type defoaming agent, NXZ of Santo Puke company.
The film-forming assistant is alcohol ester twelve, and Runtai chemical production.
The PU micro-beads are model Dec0 sphaara PU micro-beads produced by Ningbodi Co.
The anti-settling agent is model KW inorganic bentonite produced by Shanghai grid International trade company Limited.
The cellulose is hydroxyethyl cellulose, HBR250 produced by Himalayan.
The leveling agent is an American Rohm and Haas RM2020 leveling agent.
The antistatic auxiliary agent is a model JL-E12 produced by Strength gathering antistatic science and technology Limited.
The emulsion is the emulsion of model DP 233 produced by Shanghai Duplei chemical technology Limited.
The photocatalyst powder is nano titanium dioxide, and is produced by new materials, Inc. of Guangzhou, Brilliant province.
The bactericide is 631 carbazone and BIT compound bactericide produced by Dow chemical.
Example 2
A water-based antistatic suede handfeel artistic coating comprises the following raw materials in percentage by weight:
Figure BDA0002196880070000041
the dispersing agent is sodium polyacrylate and P30 produced by high-purity-content assistant
The defoaming agent is mineral oil type defoaming agent, NXZ of Santo Puke company.
The film-forming additive is preferably alcohol ester twelve, produced by Ismann chemistry.
The PU micro-beads are model Dec0 sphaara PU micro-beads produced by Ningbodi Co.
The anti-settling agent is model KW inorganic bentonite produced by Shanghai grid International trade company Limited.
The cellulose is hydroxyethyl cellulose, HEC30000 produced by Luzhou northern chemistry.
The leveling agent is an American Rohm and Haas RM2020 leveling agent.
The antistatic auxiliary agent is a model JL-E12 produced by Strength gathering antistatic science and technology Limited.
The emulsion is the emulsion of model DP 233 produced by Shanghai Duplei chemical technology Limited.
The photocatalyst powder is nano titanium dioxide, and is produced by new materials, Inc. of Guangzhou, Brilliant province.
The bactericide is 631 carbazone and BIT compound bactericide produced by Dow chemical.
The coating materials of examples 1 and 2 were used as a top coat, and were applied to a wall surface having been subjected to a bottom treatment or a middle coat by roll coating 1 to 3 times, followed by natural drying. The wall surface using the product has composite color and elastic velvet handfeel on the wall surface, is thin like a flannelette pasting wall, has the functions of decorating the wall surface, and also has the functions of formaldehyde purification, sterilization, odor removal, static electricity resistance and the like.

Claims (10)

1. The water-based antistatic suede handfeel artistic coating is characterized by comprising the following raw materials in percentage by weight:
Figure FDA0002196880060000011
2. the aqueous antistatic suede artistic coating of claim 1, wherein the dispersant is a polyacrylate.
3. The aqueous antistatic suede artistic coating of claim 2, wherein the dispersant is a sodium, potassium or ammonium salt of polyacrylic acids.
4. The aqueous antistatic suede artistic coating of claim 1, wherein the defoamer is a mineral oil type defoamer; the film-forming additive is alcohol ester twelve; the leveling agent is an American Rohm and Haas RM2020 leveling agent; the antistatic auxiliary agent is a model JL-E12 produced by Strength gathering antistatic science and technology Limited.
5. The aqueous antistatic suede artistic coating of claim 1, wherein the PU beads are model Dec0 sport PU beads from ningceddi ltd.
6. The aqueous antistatic suede artistic coating of claim 1, wherein the anti-settling agent is model KW inorganic bentonite manufactured by shanghai grid international trade limited.
7. The aqueous antistatic suede artistic coating of claim 1, wherein the cellulose is hydroxyethyl cellulose.
8. The aqueous antistatic suede-like artistic paint of claim 1, wherein the emulsion is any one of a type DP 233 emulsion, a pure acrylic emulsion, a styrene-acrylic emulsion and a silicone acrylic emulsion manufactured by shanghai duplei chemical technology ltd.
9. The aqueous antistatic suede-like artistic paint of claim 1, wherein the photocatalyst powder is at least one of nano titanium dioxide and nano zinc dioxide.
10. The aqueous antistatic suede artistic coating of claim 1, further comprising other adjuvants: at least one of a bactericide, a preservative and a mildewcide.
CN201910850864.5A 2019-09-10 2019-09-10 Aqueous antistatic suede handfeel artistic coating Pending CN110655865A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116676008A (en) * 2023-05-26 2023-09-01 吉力水性新材料科技(珠海)有限公司 Water-based antibacterial antistatic coating and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5879065A (en) * 1982-10-23 1983-05-12 Fujiwara Kagaku Kogyo Kk Material for sand-coated wall
CN107964312A (en) * 2017-11-30 2018-04-27 浙江华德新材料有限公司 A kind of art coatings of imitative cotton clothes' feel and preparation method thereof
CN108300031A (en) * 2017-07-26 2018-07-20 谢灿津 A kind of interior wall multi-functional environment-protection texture coating and its preparation process
CN110003744A (en) * 2019-04-23 2019-07-12 广东金涂宝新材料股份有限公司 Scratch resistance imitates the art coatings and its manufacturing method of nap effect

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5879065A (en) * 1982-10-23 1983-05-12 Fujiwara Kagaku Kogyo Kk Material for sand-coated wall
CN108300031A (en) * 2017-07-26 2018-07-20 谢灿津 A kind of interior wall multi-functional environment-protection texture coating and its preparation process
CN107964312A (en) * 2017-11-30 2018-04-27 浙江华德新材料有限公司 A kind of art coatings of imitative cotton clothes' feel and preparation method thereof
CN110003744A (en) * 2019-04-23 2019-07-12 广东金涂宝新材料股份有限公司 Scratch resistance imitates the art coatings and its manufacturing method of nap effect

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
哈尔滨建筑大学等: "《建筑装饰材料》", 31 January 1998, 中国建材工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116676008A (en) * 2023-05-26 2023-09-01 吉力水性新材料科技(珠海)有限公司 Water-based antibacterial antistatic coating and preparation method thereof

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